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公开(公告)号：US07250123B2
公开(公告)日：2007-07-31
申请号：US11070503
申请日：2005-03-01
IPC分类号： B29C44/00
CPC分类号： B22F3/20 , B22F7/062 , B22F2999/00 , B29C47/0014 , B29C47/025 , B32B18/00 , B32B2315/02 , C04B35/117 , C04B35/119 , C04B35/5626 , C04B35/565 , C04B35/58021 , C04B35/584 , C04B37/001 , C04B2235/3206 , C04B2235/3217 , C04B2235/3225 , C04B2235/3232 , C04B2235/3277 , C04B2235/3418 , C04B2235/3826 , C04B2235/3839 , C04B2235/3843 , C04B2235/3847 , C04B2235/3865 , C04B2235/3873 , C04B2235/3886 , C04B2235/404 , C04B2235/405 , C04B2235/428 , C04B2235/5436 , C04B2235/5445 , C04B2235/6021 , C04B2235/652 , C04B2235/6581 , C04B2235/668 , C04B2235/721 , C04B2235/728 , C04B2235/80 , C04B2235/94 , C04B2235/96 , C04B2237/343 , C04B2237/348 , C04B2237/36 , C04B2237/361 , C04B2237/365 , C04B2237/368 , C04B2237/704 , C22C1/053 , C22C47/14 , C22C49/00 , Y10T428/24942 , Y10T428/249967 , Y10T428/2918
摘要： A composite construction 1 is obtained by coating the outer periphery of a core material 2 with a shell layer 3. The core material 2 is composed of a first sintered body that is obtained by bonding, with a binder metal, a first hard particle composed of one or more of carbides, nitrides and carbonitrides of metals of Groups 4a, 5a and 6a of the Periodic Table, or a first ceramics obtained by bonding, with a sintering additive, a first ceramic particle composed of at least one of oxides, carbides, nitrides and carbonitrides selected from the group consisting of metals of Groups 4a, 5a and 6a of the Periodic Table, Al, Si and Zn. The shell layer 3 is composed of a second hard sintered body or second ceramics having a different composition from the first hard sintered body. The ratio of the residual free carbon amount Cin in the core material 2 to the residual free carbon amount Cout in the shell layer 3, Cin/Cout, is 0.5 to 2. This prevents shrinkage during the time of sintering and also prevents the strength of the composite construction from lowering due to poor sintering.
摘要翻译： 通过用壳层3涂覆芯材2的外周来获得复合结构1。 芯材2由第一烧结体构成，该第一烧结体通过与粘合剂金属粘合由第一组分，第一组和第二组中的一种或多种碳化物，氮化物和碳氮化物组成的第一硬质颗粒 元素周期表或通过与烧结添加剂结合而获得的第一陶瓷颗粒，所述第一陶瓷颗粒由选自第4a，5a和6组的金属的氧化物，碳化物，氮化物和碳氮化物中的至少一种组成 a的元素周期表，Al，Si和Zn。 壳层3由与第一硬质烧结体成分不同的第二硬质烧结体或第二陶瓷构成。 核心材料2中的中的残留游离碳量C 与壳层3中的剩余游离碳量C 的比例< 其为0.5〜2.这样可以防止烧结时的收缩，同时也防止复合结构的强度因烧结不良而降低。
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公开(公告)号：US06878434B2
公开(公告)日：2005-04-12
申请号：US10389263
申请日：2003-03-14
IPC分类号： B22F7/06 , B29C47/02 , C04B35/117 , C04B35/119 , C04B37/00 , C22C1/05 , C22C47/14 , C22C49/00 , B23B51/00
CPC分类号： B22F3/20 , B22F7/062 , B22F2999/00 , B29C47/0014 , B29C47/025 , B32B18/00 , B32B2315/02 , C04B35/117 , C04B35/119 , C04B35/5626 , C04B35/565 , C04B35/58021 , C04B35/584 , C04B37/001 , C04B2235/3206 , C04B2235/3217 , C04B2235/3225 , C04B2235/3232 , C04B2235/3277 , C04B2235/3418 , C04B2235/3826 , C04B2235/3839 , C04B2235/3843 , C04B2235/3847 , C04B2235/3865 , C04B2235/3873 , C04B2235/3886 , C04B2235/404 , C04B2235/405 , C04B2235/428 , C04B2235/5436 , C04B2235/5445 , C04B2235/6021 , C04B2235/652 , C04B2235/6581 , C04B2235/668 , C04B2235/721 , C04B2235/728 , C04B2235/80 , C04B2235/94 , C04B2235/96 , C04B2237/343 , C04B2237/348 , C04B2237/36 , C04B2237/361 , C04B2237/365 , C04B2237/368 , C04B2237/704 , C22C1/053 , C22C47/14 , C22C49/00 , Y10T428/24942 , Y10T428/249967 , Y10T428/2918
摘要： A composite construction 1 is obtained by coating the outer periphery of a core material 2 with a shell layer 3. The core material 2 is composed of a first sintered body that is obtained by bonding, with a binder metal, a first hard particle composed of one or more of carbides, nitrides and carbonitrides of metals of Groups 4a, 5a and 6a of the Periodic Table, or a first ceramics obtained by bonding, with a sintering additive, a first ceramic particle composed of at least one of oxides, carbides, nitrides and carbonitrides selected from the group consisting of metals of Groups 4a, 5a and 6a of the Periodic Table, Al, Si and Zn. The shell layer 3 is composed of a second hard sintered body or second ceramics having a different composition from the first hard sintered body. The ratio of the residual free carbon amount Cin in the core material 2 to the residual free carbon amount Cout in the shell layer 3, Cin/Cout, is 0.5 to 2. This prevents shrinkage during the time of sintering and also prevents the strength of the composite construction from lowering due to poor sintering.
摘要翻译： 复合结构1通过用壳层3涂覆芯材2的外周来获得。芯材2由第一烧结体组成，该第一烧结体通过与粘合剂金属粘合，由第一烧结体 元素周期表4a，5a和6a族金属的碳化物，氮化物和碳氮化物中的一种或多种，或通过烧结添加剂将由氧化物，碳化物， 氮化物和碳氮化物，其选自周期表第4a，5a和6a族的金属，Al，Si和Zn。 壳层3由与第一硬质烧结体成分不同的第二硬质烧结体或第二陶瓷构成。 壳层3中的芯材2中的剩余游离碳量Cin与Cin / Cout的残留游离碳量Cout的比例为0.5〜2。这样可以防止烧结时的收缩， 复合结构由于烧结不良而降低。
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公开(公告)号：US20050147851A1
公开(公告)日：2005-07-07
申请号：US11070503
申请日：2005-03-01
IPC分类号： B22F7/06 , B29C47/02 , C04B35/117 , C04B35/119 , C04B37/00 , C22C1/05 , C22C47/14 , C22C49/00 , B22F7/00
CPC分类号： B22F3/20 , B22F7/062 , B22F2999/00 , B29C47/0014 , B29C47/025 , B32B18/00 , B32B2315/02 , C04B35/117 , C04B35/119 , C04B35/5626 , C04B35/565 , C04B35/58021 , C04B35/584 , C04B37/001 , C04B2235/3206 , C04B2235/3217 , C04B2235/3225 , C04B2235/3232 , C04B2235/3277 , C04B2235/3418 , C04B2235/3826 , C04B2235/3839 , C04B2235/3843 , C04B2235/3847 , C04B2235/3865 , C04B2235/3873 , C04B2235/3886 , C04B2235/404 , C04B2235/405 , C04B2235/428 , C04B2235/5436 , C04B2235/5445 , C04B2235/6021 , C04B2235/652 , C04B2235/6581 , C04B2235/668 , C04B2235/721 , C04B2235/728 , C04B2235/80 , C04B2235/94 , C04B2235/96 , C04B2237/343 , C04B2237/348 , C04B2237/36 , C04B2237/361 , C04B2237/365 , C04B2237/368 , C04B2237/704 , C22C1/053 , C22C47/14 , C22C49/00 , Y10T428/24942 , Y10T428/249967 , Y10T428/2918
摘要： A composite construction 1 is obtained by coating the outer periphery of a core material 2 with a shell layer 3. The core material 2 is composed of a first sintered body that is obtained by bonding, with a binder metal, a first hard particle composed of one or more of carbides, nitrides and carbonitrides of metals of Groups 4a, 5a and 6a of the Periodic Table, or a first ceramics obtained by bonding, with a sintering additive, a first ceramic particle composed of at least one of oxides, carbides, nitrides and carbonitrides selected from the group consisting of metals of Groups 4a, 5a and 6a of the Periodic Table, Al, Si and Zn. The shell layer 3 is composed of a second hard sintered body or second ceramics having a different composition from the first hard sintered body. The ratio of the residual free carbon amount Cin in the core material 2 to the residual free carbon amount Cout in the shell layer 3, Cin/Cout, is 0.5 to 2. This prevents shrinkage during the time of sintering and also prevents the strength of the composite construction from lowering due to poor sintering.
摘要翻译： 复合结构1通过用壳层3涂覆芯材2的外周来获得。芯材2由第一烧结体组成，该第一烧结体通过与粘合剂金属粘合，由第一烧结体 元素周期表4a，5a和6a族金属的碳化物，氮化物和碳氮化物中的一种或多种，或通过烧结添加剂将由氧化物，碳化物， 氮化物和碳氮化物，其选自周期表第4a，5a和6a族的金属，Al，Si和Zn。 壳层3由与第一硬质烧结体成分不同的第二硬质烧结体或第二陶瓷构成。 核心材料2中的中的残留游离碳量C 与壳层3中的剩余游离碳量C 的比例< 其为0.5〜2.这样可以防止烧结时的收缩，同时也防止复合结构的强度因烧结不良而降低。
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公开(公告)号：US20080075543A1
公开(公告)日：2008-03-27
申请号：US11863113
申请日：2007-09-27
IPC分类号： B26D1/00
CPC分类号： B23B27/14 , B23B2200/201 , B23B2228/10 , C04B35/119 , C04B35/5611 , C04B35/58014 , C04B35/58021 , C04B35/581 , C04B35/5831 , C04B41/009 , C04B41/5068 , C04B41/87 , C04B2235/3206 , C04B2235/3217 , C04B2235/3275 , C04B2235/3279 , C04B2235/3804 , C04B2235/3813 , C04B2235/3817 , C04B2235/3826 , C04B2235/3839 , C04B2235/3843 , C04B2235/3847 , C04B2235/3852 , C04B2235/3856 , C04B2235/386 , C04B2235/3865 , C04B2235/3873 , C04B2235/3886 , C04B2235/40 , C04B2235/402 , C04B2235/404 , C04B2235/405 , C04B2235/428 , C04B2235/46 , C04B2235/5445 , C04B2235/656 , C04B2235/6562 , C04B2235/6565 , C04B2235/6567 , C04B2235/762 , C04B2235/767 , C04B2235/80 , C04B2235/96 , C22C29/08 , C23C14/0641 , C23C30/005 , Y10T407/27 , Y10T408/03 , Y10T428/252 , C04B41/4529 , C04B41/455 , C04B41/5057 , C04B41/5061 , C04B41/5063 , C04B35/10 , C04B35/117
摘要： A cutting tool having a substrate and a coating layer for coating the surface of the substrate, the coating layer being composed of Ti1-a-b-c-dAlaWbSicMd(CxN1-x) where M is at least one selected from Nb, Mo, Ta, Hf and Y, 0.45≦a≦0.55, 0.01≦b≦0.1, 0.01≦c≦0.05, 0.01≦d≦0.1, and 0≦x≦1. The cutting tool has excellent wear resistance and fracture resistance. The cutting tool may be further provided with a layer composed of at least one selected from carbides, nitrides and carbonitrides of Al and the elements of the groups 4, 5 and 6 of the periodic table.
摘要翻译： 一种切削工具，其具有基材和用于涂覆基材表面的涂层，所述涂层由Ti 1-abcd Al a a B b， 其中M是至少一个选择的（C x N 1 N x）其中M是至少一个选择的 从Nb，Mo，Ta，Hf和Y，0.45 <= a <= 0.55,0.01 <= b <= 0.1,0.01 <= c <= 0.05,0.01 <= d <= 0.1，0 <= x < 1。 该切削工具具有优异的耐磨性和抗断裂性。 切割工具还可以具有由选自Al的碳化物，氮化物和碳氮化物中的至少一种和元素周期表第4,5,6族的元素组成的层。
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5.发明授权公开(公告)号：US07749932B2
公开(公告)日：2010-07-06
申请号：US12071502
申请日：2008-02-21
IPC分类号： C04B35/587
CPC分类号： C04B35/584 , Y10T428/252
摘要： A sintered product of silicon nitride includes a crystal phase mainly having silicon nitride crystal grains and an amorphous grain-boundary phase located on the grain boundaries of the silicon nitride crystal grains. The grain-boundary phase contains lanthanum, aluminum, magnesium, silicon, and oxygen. The sintered product described above contains 0.1% by mass or more of lanthanum on an oxide basis, 0.05 to 0.6% by mass of aluminum on an oxide basis, 0.3% by mass or more of magnesium on an oxide basis, and 2.5% by mass or less of oxygen. The total amount of lanthanum on an oxide basis, aluminum on an oxide basis, and magnesium on an oxide basis is 3.5% by mass or less.
摘要翻译： 氮化硅的烧结体包括主要具有氮化硅晶粒的晶相和位于氮化硅晶粒的晶界上的无定形晶界相。 晶界相包含镧，铝，镁，硅和氧。 上述烧结体含有0.1质量％以上的氧化镧，0.05〜0.6质量％的氧化铝，0.3质量％以上的氧化镁，2.5质量％ 以下的氧气。 以氧化物为基准的镧的总量，以氧化物为基准的铝和氧化物的镁为3.5质量％以下。
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6.发明申请公开(公告)号：US20080220243A1
公开(公告)日：2008-09-11
申请号：US12071502
申请日：2008-02-21
IPC分类号： C04B35/584 , B32B18/00
CPC分类号： C04B35/584 , Y10T428/252
摘要： A sintered product of silicon nitride includes a crystal phase mainly having silicon nitride crystal grains and an amorphous grain-boundary phase located on the grain boundaries of the silicon nitride crystal grains. The grain-boundary phase contains lanthanum, aluminum, magnesium, silicon, and oxygen. The sintered product described above contains 0.1% by mass or more of lanthanum on an oxide basis, 0.05 to 0.6% by mass of aluminum on an oxide basis, 0.3% by mass or more of magnesium on an oxide basis, and 2.5% by mass or less of oxygen. The total amount of lanthanum on an oxide basis, aluminum on an oxide basis, and magnesium on an oxide basis is 3.5% by mass or less.
摘要翻译： 氮化硅的烧结体包括主要具有氮化硅晶粒的晶相和位于氮化硅晶粒的晶界上的无定形晶界相。 晶界相包含镧，铝，镁，硅和氧。 上述烧结体含有0.1质量％以上的氧化镧，0.05〜0.6质量％的氧化铝，0.3质量％以上的氧化镁，2.5质量％ 以下的氧气。 以氧化物为基准的镧的总量，以氧化物为基准的铝和氧化物的镁为3.5质量％以下。
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公开(公告)号：US08496718B2
公开(公告)日：2013-07-30
申请号：US12411186
申请日：2009-03-25
IPC分类号： C09K3/14
CPC分类号： C04B35/587 , B23C2226/73 , C04B35/593 , C04B35/5935 , C04B35/6455 , C04B2235/3206 , C04B2235/3217 , C04B2235/3224 , C04B2235/3225 , C04B2235/3227 , C04B2235/3229 , C04B2235/3418 , C04B2235/3869 , C04B2235/3878 , C04B2235/3882 , C04B2235/3891 , C04B2235/5436 , C04B2235/5445 , C04B2235/6562 , C04B2235/6565 , C04B2235/658 , C04B2235/6587 , C04B2235/723 , C04B2235/75 , C04B2235/77 , C04B2235/786 , C04B2235/80 , Y10T428/24355 , Y10T428/24942 , Y10T428/24983
摘要： A silicon nitride cutting tool comprising a sintered product is disclosed. The sintered product comprises silicon nitride, at least one rare earth element compound, and a magnesium compound. The silicon nitride cutting tool further comprises a surface region and an inside region comprising the sintered product with varying content ratios of component compounds to provide enhanced wear and fracture resistance.
摘要翻译： 公开了一种包含烧结产品的氮化硅切割工具。 烧结产品包括氮化硅，至少一种稀土元素化合物和镁化合物。 氮化硅切割工具还包括表面区域和内部区域，其包含具有不同成分化合物含量比的烧结产品，以提供增强的耐磨性和耐断裂性。
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公开(公告)号：US07811683B2
公开(公告)日：2010-10-12
申请号：US11863113
申请日：2007-09-27
IPC分类号： B32B9/00
CPC分类号： B23B27/14 , B23B2200/201 , B23B2228/10 , C04B35/119 , C04B35/5611 , C04B35/58014 , C04B35/58021 , C04B35/581 , C04B35/5831 , C04B41/009 , C04B41/5068 , C04B41/87 , C04B2235/3206 , C04B2235/3217 , C04B2235/3275 , C04B2235/3279 , C04B2235/3804 , C04B2235/3813 , C04B2235/3817 , C04B2235/3826 , C04B2235/3839 , C04B2235/3843 , C04B2235/3847 , C04B2235/3852 , C04B2235/3856 , C04B2235/386 , C04B2235/3865 , C04B2235/3873 , C04B2235/3886 , C04B2235/40 , C04B2235/402 , C04B2235/404 , C04B2235/405 , C04B2235/428 , C04B2235/46 , C04B2235/5445 , C04B2235/656 , C04B2235/6562 , C04B2235/6565 , C04B2235/6567 , C04B2235/762 , C04B2235/767 , C04B2235/80 , C04B2235/96 , C22C29/08 , C23C14/0641 , C23C30/005 , Y10T407/27 , Y10T408/03 , Y10T428/252 , C04B41/4529 , C04B41/455 , C04B41/5057 , C04B41/5061 , C04B41/5063 , C04B35/10 , C04B35/117
摘要： A cutting tool having a substrate and a coating layer for coating the surface of the substrate, the coating layer being composed of Ti1−a−b−c−dAlaWbSicMd(CxN1−x), where M is at least one selected from Nb, Mo, Ta, Hf and Y, 0.45≦a≦0.55, 0.01≦b≦0.1, 0.01≦c≦0.05, 0.01≦d≦0.1, and 0≦x≦1. The cutting tool has excellent wear resistance and fracture resistance. The cutting tool may be further provided with a layer composed of at least one selected from carbides, nitrides and carbonitrides of Al and the elements of the groups 4, 5 and 6 of the periodic table.
摘要翻译： 一种切割工具，具有用于涂覆基板表面的基板和涂层，所述涂层由Ti1-a-b-c-dAlaWbSicMd（CxN1-x）构成，其中M为选自Nb，Mo ，Ta，Hf和Y，0.45＆nlE; a＆nlE; 0.55,0.01和nlE; b＆nlE; 0.1,0.01和nlE; c＆nlE; 0.05,0.01和nlE; d＆nlE; 0.1,0和nlE; x和nlE; 该切削工具具有优异的耐磨性和耐断裂性。 切割工具还可以具有由选自Al的碳化物，氮化物和碳氮化物中的至少一种和元素周期表第4,5,6族的元素组成的层。
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公开(公告)号：US08236411B2
公开(公告)日：2012-08-07
申请号：US12598175
申请日：2009-03-25
申请人： Masahiro Waki , Tatsuyuki Nakaoka , Shuichi Tateno , Takashi Watanabe , Kenji Noda , Takahiko Makino , YaoCan Zhu
发明人： Masahiro Waki , Tatsuyuki Nakaoka , Shuichi Tateno , Takashi Watanabe , Kenji Noda , Takahiko Makino , YaoCan Zhu
IPC分类号： B23B27/14
CPC分类号： C23C14/0641 , C04B41/009 , C04B41/52 , C04B41/89 , C23C14/0664 , C23C30/005 , Y10T407/27 , Y10T428/24975 , Y10T428/252 , Y10T428/265 , C04B35/117 , C04B35/5831 , C04B35/584 , C04B41/4529 , C04B41/5063 , C04B41/5068 , C04B41/5061 , C04B41/522
摘要： An object of embodiments according to the invention is to provide a cutting tool having good wear resistance, good sliding property and good fracture resistance.A cutting tool 1 comprising a substrate 2 and a coating layer 6 or a coating layer 9 which covers a surface of the substrate 2. The coating layer 6 or the coating layer 9 comprising a first layer 7 and a second layer 8. The first layer 7 comprises Ti1-a-b-c-dAlaWbSicMd(C1-xNx) when M is at least one selected from Nb, Mo, Hf and Y, 0.45≦a≦0.55, 0.01≦b≦0.1, 0≦c≦0.05, 0.01≦d≦0.1, 0≦x≦1). The second layer 8 comprises Ti1-e-f-gAleSifM′g(C1-yNy) when M′ is at least one selected from Nb, Mo, Ta, Hf and Y, 0.50≦e≦0.60, 0≦f≦0.1, 0.05≦g≦0.15, 0≦y≦1).
摘要翻译： 根据本发明的实施例的目的是提供具有良好的耐磨性，良好的滑动性和良好的抗断裂性的切削工具。 包括基材2和涂层6或覆盖基材2的表面的涂层9的切削工具1.涂层6或涂层9包括第一层7和第二层8.第一层 当M是选自Nb，Mo，Hf和Y中的至少一种时，7包括Ti1-abc-dAlaWbSicMd（C1-xNx），0.45和n1E; a＆nlE; 0.55,0.01和nlE; b＆lt;0.1,0,0≤n1E; ; d＆nlE; 0.1,0＆amp; nlE; x＆nlE; 1）。 当M'为选自Nb，Mo，Ta，Hf和Y中的至少一种时，第二层8包括Ti1-ef-gAleSifM'g（C1-yNy），0.50＆nlE; e＆nlE; 0.60,0和nlE; f＆nlE; 0.1,0.05 ＆nlE; g＆nlE; 0.15,0和nlE; y＆nlE; 1）。
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公开(公告)号：US20100129168A1
公开(公告)日：2010-05-27
申请号：US12598175
申请日：2009-03-25
申请人： Masahiro Waki , Tatsuyuki Nakaoka , Shuichi Tateno , Takashi Watanabe , Kenji Noda , Takahiko Makino
发明人： Masahiro Waki , Tatsuyuki Nakaoka , Shuichi Tateno , Takashi Watanabe , Kenji Noda , Takahiko Makino
IPC分类号： B23B27/14
CPC分类号： C23C14/0641 , C04B41/009 , C04B41/52 , C04B41/89 , C23C14/0664 , C23C30/005 , Y10T407/27 , Y10T428/24975 , Y10T428/252 , Y10T428/265 , C04B35/117 , C04B35/5831 , C04B35/584 , C04B41/4529 , C04B41/5063 , C04B41/5068 , C04B41/5061 , C04B41/522
摘要： An object of embodiments according to the invention is to provide a cutting tool having good wear resistance, good sliding property and good fracture resistance.A cutting tool 1 comprising a substrate 2 and a coating layer 6 or a coating layer 9 which covers a surface of the substrate 2. The coating layer 6 or the coating layer 9 comprising a first layer 7 and a second layer 8. The first layer 7 comprises Ti1-a-b-c-dAlaWbSicMd(C1-xNx) when M is at least one selected from Nb, Mo, Hf and Y, 0.45≦a≦0.55, 0.01≦b≦0.1, 0≦c≦0.05, 0.01≦d≦0.1, 0≦x≦1). The second layer 8 comprises Ti1-e-f-gAleSifM′g(C1-yNy) when M′ is at least one selected from Nb, Mo, Ta, Hf and Y, 0.50≦e≦0.60, 0≦f≦0.1, 0.05≦g≦0.15, 0≦y≦1).
摘要翻译： 根据本发明的实施例的目的是提供具有良好的耐磨性，良好的滑动性和良好的抗断裂性的切削工具。 包括基材2和涂层6或覆盖基材2的表面的涂层9的切削工具1.涂层6或涂层9包括第一层7和第二层8.第一层 当M是选自Nb，Mo，Hf和Y中的至少一种时，7包括Ti1-abc-dAlaWbSicMd（C1-xNx），0.45和n1E; a＆nlE; 0.55,0.01和nlE; b＆lt;0.1,0,0≤n1E; ; d＆nlE; 0.1,0＆amp; nlE; x＆nlE; 1）。 当M'为选自Nb，Mo，Ta，Hf和Y中的至少一种时，第二层8包括Ti1-ef-gAleSifM'g（C1-yNy），0.50＆nlE; e＆nlE; 0.60,0和nlE; f＆nlE; 0.1,0.05 ＆nlE; g＆nlE; 0.15,0和nlE; y＆nlE; 1）。
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