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33 条记录 (耗时 0.032 秒)

    Reaction products of olefinically unsaturated carboxylic acids and polyetherols and their use as demulsifiers for crude oil emulsions
    3.
    发明授权
    Reaction products of olefinically unsaturated carboxylic acids and polyetherols and their use as demulsifiers for crude oil emulsions 失效

    公开(公告)号：US5661220A

    公开(公告)日：1997-08-26

    申请号：US592290

    申请日：1996-02-07

    申请人： Dieter Faul ,  Joachim Roser ,  Heinrich Hartmann ,  Hans-Henning Vogel ,  Wilhelmus Slotman ,  Gerd Konrad

    发明人： Dieter Faul ,  Joachim Roser ,  Heinrich Hartmann ,  Hans-Henning Vogel ,  Wilhelmus Slotman ,  Gerd Konrad

    IPC分类号： B01D17/04 ,  C08F220/26 ,  C08G63/676 ,  C08G65/332 ,  C09K8/36 ,  C10G33/04 ,  C08F8/00 ,  C08F8/14

    CPC分类号： B01D17/047 ,  C08F220/26 ,  C08G63/676 ,  C08G65/3322 ,  C09K8/36 ,  C10G33/04 ,  C08G2650/20 ,  C08L2312/00

    摘要： Reaction products which are suitable as demulsifiers for crude oil emulsions, comprise olefinically unsaturated carboxylic acids and polyetherols and are obtainable byA) condensation of one or more unsaturated C.sub.3 -C.sub.10 -carboxylic acids or their derivatives of the general formula I ##STR1## where R.sup.1 and R.sup.2 are each hydrogen, C.sub.1 -C.sub.4 -alkyl or carboxyl, R.sup.3 is hydrogen or methyl and R.sup.1 together with the carboxyl group may form a 5-membered or 6-membered anhydride ring, with a polyetherol of the general formula II ##STR2## where R.sup.4 is a radical of a monohydric or polyhydric alcohol or of a phenol or of an alkylphenol of 7 to 30 carbon atoms or a radical of an alkylphenol/formaldehyde or alkylphenol/acetaldehyde condensate, R.sup.5 is a branched or straight-chain C.sub.2 -C.sub.4 -alkylene group, where different units [R.sup.5 -O] may be present within a polyalkylene oxide chain, and X is an integer of from 5 to 120, in a molar ratio of compounds II to I of from 2:1 to 10:1 and in a weight ratio of from 25:1 to 1,000:1,B) polymerization of the resulting condensate with one or more unsaturated carboxylic acids I and, if required, further olefinically unsaturated monomers copolymerizable with the carboxylic acids I, the amount of the carboxylic acids I being from 50 to 100 mol %, based on the amount of the olefinically unsaturated monomers, and the molar ratio of the polyetherol II to the sum of the olefinically unsaturated monomers used in process steps A) and B) being from 1:5 to 1:200, and subsequentC) condensation of the resulting reaction mixture, with the proviso that not all hydroxyl groups are converted,and a process for their preparation, mixtures of the reaction products with organic solvents and the use of the reaction products and of the mixtures as demulsifiers for crude oil emulsions.

    Dispersion resins containing itaconic acid for improving wet abrasion resistance
    4.
    发明授权
    Dispersion resins containing itaconic acid for improving wet abrasion resistance 有权
    含有衣康酸的分散树脂用于改善耐湿磨损性

    公开(公告)号：US06790272B1

    公开(公告)日：2004-09-14

    申请号：US09623487

    申请日：2000-09-15

    申请人： Cheng-Le Zhao ,  Joachim Roser ,  Rolf Dersch ,  Roland Baumstark

    发明人： Cheng-Le Zhao ,  Joachim Roser ,  Rolf Dersch ,  Roland Baumstark

    IPC分类号： C09D502

    CPC分类号： C09D17/004 ,  C08F222/02 ,  C09D5/024 ,  C09D133/064 ,  C08L2666/54

    摘要： The invention relates to aqueous pigment preparations containing i) at least one copolymer P of ethylenically unsaturated monomers M in the form of an aqueous polymer dispersion which contains between 0.1 and 1.5 weight %, in relation to the total weight of the copolymer P, of polymerized itaconic acid as acid monomer M1, its salts and/or anhydride, where up to 50 weight % of the itaconic acid can be substituted by another monomer having at least one acid group or a neutralized acid group, and whose glass transition temperature TG lies between −10 and +50° C.; ii) at least one inorganic pigment; iii) possibly inorganic fillers; and iv) standard additives. The invention also relates to the use of the copolymers P containing itaconic acid for improving the wet-abrasion resistance of polymer-bound coatings containing pigments.

    摘要翻译： 本发明涉及水性颜料制剂，其含有i）至少一种含水聚合物分散体形式的烯属不饱和单体M的共聚物P，其相对于共聚物P的总重量为0.1至1.5重量％，聚合的 衣康酸作为酸单体M1，其盐和/或酸酐，其中至多50重量％的衣康酸可以被具有至少一个酸基或中和的酸基的另一个单体取代，并且其玻璃化转变温度TG位于 -10和+ 50°C。 ii）至少一种无机颜料; iii）可能的无机填料; 和iv）标准添加剂。 本发明还涉及含有衣康酸的共聚物P用于改善含有颜料的聚合物结合涂层的耐湿耐磨性的用途。

    Storage-stable solution of a carboxyl-containing copolymer and production of photosensitive coatings and offset printing plates
    8.
    发明授权
    Storage-stable solution of a carboxyl-containing copolymer and production of photosensitive coatings and offset printing plates 失效
    含羧基共聚物的储存稳定溶液和感光涂料和胶印印版的生产

    公开(公告)号：US5262278A

    公开(公告)日：1993-11-16

    申请号：US822266

    申请日：1992-01-17

    申请人： Harald Lauke ,  Thomas Loerzer ,  Axel Sanner ,  Joachim Roser

    发明人： Harald Lauke ,  Thomas Loerzer ,  Axel Sanner ,  Joachim Roser

    IPC分类号： C08F2/40 ,  C08F2/38 ,  C08F290/00 ,  C08F290/12 ,  C08F299/00 ,  C09D4/02 ,  G03F7/028 ,  G03F7/033 ,  G03F7/038

    CPC分类号： C08F290/126 ,  G03F7/033 ,  Y10S430/119

    摘要： Storage-stable solutions of film forming carboxyl-containing copolymers, from 5 to 80% of whose carboxyl groups have been reacted with glycidyl (meth)acrylate, in an inert organic solvent or solvent mixture additionally contain a phosphoric ester of a hydroxyalkyl (meth)acrylate and, if required, orthophosphoric acid, and photosensitive coatings which contain a photoinitiator, ethylenically unsaturated organic monomeric compounds which can be subjected to free radical polymerization and, if required, plasticizers, dyes, dye precursors and thermal polymerization inhibitors are produced in such storage-stable solutions.They are particularly suitable for the production of offset printing plates.

    摘要翻译： 含羧基的共聚物的存储稳定溶液，其羧基的5-80％已经与（甲基）丙烯酸缩水甘油酯反应，在惰性有机溶剂或溶剂混合物中另外含有（甲基）丙烯酸羟烷基酯的磷酸酯， 丙烯酸酯，并且如果需要的话，正磷酸和含有可以进行自由基聚合的光引发剂，烯键式不饱和有机单体化合物和如果需要的增塑剂，染料，染料前体和热聚合抑制剂的光敏涂料在这种储存 稳定的解决方案 它们特别适用于生产胶版印刷版。