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公开(公告)号：US5744646A
公开(公告)日：1998-04-28
申请号：US832150
申请日：1997-04-02
IPC分类号： C07F5/02
CPC分类号： C07F5/027
摘要： A process for preparing tris(pentafluorophenyl)borane, the steps of the process comprising: a) forming a pentafluorophenyl metal compound wherein the metal is selected from Group 11 or 12; contacting the (pentafluorophenyl) metal compound from step a) with a boron halide compound to form tris (pentafluorophenyl)borane; and c) recovering the resulting tris(pentafluorophenyl)borane.
摘要翻译： 一种制备三（五氟苯基）硼烷的方法，所述方法的步骤包括：a）形成其中金属选自11或12族的五氟苯基金属化合物; 使来自步骤a）的（五氟苯基）金属化合物与卤化硼化合物接触形成三（五氟苯基）硼烷; 和c）回收所得的三（五氟苯基）硼烷。
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公开(公告)号：US08574773B2
公开(公告)日：2013-11-05
申请号：US13132374
申请日：2009-11-16
申请人： David R. Wilson , Ravi B. Shankar , Houxiang Tang , Andrew J. Pasztor, Jr. , Peter M. Margl , William J. Kruper, Jr. , Mark D. Newsham , Jing Jin , Matthew M. Yonkey , Deidre A. Strand , Thomas D. Gregory , Jamie L. Cohen , Jeremy R. Stajdl
发明人： David R. Wilson , Ravi B. Shankar , Houxiang Tang , Andrew J. Pasztor, Jr. , Peter M. Margl , William J. Kruper, Jr. , Mark D. Newsham , Jing Jin , Matthew M. Yonkey , Deidre A. Strand , Thomas D. Gregory , Jamie L. Cohen , Jeremy R. Stajdl
IPC分类号： H01M10/0567 , H01M10/052
CPC分类号： H01M10/0567 , H01M6/168 , H01M10/052 , H01M10/4235 , H01M2300/0025 , Y02T10/7011
摘要： A battery electrolyte solution contains from 0.01 to 80% by weight of an aromatic phosphorus compound. The aromatic phosphorus compound provides increased thermal stability for the electrolyte, helping to reduce thermal degradation, thermal runaway reactions and the possibility of burning. The aromatic phosphorus compound has little adverse impact on the electrical properties of the battery, and in some cases actually improves battery performance.
摘要翻译： 电池电解液含有0.01〜80重量％的芳香族磷化合物。 芳族磷化合物为电解质提供了增加的热稳定性，有助于减少热降解，热失控反应和燃烧的可能性。 芳香族磷化合物对电池的电气性能几乎没有不利影响，在某些情况下实际上提高了电池性能。
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公开(公告)号：US08324416B2
公开(公告)日：2012-12-04
申请号：US12845023
申请日：2010-07-28
CPC分类号： C08F2/38 , C08F10/00 , C08F10/14 , H01M2/1653 , H01M10/0525 , H01M10/4235 , C08F4/64113
摘要： The invention generally relates to chain shuttling agents (CSAs), a process of preparing the CSAs, a composition comprising a CSA and a catalyst, a process of preparing the composition, a processes of preparing polyolefins, end functional polyolefins, and telechelic polyolefins with the composition, and the polyolefins, end functional polyolefins, and telechelic polyolefins prepared by the processes.
摘要翻译： 本发明通常涉及链穿梭剂（CSA），制备CSA的方法，包含CSA和催化剂的组合物，制备组合物的方法，制备聚烯烃，末端官能聚烯烃和遥爪聚烯烃的方法，其中 组合物，以及通过该方法制备的聚烯烃，末端官能聚烯烃和遥爪聚烯烃。
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公开(公告)号：US20080153950A1
公开(公告)日：2008-06-26
申请号：US12004345
申请日：2007-12-20
申请人： Ravi B. Shankar , William J. Kruper , David R. Wilson , Bruce A. King , Michelle L. Hudack , Daniel J. Murray , Chun Wang , William Gerald Stobby , Ted A. Morgan , Mark W. Beach , Inken Beulich , Ing Feng Hu
发明人： Ravi B. Shankar , William J. Kruper , David R. Wilson , Bruce A. King , Michelle L. Hudack , Daniel J. Murray , Chun Wang , William Gerald Stobby , Ted A. Morgan , Mark W. Beach , Inken Beulich , Ing Feng Hu
IPC分类号： C08K5/5398 , C08K5/51 , C07F9/6571
CPC分类号： C07F9/1653 , C07F9/173 , C07F9/657136 , C07F9/657154 , C07F9/657181 , C08K5/5398
摘要： Phosphorus-sulfur compounds have flame retardant activity in organic polymer systems. The phosphorus-sulfur compounds can be represented by the structure: wherein X is oxygen or sulfur, T is a covalent bond, oxygen, sulfur or nitrogen, provided that at least one of X and T is sulfur, each X′ is independently oxygen or sulfur, each m is independently zero or 1 when X′ is oxygen and zero, 1 or 2 when X′ is sulfur, n is at least 1 and preferably at least 2, each R is independently an unsubstituted or inertly substituted hydrocarbyl group or the R groups together form an unsubstituted or inertly substituted divalent organic group and A is an organic linking group.
摘要翻译： 磷 - 硫化合物在有机聚合物体系中具有阻燃活性。 磷硫化合物可以由以下结构表示：其中X是氧或硫，T是共价键，氧，硫或氮，条件是X和T中的至少一个是硫，每个X'独立地是氧或 硫，当X'为氧时，每个m独立为0或1，当X'为硫时为0,1或2，n为至少1，优选为至少2，每个R独立地为未取代或惰性取代的烃基或 R基团一起形成未取代或惰性取代的二价有机基团，A是有机连接基团。
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公开(公告)号：US06538080B1
公开(公告)日：2003-03-25
申请号：US09498912
申请日：2000-02-04
申请人： Robert D. Swindoll , Bruce A. Story , Brian W. S. Kolthammer , Kevin P. Peil , David R. Wilson , James C. Stevens
发明人： Robert D. Swindoll , Bruce A. Story , Brian W. S. Kolthammer , Kevin P. Peil , David R. Wilson , James C. Stevens
IPC分类号： C08F442
CPC分类号： C08G83/003 , B29C47/00 , B29C47/0004 , B29C47/0009 , B29C47/02 , B29K2995/0022 , B32B27/08 , B32B27/322 , C07F7/10 , C07F9/5045 , C07F17/00 , C08F4/65904 , C08F4/65908 , C08F4/65912 , C08F4/65916 , C08F4/6592 , C08F10/00 , C08F10/02 , C08F110/00 , C08F110/02 , C08F110/14 , C08F210/02 , C08F210/16 , C08F297/08 , C08J5/18 , C08J2303/08 , C08J2323/08 , C08L23/02 , C08L23/04 , C08L23/08 , C08L23/0815 , C08L23/0838 , C08L23/16 , C08L25/06 , C08L2203/14 , C08L2205/02 , C08L2308/00 , C08L2314/02 , C08L2314/04 , C08L2314/06 , Y10S526/901 , Y10S526/943 , C08F2/34 , C08F2/001 , C08F4/6555 , C08L2666/04 , C08F2500/12 , C08F2500/07 , C08F2500/03 , C08F2500/19 , C08F2500/17 , C08F2500/08 , C08F2500/09 , C08F2500/11 , C08F2500/05 , C08F212/08 , C08F214/08 , C08F210/06 , C08F2500/20 , C08F2500/26 , C08F210/08 , C08F210/14 , C08F2500/06 , C08F2500/02
摘要： A gas phase fluidized bed process is described for producing ethylene polymers having improved processability and an MWD of less than about 2.9. Multiple reactors in series or parallel may be used to produce in-situ blended polymers. Each reactor can separately have a constrained geometry catalyst or a conventional Ziegler-Natta catalyst as needed for obtaining in-situ blended polymer with the desired properties as long as there is a constrained geometry catalyst in at least one reactor. Olefin polymers can be produced according to this invention which have low susceptibility to melt fracture, even under high shear stress conditions.
摘要翻译： 描述了一种气相流化床方法，用于生产具有改进的加工性和MWD小于约2.9的乙烯聚合物。 串联或并联的多个反应器可用于生产原位共混的聚合物。 只要在至少一个反应器中存在约束几何催化剂，每个反应器可以分开地具有约束几何催化剂或常规的齐格勒 - 纳塔催化剂，以获得具有所需性质的原位共混聚合物。 烯烃聚合物可以根据本发明生产，即使在高剪切应力条件下，熔体破裂的敏感性也低。
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6.发明授权Polyolefin composition with molecular weight maximum occurring in that part of the composition that has the highest comonomer content 有权具有分子量最大值的聚烯烃组合物出现在具有最高共聚单体含量的该组合物的该部分中公开(公告)号：US06462161B1
公开(公告)日：2002-10-08
申请号：US09180414
申请日：1998-11-06
申请人： Larry D. Cady , Christopher J. Frye , Philip Howard , Teresa P. Karjala , Peter J. Maddox , Ian M. Munro , Deepak R. Parikh , S. Roy Partington , Kevin P. Peil , Lee Spencer , William R. Van Volkenburgh , Peter S. Williams , David R. Wilson , J. Mark Winter
发明人： Larry D. Cady , Christopher J. Frye , Philip Howard , Teresa P. Karjala , Peter J. Maddox , Ian M. Munro , Deepak R. Parikh , S. Roy Partington , Kevin P. Peil , Lee Spencer , William R. Van Volkenburgh , Peter S. Williams , David R. Wilson , J. Mark Winter
IPC分类号： C08F1002
CPC分类号： C08F210/00 , C08F4/65908 , C08F4/65912 , C08F4/65916 , C08F4/6592 , C08F4/65927 , C08F210/16 , C08F2410/02 , C08J5/18 , C08J2323/08 , C08L23/06 , C08L23/0815 , C08L2205/02 , C08L2205/025 , C08L2207/07 , C08L2308/00 , C08L2314/06 , Y10S526/901 , Y10S526/916 , Y10S526/943 , C08L2666/06 , C08F210/14 , C08F2500/09 , C08F2500/20 , C08L2666/04
摘要： The invention relates to a polyolefin copolymer composition produced with a catalyst having a metallocene, complex in a single reactor for the polymer of an &agr;-olefin monomer with one or more olefin comonomers, and a molecule weight maximum which occurs in that 50 percent by weight of the composition which has the highest weight percent comonomer content. Preferably, the composition has a comonomer partitioning fact Cpf which is equal to or greater than 1.10 or molecule weight partitioning fact Mpf which is equal to or greater than 1.15. Preferred composition also have at least 0.01 long chain branches per 1000 carbon atoms along the polymer backbone. These compositions with reverse molecular engineering have. superior properties and are easily processable due to the simultaneous presence of the association of high molecular weight with high comonomer content and of long chain branching.
摘要翻译： 本发明涉及一种聚烯烃共聚物组合物，该聚烯烃共聚物组合物由具有茂金属的催化剂制备，在具有一种或多种烯烃共聚单体的α-烯烃单体的聚合物的单个反应器中为复合物，分子量最大值为50重量％ 具有最高重量百分比共聚单体含量的组合物。 优选地，组合物具有等于或大于1.10的共聚单体分配事实Cpf或等于或大于1.15的分子量分配事实Mpf。 优选的组合物也沿着聚合物主链每1000个碳原子具有至少0.01个长链分支。 这些具有反向分子工程的组合物具有。 优异的性能并且由于高分子量与高共聚单体含量和长链支化的结合的同时存在而容易加工。
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公开(公告)号：US6136993A
公开(公告)日：2000-10-24
申请号：US420625
申请日：1999-10-20
申请人： Eugene Y. Chen , Richard E. Campbell, Jr. , David D. Devore , D. Patrick Green , Jasson T. Patton , Jorge Soto , David R. Wilson
发明人： Eugene Y. Chen , Richard E. Campbell, Jr. , David D. Devore , D. Patrick Green , Jasson T. Patton , Jorge Soto , David R. Wilson
CPC分类号： C07F17/00 , C07F7/00 , C07F7/082 , C07F9/5045 , Y02P20/125 , Y10S526/943
摘要： Disclosed is a process for preparing bridged Group 4 metal complexes containing a neutral diene ligand starting from the corresponding novel, metal diene containing complexes by reaction thereof with the divalent derivative of a bridged bidentate ligand compound. The novel, intermediate metal diene complexes, their formation from tetravalent metal salts and an integrated process combining both process steps are claimed.
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8.发明授权Syndiotactic prochiral olefin polymerization using non-aromatic, anionic, dienyl group containing complexes 失效使用非芳族，阴离子，二烯基的络合物进行间规前置手性烯烃聚合
公开(公告)号：US5990033A
公开(公告)日：1999-11-23
申请号：US990182
申请日：1997-12-12
申请人： David R. Wilson , Greg F. Schmidt
发明人： David R. Wilson , Greg F. Schmidt
CPC分类号： C08F10/00 , C07F17/00 , C08F12/04 , C08F4/659 , C08F4/65908 , C08F4/65912 , Y10S526/943
摘要： Compositions comprising Group 4 metal complexes in the +2 or +3 formal oxidation state and containing an anionic pentadienyl ligand or a substituted derivative thereof and activating cocatalysts are used as catalysts for polymerizing olefins, diolefins and/or acetylenically unsaturated monomers. Monovinylidene aromatic monomers in particular are polymerized to form highly syndiotactic polymers.
摘要翻译： 包含+2或+3形式氧化态的含有阴离子戊二烯基配体或其取代衍生物的组4金属络合物和活化助催化剂的组合物用作聚合烯烃，二烯烃和/或炔属不饱和单体的催化剂。 单亚乙烯基芳族单体特别聚合形成高度间同立构聚合物。
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9.发明授权Metal complexes containing partially delocalized II-bound groups and addition polymerization catalysts therefrom 失效含有部分离域II结合基团的金属络合物及其加成聚合催化剂
公开(公告)号：US5541349A
公开(公告)日：1996-07-30
申请号：US304301
申请日：1994-09-12
CPC分类号： C07F17/00 , C07F7/00 , C07F7/28 , C08F10/00 , C08F4/659 , C08F4/65908 , C08F4/65912
摘要： Novel Group 4 metal complexes wherein the metal is in the +2 or +4 formal oxidation state containing a cyclic or noncyclic, non-aromatic, anionic, dienyl ligand group bound to M and having a bridged ligand structure, catalytic derivatives of such complexes including novel zwitterionic complexes; and the use thereof as catalysts for polymerizing addition polymerizable monomers are disclosed.
摘要翻译： 新型4族金属络合物，其中金属为+2或+4形式氧化态，其含有与M结合并具有桥连配体结构的环状或非环状，非芳族，阴离子，二烯基配体基团，所述络合物的催化衍生物包括 新型两性离子复合物; 并且公开了其作为用于聚合加成聚合单体的催化剂的用途。
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10.发明授权Metal (III) complexes containing conjugated, non-aromatic anionic II-bound groups and addition polymerization catalysts therefrom 失效含有共轭非芳族阴离子II键合基团的金属（III）配合物及其加成聚合催化剂
公开(公告)号：US5495036A
公开(公告)日：1996-02-27
申请号：US304315
申请日：1994-09-12
IPC分类号： C07F5/00 , C07F7/00 , C07F13/00 , C07F17/00 , C08F4/642 , C08F4/659 , C08F4/6592 , C08F10/00 , C07F7/28
CPC分类号： C07F17/00 , C08F10/00 , C08F4/65908 , C08F4/65912 , C08F4/6592
摘要： Novel Group 4, Group 3 or Lanthanide metal complexes wherein the metal is in the +3 formal oxidation state containing a cyclic or non-cyclic, nonaromatic, anionic, dienyl ligand group bound to M and having a bridged ligand structure, catalytic derivatives of such complexes; and the use thereof as catalysts for polymerizing addition polymerizable monomers are disclosed.
摘要翻译： 新型第4族，第3族或镧系元素金属络合物，其中金属为+3形式氧化态，其含有与M结合并具有桥连配体结构的环状或非环状，非芳族，阴离子，二烯基配体基团， 复合物 并且公开了其作为用于聚合加成聚合单体的催化剂的用途。
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