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1.发明授权Preparation of finely divided polyolefin molding materials containing conductive carbon black, and their use for the production of moldings 失效制备含有导电炭黑的细碎聚烯烃成型材料，以及它们用于生产模制品的用途
公开(公告)号：US4287117A
公开(公告)日：1981-09-01
申请号：US107905
申请日：1979-12-28
申请人： Rainer Theysohn , Gerhard Zeitler , Frank Weiss , Hans Willing , Erhard Seiler
发明人： Rainer Theysohn , Gerhard Zeitler , Frank Weiss , Hans Willing , Erhard Seiler
CPC分类号： C08J3/203 , B29C70/882 , H01B1/24 , B29K2023/06 , B29K2995/0005 , C08J2323/02
摘要： A process for the preparation of finely divided polyolefin molding materials from 100 parts by weight of polyolefin and from 1 to 30 parts by weight of a conductive carbon black, with or without other additives, wherein the mixture of polyolefin powder and carbon black is compounded, in a first stage, until the crystallite melting point of the polyolefin is reached, and is then brought, in a second stage, to a temperature which is from 3.degree. to 40.degree. C. above the said crystallite melting point, after which the mixture is discharged from the mixer within from 0.5 to 30 seconds and is cooled within 120 seconds.
摘要翻译： 一种由100重量份聚烯烃和1至30重量份导电炭黑制备细碎聚烯烃成型材料的方法，其具有或不含其它添加剂，其中聚烯烃粉末和炭黑的混合物复合， 在第一阶段中，直到达到聚烯烃的微晶熔点，然后在第二阶段中将其升至高于所述微晶熔点3℃至40℃的温度，之后混合物 在0.5至30秒内从混合器中排出，并在120秒内冷却。
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公开(公告)号：US4350652A
公开(公告)日：1982-09-21
申请号：US254937
申请日：1981-04-16
申请人： Rainer Theysohn , Klaus Boehlke , Erhard Seiler , Martin Welz
发明人： Rainer Theysohn , Klaus Boehlke , Erhard Seiler , Martin Welz
CPC分类号： C08J3/203 , B29C70/882 , H01B1/24 , B29K2995/0005 , C08J2323/02
摘要： A process for the preparation of finely divided polyolefin molding materials from 100 parts by weight of a polyolefin and from 0.01 to 30 parts by weight of an electrically conductive additive, with or without other additives, wherein the mixture of the finely divided polyolefin particles and the electrically conductive additives is brought to the crystallite melting point of the polyolefin by the heating effect of the mixing action, and is then brought to a temperature which is from 3.degree. to 40.degree. C. above the said crystallite melting point while being subjected to a defined mixing intensity, after which the mixture is either cooled within 120 seconds or is directly compression-molded.
摘要翻译： 一种由100重量份的聚烯烃和0.01至30重量份的具有或不含其它添加剂的导电添加剂制备细分散的聚烯烃模塑材料的方法，其中细分散的聚烯烃颗粒和 导电性添加剂通过混合作用的加热效果达到聚烯烃的微晶熔点，然后在高于所述微晶熔点的温度下升温至3〜40℃，同时进行 混合物在120秒内冷却或直接压缩成型。
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公开(公告)号：US5244976A
公开(公告)日：1993-09-14
申请号：US847403
申请日：1992-03-06
申请人： Sibylle Brosius , Klaus-Dieter Ruempler , Erhard Seiler , Susanne Hahn , Karl Huber , Rainer A. Werner
发明人： Sibylle Brosius , Klaus-Dieter Ruempler , Erhard Seiler , Susanne Hahn , Karl Huber , Rainer A. Werner
IPC分类号： C08F255/02
CPC分类号： C08F255/02
摘要： A partially crosslinked polymer composition having a melt flow index of from 0.1 to 50 g/10 min at 230.degree. C. under a weight of 2.16 kg and comprisinga) a polymer comprising from 25 to 95% by weight of polypropylene and 5 to 75% by weight of a propylene copolymer with copolymerized C.sub.2 -C.sub.10 -alk-1-enes, the comonomer content being from 1 to 45% by weight, based on the total polymer,b) an organosilane compound of the formula (I)A.sub.4-n SiR.sub.n (i) where A are identical or different acrylates or methacrylates or vinyl groups, R are identical or different C.sub.1 -C.sub.8 -alkoxy or C.sub.1 -C.sub.8 -acetoxy groups, and n is 1, 2 or 3, obtainable by reacting the polymer a) with the organosilane compound b) in the presence of a free-radical initiator and in the presence of a condensation catalyst at from 180.degree. to 280.degree. C., and at from 1 to 100 bar and at a mean residence time of the reaction mixture of from 0.2 to 10 minutes,has, in particular, high notched impact strength, increased puncture resistance and improved weld line strength.
摘要翻译： 一种部分交联的聚合物组合物，其熔体流动指数为0.1至50g / 10min，在230℃，重量为2.16kg，并包含a）包含25至95重量％的聚丙烯和5至75的聚合物 重量％的具有共聚的C 2 -C 10 - 烷-1-烯的丙烯共聚物，基于总聚合物的共聚单体含量为1至45重量％，b）式（I）的有机硅烷化合物， nSiRn（i）其中A是相同或不同的丙烯酸酯或甲基丙烯酸酯或乙烯基，R是相同或不同的C 1 -C 8 - 烷氧基或C 1 -C 8 - 乙酰氧基，n是1,2或3，可通过使聚合物a ）与有机硅烷化合物b）在自由基引发剂的存在下，在缩合催化剂存在下，在180-280℃，和1-100巴，反应的平均停留时间 0.2〜10分钟的混合物，特别是具有高缺口冲击强度，抗穿刺性提高 焊线强度。
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公开(公告)号：US5179164A
公开(公告)日：1993-01-12
申请号：US668701
申请日：1991-03-08
IPC分类号： C08K7/14 , C08L23/08 , C08L23/10 , C08L23/14 , C08L51/04 , C08L51/06 , C08L53/00 , C08L77/00
CPC分类号： C08L77/00 , C08L23/10 , C08L23/142 , C08L53/00 , C08K7/14 , C08L2205/03 , C08L2205/035 , C08L23/0869 , C08L51/04 , C08L51/06
摘要： Polypropylene/polyamide molding compositions, suitable in particular for producing moldings, advantageously consist of, in each case based on 100 parts by weight of the molding composition,A) from 10 to 89.5 parts by weight of one or more polypropylene homopolymers and/or copolymers,B) from 10 to 89.5 parts by weight of one or more polyamides,C) from 0.5 to 30 parts by weight of an ethylene copolymer as adhesion promoter,D) from 0 to 30 parts by weight of an impact modifier andE) from 0 to 60 parts by weight of a reinforcing agent and/or additive,the ethylene copolymer (C) advantageously being polymerized from, in each case based on (C),a) from 50 to 98% by weight of ethylene,b) from 1 to 45% by weight of one or more alkyl (meth)acrylates having 1 to 8 carbon atoms in the alkyl, but not tert-butyl (meth)acrylate, andc) from 1 to 40% by weight of one or more further monomers containing in bonded form a group which is reactive toward the polyamide, for example a carboxyl, carboxylic anhydride, tert-butyl carboxylate, sulfo, sulfonyl, oxazolinyl or epoxide group,and are produced by melting together components (A) to (C) and any (D) and/or (E) at from 200.degree. to 300.degree. C.
摘要翻译： 适合于特别用于生产模制品的聚丙烯/聚酰胺模塑组合物有利地包括在每种情况下基于100重量份的模塑组合物A）10至89.5重量份的一种或多种聚丙烯均聚物和/或共聚物 ，B）10至89.5重量份的一种或多种聚酰胺，C）0.5至30重量份的作为粘合促进剂的乙烯共聚物，D）0至30重量份的抗冲改性剂，E） 0至60重量份的增强剂和/或添加剂，乙烯共聚物（C）有利地在每种情况下基于（C）聚合，a）50至98重量％的乙烯，b）从 1〜45重量％的一种或多种烷基中具有1-8个碳原子的（甲基）丙烯酸烷基酯，但不是（甲基）丙烯酸叔丁酯，和c）1至40重量％的一种或多种 含有键合形式的对聚酰胺具有反应性的基团的单体，例如羧基，羧基 通过将组分（A）至（C）和（200）至（300）的任何（D）和/或（E））熔融在一起而制备， 。
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5.发明授权
公开(公告)号：US5162422A
公开(公告)日：1992-11-10
申请号：US534883
申请日：1990-06-08
CPC分类号： C08L77/02 , C08K5/09 , C08L23/10 , C08L23/12 , C08L23/142 , C08L53/00 , C08L77/00 , C08L77/06 , C08K7/14 , C08L23/0869 , C08L23/0884 , C08L51/04 , C08L51/06
摘要： Novel polypropylene-polyamide molding compositions which comprise, based on 100 parts by weight of the molding compositions,A) 10 to 89.9 parts by weight of one or more polypropylene homopolymer and/or copolymer,B) 10 to 89.9 parts by weight of one or more polyamide,C) 0.1 to 5.0 parts by weight of one or more olefinically unsaturated carboxylic acid and/or one or more olefinically unsaturated carboxylic acid derivate,D) 0 to 3.0 parts by weight of an impact modifier, andE) 0 to 60.0 parts by weight of a reinforcing agent and/or additive,are prepared by melting together components (A), (C) and, if desired (D) at from 200.degree. to 300.degree. C. in a first reaction step and then, in a second reaction step, introducing component (B) and, if appropriate, components (D) and/or (E) into the modified melt obtained, and melting together the components.The molding compositions obtained are used for the production of moldings.
摘要翻译： 基于100重量份成型组合物的新型聚丙烯 - 聚酰胺模塑组合物，A）10至89.9重量份的一种或多种聚丙烯均聚物和/或共聚物，B）10至89.9重量份的一种或多种 更多的聚酰胺，C）0.1至5.0重量份的一种或多种烯属不饱和羧酸和/或一种或多种烯属不饱和羧酸衍生物，D）0-3.0重量份抗冲改性剂，E）0-60.0 通过在第一反应步骤中将组分（A），（C）和（如果需要的话）（D）在200℃至300℃下熔融在一起制备增强剂和/或添加剂的重量份，然后在 第二反应步骤，将组分（B）和（如果合适的话）将组分（D）和/或（E）引入所获得的改性熔体中并将组分一起熔化。 得到的成型组合物用于制造模制品。
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公开(公告)号：US5122398A
公开(公告)日：1992-06-16
申请号：US618331
申请日：1990-11-26
申请人： Erhard Seiler , Klaus-Dieter Ruempler , Norbert Jung , Udo Haardt , Rainer Henning , Juergen Hamprecht
发明人： Erhard Seiler , Klaus-Dieter Ruempler , Norbert Jung , Udo Haardt , Rainer Henning , Juergen Hamprecht
CPC分类号： B60R19/03 , B60R2019/1853 , B60R2019/1873 , B60R2019/1886 , Y10T428/233 , Y10T428/24744 , Y10T428/249992
摘要： A recyclable bumper system based on polypropylene comprises a bumper support A of glass fiber reinforced polypropylene, an energy-absorbing foam core B of foamed polypropylene and a tough shell C of EP-rubber modified polypropylene which may be coated, and can be recycled by mechanical comminution, extrusion and granulation, resulting in granules from which injection moldings having good mechanical properties can be produced.
摘要翻译： 基于聚丙烯的可回收保险杠系统包括玻璃纤维增强聚丙烯的保险杠支撑件A，发泡聚丙烯的能量吸收泡沫芯B和可以被涂覆的EP-橡胶改性聚丙烯的韧性壳体C，并且可以通过机械 粉碎，挤出和造粒，从而可以生产具有良好机械性能的注射成型品的颗粒。
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7.发明授权Thermoplastic molding compositions based on polycarbonates, polyesters and polyamides 失效基于聚碳酸酯，聚酯和聚酰胺的热塑性模塑组合物
公开(公告)号：US4879324A
公开(公告)日：1989-11-07
申请号：US311392
申请日：1989-02-16
摘要： Thermoplastic molding compositions contain as essential components(A) from 1 to 90% by weight of a polycarbonate,(B) from 1 to 90% by weight of a polyester,(C) from 1 to 90% by weight of a polyamide,(D) from 0.5 to 30% by weight of a polymeric component having hydroxyl groups and in addition(E) from 0 to 30% by weight of an impact-modifying rubber and(F) from 0 to 60% by weight of a fibrous or particulate filler.
摘要翻译： 热塑性成型组合物含有作为必要组分（A）的1-90重量％的聚碳酸酯，（B）1-90重量％的聚酯，（C）1-90重量％的聚酰胺（ D）0.5至30重量％的具有羟基的聚合物组分，另外（E）为0至30重量％的冲击改性橡胶，（F）0至60重量％的纤维或 颗粒填料。
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公开(公告)号：US4002703A
公开(公告)日：1977-01-11
申请号：US603857
申请日：1975-08-12
申请人： Gerhard Fahrbach , Erhard Seiler , Dieter Stein
发明人： Gerhard Fahrbach , Erhard Seiler , Dieter Stein
CPC分类号： C08G81/025
摘要： This invention relates to a process for the manufacture of graft copolymers based on methyl methacrylate polymers. The methyl methacrylate polymer is reacted with a high molecular weight organic compound containing at least one alkylene oxide unit having an alkali metal alcoholate end group, during which reaction transesterification occurs to eliminate alkali metal methoxide and cause chain joining. The graft copolymers may be used for the production of shaped articles or coating compositions and as additives, antistatic agents or adhesion promoters for plastics materials.
摘要翻译： 本发明涉及一种制备基于甲基丙烯酸甲酯聚合物的接枝共聚物的方法。 甲基丙烯酸甲酯聚合物与含有至少一个具有碱金属醇化物端基的烯化氧单元的高分子量有机化合物反应，在此期间进行反应酯交换以除去碱金属甲醇盐并引起链接。 接枝共聚物可用于生产成形制品或涂料组合物，以及用作塑料材料的抗静电剂或粘合促进剂的添加剂。
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公开(公告)号：US3933774A
公开(公告)日：1976-01-20
申请号：US453375
申请日：1974-03-21
申请人： Franz Neumayr , Gerhard Fahrbach , Erhard Seiler
发明人： Franz Neumayr , Gerhard Fahrbach , Erhard Seiler
IPC分类号： C08C19/26 , C08F8/42 , C08F236/04 , C08F257/00 , C08F279/02 , C08F210/00 , C08F136/02 , C08F212/00
CPC分类号： C08F279/02 , C08C19/26 , C08F236/04 , C08F257/00 , C08F8/42
摘要： Modified copolymers of vinyl aromatic compounds or diene hydrocarbons with diisopropenylbenzene. They contain at least 0.2% of polymerized units of a group of the general formulaThe copolymers are intermediates in the manufacture of block copolymers and graft copolymers suitable for use as impact-resistant plastics or polymeric antistatic agents.
摘要翻译： 乙烯基芳族化合物或二烯烃与二异丙烯基苯的改性共聚物。 它们含有至少0.2％的通式基团的聚合单元。该共聚物是制备适合用作抗冲击塑料或聚合抗静电剂的嵌段共聚物和接枝共聚物的中间体。
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公开(公告)号：US5641821A
公开(公告)日：1997-06-24
申请号：US418607
申请日：1995-04-07
申请人： Erhard Seiler , Werner Schone
发明人： Erhard Seiler , Werner Schone
CPC分类号： C08L23/10 , C08J5/18 , C08L23/12 , C08L23/142 , C08J2323/10 , C08L23/06 , C08L23/0815 , Y10T428/13 , Y10T428/1331
摘要： Molding materials comprisingA) polymers of propylene and up to 20% by weight of further monomers, containingB) from 0.05 to 0.4% by weight of a monofunctional or polyfunctional carboxamide or of a carboxamide mixture having a molecular weight of from 150 to 600 andc) from 0.1 to 3.0% by weight of an ethylene polymer with up to 20% by weight of comonomers, having a density of from 0.890 to 0.945 g/cm.sup.3 and an MFI of from 10 to 100 g/10 min, measured according to ISO 1133 at 190.degree.C./2.16 kg.The films and moldings produced using the novel molding materials have particularly good frictional properties.
摘要翻译： 包括A）丙烯聚合物和至多20重量％的其它单体的聚合物，其包含B）0.05至0.4重量％的单官能或多官能羧酰胺或分子量为150至600的羧酰胺混合物，以及 c）0.1至3.0重量％的具有至多20重量％共聚单体的乙烯聚合物，密度为0.890至0.945g / cm 3，MFI为10至100g / 10min，根据 ISO 1133在190℃/2.16kg。 使用新型成型材料制造的薄膜和模制品具有特别好的摩擦性能。
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