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    Electro chemical biosensor containing diazacyanine mediator for co-enzyme regeneration
    3.
    发明授权
    Electro chemical biosensor containing diazacyanine mediator for co-enzyme regeneration 失效
    含有二氮芥酸介质的电化学生物传感器用于辅酶再生

    公开(公告)号：US5866353A

    公开(公告)日：1999-02-02

    申请号：US762098

    申请日：1996-12-09

    申请人： Horst Berneth ,  Thomas Bocker ,  Henry Giera ,  Alison J. Murray ,  Hans-Ulrich Siegmund

    发明人： Horst Berneth ,  Thomas Bocker ,  Henry Giera ,  Alison J. Murray ,  Hans-Ulrich Siegmund

    IPC分类号： G01N27/327 ,  C12Q1/00 ,  C12Q1/32 ,  C09B44/10 ,  C12M1/00 ,  G01N27/26

    CPC分类号： C12Q1/004 ,  Y10S435/817

    摘要： A variety of diazacyanine mediators that are soluble in aqueous media and which do not inhibit enzymatic activity are provided for use on the surface of a working electrode of a electrochemical biosensor for electrochemical co-enzyme regeneration. The co-enzyme, dihydronicotinamide adenine dinucleotide (NADH) or dihydronicotinamide adenine dinucleotide phosphate (NADPH), is oxidized to NAD.sup.+ OR NADP.sup.+ which is reduced by an oxidoreductase such as a dehydrogenase acting on a substrate. By applying the mediator together with NADH or NADPH to the surface of the working electrode, the voltage necessary to achieve oxidation is substantially reduced. Biosensor electrodes such as graphite electrodes may be produced-by screen printing techniques.

    摘要翻译： 提供了可溶于水性介质并且不抑制酶活性的各种二氮芥酸介质用于电化学生物传感器用于电化学辅酶再生的工作电极的表面。 辅酶，二氢烟酰胺腺嘌呤二核苷酸（NADH）或二氢烟酰胺腺嘌呤二核苷酸磷酸（NADPH）被氧化成NAD + OR NADP +，其由氧化还原酶例如作用于底物的脱氢酶而还原。 通过将介体与NADH或NADPH一起施加到工作电极的表面，实现氧化所需的电压显着降低。 生物传感器电极如石墨电极可以通过丝网印刷技术制造。

    Dyeing or printing process with new and known cationic 4,5-dihydro-iH-1,2,3-triazolium compounds as dyestuffs and new cationic 4,5-dihydro-1H-1,2,3-triazolium compounds
    4.
    发明授权
    Dyeing or printing process with new and known cationic 4,5-dihydro-iH-1,2,3-triazolium compounds as dyestuffs and new cationic 4,5-dihydro-1H-1,2,3-triazolium compounds 失效
    新的和已知的阳离子4,5-二氢-h-1,2,3-三唑鎓化合物作为染料和新的阳离子4,5-二氢-1H-1,2,3-三唑鎓化合物的染色或印刷方法

    公开(公告)号：US5749925A

    公开(公告)日：1998-05-12

    申请号：US670913

    申请日：1996-06-26

    申请人： Thomas Bocker ,  Horst Berneth ,  Henry Giera

    发明人： Thomas Bocker ,  Horst Berneth ,  Henry Giera

    IPC分类号： C07D249/06 ,  C07D417/04 ,  C09B26/06 ,  C09B57/00 ,  D06P3/24 ,  D06P3/32 ,  D06P3/52 ,  D06P3/70 ,  D06P1/42 ,  D06P3/76

    CPC分类号： C07D417/04 ,  C07D249/06 ,  C09B26/06 ,  C09B57/00 ,  Y10S8/917 ,  Y10S8/918 ,  Y10S8/919 ,  Y10S8/927

    摘要： 4,5-Dihydro-1H-1,2,3-triazolium compounds of the formula (I) ##STR1## in which R.sup.1 and R.sup.2 independently of one another denote C.sub.6 -C.sub.14 -aryl or a heterocyclic radical having up to 3 rings and up to 4 heteroatoms from the series consisting of O, S and N, R.sup.3 and R.sup.4 independently of one another denote hydrogen, C.sub.1 -C.sub.12 -alkyl, C.sub.2 -C.sub.12 -alkenyl, C.sub.4 -C.sub.8 -cycloalkyl, C.sub.7 -C.sub.17 -aralkyl, C.sub.6 -C.sub.14 -aryl or nitrile or R.sup.3 and R.sup.4 together denote a 2- to 5-membered C bridge, which can optionally be interrupted by up to two oxygen and/or nitrogen atoms, and X.sup.- denotes an anion, wherein all the alkyl, alkenyl, cycloalkyl, aralkyl and aryl radicals and fused and heterocyclic radicals present can optionally be substituted by nonionic substituents, carboxyl groups, ammonium groups and/or pyridinium groups, are used as dyestuffs. New 4,5-dihydro-1H-1,2,3-triazolium compounds correspond to the formula (I), with the provisos that if R.sup.3 and R.sup.4 in each case denote hydrogen then in the case where R.sup.1 =4-methylphenyl R.sup.2 does not represent 4-nitrophenyl, 4-methoxyphenyl or phenyl and R.sup.1 and R.sup.2 do not both simultaneously represent 4-methylphenyl, 4-nitrophenyl, 4-methoxyphenyl or phenyl.

    摘要翻译： R 1和R 2彼此独立地表示的式（I）的化合物（I）的4,5-二氢-1H-1,2,3-三唑鎓表示C 6 -C 14 - 芳基或具有至多 3个环和至多4个由O，S和N组成的系列的杂原子，R 3和R 4彼此独立地表示氢，C 1 -C 12 - 烷基，C 2 -C 12 - 链烯基，C 4 -C 8环烷基，C 7 -C 17 - 芳烷基，C 6 -C 14 - 芳基或腈，或者R 3和R 4一起表示2-至5-元C桥，其可以任选地被多达两个氧和/或氮原子间隔，X-表示阴离子，其中所有 存在的烷基，烯基，环烷基，芳烷基和芳基以及稠合和杂环基团可任选被非离子取代基，羧基，铵基和/或吡啶鎓基取代，用作染料。 新的4,5-二氢-1H-1,2,3-三唑鎓化合物对应于式（I），条件是如果R 3和R 4在每种情况下表示氢，则在R1 = 4-甲基苯基R2的情况下 不代表4-硝基苯基，4-甲氧基苯基或苯基，R1和R2不同时表示4-甲基苯基，4-硝基苯基，4-甲氧基苯基或苯基。

    Process for preparing 4-aminodiphenylamine
    7.
    发明授权
    Process for preparing 4-aminodiphenylamine 失效
    制备4-氨基二苯胺的方法

    公开(公告)号：US06414192B1

    公开(公告)日：2002-07-02

    申请号：US10007014

    申请日：2001-11-06

    申请人： Michael Schelhaas ,  Carl Casser ,  Dietmar Bielefeldt ,  Pieter Ooms ,  Joachim Haider ,  Manfred Jautelat ,  Christian Laue ,  Henry Giera

    发明人： Michael Schelhaas ,  Carl Casser ,  Dietmar Bielefeldt ,  Pieter Ooms ,  Joachim Haider ,  Manfred Jautelat ,  Christian Laue ,  Henry Giera

    IPC分类号： C07C20900

    CPC分类号： C07C209/38 ,  C07C211/55

    摘要： The invention provides a process for preparing 4-aminodiphenylamine, an important starting product for synthesizing antioxidants and stabilizers in the rubber and polymer industry, by hydrogenating nitrosobenzene with hydrogen in the presence of a proton acid as catalyst and in the presence of a hydrogenating catalyst, optionally in the presence of an inert organic solvent and thermally decomposing the 4-ADPA ammonium salt produced in this way, wherein 4-ADPA is obtained. 4-aminodiphenylamine is produced in good yields and high purity by the process according to the present invention. Furthermore, no effluent is produced, which makes the process particularly economic and ecological.

    摘要翻译： 本发明提供一种制备4-氨基二苯胺的方法，该方法是在质子酸作为催化剂存在下，在氢化催化剂存在下，通过在氢气存在下，用氢气将亚硝基苯氢化，在橡胶和聚合物工业中合成抗氧化剂和稳定剂的重要起始产物， 任选地在惰性有机溶剂的存在下，并以这种方式产生的4-ADPA铵盐热分解，得到4-ADPA。4-氨基二苯胺通过本发明的方法以良好的产率和高纯度生产。 此外，没有产生流出物，这使得该过程特别经济和生态。