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公开(公告)号：US06593270B1
公开(公告)日：2003-07-15
申请号：US09187420
申请日：1998-11-06
IPC分类号： B01J2344
CPC分类号： C04B35/14 , B01J21/08 , B01J35/002 , B01J35/023 , B01J35/1014 , B01J35/1019 , B01J35/1047 , B01J37/0018 , C07C67/055 , C07C69/01 , C07C69/15
摘要： Moldings based on pyrogenic silicon dioxide with a pore volume of 0.5 to 1.8 ml/g are prepared by homogenizing pyrogenic silicon dioxide with methylhydroxyethyl cellulose, wax and polyethylene glycol with the addition of water, subjecting this mixture to a compounding and shaping process, extruding, optionally cutting the extrudate to the desired length using a cutting device, drying at a temperature of 70° to 150° C. and conditioning for a period of 30 minutes to 10 hours at a temperature of 400° to 1200° C. The moldings may be used as catalysts or catalyst supports for the preparation of vinyl acetate monomer, the hydration of ethylene and the hydration of propylene.
摘要翻译： 通过用甲基羟乙基纤维素，蜡和聚乙二醇与加入水均匀化热解二氧化硅，制备孔体积为0.5至1.8ml / g的热解二氧化硅的模制品，使该混合物进行配混和成型过程， 任选地使用切割装置将挤出物切割成所需长度，在70℃至150℃的温度下干燥，并在400-1200℃的温度下调理30分钟至10小时。模制品可以 用作制备乙酸乙烯酯单体的催化剂或催化剂载体，乙烯的水合和丙烯的水合。
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公开(公告)号：US06207610B1
公开(公告)日：2001-03-27
申请号：US08857491
申请日：1997-05-16
申请人： Helmfried Krause , Hermanus Lansink Rotgerink , Thomas Tacke , Peter Panster , Roland Burmeister
发明人： Helmfried Krause , Hermanus Lansink Rotgerink , Thomas Tacke , Peter Panster , Roland Burmeister
IPC分类号： B01J2108
CPC分类号： C04B35/63452 , B01J21/08 , B01J23/52 , B01J23/58 , B01J35/0026 , B01J35/023 , B01J35/1014 , B01J35/1019 , B01J35/1042 , B01J35/1076 , B01J37/0018 , B01J37/0205 , C04B35/14 , C04B35/634 , C04B35/6365 , C07C67/035 , C07C69/01 , C07C69/15
摘要： Compacts based on pyrogenically produced silicon dioxide and having the following physical and chemical characteristics: Outer diameter 0.8-20 mm BET surface area 30-400 m2/g Pore volume 0.5-1.3 ml/g Breaking strength 10-250N Composition >99.8 wt. % SiO2 Other constituents
摘要翻译： 基于热解产生的二氧化硅并具有以下物理和化学特性的压块：产生的原因在于，热解产生的二氧化硅用甲基纤维素，微蜡和聚乙二醇加水均化，在80-150℃的温度下干燥。 并粉碎成粉末，任选地将粉末压缩成压坯，并在400至1200℃的温度下热处理0.5至8小时。 这些压块可用作乙酸乙烯酯单体生产和乙烯水合中的催化剂或催化剂载体。
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公开(公告)号：US20050202962A1
公开(公告)日：2005-09-15
申请号：US11124104
申请日：2005-05-09
CPC分类号： B01J21/066 , B01J21/063 , B01J21/08 , B01J27/16 , B01J37/0009 , B01J37/0018
摘要： A catalyst support consisting mainly of synthetic silica, with 0.5-10 parts by weight of one or more oxides or phosphates of the elements of group IIA, IIIB, IVB, VB, VIB, VIIB, VIII, IB, IIB, IIIA, IVA and the lanthanides characterised in that the support preparation method comprises mixing particulate synthetic silica with particulate oxides or phospates of the elements of Groups IIA, IIIB, IVB, VB, VIB, VIIB, VIII, IB, IIB, IIIA, IVA and the lanthanides, or with precursors thereof, a forming step and calcination. The catalyst support is used together with phosphoric acid in the production of alcohols from olefins by hydration.
摘要翻译： 主要由合成二氧化硅组成的催化剂载体，其具有0.5-10重量份的IIA，IIIB，IVB，VB，VIB，VIIB，VIII，IB，IIB，IIIA，IVA族元素的一种或多种氧化物或磷酸盐，以及 镧系元素的特征在于载体制备方法包括将颗粒状合成二氧化硅与IIA，IIIB，IVB，VB，VIB，VIIB，VIII，IB，IIB，IIIA，IVA族和镧系元素的元素的颗粒氧化物或磷酸盐混合，或 其前体，成型步骤和煅烧。 催化剂载体与磷酸一起用于通过水合由烯烃生产醇。
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4.发明授权Use of catalysts based on catalyst supports containing silicon dioxide for catalytic reactions under hydrothermal conditions 失效在含有二氧化硅的催化剂载体上，在水热条件下催化反应使用催化剂
公开(公告)号：US5959164A
公开(公告)日：1999-09-28
申请号：US806715
申请日：1997-02-27
申请人： H. G. J. Lansink-Rotgerink , Heike Riedemann , Thomas Tacke , Helmfried Krause , Andreas Freund , Roland Burmeister , Peter Panster
发明人： H. G. J. Lansink-Rotgerink , Heike Riedemann , Thomas Tacke , Helmfried Krause , Andreas Freund , Roland Burmeister , Peter Panster
CPC分类号： B01J21/066 , B01J21/063 , B01J21/08 , B01J27/16 , C07C29/04
摘要： The use of modified silicon dioxide as a catalyst support in catalytic reactions under hydrothermal conditions is described. The pore structure of the supports may be stabilized against hydrothermal reaction conditions by impregnating the catalyst supports with elements of Group IVB of the Periodic Tube of Elements.
摘要翻译： 描述了在水热条件下在催化反应中使用改性二氧化硅作为催化剂载体。 通过用元素周期管的IVB族元素浸渍催化剂载体，可以稳定支撑体的孔结构，防止水热反应条件。
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公开(公告)号：US06821922B1
公开(公告)日：2004-11-23
申请号：US09404537
申请日：1999-09-24
申请人： Thomas Tacke , Helmfried Krause , Hermanus G. J. Lansink Rotgerink , Francis Daly , Martin Reisinger , Helmut Mangold
发明人： Thomas Tacke , Helmfried Krause , Hermanus G. J. Lansink Rotgerink , Francis Daly , Martin Reisinger , Helmut Mangold
IPC分类号： B01J2358
CPC分类号： B01J37/0018 , B01J21/063 , B01J21/066 , B01J21/08 , B01J23/52 , B01J23/58 , B01J23/60 , B01J23/66 , B01J35/1014 , B01J35/1019 , B01J35/1038 , B01J35/1042 , C07C67/055 , C07C69/01 , C07C69/15
摘要： Moldings based on pyrogenically produced mixed oxide having the following physicochemical parameters: External diameter 0.8-25 mm BET surface area 5-400 m2/g Pore Volume 0.2-1.8 ml/g Fracture strength 5 to 350 N Composition At least two oxides selected from the group SiO2, Al2O3, TiO 2 and ZrO2 in any desired combination but with the exception of SiO2/Al2O3 mixed oxides, in which > 75 wt. % of SiO2 is present. Other constituents
摘要翻译： 基于具有以下物理化学参数的热解产生的混合氧化物的模制品是通过根据需要将一种或多种化合物与一种或多种来自甲基纤维素，甲基羟乙基纤维素，蜡，聚乙二醇，硬脂酸镁和/或硬脂酸铝的化合物均化， 水，在70-150℃的温度下干燥产物，任选地粉碎干燥的产物以产生粉末，任选地压缩粉末以产生模制品并在400℃的温度下进行0.5至10小时的热处理 °至1200℃。然后用合适的催化活性组分掺杂这些模制品，用于使用气相法生产乙酸乙烯酯单体。
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公开(公告)号：US06432869B1
公开(公告)日：2002-08-13
申请号：US09401498
申请日：1999-09-22
申请人： Helmfried Krause , Hermanus Gerhardus Josef Lansink Rotgerink , Thomas Tacke , Helmut Mangold , Heike Riedemann , Manfred Fuchs
发明人： Helmfried Krause , Hermanus Gerhardus Josef Lansink Rotgerink , Thomas Tacke , Helmut Mangold , Heike Riedemann , Manfred Fuchs
IPC分类号： B01J2108
CPC分类号： B01J21/066 , B01J21/00 , B01J21/063 , B01J27/16 , B01J35/0026 , B01J35/1014 , B01J35/1019 , B01J35/1038 , B01J35/1042 , B01J35/1047 , B01J37/0009 , C04B35/16 , C04B35/46
摘要： Moldings are disclosed for use as a catalyst or catalyst support for hydrating olefin, such as ethylene and propylene. The moldings are based on a pyrogenically produced mixed oxide having the following physicochemical parameters: External diameter 0.8-25 mm BET surface area 5-400 m2/g Pore volume 0.2-1.8 ml/g Fracture strength 5 to 350 N Composition At least two materials selected from the group of SiO2, Al2O3, TiO2 and ZrO2 in any desired combination, with the proviso that when the combination is a SiO2/Al2O3 mixed oxide, at least 75 wt. % of SiO2 is present based on the total weight of the mixed oxide. Other constituents
摘要翻译： 公开了用作催化剂或催化剂载体的模制品，用于使烯烃如乙烯和丙烯水合。 模制品基于具有以下物理化学参数的热解产生的混合氧化物：模制品通过将水和一种或多种选自甲基纤维素，甲基羟乙基纤维素，蜡，聚乙二醇，镁的化合物中的一种或多种化合物均化成热解产生的混合氧化物 硬脂酸酯或硬脂酸铝; 在70-150℃的温度下干燥产品; 任选地粉碎以产生粉末; 可选地压缩成型粉末以产生模制品; 并在400〜1200℃的温度下进行0.5〜10小时的热处理。在干燥之前，也可对混合物进行捏合和/或成型加工并挤出。
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7.发明授权Catalyst, method of its production and its use for the production of vinyl acetate monomer 失效催化剂，其生产方法及其在乙酸乙烯酯单体生产中的应用
公开(公告)号：US5808136A
公开(公告)日：1998-09-15
申请号：US589256
申请日：1996-01-23
申请人： Thomas Tacke , Herbert Mueller , Uwe Ohlrogge , Francis P. Daly , Hans Lansink Rotgerink , Helmfried Krause
发明人： Thomas Tacke , Herbert Mueller , Uwe Ohlrogge , Francis P. Daly , Hans Lansink Rotgerink , Helmfried Krause
IPC分类号： B01J21/06 , B01J23/52 , B01J23/58 , B01J23/62 , B01J23/66 , B01J31/04 , B01J37/02 , C07B61/00 , C07C67/05 , C07C67/055 , C07C69/15 , B01J23/38
CPC分类号： B01J21/066 , B01J21/063 , B01J23/52 , B01J23/58 , B01J23/66 , B01J31/04 , B01J31/26 , B01J37/0205 , B01J37/0207 , B01J37/0221 , C07C67/055 , B01J37/0201 , B01J37/0248
摘要： A catalyst and method of its production for use in making vinyl acetate monomer. The carrier is impregnated with a basic solution and a solution containing gold salts and palladium salts and finally impregnated with alkali acetate. The activity and selectivity of the catalyst, its mechanical strength, the noble-metal adhesion and the dispersion of noble metal on the carrier can be improved if the carrier is impregnated in a pretreatment with salts containing as cation elements of groups IA, IIA, IIIA and IVB of the periodic table and as anions elements of group VIIA or complex anions such as nitrate, sulfate or anions of organic acids such as acetate and lactate and is subsequently dried and calcined at temperatures of at least 160.degree. C.
摘要翻译： 用于制备乙酸乙烯酯单体的催化剂及其制备方法。 载体用碱性溶液和含有金盐和钯盐的溶液浸渍，最后用乙酸碱浸渍。 如果载体浸渍在含有作为IA，IIA，IIIA族的阳离子元素的盐的预处理中，则可以提高催化剂的活性和选择性，其机械强度，贵金属粘附性和贵金属在载体上的分散性 和IVB，并且是VIIA族的阴离子元素或诸如硝酸盐，硫酸盐或阴离子的有机酸如乙酸盐和乳酸盐的复合阴离子，随后在至少160℃的温度下干燥和煅烧。
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8.发明授权Molded articles based on pyrogenically prepared aluminum oxide and process for their production 失效基于热解法制备的氧化铝的成型制品及其生产工艺
公开(公告)号：US5015615A
公开(公告)日：1991-05-14
申请号：US492397
申请日：1990-03-07
申请人： Klaus Deller , Rainhard Klingel , Helmfried Krause
发明人： Klaus Deller , Rainhard Klingel , Helmfried Krause
CPC分类号： B01J21/04 , C04B35/111 , C04B38/00 , B01J35/0026 , B01J35/023 , B01J35/1014 , B01J35/1019 , B01J35/1038 , B01J35/1042 , B01J35/108 , C04B2111/0081
摘要： Molded articles based on pyrogenically prepared aluminum oxide and having the following physical-chemical characteristic data:______________________________________ External diameter: 2 to 15 mm BET surface area: 60 to 115 m.sup.2 /g Total Pore volume: 0.30 to 0.80 ml/g Crushing strength: 100 to 300N Pore size distribution: no pores
摘要翻译： 基于热解法制备的氧化铝并具有以下物理化学特性数据的成型制品：外径：2至15mm -BET表面积：60至115m2 / g - 总孔体积：0.30至0.80ml / g - 冲洗 强度：100〜300N - 孔径分布：直径不大于5nm的孔径， - 直径为10〜40nm范围的至少80％。 - 组合物：94〜99重量％的Al 2 O 3 - 剩余SiO 2。 - 它们是通过用高岭土和/或石墨，尿素，蜡，糖或淀粉加热水均匀化热解法制备的氧化铝来制备的，在80-120℃的温度下干燥该混合物，并将其粉碎形成 粉末，压制粉末以形成成型体，并通过在400℃至1200℃的温度下加热回火成型体0.5至6小时。 模制品可用作催化剂载体或催化剂。
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9.发明授权
公开(公告)号：US5132452A
公开(公告)日：1992-07-21
申请号：US626422
申请日：1990-12-14
IPC分类号： C07B61/00 , B01J23/644 , C07C51/31 , C07C59/105
CPC分类号： C07C51/313 , B01J23/6447
摘要： A process for making gluconic acid and its alkali metal salts by oxidizing glucose with oxygen or oxygen containing gas in an aqueous alkaline solution in the presence of an activated charcoal supported catalyst containing a platinum group metal component, e.g. platinum and palladium and bismuth wherein the platinum, palladium and bismuth are simultaneously deposited on the charcoal support.
摘要翻译： 在含有铂族金属组分的活性炭负载型催化剂存在下，通过在碱性水溶液中氧化含氧气体或含氧气体的葡萄糖酸及其碱金属盐的方法。 铂和钯和铋，其中铂，钯和铋同时沉积在木炭载体上。
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10.发明授权
公开(公告)号：US5099085A
公开(公告)日：1992-03-24
申请号：US664468
申请日：1991-03-01
IPC分类号： B01J35/04 , B01J12/00 , B01J19/24 , C07B39/00 , C07B61/00 , C07C17/15 , C07C17/156 , C07C19/045
CPC分类号： C07C17/15 , B01J12/007 , B01J19/2485 , C07B39/00 , B01J2219/00094 , B01J2219/00099
摘要： The use of hitherto known supported catalysts in chlorination processes and oxychlorination processes leads to high pressure drops and to the formation of hot spot temperatures in the reactor. When honeycomb monolithic catalyst supports provided with a multiplicity of channels open at both ends and parallel to the longitudinal axis are used, both the heat dissipation is improved and the pressure drops across the reactor are lowered drastically. This leads ultimately to an increase in the selectivity of the reaction and to a minimization of the combustion rate.
摘要翻译： 在氯化过程和氧氯化过程中使用迄今已知的负载型催化剂导致高压降和反应器中热点温度的形成。 当使用具有在两端开放并平行于纵向轴线的多个通道的蜂窝状整体式催化剂载体时，散热得到改善，并且跨过反应器的压降大幅降低。 这最终导致反应的选择性的增加和燃烧速率的最小化。
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