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公开(公告)号：US4064198A
公开(公告)日：1977-12-20
申请号：US679021
申请日：1976-04-21
IPC分类号： C08F255/02 , C08F263/04 , C08F265/04
CPC分类号： C08F255/02
摘要： Process for the manufacture of shaped articles of a mixture of polystyrene and a copolymer of ethylene with vinyl ester, acrylate or methacrylate. To this end, the said copolymers having a content of from 3 to 40% by weight of unsaturated ester are reacted with monomeric styrene in aqueous suspension in the presence of free-radical polymerization initiators. Whereas a portion of the styrene used is directly grafted onto the ethylene copolymer, the remainder of the polymerized styrene is present in a finely divided state as a homopolymer beside or within the grafted ethylene copolymer. There are obtained homogeneous shaped articles having a styrene content of more than 50% by weight.
摘要翻译： 用于制造聚苯乙烯和乙烯与乙烯基酯，丙烯酸酯或甲基丙烯酸酯的共聚物的混合物的成形制品的方法。 为此，所述具有3至40重量％不饱和酯含量的共聚物在自由基聚合引发剂存在下与含水悬浮液中的单体苯乙烯反应。 而使用的苯乙烯的一部分直接接枝到乙烯共聚物上，其余的聚合苯乙烯在接枝乙烯共聚物旁边或内部作为均聚物以细分的状态存在。 得到苯乙烯含量大于50重量％的均匀成型制品。
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公开(公告)号：US3949019A
公开(公告)日：1976-04-06
申请号：US497572
申请日：1974-08-15
IPC分类号： C08F255/00 , C08F255/02 , C08F265/04 , C08L23/26
CPC分类号： C08F255/02
摘要： Process for the manufacture of graft polymers from copolymers of ethylene with vinyl esters, acrylates or methacrylates by grafting an ethylenically unsaturated carboxylic acid thereto in the presence of a free-radical polymerization initiator. Homogeneous graft copolymers are obtained from which sheeting can be made. To this end, the unsaturated carboxylic acid is first caused to diffuse into the copolymer and the mixture is then extruded at temperatures above the crystallite melting point of the ethylene copolymer.
摘要翻译： 通过在自由基聚合引发剂存在下将乙烯基不饱和羧酸接枝到乙烯基酯，丙烯酸酯或甲基丙烯酸酯的共聚物上来制备接枝聚合物的方法。 得到均匀的接枝共聚物，可从中制备片材。 为此，首先使不饱和羧酸扩散到共聚物中，然后在高于乙烯共聚物的微晶熔点的温度下挤出该混合物。
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3.发明授权Extrudable foamable composition comprising an olefin polymer, a styrene polymer and a hydrogenated styrene butadiene block copolymer 失效包含烯烃聚合物，苯乙烯聚合物和氢化苯乙烯丁二烯嵌段共聚物的可挤出可发泡组合物
公开(公告)号：US4020025A
公开(公告)日：1977-04-26
申请号：US686901
申请日：1976-05-17
CPC分类号： C08J9/0061 , C08J2323/02 , C08J2325/02 , C08J2423/02 , C08J2425/02 , C08J2425/10 , Y10S264/05 , Y10S264/18
摘要： Foams of mixtures of polyolefins and styrene polymers are produced by mixing the polymers with low-boiling expanding agents in the presence of a hydrogenated styrene/butadiene block polymer or a graft polymer of styrene on a polyolefin at temperatures above the softening point of the polymer mixture and under a pressure which prevents foaming of the mixture, followed by extrusion of the foamable mixture into a zone of lower pressure. The resulting foams are resistant to organic solvents.
摘要翻译： 聚烯烃和苯乙烯聚合物的混合物的泡沫是通过在高于聚合物混合物的软化点的温度下在氢化苯乙烯/丁二烯嵌段聚合物或苯乙烯的接枝聚合物存在下将聚合物与低沸点发泡剂混合而制得的 并且在防止混合物起泡的压力下，然后将可发泡混合物挤出到较低压力的区域中。 所得泡沫材料耐有机溶剂。
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公开(公告)号：US3992341A
公开(公告)日：1976-11-16
申请号：US573164
申请日：1975-04-30
CPC分类号： D01F6/46
摘要： Filaments and fibers based on polypropylene or copolymers thereof having a content of from 10 to 90% by weight of bitumen and a process for their manufacture, in which a mixture based on polypropylene or copolymers thereof and containing from 10 to 90% by weight of bitumen is melt-spun and drawn. The filaments and fibers produced in the manner of the invention are suitable for the production of woven and non-woven fabrics for insulating purposes and carpet underlays.
摘要翻译： 基于聚丙烯的纤维和纤维或其共聚物，其含量为沥青的10至90重量％及其制造方法，其中基于聚丙烯或其共聚物的混合物含有10至90重量％的沥青 被熔纺并拉伸。 以本发明的方式生产的长丝和纤维适于生产用于绝缘目的的织造和非织造织物以及地毯衬垫。
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公开(公告)号：US3998912A
公开(公告)日：1976-12-21
申请号：US619782
申请日：1975-10-06
IPC分类号： C08F255/00 , C08F255/02 , C08J7/16 , C08F263/04 , C08F265/02 , C08F265/04
CPC分类号： C08J7/16 , C08F255/02 , C08J2323/08
摘要： Unsaturated carboxylic acids are grafted onto copolymers of ethylene and carboxylates. Carboxylic acid containing initiator is caused to diffuse into shaped elements of the copolymers, polymerization then being carried to completion by heating. The products exhibit no fish eyes and are highly suitable for sheet manufacture.
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6.发明授权Preparation of finely divided polyolefin molding materials containing conductive carbon black, and their use for the production of moldings 失效制备含有导电炭黑的细碎聚烯烃成型材料，以及它们用于生产模制品的用途
公开(公告)号：US4287117A
公开(公告)日：1981-09-01
申请号：US107905
申请日：1979-12-28
申请人： Rainer Theysohn , Gerhard Zeitler , Frank Weiss , Hans Willing , Erhard Seiler
发明人： Rainer Theysohn , Gerhard Zeitler , Frank Weiss , Hans Willing , Erhard Seiler
CPC分类号： C08J3/203 , B29C70/882 , H01B1/24 , B29K2023/06 , B29K2995/0005 , C08J2323/02
摘要： A process for the preparation of finely divided polyolefin molding materials from 100 parts by weight of polyolefin and from 1 to 30 parts by weight of a conductive carbon black, with or without other additives, wherein the mixture of polyolefin powder and carbon black is compounded, in a first stage, until the crystallite melting point of the polyolefin is reached, and is then brought, in a second stage, to a temperature which is from 3.degree. to 40.degree. C. above the said crystallite melting point, after which the mixture is discharged from the mixer within from 0.5 to 30 seconds and is cooled within 120 seconds.
摘要翻译： 一种由100重量份聚烯烃和1至30重量份导电炭黑制备细碎聚烯烃成型材料的方法，其具有或不含其它添加剂，其中聚烯烃粉末和炭黑的混合物复合， 在第一阶段中，直到达到聚烯烃的微晶熔点，然后在第二阶段中将其升至高于所述微晶熔点3℃至40℃的温度，之后混合物 在0.5至30秒内从混合器中排出，并在120秒内冷却。
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7.发明授权Composite element comprising a top layer and a base layer of thermoplastic polyurethanes, its preparation, and its use 失效复合元件包括热塑性聚氨酯的顶层和基层，其制备及其用途
公开(公告)号：US5288549A
公开(公告)日：1994-02-22
申请号：US848616
申请日：1992-03-09
申请人： Gerhard Zeitler , Thomas Friedl
发明人： Gerhard Zeitler , Thomas Friedl
IPC分类号： B29C39/10 , B29K75/00 , B29K105/04 , B29L9/00 , B29L31/58 , B32B5/18 , B32B27/40 , C08G18/65 , C08G18/66 , C08J9/10 , C08J9/36 , B32B3/26 , B29C65/00 , B29C67/00 , B32B27/00
CPC分类号： C08J9/365 , B32B27/40 , C08G18/6674 , C08J9/10 , C08G2101/0083 , C08J2375/04 , Y10T428/249988 , Y10T428/249989 , Y10T428/249991 , Y10T428/31554
摘要： A composite element which comprises an elastic, cellular top layer (A) and a rigid base layer (B) of thermoplastic polyurethanes, the polyurethane elastomer (B) of the base layer being prepared by reactingBa) 1 mol of at least one essentially linear, relatively high-molecular-weight polyesterol or polyetherol,Bb) from 6 to 15 mol of an organic diisocyanate, preferably 4,4'-diphenylmethane diisocyanate, andBc) from 5 to 14 mol of at least one alkanediol or dialkylene glycol,in the presence ofBd) from 0.05 to 0.3% by weight, based on the total weight of (Ba) to (Bc), of water, and, if desired,Be) a catalyst, andBf) assistants and/or additives, is used as a cushioned fitting for vehicles.
摘要翻译： 一种复合元件，其包括热塑性聚氨酯的弹性，细胞顶层（A）和刚性基层（B），所述基层的聚氨酯弹性体（B）通过使Ba）1mol至少一种基本上线性 ，相对高分子量的聚酯或聚醚醚，Bb）6至15摩尔有机二异氰酸酯，优选4,4'-二苯基甲烷二异氰酸酯和Bc）5至14摩尔至少一种链烷二醇或二亚烷基二醇， 基于（Ba）至（Bc）的水的总重量，以及如果需要的话，Bd）的存在为0.05-0.3重量％，如果需要，Be）催化剂和Bf）助剂和/或添加剂是 用作车辆的缓冲配件。
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8.发明授权Flexible elastic polyurethane films a process for their preparation and their use 失效柔性弹性聚氨酯薄膜的制备及其应用的过程
公开(公告)号：US5218058A
公开(公告)日：1993-06-08
申请号：US527512
申请日：1990-05-23
申请人： Gerhard Zeitler , Gerhard Lehr
发明人： Gerhard Zeitler , Gerhard Lehr
CPC分类号： C08J5/18 , C08G18/6674 , C08K3/22 , C08K3/36 , C08L75/04 , C08J2375/04
摘要： The present invention deals with flexible elastic polyurethane films, efficaciously having a thickness from 0.3 to 3 mm, prepared by sintering powdered thermoplastic polyurethanes, having:(a) a melt index of from 50 to 350, measured at 190.degree. C. with a compression force of 21.6 kg, and(b) a Shore A hardness of from 80 to 98, preferably while using from 0.05 to 1 part by weight of powdered aluminum oxide and/or silica gel per 100 parts by weight of said thermoplastic polyurethane, utilizing a heated mold.The polyurethane films are preferably used for coating molded articles used in the interior of motor vehicles.
摘要翻译： 本发明涉及柔性弹性聚氨酯膜，其有效厚度为0.3至3mm，通过烧结粉末状热塑性聚氨酯制备，其具有：（a）熔体指数为50至350，在190℃下以压缩 力为21.6kg，（b）80至98的肖氏A硬度，优选使用0.05至1重量份的粉末状氧化铝和/或硅胶/ 100重量份的所述热塑性聚氨酯，利用 加热模具。 聚氨酯薄膜优选用于汽车内部使用的涂布模制品。
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9.发明授权
公开(公告)号：US4597927A
公开(公告)日：1986-07-01
申请号：US504795
申请日：1983-06-16
申请人： Gerhard Zeitler , Frank Werner , Gerhard Bittner , Karl-Heinz Baumann , Artur Roeber , Lothar Metzinger , Rainer Ohlinger , Hans D. Zettler
发明人： Gerhard Zeitler , Frank Werner , Gerhard Bittner , Karl-Heinz Baumann , Artur Roeber , Lothar Metzinger , Rainer Ohlinger , Hans D. Zettler
CPC分类号： B01J19/22 , C08G18/08 , C08G18/6505 , Y10S264/44 , Y10S425/012 , Y10S425/046
摘要： In order to prepare thermoplastic polyurethane elastomers(a) organic diisocyanate,(b) polyhydroxyl compounds with molecular weights of 500 to 8,000, and(c) chain extenders with molecular weights of 60 to 400 in the presence of(d) catalysts, and optionally(e) auxiliaries, and/or(f) additivesare reacted in two reaction stages at temperatures from 60.degree. C. to 250.degree. C. In the first reaction stage the components are continuously mixed, the reaction mixture is applied to a carrier, preferably a conveyor band of thermoplastic material, and is allowed to react at the reaction temperature until solidified. Subsequently, the solidified reaction mixture is melted in an extruder and the reaction is completed in the second reaction stage.
摘要翻译： 为了制备热塑性聚氨酯弹性体（a）有机二异氰酸酯，（b）分子量为500至8,000的多羟基化合物，和（c）在（d）催化剂存在下分子量为60至400的扩链剂，和 （e）助剂和/或（f）添加剂在60℃至250℃的温度下在两个反应阶段中反应。在第一反应阶段，将组分连续混合，将反应混合物施加到载体上， 优选为热塑性材料的输送带，并使其在反应温度下反应直到固化。 随后，将固化的反应混合物在挤出机中熔融，并在第二反应阶段完成反应。
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10.发明授权
公开(公告)号：US4526952A
公开(公告)日：1985-07-02
申请号：US620430
申请日：1984-06-14
CPC分类号： C08K3/04 , B29C70/882 , H01B1/24 , B29K2995/0005 , Y10S524/91
摘要： Antistatic and/or electrically conductive thermoplastic polyurethanes contain carbon black whose surface area determined by the BET method is from 600 to 1200 m.sup.2 /g, have a dibutylphthalate absorption number of 300 to 450 cm.sup.3 /100 g, a pour density of less than 250 kg/m.sup.3, and an average particle size less than 50 nm.Incorporation of the carbon black into the thermoplastic polyurethane produced by the continuous sheet method takes place at temperatures under the primary melt peak for the crystalline rigid segments, measured by means of differential calorimetry, preferably in an extruder.The products are suitable for preparing films for flat heating elements, antistatic hoses, cables, and profiles.
摘要翻译： 抗静电和/或导电的热塑性聚氨酯含有炭黑，其表面积由BET法测定为600至1200m2 / g，邻苯二甲酸二丁酯吸收值为300至450cm 3 / 100g，倾倒密度小于250kg / m 3，平均粒径小于50nm。 通过连续片材法生产的热塑性聚氨酯中的碳黑，是通过差示热量法，优选在挤出机中测量的结晶刚性链段的初级熔融峰下的温度下进行的。 该产品适用于制备平面加热元件，抗静电软管，电缆和型材的薄膜。
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