公开(公告)号：US07122617B2

公开(公告)日：2006-10-17

申请号：US10627353

申请日：2003-07-25

申请人： Fumio Saitoh ,  Toru Kimura ,  Masayuki Tobita ,  Masatoshi Hasegawa

发明人： Fumio Saitoh ,  Toru Kimura ,  Masayuki Tobita ,  Masatoshi Hasegawa

IPC分类号： C08G69/26 ,  C08G69/28 ,  C08G63/44

CPC分类号： C08J5/18 ,  B29C67/00 ,  C08G73/18 ,  C08G73/22 ,  C08J2379/04 ,  C09K19/3809 ,  C09K2019/521 ,  G02F1/13378 ,  G02F2001/133715 ,  Y10T428/31725

摘要： The first film of the present invention is a film produced by solidifying a polybenzazole precursor that has been oriented in a given direction by the application of a magnetic or electric field. The second film of the present invention is a film produced by solidifying a polybenzazole that has been oriented in a given direction by the application of a magnetic or electric field. The first and second films have a strong anisotropy.

摘要翻译： 本发明的第一膜是通过施加磁场或电场使已经沿给定方向取向的聚吲哚前体固化而制得的膜。 本发明的第二膜是通过施加磁场或电场使已经在给定方向取向的聚苯并吡唑固化而制得的膜。 第一和第二片具有很强的各向异性。

公开(公告)号：US20050249961A1

公开(公告)日：2005-11-10

申请号：US10627353

申请日：2003-07-25

申请人： Fumio Saitoh ,  Toru Kimura ,  Masayuki Tobita ,  Masatoshi Hasegawa

发明人： Fumio Saitoh ,  Toru Kimura ,  Masayuki Tobita ,  Masatoshi Hasegawa

IPC分类号： C08J5/18 ,  B29C67/00 ,  C08G73/06 ,  C08G73/18 ,  C08G73/22 ,  G02F1/1337 ,  B32B27/08

CPC分类号： C08J5/18 ,  B29C67/00 ,  C08G73/18 ,  C08G73/22 ,  C08J2379/04 ,  C09K19/3809 ,  C09K2019/521 ,  G02F1/13378 ,  G02F2001/133715 ,  Y10T428/31725

摘要： The first film of the present invention is a film produced by solidifying a polybenzazole precursor that has been oriented in a given direction by the application of a magnetic or electric field. The second film of the present invention is a film produced by solidifying a polybenzazole that has been oriented in a given direction by the application of a magnetic or electric field. The first and second films have a strong anisotropy.

摘要翻译： 本发明的第一膜是通过施加磁场或电场使已经沿给定方向取向的聚吲哚前体固化而制得的膜。 本发明的第二膜是通过施加磁场或电场使已经在给定方向取向的聚苯并吡唑固化而制得的膜。 第一和第二片具有很强的各向异性。

公开(公告)号：US07540991B2

公开(公告)日：2009-06-02

申请号：US11173721

申请日：2005-07-01

申请人： Naoyuki Shimoyama ,  Fumio Saitoh ,  Toru Kimura ,  Masayuki Tobita

发明人： Naoyuki Shimoyama ,  Fumio Saitoh ,  Toru Kimura ,  Masayuki Tobita

IPC分类号： H05B6/00

CPC分类号： H01M10/0565 ,  C08J5/2256 ,  C08J2379/06 ,  H01M8/1027 ,  H01M8/103 ,  H01M8/1081 ,  H01M8/1086 ,  H01M10/0525 ,  H01M2300/0082 ,  Y02P70/56

摘要： The present invention provides an electrolyte membrane formed of an ion conductive composition. Said composition contains a liquid crystalline polymer having an ionic dissociative group. Molecular chains of the liquid crystalline polymer are orientated in a specific direction. The degree of orientation α of the liquid crystalline polymer is in a range of 0.45 or more and less than 1, as defined by equation (1) as follows, Degree of orientation α=(180−Δβ)/180  (1), wherein Δβ is a full width at half maximum of a peak in an X-ray diffraction intensity distribution pattern obtained by measuring an intensity distribution from 0 to 360 degrees in the azimuthal angle direction, at a peak scattering angle, in an X-ray diffraction image of the electrolyte membrane. Ionic conductivity in a thickness direction of the membrane is higher than the ionic conductivity in a direction parallel to a surface of the membrane. The present invention also provides a method for manufacturing an electrolyte membrane formed of an ion conductive composition.

摘要翻译： 本发明提供由离子导电组合物形成的电解质膜。 所述组合物含有具有离子解离基团的液晶聚合物。 液晶聚合物的分子链沿特定方向取向。 如式（1）所定义，液晶聚合物的取向度α在0.45以上且小于1的范围内，<？在线式说明=“在线式”末端= “lead”？>取向度α=（180-Deltabeta）/ 180（1），<？in-line-formula description =“In-line formula”end =“tail”？>其中Deltabeta是 在电解质膜的X射线衍射图像中，以峰值散射角测量方位角方向的0〜360度的强度分布而得到的X射线衍射强度分布图案中的峰的半值最大值。 膜的厚度方向上的离子传导率在平行于膜的表面的方向上高于离子导电率。 本发明还提供一种由离子导电组合物形成的电解质膜的制造方法。

公开(公告)号：US20060004112A1

公开(公告)日：2006-01-05

申请号：US11173721

申请日：2005-07-01

申请人： Naoyuki Shimoyama ,  Fumio Saitoh ,  Toru Kimura ,  Masayuki Tobita

发明人： Naoyuki Shimoyama ,  Fumio Saitoh ,  Toru Kimura ,  Masayuki Tobita

IPC分类号： C08J5/20 ,  H01M8/10

CPC分类号： H01M10/0565 ,  C08J5/2256 ,  C08J2379/06 ,  H01M8/1027 ,  H01M8/103 ,  H01M8/1081 ,  H01M8/1086 ,  H01M10/0525 ,  H01M2300/0082 ,  Y02P70/56

摘要： The present invention provides an electrolyte membrane formed of an ion conductive composition. Said composition contains a liquid crystalline polymer having an ionic dissociative group. Molecular chains of the liquid crystalline polymer are orientated in a specific direction. The degree of orientation α of the liquid crystalline polymer is in a range of 0.45 or more and less than 1, as defined by equation (1) as follows; Degree of orientation α=(180−ΔB/180) (1), wherein ΔB is a full width at half maximum of a peak in an X-ray diffraction intensity distribution pattern obtained by measuring an intensity distribution from 0 to 360 degrees in the azimuthal angle direction, at a peak scattering angle, in an X-ray diffraction image of the electrolyte membrane. Ionic conductivity in a thickness direction of the membrane is higher than the ionic conductivity in a direction parallel to a surface of the membrane. The present invention also provides a method for manufacturing an electrolyte membrane formed of an ion conductive composition.

摘要翻译： 本发明提供由离子导电组合物形成的电解质膜。 所述组合物含有具有离子解离基团的液晶聚合物。 液晶聚合物的分子链沿特定方向取向。 液晶聚合物的取向度为如下式（1）所定义的0.45以上且小于1的范围; 取向度α=（180-ΔB/ 180）（1），其中DeltaB是通过测量从0到360度的强度分布而获得的X射线衍射强度分布图中的峰的半峰全宽 在电解质膜的X射线衍射图像中以峰值散射角度的方位角方向。 膜的厚度方向上的离子传导率在平行于膜的表面的方向上高于离子导电率。 本发明还提供一种由离子导电组合物形成的电解质膜的制造方法。

公开(公告)号：US20050156356A1

公开(公告)日：2005-07-21

申请号：US11040253

申请日：2005-01-19

申请人： Fumio Saitoh ,  Toru Kimura ,  Masayuki Tobita

发明人： Fumio Saitoh ,  Toru Kimura ,  Masayuki Tobita

IPC分类号： B29C67/00 ,  B29C67/24 ,  C08G73/00 ,  C08G73/06 ,  C08G73/18 ,  C08G73/22 ,  C08G75/32 ,  C08J5/18 ,  C09K19/02 ,  C09K19/38 ,  D01D1/10 ,  C08G63/02

CPC分类号： B29C67/24 ,  C08G73/18 ,  C08G73/22 ,  C08J5/18 ,  C08J2379/04 ,  C09K19/3823

摘要： An article formed of polybenzazole comprising at least one repeating unit represented by one of specific formulas is provided. In the article, the molecular chains of said polybenzazole are orientated in a specific direction. In one aspect of the article, a degree of orientation A of the molecular chains is 0.6 or more and less than 1. In another aspect of the article, anisotropic magnetic susceptibility Δχ of the article is in a range of 1.0×10−8 to 1.0×10−6 [emu/g]. The present invention also directs to methods for producing the above-described articles. The methods comprise steps of preparing a liquid containing said polybenzazole, shaping a liquid containing said polybenzazole into a desired shape, applying one of magnetic and electric fields in a specific direction to the liquid so as to orientate the molecular chains of said polybenzazole therein in the specific direction, solidifying the liquid in the desired shape while the orientation of the molecular chains is maintained.

摘要翻译： 提供由包含至少一个由特定式表示的重复单元的聚吲哚形成的制品。 在该文章中，所述聚吲哚的分子链在特定方向上取向。 在制品的一个方面，分子链的取向度为0.6以上且小于1.在制品的另一方面，制品的各向异性磁化率Deltachi在1.0×10 -6以上的范围内， 8至1.0×10 -6 [emu / g]。 本发明还涉及制造上述制品的方法。 所述方法包括以下步骤：制备含有所述聚吲哚的液体，将含有所述聚吲哚的液体成形为期望的形状，将特定方向的磁场和电场中的一个施加到液体中，以使其中的所述聚吲哚的分子链在 在保持分子链的取向的同时将液体固化成所需形状。

公开(公告)号：US20050058805A1

公开(公告)日：2005-03-17

申请号：US10664988

申请日：2003-09-17

申请人： Toru Kimura ,  Naoyuki Shimoyama ,  Masayuki Tobita

发明人： Toru Kimura ,  Naoyuki Shimoyama ,  Masayuki Tobita

IPC分类号： B29C70/08 ,  B29C70/14 ,  B32B5/02 ,  B32B3/00 ,  B32B9/00

CPC分类号： B29C70/14 ,  B29C70/081 ,  Y10T428/24124 ,  Y10T428/24994 ,  Y10T442/20 ,  Y10T442/3715 ,  Y10T442/643 ,  Y10T442/659

摘要： A polymer composite molded body contains a fiber and at least one sheet of fiber cloth in a polymer matrix. The fiber cloth is disposed in the polymer composite molded body along a surface thereof. A polymer composition containing the fiber and polymer matrix is impregnated into the fiber cloth. Then a magnetic field is applied to the polymer composition to orient the fibers in the composition in a direction crossing with the fiber cloth. Then the polymer composition is solidified to obtain the polymer composite molded body.

摘要翻译： 聚合物复合成型体在聚合物基体中含有纤维和至少一层纤维布。 纤维布沿其表面设置在聚合物复合成型体中。 将含有纤维和聚合物基质的聚合物组合物浸渍到纤维布中。 然后将磁场施加到聚合物组合物上以使纤维在与纤维布交叉的方向上定向组合物中的纤维。 然后将聚合物组合物固化，得到聚合物复合成型体。

公开(公告)号：US20070116938A1

公开(公告)日：2007-05-24

申请号：US10582558

申请日：2005-02-18

申请人： Masayuki Tobita ,  Toru Kimura ,  Hisashi Aoki ,  Naoyuki Shimoyama ,  Tsukasa Ishigaki ,  Mitsukazu Ochi ,  Miyuki Harada

发明人： Masayuki Tobita ,  Toru Kimura ,  Hisashi Aoki ,  Naoyuki Shimoyama ,  Tsukasa Ishigaki ,  Mitsukazu Ochi ,  Miyuki Harada

IPC分类号： D04H13/00

CPC分类号： C08G59/28 ,  B32B15/08 ,  B32B15/092 ,  B32B15/20 ,  B32B27/04 ,  B32B27/18 ,  B32B27/38 ,  B32B2250/03 ,  B32B2250/40 ,  B32B2274/00 ,  B32B2307/202 ,  B32B2307/206 ,  B32B2457/08 ,  C08G59/5033 ,  C08J5/24 ,  C08J2363/00 ,  C08K7/02 ,  H05K1/0366 ,  H05K2201/0129 ,  H05K2201/0141 ,  H05K2201/0287 ,  H05K2201/029 ,  H05K2201/068 ,  Y10T428/249924 ,  C08L63/00

摘要： A thermoplastic polymer composite formed article or a thermoplastic polymer composite formed article formed from a thermoplastic polymer or a thermoplastic polymer and a fiber, wherein the fiber is arranged along a first plane and the molecular chains of the thermoplastic polymer or thermoplastic polymer is oriented in the direction intersecting with the first plane, and the molecular chains of the thermoplastic polymer or thermoplastic polymer has a degree (a) of orientation in a range of 0.5 or more and less than 1.0, and wherein the thermal expansion coefficients of said formed article in the direction along the first plane and in the direction intersecting with the first plane are both 5×10−6 to 50×10−6 (/K), and the difference between the thermal expansion coefficient in the direction along the first plane and the thermal expansion coefficient in the direction intersecting with the first plane is 30×10−6 (/K) or less.

摘要翻译： 由热塑性聚合物或热塑性聚合物和纤维形成的热塑性聚合物复合成型制品或热塑性聚合物复合成型制品，其中纤维沿着第一平面布置，热塑性聚合物或热塑性聚合物的分子链定向于 方向与第一平面相交，并且热塑性聚合物或热塑性聚合物的分子链具有在0.5以上且小于1.0的范围内的取向度（a），并且其中所述成型制品的热膨胀系数在 沿着第一平面和与第一平面相交的方向的方向均为5×10 -6〜50×10 -6（/ K），热膨胀系数 沿着第一平面的方向和与第一平面相交的方向的热膨胀系数为30×10 -6（/ K）以下。

公开(公告)号：US07347955B2

公开(公告)日：2008-03-25

申请号：US10686384

申请日：2003-10-14

申请人： Masayuki Tobita ,  Naoyuki Shimoyama ,  Tsukasa Ishigaki ,  Hisashi Aoki ,  Toru Kimura ,  Tsunehisa Kimura ,  Masafumi Yamato

发明人： Masayuki Tobita ,  Naoyuki Shimoyama ,  Tsukasa Ishigaki ,  Hisashi Aoki ,  Toru Kimura ,  Tsunehisa Kimura ,  Masafumi Yamato

IPC分类号： C09K19/52 ,  C09K19/38 ,  C09K19/54 ,  B32B27/94

CPC分类号： C09K19/3809 ,  C09K19/38 ,  C09K19/3838 ,  C09K19/52 ,  Y10T428/24994 ,  Y10T428/249942

摘要： A mold product comprising liquid crystal composition for conducting heat. The liquid crystal composition contains liquid crystal polymer having an orientation degree α obtained by equation 1 below: Orientation degree α=(180−Δβ)/180 equation 1 In equation 1, Δβ is a half width in the intensity distribution obtained by fixing peak scattering angle in X-ray diffraction measurement and by varying the azimuth angle from 0 to 360 degrees, and orientation degree α is in a range between 0.5 and 1.0.

摘要翻译： 一种包含用于传导热量的液晶组合物的模具产品。 该液晶组合物含有具有以下等式1得到的取向度α的液晶聚合物：<？in-line-formula description =“In-line formula”end =“lead”？>取向度α=（180-Deltabeta） 方程式1 <？in-line-formula description =“In-line Formulas”end =“tail”？>在等式1中，Deltabeta是通过固定X射线衍射中的峰值散射角得到的强度分布的半宽度 并且通过将方位角从0变化到360度，并且取向度α在0.5和1.0之间的范围内。

公开(公告)号：US07189778B2

公开(公告)日：2007-03-13

申请号：US10623860

申请日：2003-07-21

申请人： Masayuki Tobita ,  Naoyuki Shimoyama ,  Tsukasa Ishigaki ,  Toru Kimura

发明人： Masayuki Tobita ,  Naoyuki Shimoyama ,  Tsukasa Ishigaki ,  Toru Kimura

IPC分类号： C08J3/20 ,  B32B27/04 ,  B29D7/01 ,  C09K19/52 ,  C09K19/38

CPC分类号： B29C55/00 ,  B29C70/62 ,  B29C70/88 ,  B29K2105/18 ,  B29K2995/0013 ,  C09K19/3809 ,  C09K2019/521 ,  Y10T428/1352 ,  Y10T428/24994 ,  Y10T428/249945

摘要： A thermally conductive polymer molded article formed by molding a thermally conductive composition which comprises a liquid crystalline polymer and thermally conductive filler having magnetic anisotropy, wherein the liquid crystalline polymer and the thermally conductive filler are oriented in a predetermined direction by a magnetic field. The thermally conductive composition contains 100 parts by weight of the liquid crystalline polymer and 5 to 800 parts by weight of the thermally conductive filler having magnetic anisotropy. The thermally conductive filler has a thermal conductivity in at least one direction higher than the thermal conductivity of the liquid crystalline polymer.

摘要翻译： 一种导热聚合物模制品，其通过模制包含液晶聚合物和具有磁各向异性的导热填料的导热组合物而形成，其中液晶聚合物和导热填料通过磁场沿预定方向取向。 导热组合物含有100重量份液晶聚合物和5至800重量份具有磁各向异性的导热填料。 导热填料在比液晶聚合物的热导率高至少一个方向上具有导热性。

公开(公告)号：US07079405B2

公开(公告)日：2006-07-18

申请号：US10617517

申请日：2003-07-11

申请人： Masayuki Tobita ,  Toru Kimura ,  Naoyuki Shimoyama ,  Tsukasa Ishigaki

发明人： Masayuki Tobita ,  Toru Kimura ,  Naoyuki Shimoyama ,  Tsukasa Ishigaki

IPC分类号： H02M3/335

CPC分类号： C09K19/3809 ,  B29C70/88 ,  B29C71/00 ,  B29C71/0081 ,  B29K2077/00 ,  B29K2077/10 ,  B29K2105/0079 ,  B29K2995/0013

摘要： A thermal conductive polymer molded article is formed by molding a thermotropic liquid crystalline composition comprised mainly of a thermotropic liquid crystalline polymer, wherein the thermal conductive polymer molded article is formed by applying a magnetic field or an electric field to the thermotropic liquid crystalline composition melted by heating so that the thermal conductive polymer molded article has a first thermal conductivity (λ1) higher than a second thermal conductivity (λ2) of a molded article formed by molding the thermotropic liquid crystalline polymer without the application of the field. The thermal conductive polymer molded article preferably has a first thermal conductivity (λ1) of between 0.7 and 20 W/(m·K). Preferably, the thermotropic liquid crystalline polymer comprises at least one polymer selected from (A) a wholly aromatic polyester and (B) a wholly aromatic polyester amide.

摘要翻译： 导热聚合物模制品通过模制一种主要由热致液晶聚合物组成的热致液晶组合物而形成，其中通过向由热致液晶组合物熔化的热致变液晶组合物施加磁场或电场而形成导热聚合物模塑制品 加热，使得导热聚合物模塑制品具有比通过模塑成型制成的模塑制品的第二热导率（λ/ 2> 2）高的第一热导率（λ<1/2） 热致液晶聚合物无应用领域。 导热聚合物模塑制品优选具有0.7至20W /（m.K）之间的第一热导率（λ<1/2）。 优选地，热致液晶聚合物包含至少一种选自（A）全芳族聚酯和（B）全芳族聚酯酰胺的聚合物。