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47 条记录 (耗时 0.027 秒)

    Process for the preparation of adducts of epoxides and alcohols
    1.
    发明授权
    Process for the preparation of adducts of epoxides and alcohols 失效
    制备环氧化物和醇的加合物的方法

    公开(公告)号：US5342903A

    公开(公告)日：1994-08-30

    申请号：US55656

    申请日：1993-04-30

    申请人： Heinz Wolleb ,  Andreas Hafner ,  William M. Rolfe

    发明人： Heinz Wolleb ,  Andreas Hafner ,  William M. Rolfe

    IPC分类号： B01J31/22 ,  C07B61/00 ,  C07C41/03 ,  C07D301/28 ,  C07D303/22 ,  C07D303/24 ,  C08G59/62 ,  C08G59/68 ,  C07D303/04

    CPC分类号： C07D303/22 ,  C07C41/03 ,  C07D303/24

    摘要： A process for the preparation of adducts by reacting an alcohol with an epoxy compound in the presence of a catalyst, which comprises reacting an alcohol of formula I ##STR1## wherein A is an aliphatic, cycloaliphatic or araliphatic radical and r is a number from 1 to 10, with a mono- or diepoxide in the equivalent ratio of 1:20 to 20:1, based on the hydroxyl and epoxy groups, in the presence of a metal complex of formula II as catalyst[M.sup.n+ (L.sub.1).sub.x (L.sub.2).sub.y (L.sub.3.sup.m-).sub.z ][X.sup.k- ].sub.(n-zm)/k (II),whereinM is a metal of the main groups or subgroups of the Periodic Table of the Elements,L.sub.1 and L.sub.2 are weakly bonded, neutral, unidentale or multidentate ligands,L.sub.3 is a strongly bonded, non-replaceable neutral or anionic unidentale or multidentate ligand,X is an anion of the following formulae BF.sub.4.sup.-, PF.sub.6.sup.-, AsF.sub.6.sup.-, SbF.sub.6.sup.-, ClO.sub.4.sup.-, IO.sub.4.sup.-, NO.sub.3.sup.- or is the sulfonate radical of a perfluorinated alkanesulfonic acid,n is an integer from 1 to 6,m is 0 or an integer from 1 to 6,k is 1 or 2,x is an integer from 1 to 1000,y is 0 or an integer from 1 to 1000, andz is 0 or an integer from 1 to 6.

    摘要翻译： 一种通过在催化剂存在下使醇与环氧化合物反应制备加合物的方法，该方法包括使式IA [OH] r，（I）的醇与其中A是脂族，环脂族或芳脂族基团和r 是1至10的数，其中基于羟基和环氧基的当量比为1:20至20:1的单环或二环氧化物在作为催化剂的式II的金属配合物存在下[Mn +（ L1）x（L2）y（L3m-）z] [Xk-]（n-zm）/ k（II）其中M是元素周期表的主要组或亚组的金属，L1和L2 是弱结合的，中性的，不含义的或多齿的配体，L3是强键合的，不可替代的中性或阴离子异氰酸酯或多齿配体，X是下列式的阴离子：BF4-，PF6-，AsF6-，SbF6-，ClO4- ，O4-，NO3-或全氟化烷烃磺酸的磺酸根，n为1〜6的整数，m为0或1〜6的整数，k为1或2，x为1〜 1000，y为0或1〜1000的整数，z为0或1〜6的整数。

    Catalyst mixture and polymerizable composition
    5.
    发明授权
    Catalyst mixture and polymerizable composition 失效
    催化剂混合物和可聚合组合物

    公开(公告)号：US6162883A

    公开(公告)日：2000-12-19

    申请号：US155561

    申请日：1998-09-30

    申请人： Andreas Muhlebach ,  Paul Adriaan Van Der Schaaf ,  Andreas Hafner

    发明人： Andreas Muhlebach ,  Paul Adriaan Van Der Schaaf ,  Andreas Hafner

    IPC分类号： B01J31/24 ,  C08G61/08 ,  C08G61/12 ,  C09D145/00

    CPC分类号： C08G61/12 ,  C08G61/08 ,  Y10T428/2991 ,  Y10T428/2993 ,  Y10T428/31678

    摘要： A mixture of at least one thermal carbene-free ruthenium catalyst A and at least one thermal ruthenium carbene catalyst B, both of which initiate the ring-opening metathesis polymerization on their own, said catalysts being present in a weight ratio of A to B from 10:1 to 1:10. By adding this mixture even in small amounts, the ring-opening metathesis polymerization of strained cycloolefins can be effectively catalyzed.

    摘要翻译： PCT No.PCT / EP97 / 01579 Sec。 371日期：1998年9月30日 102（e）1998年9月30日PCT PCT 1997年3月27日PCT公布。 公开号WO97 / 38036 日期1997年10月16日将至少一种不含热不卡宾的钌催化剂A和至少一种热钌卡宾催化剂B的混合物二者自身引发开环易位聚合，所述催化剂以重量比存在 的A到B从10：1到1:10。 通过少量加入该混合物，可以有效催化应变环烯烃的开环易位聚合。

    METHODS IN CELL CULTURES, AND RELATED INVENTIONS, EMPLOYING CERTAIN ADDITIVES
    7.
    发明申请
    METHODS IN CELL CULTURES, AND RELATED INVENTIONS, EMPLOYING CERTAIN ADDITIVES 有权
    细胞培养方法和相关发明，使用某些添加剂

    公开(公告)号：US20120164162A1

    公开(公告)日：2012-06-28

    申请号：US13389549

    申请日：2010-08-11

    申请人： Franz Kaufmann ,  Trine Hefsgaard Miller ,  Johannes Flothmann ,  Beate Winter ,  Andreas Hafner

    发明人： Franz Kaufmann ,  Trine Hefsgaard Miller ,  Johannes Flothmann ,  Beate Winter ,  Andreas Hafner

    IPC分类号： C12P21/00 ,  C12N9/00 ,  C12N1/20 ,  C07K14/575 ,  A61K39/00 ,  C07K14/00 ,  C07K14/555 ,  C07K14/715 ,  C07K14/475 ,  C07H21/00 ,  C12P19/34 ,  A61P37/04 ,  C07K14/525 ,  C07K14/54 ,  C12P1/04

    CPC分类号： C12N1/38 ,  C12P21/02

    摘要： A method for the manufacture of products by biotechnological methods in bacterial cell culture is disclosed as well as products obtained, the use of certain additives to the media used in the manufacture of said products in bacterial cell culture media, and the use of said additives in reducing the detrimental effects of radicals in the manufacture of the products, as well as aspects related to these invention embodiments. The manufacturing process or method comprises adding one or more radical scavenging and/or antioxidative additive preferably selected from the group consisting of sterically hindered nitroxyls, sterically hindered hydroxylamines, sterically hindered hydroxylamine salt compounds, sterically hindered amino compounds and sterically hindered N-hydrocarbyloxyamines, benzofuranone compounds, as obligatory component(s) to the medium used during biosynthesis.

    摘要翻译： 公开了通过生物技术在细菌细胞培养中制造产品的方法，以及获得的产品，在细菌细胞培养基中用于制造所述产品的培养基中使用某些添加剂，以及所述添加剂在 降低了在制造产品中自由基的有害影响，以及与本发明实施方案相关的方面。 制备方法或方法包括加入一种或多种自由基清除和/或抗氧化添加剂，其优选选自空间位阻硝酰基，空间位阻羟胺，空间位阻羟胺盐化合物，空间位阻氨基化合物和空间位阻N-烃氧基胺，苯并呋喃酮 作为生物合成过程中使用的培养基的强制性成分。

    Process for the synthesis of amine ethers from secondary amino oxides
    8.
    发明授权
    Process for the synthesis of amine ethers from secondary amino oxides 有权

    公开(公告)号：US07402675B2

    公开(公告)日：2008-07-22

    申请号：US10919776

    申请日：2004-08-17

    申请人： Andreas Hafner ,  Hans Jürg Kirner ,  Franz Schwarzenbach ,  Paul Adriaan Van Der Schaaf ,  Peter Nesvadba

    发明人： Andreas Hafner ,  Hans Jürg Kirner ,  Franz Schwarzenbach ,  Paul Adriaan Van Der Schaaf ,  Peter Nesvadba

    IPC分类号： C07D211/54

    CPC分类号： C07D401/14 ,  C04B35/632 ,  C07D209/44 ,  C07D211/94 ,  C07D217/26 ,  C07D241/08 ,  C07D401/12 ,  C07D405/12 ,  C08K5/3412

    摘要： An amine ether of formula A wherein a is 1 or 2; and when a is 1, E is E′; when a is 2, E is L; E′ is C1-C36 alkyl; C3-C18 alkenyl; C2-C18 alkinyl; C5-C18 cycloalkyl; C5-C18 cycloalkenyl; a radical of a saturated or unsaturated aliphatic bicyclic or tricyclic hydrocarbon of 7 to 12 carbon atoms; C2-C7alkyl or C3-C7alkenyl substituted by halogen; C7-C15 aralkyl or C7-C15 aralkyl substituted by C1-C4 alkyl or phenyl; or E′ is a radical of formula (VII) as explained in claim 1; T′ is tertiary C4-C18alkyl or phenyl, each of which are unsubstituted or substituted by halogen, OH, COOR21 or C(O)—R22; or T′ is C5-C12cycloalkyl; C5-C12cycloalkyl which is interrupted by at least one O or —NR18—; a polycyclic alkyl radical having 7-18 carbon atoms, or the same radical which is interrupted by at least one O or —NR18—; or T′ is —C(G1)(G2)-T″; or C1-C18alkyl or C5-C12cycloalkyl substituted by T″ is hydrogen, halogen, NO2, cyano, or is a monovalent organic radical comprising 1-50 carbon atoms; or T″ and T′ together form a divalent organic linking group completing, together with the hindered amine nitrogen atom and the quaternary carbon atom substituted by G1 and G2, an optionally substituted five- or six-membered ring structure; and all other residues are as defined in claim 1, are obtained in good yield from the corresponding N-oxyl hindered amine precursor by reaction with a hydrocarbon E1-H or H-L-H in the presence of an organic hydroperoxide and a catalytic amount of copper or a copper compound. The products of present process find utility as polymerization regulators and/or light stabilizers for organic material.