公开(公告)号：US09010079B2

公开(公告)日：2015-04-21

申请号：US13699299

申请日：2011-05-06

Applicant: Emmanuel Custodero ,  Sébastien Rigo ,  Jérémy Toussain

Inventor： Emmanuel Custodero ,  Sébastien Rigo ,  Jérémy Toussain

IPC: D02G3/48 ,  D07B7/14 ,  D02G3/12 ,  D07B1/06

CPC classification number: D02G3/48 ,  D02G3/12 ,  D07B1/0626 ,  D07B1/0633 ,  D07B1/0646 ,  D07B1/0653 ,  D07B7/145 ,  D07B2201/2011 ,  D07B2201/2028 ,  D07B2201/2037 ,  D07B2201/2046 ,  D07B2201/2048 ,  D07B2201/2059 ,  D07B2201/2082 ,  D07B2205/2003 ,  D07B2205/2082 ,  D07B2207/205 ,  D07B2207/4072 ,  D07B2401/208 ,  D07B2501/2046 ,  D07B2801/12 ,  D07B2801/18 ,  D07B2801/16

Abstract: Method for manufacturing a metal cord with three concentric layers including a first layer of diameter dc made up of M wire(s) of diameter d1, around which layer are wound together as a helix at a pitch p2, as a second layer, N wires of diameter d2, around which are wound as a helix at pitch p3, as a third layer, P wires of diameter d3. The N wires of the second layer are assembled around the layer to form, at a point called “assembling point”, an intermediate cord called “core strand” of M+N construction; upstream and/or downstream of the assembling point, the layer and/or the core strand is sheathed with a rubber or rubber composition by passing through at least one extrusion head; then the P wires of the third layer are assembled around the core strand to form a cord of M+N+P construction thus rubberized from the inside.

Abstract translation: 用于制造具有三个同心层的金属帘线的方法，所述金属帘线包括由直径为d1的M线构成的直径为直径为d的第一直径直径为d的层，以层间距p2作为螺旋缠绕在一起作为第二层，N线 直径为d2，以间距p3作为螺旋缠绕，作为第三层，直径为d3的P线。 第二层的N根线被组装在层上，在称为“组装点”的点形成称为M + N结构的“芯线”的中间线; 在组装点的上游和/或下游，通过穿过至少一个挤出头，用橡胶或橡胶组合物包裹层和/或芯股线; 那么第三层的P线组装在芯股线周围，形成一个M + N + P结构的绳索，从而从里面涂上橡胶。

公开(公告)号：US20130232936A1

公开(公告)日：2013-09-12

申请号：US13699299

申请日：2011-05-06

Applicant: Emmanuel Custodero ,  Sébastien Rigo ,  Jérémy Toussain

Inventor： Emmanuel Custodero ,  Sébastien Rigo ,  Jérémy Toussain

IPC: D02G3/48 ,  D02G3/12

CPC classification number: D02G3/48 ,  D02G3/12 ,  D07B1/0626 ,  D07B1/0633 ,  D07B1/0646 ,  D07B1/0653 ,  D07B7/145 ,  D07B2201/2011 ,  D07B2201/2028 ,  D07B2201/2037 ,  D07B2201/2046 ,  D07B2201/2048 ,  D07B2201/2059 ,  D07B2201/2082 ,  D07B2205/2003 ,  D07B2205/2082 ,  D07B2207/205 ,  D07B2207/4072 ,  D07B2401/208 ,  D07B2501/2046 ,  D07B2801/12 ,  D07B2801/18 ,  D07B2801/16

Abstract: Method for manufacturing a metal cord with three concentric layers including a first layer of diameter dc made up of M wire(s) of diameter d1, around which layer are wound together as a helix at a pitch p2, as a second layer, N wires of diameter d2, around which are wound as a helix at pitch p3, as a third layer, P wires of diameter d3. The N wires of the second layer are assembled around the layer to form, at a point called “assembling point”, an intermediate cord called “core strand” of M+N construction; upstream and/or downstream of the assembling point, the layer and/or the core strand is sheathed with a rubber or rubber composition by passing through at least one extrusion head; then the P wires of the third layer are assembled around the core strand to form a cord of M+N+P construction thus rubberized from the inside.

Abstract translation: 用于制造具有三个同心层的金属帘线的方法，所述金属帘线包括由直径为d1的M线构成的直径为直径为d的第一直径直径为d的层，以层间距p2作为螺旋缠绕在一起作为第二层，N线 直径为d2，以间距p3作为螺旋缠绕，作为第三层，直径为d3的P线。 第二层的N根线被组装在层上，在称为“组装点”的点形成称为M + N结构的“芯线”的中间线; 在组装点的上游和/或下游，通过穿过至少一个挤出头，用橡胶或橡胶组合物包裹层和/或芯股线; 那么第三层的P线组装在芯股线周围，形成一个M + N + P结构的绳索，从而从里面涂上橡胶。

公开(公告)号：US09150984B2

公开(公告)日：2015-10-06

申请号：US13699300

申请日：2011-05-06

Applicant: Emmanuel Custodero ,  Sébastien Rigo ,  Jérémy Toussain

Inventor： Emmanuel Custodero ,  Sébastien Rigo ,  Jérémy Toussain

IPC: D07B1/06 ,  D02G3/02 ,  D07B7/14 ,  D07B5/12

CPC classification number: D02G3/02 ,  D07B1/062 ,  D07B1/0633 ,  D07B1/0646 ,  D07B1/0653 ,  D07B5/12 ,  D07B7/145 ,  D07B2201/2028 ,  D07B2201/2046 ,  D07B2201/2048 ,  D07B2201/2059 ,  D07B2201/2062 ,  D07B2201/2082 ,  D07B2205/2003 ,  D07B2205/2082 ,  D07B2207/205 ,  D07B2207/4072 ,  D07B2501/2046 ,  D07B2801/12 ,  D07B2801/18 ,  D07B2801/16

Abstract: Method of manufacturing a multi-layer metal cord having a plurality of concentric layers of wires, comprising one or more inner layer(s) and an outer layer, of the type “rubberized in situ. The method includes the following steps: at least one step of sheathing at least one inner layer with the rubber or the rubber composition by passing through at least one extrusion head; and an assembling step in which the wires of the outer layer are assembled around the inner layer adjacent to it, in order to form the multi-layer cord thus rubberized from the inside. The rubber is an unsaturated thermoplastic elastomer extruded in the molten state, preferably a thermoplastic elastomer of the thermoplastic stirene (TPS) elastomer type such as an SBS, SBBS, SIS or SBIS block copolymer for example.

Abstract translation: 制造多层金属帘线的方法，该多层金属帘线具有多个同心层的电线，其包括一种或多种“原位胶化”的内层和外层。 该方法包括以下步骤：通过使至少一个挤出头穿过橡胶或橡胶组合物的至少一个内层的至少一个步骤; 以及组装步骤，其中外层的电线围绕其邻近的内层组装，以便形成从内部涂覆的多层帘线。 橡胶是在熔融状态下挤出的不饱和热塑性弹性体，优选热塑性弹性体（TPS）弹性体类型的热塑性弹性体，例如SBS，SBBS，SIS或SBIS嵌段共聚物。

公开(公告)号：US20130227924A1

公开(公告)日：2013-09-05

申请号：US13699300

申请日：2011-05-06

Applicant: Emmanuel Custodero ,  Sébastien Rigo ,  Jérémy Toussain

Inventor： Emmanuel Custodero ,  Sébastien Rigo ,  Jérémy Toussain

IPC: D02G3/02

CPC classification number: D02G3/02 ,  D07B1/062 ,  D07B1/0633 ,  D07B1/0646 ,  D07B1/0653 ,  D07B5/12 ,  D07B7/145 ,  D07B2201/2028 ,  D07B2201/2046 ,  D07B2201/2048 ,  D07B2201/2059 ,  D07B2201/2062 ,  D07B2201/2082 ,  D07B2205/2003 ,  D07B2205/2082 ,  D07B2207/205 ,  D07B2207/4072 ,  D07B2501/2046 ,  D07B2801/12 ,  D07B2801/18 ,  D07B2801/16

Abstract: Method of manufacturing a multi-layer metal cord having a plurality of concentric layers of wires, comprising one or more inner layer(s) and an outer layer, of the type “rubberized in situ.” The method includes the following steps: at least one step of sheathing at least one inner layer with the rubber or the rubber composition by passing through at least one extrusion head; and an assembling step in which the wires of the outer layer are assembled around the inner layer adjacent to it, in order to form the multi-layer cord thus rubberized from the inside. The rubber is an unsaturated thermoplastic elastomer extruded in the molten state, preferably a thermoplastic elastomer of the thermoplastic stirene (TPS) elastomer type such as an SBS, SBBS, SIS or SBIS block copolymer for example.

Abstract translation: 制造多层金属帘线的方法，该多层金属帘线具有多个同心层的电线，包括“原位胶化”类型的一个或多个内层和外层。 该方法包括以下步骤：通过使至少一个挤出头穿过橡胶或橡胶组合物的至少一个内层的至少一个步骤; 以及组装步骤，其中外层的电线围绕其邻近的内层组装，以便形成从内部涂覆的多层帘线。 橡胶是在熔融状态下挤出的不饱和热塑性弹性体，优选热塑性弹性体（TPS）弹性体类型的热塑性弹性体，例如SBS，SBBS，SIS或SBIS嵌段共聚物。

公开(公告)号：US20130220506A1

公开(公告)日：2013-08-29

申请号：US13699291

申请日：2011-05-06

Applicant: Thibaud Pottier ,  Sébastien Rigo ,  Jérémy Toussain

Inventor： Thibaud Pottier ,  Sébastien Rigo ,  Jérémy Toussain

IPC: B60C9/00

CPC classification number: B60C9/005 ,  B60C2009/0014 ,  D07B1/0613 ,  D07B1/0626 ,  D07B1/0633 ,  D07B7/145 ,  D07B2201/2011 ,  D07B2201/2028 ,  D07B2201/2046 ,  D07B2201/2062 ,  D07B2201/2082 ,  D07B2205/2003 ,  D07B2205/2082 ,  D07B2207/205 ,  D07B2207/4072 ,  D07B2501/2046 ,  D07B2801/12 ,  D07B2801/18 ,  D07B2801/16

Abstract: Metal cord with three concentric layers including a first layer of diameter dc made up of M wire(s) of diameter d1, around which are wound as a helix at a pitch p2, as a second layer, N wires of diameter d2, around which are wound as a helix at pitch p3, as a third layer, P wires of diameter d3. Some gaps or capillaries in the cord situated between the core and the second layer and between the core wires themselves when M is greater than 1 and between the N wires of the second layer and the P wires of the third layer, contain a filling rubber based on an unsaturated thermoplastic elastomer

Abstract translation: 具有三个同心层的金属线，包括由直径为d1的M线组成的第一直径直径的直径为d的绕组，以间距p2作为螺旋缠绕，作为第二层，N直径为d2的线 以间距p3作为螺旋缠绕，作为第三层，直径为d3的P线。 当M大于1且在第二层的N线和第三层的P线之间时，位于芯和第二层之间以及芯线本身之间的线中的一些间隙或毛细管包含基于 在不饱和热塑性弹性体上

公开(公告)号：US20130220505A1

公开(公告)日：2013-08-29

申请号：US13699281

申请日：2011-05-06

Applicant: Thibaud Pottier ,  Sébastien Rigo ,  Jérémy Toussain

Inventor： Thibaud Pottier ,  Sébastien Rigo ,  Jérémy Toussain

IPC: B60C9/00 ,  D02G3/48 ,  D02G3/12

CPC classification number: B60C9/0042 ,  D02G3/12 ,  D02G3/48 ,  D07B1/0613 ,  D07B1/062 ,  D07B1/0626 ,  D07B1/0633 ,  D07B2201/2046 ,  D07B2201/2082 ,  D07B2205/2003 ,  D07B2205/2082 ,  D07B2501/2046 ,  Y10T152/10765 ,  Y10T152/10855 ,  D07B2801/18 ,  D07B2801/16

Abstract: Metal cord with a plurality of concentric layers, of the type rubberized in situ, i.e. a cord that is rubberized from the inside, during its actual manufacture, with a rubber known as a filling rubber, in which all or some of the gaps situated between the wires of the cord contain a thermoplastic elastomer of the unsaturated type, particularly an unsaturated thermoplastic stirene (TPS) elastomer such as an SBS, SBBS, SIS or SBIS block copolymer for example. Such a thermoplastic elastomer, used in the molten state, presents no problems of parasitic stickiness if the filling rubber overspills out of the cord following manufacture; its unsaturated and therefore (co)vulcanizable nature makes it extremely compatible with the diene rubber matrices, notably natural rubber matrices as conventionally used as calendering rubber in the metal fabrics intended for reinforcing tires.

Abstract translation: 具有多个同心层的金属线，即在其实际制造过程中由内部橡胶化的帘线，即已知为填充橡胶的橡胶，其中全部或一些间隙位于 帘线的线包含不饱和型热塑性弹性体，特别是不饱和热塑性塑料（TPS）弹性体，例如SBS，SBBS，SIS或SBIS嵌段共聚物。 在熔融状态下使用的这种热塑性弹性体，如果填充橡胶在制造之后从电线中过多地渗出，则不存在寄生粘着性问题; 其不饱和和因此（共）可硫化性质使其与二烯橡胶基质，特别是通常用作用于加强轮胎的金属织物中的压延橡胶的天然橡胶基质极其相容。

公开(公告)号：US20130280511A1

公开(公告)日：2013-10-24

申请号：US13825926

申请日：2011-09-16

Applicant: Vincent Abad ,  Sébastien Rigo ,  Emmanuel Custodero

Inventor： Vincent Abad ,  Sébastien Rigo ,  Emmanuel Custodero

IPC: C08K3/08

CPC classification number: C08K3/08 ,  B29B15/08 ,  B29D30/38 ,  B29D2030/383 ,  Y10T428/294

Abstract: Pneumatic tire comprising a composite reinforcer (R-2) that is self-adhesive by curing to a diene rubber matrix, comprising: one or more reinforcing thread(s) (20), for example a carbon steel cord; covering said thread, individually each thread or collectively several threads, a layer of a thermoplastic polymer composition comprising on the one hand a thermoplastic polymer, the glass transition temperature of which is positive, on the other hand an unsaturated thermoplastic stirene elastomer, the glass transition temperature of which is negative.

Abstract translation: 包括通过固化至二烯橡胶基体而自粘的复合增强件（R-2）的气动轮胎，包括：一个或多个加强丝（20），例如碳钢帘线; 覆盖所述螺纹，单独地每个螺纹或共同的几个螺纹，一层热塑性聚合物组合物，一方面包括玻璃化转变温度为正的热塑性聚合物，另一方面包含不饱和热塑性塑料弹性体，玻璃化转变 温度为负。

公开(公告)号：US09540766B2

公开(公告)日：2017-01-10

申请号：US13825935

申请日：2011-09-16

Applicant: Vincent Abad ,  Sébastien Rigo ,  Emmanuel Custodero

Inventor： Vincent Abad ,  Sébastien Rigo ,  Emmanuel Custodero

IPC: B32B25/02 ,  D07B1/06 ,  B29B15/08 ,  B60C5/00 ,  B29D30/38

CPC classification number: D07B1/0633 ,  B29B15/08 ,  B29D2030/383 ,  B60C5/00 ,  D07B1/0666 ,  Y10T428/2938 ,  Y10T428/2947 ,  Y10T428/2967 ,  Y10T428/2969

Abstract: Composite reinforcer (R-2) that is self-adhesive, by curing, to a diene rubber matrix, which can be used as reinforcing element for a pneumatic tire, comprising: one or more reinforcing thread(s) (20), for example a carbon steel cord; a first layer (21) of a thermoplastic polymer, the glass transition temperature of which is positive, for example a polyamide, covering said thread, individually each thread or collectively several threads; a second layer (22) of a composition comprising a poly(p-phenylene ether) (“PPE”) and a functionalized diene elastomer bearing functional groups selected from epoxide, carboxyl, acid anhydride and acid ester groups, in particular an epoxidized SBR, covering the first layer (21). Process for manufacturing such a composite reinforcer and rubber article or semi-finished product, especially a pneumatic tire, incorporating such a composite reinforcer.

Abstract translation: 复合增强件（R-2），其通过固化而自粘合到可用作充气轮胎的增强元件的二烯橡胶基质上，包括：一个或多个加强丝（20），例如 碳钢绳; 热塑性聚合物的第一层（21），其玻璃化转变温度为正，例如聚酰胺，覆盖所述螺纹，单独地每个螺纹或共同的几个螺纹; 包含聚（对亚苯基醚）（“PPE”）和具有选自环氧化物，羧基，酸酐和酸酯基团的官能团的官能化二烯弹性体，特别是环氧化SBR的组合物的第二层（22） 覆盖第一层（21）。 用于制造这种复合增强件和橡胶制品或半成品的方法，特别是包含这种复合增强件的充气轮胎。

公开(公告)号：US20140051312A1

公开(公告)日：2014-02-20

申请号：US13981677

申请日：2012-01-31

Applicant: Vincent Abad ,  Sébastien Rigo ,  Emmanuel Custodero

Inventor： Vincent Abad ,  Sébastien Rigo ,  Emmanuel Custodero

IPC: B32B27/04 ,  B29D30/06 ,  C09J7/04

CPC classification number: B60C9/0057 ,  B29B15/125 ,  B29D30/0601 ,  B29D30/40 ,  B29K2009/06 ,  B29K2021/003 ,  B29K2071/12 ,  B29L2030/00 ,  B60C9/0042 ,  C08L53/02 ,  C09J7/21 ,  C09J7/30 ,  C09J7/35 ,  C09J153/02 ,  C09J171/12 ,  C09J2425/00 ,  C09J2465/00 ,  D06M15/227 ,  D06M15/233 ,  D06M15/53 ,  Y10T442/2738

Abstract: Rubber composite, and in particular tyre, reinforced with a sized textile material, such as a fibre or a film, at least one portion of which is coated with an adhesive layer, capable of adhering directly via curing (crosslinking) to an unsaturated rubber matrix, such as a natural rubber matrix, characterized in that said layer comprises an adhesive composition or thermoplastic adhesive, in the liquid or solid state, which is based on at least one unsaturated thermoplastic styrene (TPS) elastomer and a poly(p-phenylene ether) (PPE).Such an adhesive based on unsaturated TPS and PPE advantageously makes it possible to replace a conventional textile adhesive of RFL type. Use of such an adhesive for the adhesive bonding of a textile material to an unsaturated, in particular diene, rubber. Process for obtaining such a composite.

Abstract translation: 橡胶复合材料，特别是轮胎，用诸如纤维或薄膜的尺寸的纺织材料增强，其至少一部分涂覆有粘合剂层，其能够通过固化（交联）直接粘附到不饱和橡胶基体 ，例如天然橡胶基质，其特征在于所述层包含基于至少一种不饱和热塑性苯乙烯（TPS）弹性体和聚（对亚苯基醚）的液体或固体状态的粘合剂组合物或热塑性粘合剂 ）（PPE）。 基于不饱和TPS和PPE的这种粘合剂有利地可以替代RFL型的常规纺织粘合剂。 使用这种粘合剂将纺织材料粘合到不饱和的，特别是二烯的橡胶上。 获得这种复合材料的方法。

公开(公告)号：US20140045984A1

公开(公告)日：2014-02-13

申请号：US13989017

申请日：2011-11-16

Applicant: Vincent Abad ,  Sébastien Rigo ,  Emmanuel Custodero

Inventor： Vincent Abad ,  Sébastien Rigo ,  Emmanuel Custodero

IPC: C09D109/06 ,  D07B1/06 ,  C09D177/02

CPC classification number: C09D109/06 ,  C09D177/02 ,  D02G3/48 ,  D07B1/0606 ,  D07B1/062 ,  D07B1/0666 ,  D07B2201/2012 ,  D07B2201/2044 ,  D07B2201/2046 ,  D07B2205/2017 ,  D07B2205/2039 ,  D07B2205/2046 ,  D07B2205/2082 ,  D07B2207/4068 ,  D07B2501/2046 ,  D07B2501/2053 ,  Y10T428/2938 ,  Y10T428/294 ,  Y10T428/2967 ,  Y10T428/2969 ,  D07B2801/18 ,  D07B2801/16

Abstract: Composite reinforcer (R-2) that is self-adhesive by curing to a diene rubber matrix, which can be used as reinforcing element for a pneumatic tire, comprising: one or more reinforcing thread(s) (20), for example a carbon steel cord; covering said thread, individually each thread or collectively several threads, a layer of a thermoplastic polymer composition comprising on the one hand a thermoplastic polymer, the glass transition temperature of which is positive, on the other hand a functionalized unsaturated thermoplastic stirene elastomer, the glass transition temperature of which is negative, said elastomer containing functional groups selected from epoxide, carboxyl and acid anhydride or ester groups. Process for manufacturing such a composite reinforcer and rubber article or semi-finished product, especially a pneumatic tire, incorporating such a composite reinforcer.

Abstract translation: 通过固化成可以用作充气轮胎的增强元件的二烯橡胶基质而具有自粘性的复合增强件（R-2），包括：一个或多个增强线（20），例如碳 钢丝绳; 覆盖所述螺纹，单独地每个螺纹或共同的几个螺纹，一层热塑性聚合物组合物，一方面包括玻璃化转变温度为正的热塑性聚合物，另一方面包括官能化的不饱和热塑性塑料弹性体，玻璃 其转变温度为负，所述弹性体含有选自环氧化物，羧基和酸酐或酯基的官能团。 用于制造这种复合增强件和橡胶制品或半成品的方法，特别是包含这种复合增强件的充气轮胎。