Distributed injection catalytic partial oxidation process and apparatus for producing synthesis gas
    4.
    发明授权
    Distributed injection catalytic partial oxidation process and apparatus for producing synthesis gas 失效
    分布式注入催化部分氧化工艺和生产合成气的设备

    公开(公告)号:US06267912B1

    公开(公告)日:2001-07-31

    申请号:US08845700

    申请日:1997-04-25

    IPC分类号: C07C102

    摘要: A novel injector/reactor apparatus and an efficient process for the partial oxidation of light hydrocarbon gases, such as methane, to convert such gases to useful synthesis gas for recovery and/or subsequent hydrocarbon synthesis. Sources of a light hydrocarbon gas, such as methane, and oxygen or an oxygen-containing gas are preheated and pressurized and injected through an injector means at high velocity into admixture with each other in the desired relative proportions, at a plurality of mixing nozzles which are open to the catalytic partial oxidation reaction zone and are uniformly-spaced over the face of the injector means, to form a reactant gaseous premix having a pressure drop equal to at least about 3% of the lowest upstream pressure of either of said gases. The gaseous premix is injected in a time period which is less than its autoignition time, preferably less than 9 milliseconds, at a velocity between about 25 to 1000 feet/second, into a catalytic partial oxidation zone so that the gaseous premix reacts in the presence of the fixed catalyst to reduce the amounts of CO2, H2O and heat produced by the partial oxidation reaction, to form a useful syngas which is cooled and recovered.

    摘要翻译: 一种新颖的注射器/反应器装置以及用于部分氧化轻质烃气体(例如甲烷)的有效方法,以将这种气体转化成有用的合成气以用于回收和/或随后的烃合成。 来自诸如甲烷和氧气或含氧气体的轻质烃气体在多个混合喷嘴处被预热和加压并通过喷射器装置以高速度以所需的相对比例彼此混合, 对催化部分氧化反应区开放,并且在喷射器装置的表面上均匀间隔开,形成具有等于任一气体的最低上压压力的至少约3%的压降的反应物气态预混物。 将气体预混物在小于其自燃时间(优选小于9毫秒)的时间内以约25至1000英尺/秒的速度注入到催化部分氧化区中,使得气态预混物在存在下反应 的固定催化剂以减少CO 2,H 2 O的量和由部分氧化反应产生的热量,以形成冷却和回收的有用的合成气。

    Superheating atomizing steam with hot FCC feed oil
    8.
    发明授权
    Superheating atomizing steam with hot FCC feed oil 失效
    用热FCC原料油过热雾化蒸汽

    公开(公告)号:US06352639B2

    公开(公告)日:2002-03-05

    申请号:US09735779

    申请日:2000-12-13

    IPC分类号: C10G1100

    摘要: An atomizing gas, such as steam, and a hot fluid comprising a hot liquid to be atomized, are passed under pressure, through separate fluid conduits in a heat exchange means, in which the hot liquid heats the steam to a superheat temperature, by indirect heat exchange. The superheated steam is then injected into the hot fluid, which comprises a two-phase fluid comprising steam and the hot liquid, subsequent to the superheated steam injection. The two-phase fluid is passed through an atomizing means, such as an orifice, into a lower pressure atomizing zone, which causes the steam to expand and atomize the liquid into a spray of liquid droplets. The two-phase fluid is formed before or as a consequence of the superheated steam injection and is preferably steam-continuous when passed through the atomizing means. This process is useful for atomizing a hot feed oil for a fluid cat cracking (FCC) process.

    摘要翻译: 雾化气体,例如蒸汽,以及包含待雾化的热液体的热流体在压力下通过热交换装置中的分开的流体导管通过,其中热液体将蒸汽加热至过热温度,间接 热交换。 然后将过热蒸汽注入到热流体中,该热流体包括在过热蒸汽注入之后包括蒸汽和热液体的两相流体。 两相流体通过诸如孔口的雾化装置进入较低压力的雾化区,这使得蒸汽膨胀并将液体雾化成液滴喷雾。 两相流体在过热蒸汽注入之前或之后形成,并且优选在通过雾化装置时是蒸汽连续的。 该方法可用于雾化用于流动性猫裂解(FCC)方法的热进料油。

    Convectively cooled liner for a combustor
    9.
    发明授权
    Convectively cooled liner for a combustor 失效
    用于燃烧器的对流冷却衬套

    公开(公告)号:US5737922A

    公开(公告)日:1998-04-14

    申请号:US380777

    申请日:1995-01-30

    IPC分类号: F23R3/00 F02C7/12

    摘要: A combustor liner (2) for convectively cooling a combustor chamber (16) in a gas turbine (4) comprises a chamber wall (30) with an array of coolant channels (60) formed therein. Supply manifolds (50) are coupled to the coolant channel inlets for directing bypass air through the channels, where the bypass air removes heat from the chamber wall, and discharge manifolds (52) are coupled to the coolant channel outlets for discharging the heated bypass air to the turbine (10). The coolant channels are spaced and distributed throughout the combustor liner so that the coolant flows through a substantial portion of the liner. The coolant channels are minute channels with relatively short flow paths to minimize both the pressure drop and the quantity of bypass air required to cool the wall. In addition, the channels are completely enclosed within the chamber wall to significantly improve the heat transfer characteristics of the combustor liner. Because the chamber wall is cooled convectively, without bleeding air directly into the combustion chamber, the combustor liner is particularly suited for fuel-rich combustors, such as the first stage of a two stage low NOx combustor.

    摘要翻译: 用于对流地冷却燃气轮机(4)中的燃烧室(16)的燃烧器衬套(2)包括具有形成在其中的冷却剂通道(60)阵列的室壁(30)。 供应歧管(50)联接到冷却剂通道入口,用于引导旁路空气通过通道,其中旁路空气从室壁移除热量,并且排出歧管(52)联接到冷却剂通道出口,用于排出加热的旁路空气 到涡轮(10)。 冷却剂通道间隔开并分布在整个燃烧器衬套中,使得冷却剂流过衬套的大部分。 冷却剂通道是具有相对较短流动路径的微通道,以最小化冷却壁所需的压降和旁路空气量。 此外,通道被完全封闭在室壁内,以显着提高燃烧器衬套的传热特性。 由于腔壁对流冷却,不会直接将空气直接排入燃烧室,所以燃烧器衬套特别适用于富燃料燃烧器,例如两级低NOx燃烧器的第一级。

    System and method for regulating the temperature of cryogenic liquids
    10.
    发明授权
    System and method for regulating the temperature of cryogenic liquids 失效
    用于调节低温液体温度的系统和方法

    公开(公告)号:US5613366A

    公开(公告)日:1997-03-25

    申请号:US451092

    申请日:1995-05-25

    申请人: Leonard Schoenman

    发明人: Leonard Schoenman

    摘要: A relatively inexpensive system and method for regulating the temperature of a cryogenic liquid in a storage vessel (2), such as vehicle refueling station, comprises inner and outer walls (6, 8) defining a inner chamber (12) for housing the cryogenic liquid. To provide a variable thermal resistance around the inner chamber, a thermal control fluid is disposed within an insulation space (10) between the inner and outer walls. A fluid conduit (30) has an inlet and outlet in fluid communication with the chamber and a heat exchanger coil (36) disposed within the insulation space. A control valve (38) allows the cryogenic liquid to flow through the fluid conduit so that the cryogenic liquid is in heat exchange relationship with the thermal control gas as the liquid passes through the coil (i.e., the cryogenic liquid cools and condenses the thermal control gas to reduce the control gas pressure). The pressure of the control gas within the insulation space can be modulated to thereby control the heat flow into the inner chamber by controlling the flow rate of the cryogenic liquid through the fluid conduit.

    摘要翻译: 用于调节诸如车辆加油站的存储容器(2)中的低温液体的温度的相对便宜的系统和方法包括限定用于容纳低温液体的内室(12)的内壁和外壁(6,8) 。 为了在内腔周围提供可变的热阻,热控制流体设置在内壁和外壁之间的绝缘空间(10)内。 流体管道(30)具有与腔室流体连通的入口和出口以及设置在绝热空间内的热交换器线圈(36)。 控制阀(38)允许低温液体流过流体导管,使得当液体通过线圈时,低温液体与热控制气体处于热交换关系(即,低温液体冷却并冷凝热控制器 气体减少控制气体压力)。 可以调节绝缘空间内的控制气体的压力,从而通过控制通过流体导管的低温液体的流量来控制进入内室的热流。