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公开(公告)号：US09293757B2
公开(公告)日：2016-03-22
申请号：US14117527
申请日：2012-05-15
CPC分类号： H01M2/34 , H01M10/425 , H01M10/44 , H01M10/48 , H01M12/08 , H02J7/0068 , Y02E60/128
摘要： The present invention relates to a rechargeable accumulator comprising one or more metal-air cells, each cell comprising a metallic negative electrode, a first positive electrode for releasing oxygen, a second positive electrode which is a porous air electrode containing at least one oxygen reducing catalyst, and an automatic device for protecting the air electrode during the charging and discharging phases of the accumulator. The invention also relates to a method for storing and releasing electrical energy using such an accumulator.
摘要翻译： 本发明涉及包含一个或多个金属空气电池的可充电蓄电池，每个电池包括金属负极，用于释放氧的第一正电极，第二正电极，其是含有至少一种氧还原催化剂的多孔空气电极 以及在蓄电池的充放电阶段保护空气极的自动装置。 本发明还涉及使用这种蓄能器来储存和释放电能的方法。
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2.发明授权Electrochemical device having a solid alkaline ion-conducting electrolyte and an aqueous electrolyte 有权具有固体碱性离子导电电解质和水性电解质的电化学装置公开(公告)号：US09178221B2
公开(公告)日：2015-11-03
申请号：US13499394
申请日：2010-10-21
CPC分类号： H01M6/185 , H01M6/187 , H01M6/188 , H01M6/24 , H01M10/26 , H01M12/06 , H01M2300/0068 , H01M2300/0094 , Y02E60/124
摘要： The present invention relates to an alkaline cation-conducting ceramic membrane covered, over at least a portion of the surface thereof, with a cation-conducting organic polyelectrolyte layer that is insoluble and chemically stable in pH-basic water. The invention also relates to an electrochemical device including such a membrane as a solid electrolyte in contact with a liquid electrolyte formed of an alkali metal hydroxide aqueous solution.
摘要翻译： 本发明涉及一种在其至少一部分表面上覆盖在pH-碱性水中不溶和化学稳定的阳离子导电有机聚电解质层的碱性阳离子导电陶瓷膜。 本发明还涉及一种电化学装置，其包括与由碱金属氢氧化物水溶液形成的液体电解质接触的固体电解质膜。
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3.发明申请ELECTROCHEMICAL DEVICE HAVING A SOLID ALKALINE ION-CONDUCTING ELECTROLYTE AND AN AQUEOUS ELECTROLYTE 有权具有固体碱性离子导电电解质和电解质电解质的电化学装置公开(公告)号：US20120183868A1
公开(公告)日：2012-07-19
申请号：US13499394
申请日：2010-10-21
CPC分类号： H01M6/185 , H01M6/187 , H01M6/188 , H01M6/24 , H01M10/26 , H01M12/06 , H01M2300/0068 , H01M2300/0094 , Y02E60/124
摘要： The present invention relates to an alkaline cation-conducting ceramic membrane covered, over at least a portion of the surface thereof, with a cation-conducting organic polyelectrolyte layer that is insoluble and chemically stable in pH-basic water. The invention also relates to an electrochemical device including such a membrane as a solid electrolyte in contact with a liquid electrolyte formed of an alkali metal hydroxide aqueous solution.
摘要翻译： 本发明涉及一种在其至少一部分表面上覆盖在pH-碱性水中不溶和化学稳定的阳离子导电有机聚电解质层的碱性阳离子导电陶瓷膜。 本发明还涉及一种电化学装置，其包括与由碱金属氢氧化物水溶液形成的液体电解质接触的固体电解质膜。
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4.发明授权Rigid negative compartment for a metal-air battery and method of manufacturing said compartment 有权用于金属空气电池的刚性负隔室和制造所述隔室的方法公开(公告)号：US09236642B2
公开(公告)日：2016-01-12
申请号：US13498649
申请日：2010-09-22
申请人： Gwenaelle Toussaint , Philippe Stevens , Georges Caillon , Patrick Viaud , Christophe Cantau , Philippe Vinatier
发明人： Gwenaelle Toussaint , Philippe Stevens , Georges Caillon , Patrick Viaud , Christophe Cantau , Philippe Vinatier
IPC分类号： H01M10/0562 , H01M12/08 , H01M2/02 , H01M2/30 , H01M4/04 , H01M4/13 , H01M4/1395 , H01M4/70 , H01M4/72 , H01M10/052
CPC分类号： H01M12/08 , H01M2/0207 , H01M2/0277 , H01M2/30 , H01M4/0438 , H01M4/13 , H01M4/134 , H01M4/1395 , H01M4/70 , H01M4/72 , H01M10/052 , H01M10/0562 , Y02E60/122 , Y02E60/128 , Y02P70/54
摘要： The present invention relates to a precursor of a negative electrode compartment for rechargeable metal-air batteries, comprising a rigid casing (1), at least one solid electrolyte membrane (2), a protective covering (5), completely covering the inside face of the solid electrolyte membrane (2), a metallic current collector (3) applied against the inside face of the protective covering (5), preferably also a block (4) of elastic material applied against the current collector and essentially filling the entire internal space defined by the walls of the rigid casing and the solid electrolyte (2), and a flexible electronic conductor (6) passing in a sealed manner through one of the walls of the rigid casing. The present invention also relates to a negative electrode compartment having a rigid casing obtained from said precursor and to a battery containing such a negative electrode compartment.
摘要翻译： 本发明涉及一种用于可再充电金属 - 空气电池的负极隔室的前体，包括刚性壳体（1），至少一个固体电解质膜（2），保护覆盖物（5），其完全覆盖 固体电解质膜（2），施加在保护罩（5）的内表面上的金属集电体（3），优选地还包括施加在集电器上的基本上填充整个内部空间的弹性材料块（4） 由刚性壳体和固体电解质（2）的壁限定，以及柔性电子导体（6），其以密封方式通过刚性壳体的一个壁。 本发明还涉及具有由所述前体获得的刚性壳体和包含这种负极隔室的电池的负极隔室。
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公开(公告)号：US20140191727A1
公开(公告)日：2014-07-10
申请号：US14117527
申请日：2012-05-15
CPC分类号： H01M2/34 , H01M10/425 , H01M10/44 , H01M10/48 , H01M12/08 , H02J7/0068 , Y02E60/128
摘要： The present invention relates to a rechargeable accumulator comprising one or more metal-air cells, each cell comprising a first terminal (1) and a second terminal (2), a metallic negative electrode (3) for metal-air cell, connected to the first terminal (1), a first positive electrode (4) for releasing oxygen, a second positive electrode (5) which is a porous air electrode containing at least one oxygen reducing catalyst, an electrolyte, control means (6) suitable for continuously comparing the voltage measured between the terminal (2) and the terminal (1) with a setpoint value and for dispatching a switching signal to the switching means (7) when the measured voltage becomes smaller than the setpoint value, switching means (7) suitable for receiving a switching signal originating from the control means (6) and for connecting and disconnecting the air electrode (5) of the second terminal (2). The present invention also relates to a method using such an accumulator.
摘要翻译： 本发明涉及一种包括一个或多个金属空气电池的可再充电蓄电池，每个电池包括第一端子（1）和第二端子（2），金属 - 空气电池的金属负极（3），连接到 第一端子（1），用于释放氧的第一正极（4），包含至少一种氧还原催化剂的多孔空气电极的第二正电极（5），电解质，适于连续比较的控制装置（6） 在所述端子（2）和所述端子（1）之间测量的电压具有设定点值，并且当所测量的电压变得小于所述设定点值时向所述开关装置（7）发送切换信号;切换装置（7），适于 接收来自所述控制装置（6）的开关信号，以及连接和断开所述第二端子（2）的空气电极（5）。 本发明还涉及使用这种蓄能器的方法。
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6.发明申请RIGID NEGATIVE COMPARTMENT FOR A METAL-AIR BATTERY AND METHOD OF MANUFACTURING SAID COMPARTMENT 有权用于金属空气电池的刚性负压舱及制造分舱的方法公开(公告)号：US20120183880A1
公开(公告)日：2012-07-19
申请号：US13498649
申请日：2010-09-22
申请人： Gwenaelle Toussaint , Philippe Stevens , Georges Caillon , Patrick Viaud , Christophe Cantau , Philippe Vinatier
发明人： Gwenaelle Toussaint , Philippe Stevens , Georges Caillon , Patrick Viaud , Christophe Cantau , Philippe Vinatier
CPC分类号： H01M12/08 , H01M2/0207 , H01M2/0277 , H01M2/30 , H01M4/0438 , H01M4/13 , H01M4/134 , H01M4/1395 , H01M4/70 , H01M4/72 , H01M10/052 , H01M10/0562 , Y02E60/122 , Y02E60/128 , Y02P70/54
摘要： The present invention relates to a precursor of a negative electrode compartment for rechargeable metal-air batteries, comprising a rigid casing (1), at least one solid electrolyte membrane (2), a protective covering (5), completely covering the inside face of the solid electrolyte membrane (2), a metallic current collector (3) applied against the inside face of the protective covering (5), preferably also a block (4) of elastic material applied against the current collector and essentially filling the entire internal space defined by the walls of the rigid casing and the solid electrolyte (2), and a flexible electronic conductor (6) passing in a sealed manner through one of the walls of the rigid casing. The present invention also relates to a negative electrode compartment having a rigid casing obtained from said precursor and to a battery containing such a negative electrode compartment.
摘要翻译： 本发明涉及一种用于可再充电金属 - 空气电池的负极隔室的前体，包括刚性壳体（1），至少一个固体电解质膜（2），保护覆盖物（5），其完全覆盖 固体电解质膜（2），施加在保护罩（5）的内表面上的金属集电体（3），优选地还包括施加在集电器上的基本上填充整个内部空间的弹性材料块（4） 由刚性壳体和固体电解质（2）的壁限定，以及柔性电子导体（6），其以密封方式通过刚性壳体的一个壁。 本发明还涉及具有由所述前体获得的刚性壳体和包含这种负极隔室的电池的负极隔室。
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公开(公告)号：US09136539B2
公开(公告)日：2015-09-15
申请号：US12992279
申请日：2009-11-11
申请人： Stephane Lascaud , Philippe Stevens
发明人： Stephane Lascaud , Philippe Stevens
CPC分类号： H01M4/74 , H01M2/1606 , H01M2/162 , H01M2/1646 , H01M2/1686 , H01M4/0445 , H01M4/049 , H01M4/24 , H01M4/521 , H01M12/08 , H01M2300/0014 , Y02E60/124 , Y02E60/128 , Y02P70/54
摘要： The invention relates to a half-cell including an electrode formed of an electron collector containing one or more transition metals from groups 4 to 12 of the Period Table of the Elements, and of an electrochemically active material present on the surface of the electron collector in the form of a nanostructured conversion film containing nanoparticles having an average diameter of between 1 nm and 1000 nm. The electrochemically active material contains at least one compound of the transition metal or the transition metals present in the electron collector. The invention further includes a continuous film of a lithium-ion conductive, solid electrolyte that is water- and air-impermeable and that is deposited directly onto, covering totally, the surface of the nanostructured active material of the electrode. The continuous film of solid electrolyte having a thickness of between 1 μm and 50 μm.
摘要翻译： 本发明涉及一种半电池，包括由含有元素周期表第4至12族中的一种或多种过渡金属的电子收集体形成的电极，以及存在于电子收集器表面上的电化学活性材料 包含平均直径在1nm和1000nm之间的纳米颗粒的纳米结构转化膜的形式。 电化学活性材料含有至少一种过渡金属化合物或存在于电子收集器中的过渡金属。 本发明还包括一种锂离子传导性固体电解质的连续膜，其是水不透气且直接沉积在电极的纳米结构的活性材料的表面上。 固体电解质的连续薄膜的厚度为1μm〜50μm。
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公开(公告)号：US07572532B2
公开(公告)日：2009-08-11
申请号：US10599132
申请日：2005-03-21
CPC分类号： H01M4/9025 , C01G1/00 , C01G3/006 , C01G37/006 , C01G45/1264 , C01G49/0054 , C01G51/40 , C01G51/70 , C01G53/40 , C01G53/70 , C01P2006/40 , H01M4/9016 , H01M2008/1293
摘要： The invention relates to an oxide material of general formula (I) A2−x−yA′XA″yM1−z M′Z04+δ, wherein A and A′ are independently a metal cation of a group formed by lanthanides and/or alkalis and/or alkaline earths, A″ is a cationic gap, i.e. a cation vacancy A and/or A′, M and M′ are independently a metal of a group formed by transition metals such as 0
摘要翻译： 本发明涉及通式（Ⅰ）A2-x-yA'A''yM1-zM'Z04 +δ的氧化物材料，其中A和A'独立地是由镧系元素形成的基团的金属阳离子和/或 碱和/或碱土金属，A“是阳离子间隙，即阳离子空位A和/或A'，M和M'独立地是由过渡金属如0
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9.发明申请INTERPENETRATING NETWORK OF ANION-EXCHANGE POLYMERS, PRODUCTION METHOD THEREOF AND USE OF SAME 有权阴离子交换聚合物的交联网络及其生产方法及其使用公开(公告)号：US20120058413A1
公开(公告)日：2012-03-08
申请号：US13318497
申请日：2010-05-04
CPC分类号： H01M8/1044 , C08J3/246 , C08J5/2275 , C08J2300/208 , C08L71/03 , H01M8/083 , H01M12/02 , H01M12/06 , H01M2008/1095 , H01M2300/0082 , Y02E60/50 , Y02P70/56 , C08L2666/04 , C08L2666/06
摘要： The invention relates to a method for producing an anion-exchange polymer material having an IPN or semi-IPN structure, said method consisting in: (A) preparing a homogeneous reaction solution containing, in a suitable organic solvent, (a) at least one organic polymer bearing reactive halogen groups, (b) at least one tertiary diamine, (c) at least one monomer comprising an ethylenic unsaturation polymerizable by free radical polymerization, (d) optionally at least one cross-linking agent including at least two ethylenic unsaturations polymerizable by free radical polymerization, and e) at least one free radical polymerization initiator; and (B) heating the prepared solution to a temperature and for a duration that are sufficient to allow both a nucleophilic substitution reaction between components (a) and (b) and a free radical copolymerization reaction of components (c) and optionally (d) initiated by component (e). The invention also relates to the resulting IPN or semi-IPN material and to the use thereof in electrochemical devices, in direct contact with an air electrode.
摘要翻译： 本发明涉及一种具有IPN或半IPN结构的阴离子交换聚合物材料的制备方法，所述方法包括：（A）制备均匀的反应溶液，该溶液含有在合适的有机溶剂中，（a）至少一种 带有反应性卤素基团的有机聚合物，（b）至少一种叔胺，（c）至少一种包含通过自由基聚合可聚合的烯属不饱和度的单体，（d）任选至少一种包含至少两个烯属不饱和键的交联剂 可通过自由基聚合反应，和e）至少一种自由基聚合引发剂; 和（B）将制备的溶液加热到足以允许组分（a）和（b）之间的亲核取代反应和组分（c）和任选（d）的自由基共聚反应的温度和持续时间， 由组件（e）启动。 本发明还涉及所得到的IPN或半IPN材料及其在与空气电极直接接触的电化学装置中的用途。
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公开(公告)号：US20070098905A1
公开(公告)日：2007-05-03
申请号：US10561581
申请日：2004-06-17
CPC分类号： C23C18/1283 , C23C18/1216 , C23C18/1241 , C23C18/1245 , H01M4/9066
摘要： Method of preparing a metal oxide layer on a substrate, in which the following successive steps are carried out: a) a metal oxide powder is dispersed in a liquid medium comprising a dispersion solvent and a dispersant, the said liquid medium containing neither plasticizer nor binder, by means of which a suspension A of the said metal oxide powder in the said liquid medium is obtained; b) a solution of at least one polymer in a solvent is added to the said suspension A, by means of which a suspension B is obtained; c) suspension B is deposited on the substrate by a dip coating method, by means of which a green layer is obtained; d) the green layer obtained in step c) is dried; and e) the dried layer obtained in step d) is calcined.
摘要翻译： 在基材上制备金属氧化物层的方法，其中进行以下连续步骤：a）将金属氧化物粉末分散在包含分散溶剂和分散剂的液体介质中，所述液体介质既不含增塑剂也不含粘合剂 通过其获得所述液体介质中的所述金属氧化物粉末的悬浮液A; b）将至少一种聚合物在溶剂中的溶液加入到所述悬浮液A中，借此获得悬浮液B. c）通过浸涂法将悬浮液B沉积在基底上，通过该方法获得绿色层; d）将步骤c）中获得的生坯层干燥; 和e）将步骤d）中获得的干燥层煅烧。
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