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公开(公告)号：US4579973A
公开(公告)日：1986-04-01
申请号：US699874
申请日：1985-02-08
申请人： Erich Widmer , Reinhard Zell
发明人： Erich Widmer , Reinhard Zell
IPC分类号： C07C403/08 , C07C45/61 , C07C45/62 , C07C49/743 , C07C67/00 , C07C401/00 , C07C403/00 , C07C403/24 , C07F9/54 , C07C45/65
CPC分类号： C07C403/24 , C07C403/08 , C07F9/5435 , C07C2101/16
摘要： A novel process for the manufacture of cyclohexene derivatives which are suitable as intermediates for the manufacture of rhodoxanthin or zeaxanthin, as well as a process for the manufacture of rhodoxanthin or of zeaxanthin itself. The invention is also concerned with a novel starting material and novel intermediates in this process.
摘要翻译： 一种制备环己烯衍生物的新方法，其适用于制备罗红黄质或玉米黄质的中间体，以及一种制备罗丹黄质或玉米黄质本身的方法。 本发明还涉及一种新颖的起始材料和新型中间体。
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公开(公告)号：US4072715A
公开(公告)日：1978-02-07
申请号：US707123
申请日：1976-07-20
IPC分类号： C07C49/403 , C07C403/00 , C07F9/54 , C12P7/26 , C07C49/30
CPC分类号： C12P7/26 , C07C403/02 , C07C403/08 , C07C403/12 , C07C403/14 , C07C403/16 , C07C403/24 , C07C45/64 , C07F9/5428 , C07B2200/07 , C07C2101/16
摘要： A process for fermentatively hydrogenating and reducing ketoisophorone to produce optically active [4R,6R]-4-hydroxy-2,6,6-trimethyl-cyclohexanone useful as an intermediate in the production of optically active carotenoids and intermediates in the production of these carotenoids.
摘要翻译： 一种用于发酵氢化和还原酮异二酮以制备光学活性的[4R，6R] -4-羟基-2,6,6-三甲基 - 环己酮的方法，其用作制备光学活性类胡萝卜素的中间体和这些类胡萝卜素生产中的中间体 。
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公开(公告)号：US4156100A
公开(公告)日：1979-05-22
申请号：US849138
申请日：1977-11-07
IPC分类号： C07C49/403 , C07C403/00 , C07F9/54 , C12P7/26 , C07C35/18
CPC分类号： C12P7/26 , C07C403/02 , C07C403/08 , C07C403/12 , C07C403/14 , C07C403/16 , C07C403/24 , C07C45/64 , C07F9/5428 , C07B2200/07 , C07C2101/16
摘要： A process for fermentatively hydrogenating and reducing ketoisophorone to produce optically active [4R,6R]-4-hydroxy-2,6,6-trimethyl-cyclohexanone useful as an intermediate in the production of optically active carotenoids and intermediates in the production of these carotenoids.
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公开(公告)号：US4095038A
公开(公告)日：1978-06-13
申请号：US707146
申请日：1976-07-20
申请人： Walter Boguth , Hans Georg Wilhelm Leuenberger , Hans Johann Mayer , Erich Widmer , Reinhard Zell
发明人： Walter Boguth , Hans Georg Wilhelm Leuenberger , Hans Johann Mayer , Erich Widmer , Reinhard Zell
IPC分类号： C07C49/403 , C07C403/00 , C07F9/54 , C12P7/26 , C07C175/00
CPC分类号： C12P7/26 , C07C403/02 , C07C403/08 , C07C403/12 , C07C403/14 , C07C403/16 , C07C403/24 , C07C45/64 , C07F9/5428 , C07B2200/07 , C07C2101/16
摘要： A process for fermentatively hydrogenating and reducing ketoisophorone to produce optically active [4R,6R]-4-hydroxy-2,6,6-trimethyl-cyclohexanone useful as an intermediate in the production of optically active carotenoids and intermediates in the production of these carotenoids.
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公开(公告)号：US4026949A
公开(公告)日：1977-05-31
申请号：US707128
申请日：1976-07-20
申请人： Walter Boguth , Hans Georg Wilhelm Leuenberger , Hans Johann Mayer , Erich Widmer , Reinhard Zell
发明人： Walter Boguth , Hans Georg Wilhelm Leuenberger , Hans Johann Mayer , Erich Widmer , Reinhard Zell
CPC分类号： C07F9/5428 , Y10S435/822
摘要： A process for fermentatively hydrogenating and reducing ketoisophorone to produce optically active [4R,6R]-4-hydroxy-2,6,6-trimethyl-cyclohexanone useful as an intermediate in the production of optically active carotenoids and intermediates in the production of these carotenoids.
摘要翻译： 一种用于发酵氢化和还原酮异二酮以制备光学活性的[4R，6R] -4-羟基-2,6,6-三甲基 - 环己酮的方法，其用作制备光学活性类胡萝卜素的中间体和这些类胡萝卜素生产中的中间体 。
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公开(公告)号：US3988205A
公开(公告)日：1976-10-26
申请号：US601770
申请日：1975-08-04
申请人： Walter Boguth , Hans Georg Wilhelm Leuenberger , Hans Johann Mayer , Erich Widmer , Reinhard Zell
发明人： Walter Boguth , Hans Georg Wilhelm Leuenberger , Hans Johann Mayer , Erich Widmer , Reinhard Zell
IPC分类号： C07C45/64 , C07C49/403 , C07C49/497 , C07F9/54 , C12P7/26 , C12D13/00
CPC分类号： C07C403/24 , C07C403/08 , C07C403/12 , C07C403/14 , C07C45/64 , C07C49/403 , C07C49/497 , C07F9/5428 , C12P7/26 , C07B2200/07 , C07C2101/14 , C07C2101/16 , Y10S435/822 , Y10S435/823 , Y10S435/828 , Y10S435/83 , Y10S435/831 , Y10S435/832 , Y10S435/848 , Y10S435/85 , Y10S435/853 , Y10S435/872 , Y10S435/873 , Y10S435/874 , Y10S435/882 , Y10S435/885 , Y10S435/886 , Y10S435/913 , Y10S435/921 , Y10S435/929 , Y10S435/931 , Y10S435/933 , Y10S435/939 , Y10S435/94 , Y10S435/944
摘要： A process for fermentatively hydrogenating and reducing ketoisophorone to produce optically active [4R,6R]-4-hydroxy-2,6,6-trimethyl-cyclohexanone useful as an intermediate in the production of optically active carotenoids and intermediates in the production of these carotenoids.
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公开(公告)号：US4323711A
公开(公告)日：1982-04-06
申请号：US205410
申请日：1980-11-10
申请人： Teodor Lukac , Erich Widmer , Reinhard Zell
发明人： Teodor Lukac , Erich Widmer , Reinhard Zell
IPC分类号： C07C403/08 , C07C45/65 , C07C45/71 , C07C49/713 , C07C67/00 , C07C401/00 , C07C403/00 , C07C403/24 , C07F9/54 , C07C45/62 , C07C45/00
CPC分类号： C07C403/24 , C07C403/04 , C07C403/08 , C07C45/65 , C07C45/71 , C07F9/5435 , C07C2101/16
摘要： A process for producing 3-(5-hydroxy-3-methyl-1,3-pentadienyl)-2,4,4-trimethyl-2-cyclohexen-1-one, an intermediate for canthaxanthin, by hydrogenation of 5-(2,6,6-trimethyl-3-oxo-cyclohexen-1-yl)-3-methyl-2-penten-4-yn-1-ol with zinc and a carboxylic acid.
摘要翻译： 3-（5-羟基-3-甲基-1,3-戊二烯基）-2,4,4-三甲基-2-环己烯-1-酮，角黄素的中间体，5-（2 ，6,6-三甲基-3-氧代 - 环己烯-1-基）-3-甲基-2-戊烯-4-基-1-醇与锌和羧酸反应。
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公开(公告)号：US4283559A
公开(公告)日：1981-08-11
申请号：US40625
申请日：1979-05-21
IPC分类号： C07C49/743 , C07B57/00 , C07C45/00 , C07C45/62 , C07C45/64 , C07C49/497 , C07C49/713 , C07C49/753 , C07C67/00 , C07C403/00 , C07D317/46 , C07D317/64 , C07F9/54 , C12P7/26
CPC分类号： C07C403/24 , C07C403/08 , C07C45/64 , C07C49/713 , C07C49/753 , C07D317/64 , C07F9/5435 , C12P7/26 , C07C2101/16
摘要： The compound 6-hydroxy-3-(5-hydroxy-3-methyl-1,3-pentadienyl)-2,4,4-trimethyl-2-cyclohexen-1-one useful as intermediate for producing the natural coloring agent astaxanthin as well as a method for synthesizing astaxanthin from this compound and synthesizing the compound from 2-hydroxyketo isophorone.
摘要翻译： 可用作生产天然着色剂虾青素的中间体的化合物6-羟基-3-（5-羟基-3-甲基-1,3-戊二烯基）-2,4,4-三甲基-2-环己烯-1-酮 以及从该化合物合成虾青素并从2-羟基酮异佛尔酮合成化合物的方法。
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9.发明授权
公开(公告)号：US4138289A
公开(公告)日：1979-02-06
申请号：US793093
申请日：1977-05-02
IPC分类号： C07D317/18 , C07C17/20 , C07C17/26 , C07C17/354 , C07C29/09 , C07C29/10 , C07C29/124 , C07C31/125 , C07C43/12 , C07C45/67 , C07C47/14 , C07C49/04 , C07C55/02 , C07C69/74 , C07D307/02 , C07D307/33 , C07D309/12 , C07D311/72 , C07D315/00 , C07F9/54 , C12P7/02 , C12P7/04 , C12P7/40 , C12P7/62 , C12P7/64 , C12R1/04 , C12R1/07 , C12R1/11 , C12R1/285 , C12R1/32 , C12R1/365 , C12R1/38 , C12R1/39 , C12R1/425 , C12R1/46 , C12R1/465 , C12R1/47 , C12R1/54 , C12R1/56 , C12R1/61 , C12R1/65 , C12R1/66 , C12R1/67 , C12R1/68 , C12R1/685 , C12R1/725 , C12R1/785 , C12R1/80 , C12R1/825 , C12R1/845 , C12R1/86 , C12R1/865 , C12R1/88 , C12D13/02
CPC分类号： C07D315/00 , C07C17/208 , C07C17/263 , C07C17/2635 , C07C17/354 , C07C29/095 , C07C29/10 , C07C29/124 , C07C45/673 , C07C47/14 , C07C49/04 , C07D309/12 , C07D311/72 , C07F9/5456 , C12P7/02 , C12P7/62 , C07B2200/07 , Y10S435/822 , Y10S435/839 , Y10S435/862 , Y10S435/866 , Y10S435/872 , Y10S435/876 , Y10S435/881 , Y10S435/882 , Y10S435/885 , Y10S435/887 , Y10S435/896 , Y10S435/899 , Y10S435/904 , Y10S435/906 , Y10S435/909 , Y10S435/911 , Y10S435/912 , Y10S435/917 , Y10S435/921 , Y10S435/931 , Y10S435/933 , Y10S435/936 , Y10S435/939 , Y10S435/94 , Y10S435/941 , Y10S435/942 , Y10S435/944
摘要： A process for asymmetrically hydrogenating through the use of microorganisms a double bond connected to tertiary carbon atom in an olefinic aliphatic compound to produce a tertiary, optically active aliphatic compound useful as an intermediate for optically active Vitamins E and K.
摘要翻译： 通过使用微生物将烯键式脂族化合物中与叔碳原子连接的双键不对称氢化的方法，以产生用作光学活性维生素E和K的中间体的叔，光学活性脂族化合物。
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公开(公告)号：US4405417A
公开(公告)日：1983-09-20
申请号：US458428
申请日：1983-01-17
申请人： Hansjorg Grass , Reinhard Zell
发明人： Hansjorg Grass , Reinhard Zell
IPC分类号： C07C403/08 , C07C67/00 , C07C401/00 , C07C403/00 , C07C403/24 , C07F9/54 , C25B3/04 , C25B3/00
CPC分类号： C07C403/24 , C07C403/08 , C07F9/5435 , C25B3/04 , C07C2101/16
摘要： A process for the manufacture of the novel compound of the formula ##STR1## from the compound of the formula ##STR2## is described. This process comprises cathodically reducing the compound of formula I in a basic, aqueous-organic solvent mixture.The compound of formula II is an intermediate in the manufacture of rhodoxanthin or zeaxanthin.
摘要翻译： 描述了从式（Ⅰ）化合物制备式“IMAGE”II的新型化合物的方法。 该方法包括在碱性水溶性有机溶剂混合物中阴离子还原式I化合物。 式II化合物是制备红萝黄素或玉米黄质的中间体。
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