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249 条记录 (耗时 0.041 秒)

    Catalyst and process for oxychlorination of ethylene to EDC
    1.
    发明授权
    Catalyst and process for oxychlorination of ethylene to EDC 失效
    催化剂和乙烯氧氯化为EDC的方法

    公开(公告)号：US5382726A

    公开(公告)日：1995-01-17

    申请号：US156142

    申请日：1993-11-22

    申请人： George H. Young ,  Joseph A. Cowfer ,  Victor J. Johnston

    发明人： George H. Young ,  Joseph A. Cowfer ,  Victor J. Johnston

    IPC分类号： B01J23/78 ,  B01J23/83 ,  B01J27/138 ,  C07B61/00 ,  C07C17/156 ,  C07C19/045

    CPC分类号： B01J23/83 ,  C07C17/156

    摘要： The subject invention relates to catalyst compositions for oxychlorination of ethylene to produce 1,2-dichloroethane. The catalysts comprise copper chloride, at least one alkali metal, at least one rare earth metal, and at least one Group IIA metal on a high surface area support for fluid bed applications or on a high or low surface area support for fixed bed applications. The catalyst compositions are prepared by depositing the metals on a support. The use of the catalyst compositions of the invention in the oxychlorination of ethylene to EDC results in high percent ethylene efficiency, high EDC product purity and high percent HCl conversion without exhibiting catalyst stickiness. A process for oxychlorination of ethylene to produce 1,2-dichloroethane is also disclosed. The process relies on contacting a mixture of ethylene, oxygen or oxygen containing gas and hydrogen chloride with a fixed or fluidized catalyst composition in a reaction zone and recovering 1,2-dichloroethane from the effluents of the reaction zone.

    摘要翻译： 本发明涉及乙烯氧氯化以产生1,2-二氯乙烷的催化剂组合物。 催化剂包括氯化铜，至少一种碱金属，至少一种稀土金属和高表面积上的至少一种IIA族金属，用于流化床应用或用于固定床应用的高表面或低表面积。 通过将金属沉积在载体上来制备催化剂组合物。 使用本发明的催化剂组合物将乙烯氧氯化成EDC导致乙烯效率高，高EDC产物纯度和高HCl HCl转化率而不显示催化剂粘性。 还公开了乙烯氧氯化生产1,2-二氯乙烷的方法。 该方法依靠将乙烯，含氧气或含氧气体和氯化氢的混合物与固定或流化催化剂组合物在反应区中接触并从反应区的流出物回收1,2-二氯乙烷。

    Catalyst and process for oxychlorination of ethylene to EDC
    2.
    发明授权
    Catalyst and process for oxychlorination of ethylene to EDC 失效
    催化剂和乙烯氧氯化为EDC的方法

    公开(公告)号：US5292703A

    公开(公告)日：1994-03-08

    申请号：US920721

    申请日：1992-07-28

    申请人： George H. Young ,  Joseph A. Cowfer ,  Victor J. Johnston

    发明人： George H. Young ,  Joseph A. Cowfer ,  Victor J. Johnston

    IPC分类号： B01J23/78 ,  B01J23/83 ,  B01J27/138 ,  C07B61/00 ,  C07C17/156 ,  C07C19/045 ,  B01J23/72 ,  B01J23/10

    CPC分类号： B01J23/83 ,  C07C17/156

    摘要： The subject invention relates to catalyst compositions for oxychlorination of ethylene to produce 1,2-dichloroethane. The catalysts comprise copper chloride, at least one alkali metal, at least one rare earth metal, and at least one Group IIA metal on a high surface area support for fluid bed applications or on a high or low surface area support for fixed bed applications. The catalyst compositions are prepared by depositing the metals on a support. The use of the catalyst compositions of the invention in the oxychlorination of ethylene to EDC results in high percent ethylene efficiency, high EDC product purity and high percent HCl conversion without exhibiting catalyst stickiness. A process for oxychlorination of ethylene to produce 1,2-dichloroethane is also disclosed. The process relies on contacting a mixture of ethylene, oxygen or oxygen containing gas and hydrogen chloride with a fixed or fluidized catalyst composition in a reaction zone and recovering 1,2-dichloroethane from the effluents of the reaction zone.

    摘要翻译： 本发明涉及乙烯氧氯化以产生1,2-二氯乙烷的催化剂组合物。 催化剂包括氯化铜，至少一种碱金属，至少一种稀土金属和高表面积上的至少一种IIA族金属，用于流化床应用或用于固定床应用的高表面或低表面积。 通过将金属沉积在载体上来制备催化剂组合物。 使用本发明的催化剂组合物将乙烯氧氯化成EDC导致乙烯效率高，高EDC产物纯度和高HCl HCl转化率而不显示催化剂粘性。 还公开了乙烯氧氯化生产1,2-二氯乙烷的方法。 该方法依靠将乙烯，含氧气或含氧气体和氯化氢的混合物与固定或流化催化剂组合物在反应区中接触并从反应区的流出物回收1,2-二氯乙烷。

    Oxychlorination process
    3.
    发明授权
    Oxychlorination process 失效
    氧氯化过程

    公开(公告)号：US5600043A

    公开(公告)日：1997-02-04

    申请号：US411023

    申请日：1995-03-27

    申请人： Victor J. Johnston ,  Joseph A. Cowfer

    发明人： Victor J. Johnston ,  Joseph A. Cowfer

    IPC分类号： C07C17/156 ,  C07C17/15 ,  C07C17/154

    CPC分类号： C07C17/156

    摘要： The subject invention relates to a process for oxychlorination of ethylene to produce 1,2-dichloroethane. The process comprises contacting a mixture of ethylene, oxygen or oxygen containing gas and hydrogen chloride with a fixed or fluidized catalyst composition in a reaction zone and recovering 1,2-dichloroethane from the effluents of the reaction zone.The invention is embodied in a process for the oxychlorination of ethylene to produce 1,2-dichloroethane by contacting a mixture of ethylene, oxygen containing gas and hydrogen chloride with a catalyst composition in a reaction zone and recovering 1,2-dichloroethane from the effluents of the reaction zone the process comprising introducing ethylene, HCl and oxygen containing gas into said reaction zone in a ratio of 1.8 and 2.2 moles of HCl per mole of ethylene and from 0.5 to 1 mole of oxygen per mole of ethylene, the oxychlorination process taking place at a temperature of from 215.degree. C. to 230.degree. C., ethylene conversion on a weight basis is at 99% or higher and the mixture is contacted with a catalyst including a support which has deposited thereon a combination of metal chloride salts, the combination consisting essentially of from 2 to 8% copper, from 0.2 to 2% potassium and from 0.01 to 0.19% magnesium, all percentages expressed as the metals on a weight percent basis.

    摘要翻译： 本发明涉及乙烯氧氯化生产1,2-二氯乙烷的方法。 该方法包括将乙烯，含氧气或含氧气体和氯化氢的混合物与固定或流化催化剂组合物在反应区中接触并从反应区的流出物回收1,2-二氯乙烷。 本发明体现在通过使乙烯，含氧气体和氯化氢的混合物与催化剂组合物在反应区中接触并从流出物回收1,2-二氯乙烷的乙烯氧氯化生产1,2-二氯乙烷的方法中 的反应区，该方法包括以每摩尔乙烯1.8至2.2摩尔HCl /摩尔乙烯和0.5至1摩尔氧/摩尔乙烯的比例将乙烯，HCl和含氧气体引入所述反应区，所述氧氯化方法 在215℃-230℃的温度下放置，乙烯基于重量的转化率为99％以上，并将混合物与包含沉积有金属氯化物盐的载体的催化剂接触， 该组合基本上由2至8％的铜，0.2至2％的钾和0.01至0.19％的镁组成，所有百分比以重量百分数表示为金属。

    Chemisorption of ethyl acetate during hydrogenation of acetic acid to ethanol
    6.
    发明授权
    Chemisorption of ethyl acetate during hydrogenation of acetic acid to ethanol 有权
    在乙酸氢化成乙醇期间乙酸乙酯的化学吸附

    公开(公告)号：US09050585B2

    公开(公告)日：2015-06-09

    申请号：US13371064

    申请日：2012-02-10

    申请人： Zhenhua Zhou ,  Heiko Weiner ,  Dheeraj Kumar ,  Xiaoyan Tu ,  Victor J. Johnston ,  Radmila Jevtic

    发明人： Zhenhua Zhou ,  Heiko Weiner ,  Dheeraj Kumar ,  Xiaoyan Tu ,  Victor J. Johnston ,  Radmila Jevtic

    IPC分类号： C07C27/04 ,  B01J23/89 ,  C07C29/149 ,  C07C67/56 ,  C07C31/08 ,  B01J37/02 ,  B01J37/00

    CPC分类号： B01J23/8993 ,  B01J23/8966 ,  B01J23/898 ,  B01J37/0018 ,  B01J37/0201 ,  B01J37/0205 ,  C07C29/149 ,  C07C31/08 ,  C07C67/56 ,  C07C69/14

    摘要： A hydrogenation catalyst and process using the catalyst for converting a mixture comprising acetic acid and ethyl acetate to ethanol at a first temperature, and the catalyst desorbs ethyl acetate, in the absence of hydrogen, at a second temperature that is greater than the first temperature. The catalyst has a suitable chemisorption of ethyl acetate at the first temperature in the absence of hydrogen. In one embodiment, the first temperature ranges from 125° C. to 350° C. and the second temperature ranges from 300° C. to 600° C. The catalyst comprises one or more active metals or oxide thereof on a support that comprises tungsten or an oxide thereof. The one or more active metals are selected from the group consisting of cobalt, copper, gold, iron, nickel, palladium, platinum, iridium, osmium, rhenium, rhodium, ruthenium, tin, zinc, lanthanum, cerium, manganese, chromium, vanadium, and molybdenum.

    摘要翻译： 一种氢化催化剂和在第一温度下将包含乙酸和乙酸乙酯的混合物转化成乙醇的催化剂的方法，催化剂在不存在氢气的情况下在大于第一温度的第二温度下解吸乙酸乙酯。 在不存在氢气的情况下，催化剂在第一温度下具有适当的乙酸乙酯化学吸附。 在一个实施方案中，第一温度范围为125℃至350℃，第二温度范围为300℃至600℃。催化剂在包含钨的载体上包含一种或多种活性金属或其氧化物 或其氧化物。 一种或多种活性金属选自钴，铜，金，铁，镍，钯，铂，铱，锇，铼，铑，钌，锡，锌，镧，铈，锰，铬，钒 ，和钼。