摘要:
A solid oxide fuel cell (SOFC) includes a cathode electrode, a solid oxide electrolyte, and an anode electrode having a first portion and a second portion, such that the first portion is located between the electrolyte and the second portion. The anode electrode comprises a cermet comprising a nickel containing phase and a ceramic phase. The first portion of the anode electrode contains a lower porosity and a lower ratio of the nickel containing phase to the ceramic phase than the second portion of the anode electrode.
摘要:
One embodiment of the invention provides a method of operating a solid oxide fuel cell, including providing a solid oxide fuel cell comprising an anode electrode containing nickel, and electrochemically reducing an anode side of the fuel cell. Another embodiment of the invention provides a method of operating a solid oxide fuel cell, including providing a solid oxide fuel cell comprising an anode electrode containing nickel, periodically operating the fuel cell to generate electricity, and reducing an anode side of the fuel cell between electricity generation operation periods of the fuel cell.
摘要:
One embodiment of the invention provides a method of operating a solid oxide fuel cell, including providing a solid oxide fuel cell comprising an anode electrode containing nickel, and electrochemically reducing an anode side of the fuel cell. Another embodiment of the invention provides a method of operating a solid oxide fuel cell, including providing a solid oxide fuel cell comprising an anode electrode containing nickel, periodically operating the fuel cell to generate electricity, and reducing an anode side of the fuel cell between electricity generation operation periods of the fuel cell.
摘要:
A solid oxide fuel cell (SOFC) includes a cathode electrode, a solid oxide electrolyte, and an anode electrode having a first portion and a second portion, such that the first portion is located between the electrolyte and the second portion. The anode electrode comprises a cermet comprising a nickel containing phase and a ceramic phase. The first portion of the anode electrode contains a lower porosity and a lower ratio of the nickel containing phase to the ceramic phase than the second portion of the anode electrode.
摘要:
A system and method in which a high temperature fuel cell stack exhaust stream is recycled back into the fuel inlet stream of the high temperature fuel cell stack. The recycled stream may be sent to a carbon dioxide separation device which separates carbon dioxide from the fuel exhaust stream. The carbon dioxide separation device may be a carbon dioxide trap, an electrochemical carbon dioxide separator, or a membrane separator. A water separator may be used in conjunction with the carbon dioxide separation device or used separately to continuously remove water from the recycled stream.
摘要:
A fuel cell system includes a first fuel cell stack, a second fuel cell stack arranged in a cascade configuration with the first fuel cell stack, and at least one hydrocarbon fuel reformer which is thermally integrated with at least a portion of the first stack. The system is configured such that in operation, at least partial reformation of hydrocarbon fuel occurs prior to entry into the first stack or in the first stack, and the second stack uses fuel exhaust from the first stack as fuel. A method of operating the fuel cell system includes reforming a hydrocarbon fuel to form a reformed fuel while cooling at least a portion of a first fuel cell stack, generating electricity in the first fuel cell stack using the reformed fuel, providing a fuel exhaust stream from the first fuel cell stack into a second fuel cell stack, and generating electricity in the second fuel cell stack using the fuel exhaust stream from the first fuel stack as a fuel.
摘要:
A method of operating a fuel cell system includes providing a fuel inlet stream into a fuel cell stack, operating the fuel cell stack to generate electricity and a hydrogen containing fuel exhaust stream, separating at least a portion of hydrogen contained in the fuel exhaust stream using partial pressure swing adsorption, and providing the hydrogen separated from the fuel exhaust stream into the fuel inlet stream.
摘要:
A Solid Oxide Regenerative Fuel Cell (SORFC) system stores waste heat from the fuel cell in a heat storage material during the discharge mode. The heat is then used to heat water to be electrolyzed during the charge mode.
摘要:
A fuel cell system includes a controller, a fuel cell stack, a fuel inlet conduit operatively connected to the fuel cell stack, the fuel inlet conduit adapted to receive fuel from a fuel supply, a recycling conduit operatively connecting the fuel cell stack to the fuel inlet conduit, the recycling conduit adapted to recycle a portion of a fuel exhaust stream from the fuel cell stack to the fuel inlet conduit, and an ammonia or hydrazine storage vessel operatively connected to the fuel inlet conduit via a valve coupled to the controller. The controller is configured to control the operation of the valve to provide ammonia or hydrazine from the ammonia or hydrazine storage vessel into the fuel inlet conduit upon detecting a change in the fuel from the fuel supply.