摘要:
In a coated metal structure comprising a metal substrate and a coating layer of a thermoplastic polyester resin heat-bonded to the metal surface, the polyester resin has a relative viscosity of 1.2 to 1.8 as measured at 25.degree. C. in o-chlorophenol at a concentration of 0.5 g/100 ml and the tack point of the polyester resin is not lower than 130.degree. C. and the degree of crystallinity of the polyester resin is up to 30%.This structure has improved peel resistance and is excellent in mechanical and chemical properties, especially adaptability to shaping processing and corrosion resistance. This structure can easily be formed into various vessels and containers and closure means of vessels and containers by such processing as drawing and ironing. This structure provides shaped articles excellent in peel resistance, corrosion resistance and processability.
摘要:
A can at least a part of which is made of an electrolytically chromated steel sheet, said steel sheet having such a surface that when it is degreased in acetone for 1 minute and analyzed by an Auger electron spectrometer at an incident electron accelerating voltage of 3 KeV, a modulation voltage of 3 V, a modulation frequency of 12 to 20 KHz and a degree of vacuum of at least 6.times.10.sup.-8 torr, the ratio of the peak-peak distance (O.sub.P-P) of KL.sub.2.3 L.sub.2.3 of oxygen to the base-peak distance (Cr.sub.B-P) of L.sub.3 M.sub.2.3 M.sub.4.5 of chromium in the resulting Auger electron spectrum satisfies the following relation:6.5.gtoreq.(O.sub.P-P)/(Cr.sub.B-P).gtoreq.1.5.
摘要:
Disclosed is a bonded can of the key-opening type comprising a coated metal blank and a seam formed by lap-bonding outer and inner end edge portions of the coated metal blank to each other by a tape of a thermoplastic resin adhesive, wherein the adhesive is a polyamide type or polyester type adhesive, the inner end edge portion forming the seam of the bonded can is completely covered with the adhesive tape, the outer edge portion has a winding-starting tongue piece integrated therewith, a plurality of scores are formed on the outer surface of the coated metal blank from the base of the tongue piece along the entire circumference inclusive of the seam, the scores have a knife angle of 45.degree. to 120.degree. and a depth corresponding to 8 to 45% of the thickness of the metal blank, a coating of an epoxy resin having a thermal softening point of 65.degree. to 150.degree. C. as measured according to the thermomechanical method is formed at least at the seam-forming part on the outer surface and said epoxy resin coating forms a continuous layer adhering closely to the metal blank even in the portion of said scores.
摘要:
Disclosed is a bonded can of the key-opening type comprising a coated metal blank and a seam formed by lap-bonding outer and inner end edge portions of the coated metal blank to each other by a tape of a thermoplastic resin adhesive, wherein the adhesive is a polyamide type or polyester type adhesive, the inner end edge portion forming the seam of the bonded can is completely covered with the adhesive tape, the outer edge portion has a winding-starting tongue piece integrated therewith, a plurality of scores are formed on the outer surface of the coated metal blank from the base of the tongue piece along the entire circumference inclusive of the seam, the scores have a knife angle of 45.degree. to 120.degree. and a depth corresponding to 8 to 45% of the thickness of the metal blank, a coating of an epoxy resin having a thermal softening point of 65.degree. to 150.degree. C. as measured according to the thermomechanical method is formed at least at the seam-forming part on the outer surface and said epoxy resin coating forms a continuous layer adhering closely to the metal blank even in the portion of said scores.
摘要:
A can end sealing rubber composition(A) consisting essentially of a styrene-butadiene rubbery copolymer, a tackifier and a filler, and(B) having (1) a creep resistance coefficient K defined by the following equation of at least 0.1 but not exceeding 0.6,K=log J.sub.90.sup.C (10)-log J.sub.90.sup.C (1) wherein J.sub.90.sup.C (10) is the creep compliance measured 10 minutes after exerting a load when a fabricated article of the composition as a specimen is compressed in water at 90.degree. C. by a parallel plate plastometer, and J.sub.90.sup.C (1) is the creep compliance measured 1 minute after exerting a load when the specimen is compressed in water at 90.degree. C. by a parallel plate plastomer,and (2) a creep compliance J.sub.25.sup.C (1) of at least 3.times.10.sup.-9 cm.sup.2 /dyne but not exceeding 1.times.10.sup.-6 cm.sup.2 /dyne, the creep compliance being measured 1 minute after exerting a load when the specimen is compressed in water at 25.degree. C. by a parallel plate plastometer.
摘要翻译:一种基本上由苯乙烯 - 丁二烯橡胶共聚物,增粘剂和填料组成的罐端密封橡胶组合物(A)和(B)具有(1)由下式定义的抗蠕变系数K至少为0.1但不超过 0.6,K = log J90C(10)-log J90C(1)其中J90C(10)是在作为样品的组合物的制品在90℃的水中压缩时施加负荷后10分钟测量的蠕变柔量。 J90C(1)是当试样在90℃的水中通过平行板塑性体压缩后施加载荷1分钟后测得的蠕变柔量,(2)蠕变顺应性J25C(1) )为至少3×10 -9 cm 2 /达因但不超过1×10 -6 cm 2 /达因,当试样在25℃的水中通过平行平板式塑性计压缩时,在施加载荷1分钟后测量蠕变柔量。
摘要:
Disclosed is a laminate structure comprising a layer of a creep-resistant resin composed mainly of ester recurring units and a gas barrier layer containing an olefin-vinyl alcohol copolymer, which are laminated through a thermoplastic resin adhesive layer, wherein the adhesive resin is composed of a copolyester or copolyester composition comprising in the main chain at least two acid components selected from (i) an isophthalic acid component, (ii) a terephthalic acid component and (iii) a linear or cyclic aliphatic dibasic acid component.
摘要:
Disclosed is an easily openable vessel closure comprising a can end member having a preformed opening, an easily peelable opening piece which is applied to the outer side of the can end member so that the opening piece covers said opening and adheres closely to the peripheral portion of said opening, and a protecting covering layer formed to cover the cut edge of the opening of the can end member, wherein the protecting covering layer is formed of a thermoplastic resin having a heat bondability and the protecting covering layer includes a film layer heat-bonded to the inner and outer peripheral portions of the opening and a projecting cover heat-bonded to the cut edge of the opening integrally with said film layer, and said opening piece is heat-bonded to the can end member through the protecting covering layer located outside the can end member and said protecting covering layer is stuck closely to the cut edge of the opening so that when the opening piece is peeled, the protecting covering layer is left on the side of the can end member.This vessel closure is excellent in the seal reliability, corrosion resistance, flavor-retaining property and easy openability.
摘要:
Disclosed is a thickness-reduced deep-draw-formed can formed of a metal plate having an organic coating. In this can, at least the inner surface organic coating is composed of a crystalline thermoplastic resin, the thickness of the barrel wall is made smaller than the thickness of the bottom, the thermoplastic resin of the barrel wall is molecularly oriented mainly in the axial direction, and the roughness of the metal surface of the barrel wall is larger than that of the metal surface of the bottom. Since the organic coating is crystalline and is molecularly oriented, the coating can resist processing deformation when the thickness is reduced by deep-draw forming and the coating is not damaged by a tool or the like at all, and therefore, the barrier property to corrosive components and the heat resistance are prominently improved.
摘要:
Disclosed is an easily-openable vessel closure comprising a can end member having a preformed opening and an easily-tearable opening tab arranged on the outer side of the can end member to cover the opening and adhere closely to the peripheral portion of the can end member contiguous to the opening, wherein the opening of the can end member has such a size and shape that the opening is longer in the radial direction of the can end member, the opening extends from the inside of a circle concentric with the can end member, which has a diameter 0.35 time the seaming diameter of the can end member, to the point close to the outer periphery of the can end member and the portion defined by the contour of the opening and said circle involves a circle having a diameter of 5 mm, and wherein a thermoplastic resin coating having a -shaped section is formed on the cut edge of the opening of the can end member and the contiguous peripheral portion of the can end member and the opening tab is bonded to the can end member through said resin coating.
摘要:
Disclosed is a process for the preparation of a thickness-reduced deep-draw-formed can, which comprises the steps of (i) coating a crystalline thermoplastic resin on a metal plate, (ii) heating the coated metal plate at a temperature higher than the glass transition point (Tg) of the thermoplastic resin and draw-forming the coated metal plated, and (iii) heating the obtained preliminarily drawn cup at a temperature higher than the glass transition temperature (Tg) of the thermoplastic resin and redrawing the cup at a bend-pulling speed of at least 1 m/min. According to this process, damage of the coating layer can be drastically moderated, and a deep-draw-formed can having prominently improved corrosion resistance and heat resistance can be obtained.