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公开(公告)号：US4296182A
公开(公告)日：1981-10-20
申请号：US35333
申请日：1979-05-01
CPC分类号： C25D11/38 , Y10T428/1259 , Y10T428/1355 , Y10T428/31529 , Y10T428/31688
摘要： A can at least a part of which is made of an electrolytically chromated steel sheet, said steel sheet having such a surface that when it is degreased in acetone for 1 minute and analyzed by an Auger electron spectrometer at an incident electron accelerating voltage of 3 KeV, a modulation voltage of 3 V, a modulation frequency of 12 to 20 KHz and a degree of vacuum of at least 6.times.10.sup.-8 torr, the ratio of the peak-peak distance (O.sub.P-P) of KL.sub.2.3 L.sub.2.3 of oxygen to the base-peak distance (Cr.sub.B-P) of L.sub.3 M.sub.2.3 M.sub.4.5 of chromium in the resulting Auger electron spectrum satisfies the following relation:6.5.gtoreq.(O.sub.P-P)/(Cr.sub.B-P).gtoreq.1.5.
摘要翻译： 所述钢板的至少一部分由电解铬酸盐化钢板制成，所述钢板具有这样的表面，即当在丙酮中脱脂1分钟时，通过俄歇电子能谱仪以3KeV的入射电子加速电压进行分析 ，调制电压为3V，调制频率为12至20KHz，真空度至少为6×10 -8乇，氧气的KL2.3L2.3的峰 - 峰距离（OP-P）的比值 在所得俄歇电子光谱中，铬的L3M2.3M4.5的基峰距离（CrB-P）满足以下关系：6.5> / =（OP-P）/（CrB-P）> = 1.5。
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公开(公告)号：US4387830A
公开(公告)日：1983-06-14
申请号：US271238
申请日：1981-06-05
CPC分类号： B05D7/14 , B05D7/227 , B23K11/0006 , B05D2350/63 , B05D2350/65
摘要： Disclosed is a seam welded tinplate can having a side seam formed by welding, wherein the inner and outer surface portions of said side seam comprise an outermost layer formed of an oxide, which has a thickness of 50 to 400 A, and an intermediate layer formed mainly of an iron-tin alloy layer, which has a thickness corresponding to 5 to 100% of the thickness of the total tin layer, and a resin or resin composition containing a polar group selected from the group consisting of carbonyl, hydroxyl, ether and epoxy groups at a concentration of 10 to 2000 millimoles per 100 g of the resin is coated on at least one of said inner and outer surface portions of said side seam.
摘要翻译： 公开了一种具有通过焊接形成的侧缝的缝焊马口铁罐，其中所述侧缝的内表面部分和外表面部分包括由氧化物形成的最外层，该氧化物具有50至400的厚度，并形成中间层 主要是铁 - 锡合金层，其厚度相当于总锡层厚度的5至100％;以及含有极性基团的树脂或树脂组合物，所述极性基团选自羰基，羟基，醚和 浓度为10-2000毫摩尔/ 100g树脂的环氧基涂覆在所述侧缝的所述内表面部分和外表面部分中的至少一个上。
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公开(公告)号：US4384657A
公开(公告)日：1983-05-24
申请号：US270126
申请日：1981-06-03
IPC分类号： C25D11/38 , B05D7/16 , B05D7/22 , B23K11/00 , B23K11/08 , B23K11/16 , B32B15/08 , B32B15/088 , B32B15/092 , B65D8/22 , C25D5/26 , B65D90/04 , B23K1/20
CPC分类号： B05D7/227 , B05D7/14 , B23K11/0006 , B05D2350/63 , B05D2350/65 , Y10S138/07
摘要： Disclosed is a welded side-seamed can formed by welding a can blank comprising a steel plate substrate having, formed thereon, a coating layer consisting of a metallic chromium layer and a chromium oxide layer formed on the metallic chromium layer, wherein the so-formed side seam has an exposed steel plate layer consisting of a compact and dense steel oxide formed mainly of magnetite, which has a thickness of 50 to 800 A, especially 50 to 400 A, and a coating of a resin or resinous composition consisting of carbonyl, hydroxyl, ether and epoxy groups at a concentration of 10 to 2000 millimoles per 100 g of the resin is formed on at least one surface portion of said side seam through said steel oxide layer.
摘要翻译： 公开了一种焊接侧缝合罐，其通过焊接包括其上形成有由金属铬层和形成在金属铬层上的铬氧化物层的涂层形成的钢板基板的罐坯料而形成，其中所形成的 侧接缝具有由主要由磁铁矿形成的致密且致密的氧化铁组成的暴露的钢板层，其厚度为50至800，特别是50至400，以及由羰基， 通过所述钢氧化物层在所述侧缝的至少一个表面部分上形成浓度为10-2000毫摩尔/ 100g树脂的羟基，醚和环氧基。
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公开(公告)号：US4701354A
公开(公告)日：1987-10-20
申请号：US800135
申请日：1985-11-20
CPC分类号： C09J5/02 , B29C66/4322 , B29C66/72321 , C23C14/12 , B29C65/4815 , B29C66/72343 , B29L2009/00 , C09J2400/166
摘要： A very thin coating layer having a thickness of the order of angstroms of a hydroxymethyl substituted phenol is applied to the surface of a metal material. The hydroxylmethyl substituted phenol, such as saligenin, is applied in the gaseous phase to the surface of the metal material maintained at a high temperature.By forming this ultra-thin coating layer, the heat bondability of a thermoplastic resin layer to the metal material can be effectively improved. This technique is advantageously used in various fields, for example, for production of bonded cans.
摘要翻译： 将具有羟甲基取代酚的埃的埃厚度的非常薄的涂层施加到金属材料的表面上。 将羟甲基取代的苯酚（例如水杨苷）以气相的形式施加到保持在高温下的金属材料的表面。 通过形成该超薄涂层，可以有效地提高热塑性树脂层与金属材料的热粘合性。 该技术有利地用于各种领域，例如用于生产粘结罐。
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公开(公告)号：US4471883A
公开(公告)日：1984-09-18
申请号：US502604
申请日：1983-06-09
申请人： Yoichi Kitamura , Hisashi Hotta , Chikara Yurita
发明人： Yoichi Kitamura , Hisashi Hotta , Chikara Yurita
CPC分类号： B23K11/063 , Y10S220/29 , Y10T428/1259 , Y10T428/12708 , Y10T428/12722 , Y10T428/12847
摘要： Disclosed is a process for the preparation of welded cans, which comprises forming a blank comprised of a surface-treated steel plate into a cylinder and passing a lap portion of the formed cylinder between a pair of electrode rollers through an electrode wire to effect electric resistance welding, wherein said surface-treated steel plate comprises a layer of metallic tin or a tin-iron alloy formed on the steel plate substrate in an amount of 0.05 to 1.0 g/m.sup.2 as calculated as metallic tin and a hydrated chromium oxide layer formed on said tin layer in an amount of 0.005 to 0.05 g/m.sup.2 as calculated as metallic chromium and electric resistance welding is carried out in an inert atmosphere in the state where an electrode wire having a plating layer of tin or a tin alloy having a thickness of 0.1 to 20 .mu.m is kept in close contact with the surface of said surface-treated steel plate.In the inner and outer surface portions of the side seam of a welded can prepared according to this process, the thickness of the oxide layer is controlled below 400 .ANG. and the amount of tin in these inner and outer surface portions is at least 60% of the amount of tin in the starting surface-treated steel plate, and this welded can is excellent in the corrosion resistance, lacquer adhesion and appearance characteristics of the seam.
摘要翻译： 公开了一种用于制备焊接罐的方法，其包括将由表面处理的钢板组成的坯料成形为圆柱体，并将成形的圆筒的搭接部分通过电极线通过一对电极辊之间以实现电阻 焊接，其中所述表面处理钢板包括金属锡或锡 - 铁合金层，其形成在钢板基材上，其量为0.05-1.0g / m 2，以金属锡计算，并且水合氧化铬层形成在 所述锡层以金属铬计算为0.005〜0.05g / m 2，并且在惰性气氛中进行电阻焊接，其中在具有锡或锡合金镀层的电极线的厚度为 0.1〜20μm与表面处理钢板的表面保持紧密接触。 在根据该方法制备的焊接罐的侧接缝的内表面和外表面部分中，氧化物层的厚度控制在400以下，并且这些内表面部分和外表面部分中的锡的量至少为 起始表面处理钢板中的锡量，该焊接罐的接缝的耐腐蚀性，漆附着性和外观特性优异。
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公开(公告)号：US4282981A
公开(公告)日：1981-08-11
申请号：US139632
申请日：1980-04-11
申请人： Yoichi Kitamura , Hisashi Hotta , Makoto Ito
发明人： Yoichi Kitamura , Hisashi Hotta , Makoto Ito
CPC分类号： B65D7/38 , B23K11/20 , Y10S220/19 , Y10T403/478 , Y10T428/12083 , Y10T428/1259 , Y10T428/12618 , Y10T428/12722 , Y10T428/12993
摘要： Disclosed is a bright welded seam can of tinplate having a side seam formed by welding, wherein each of the inner and outer surfaces of the side seam has an outermost surface layer having a thickness of 50 to 400 A and being composed of oxides and a subsequent intermediate layer composed of an iron-tin alloy, which has a thickness corresponding to 5 to 100% of the thickness of the whole tin layer in the tinplate blank, and wherein the inner and outer surfaces of the side seam have a reflectance corresponding to at least 60% of the reflectance of the tinplate.This bright welded seam can is excellent in the appearance of the seam, the corrosion resistance and the adhesion of the coating.
摘要翻译： 公开了一种具有通过焊接形成的侧接缝的马口铁的光亮焊缝罐，其中侧接缝的内表面和外表面中的每一个具有厚度为50至400的最外表面层，并且由氧化物和随后的 中间层由铁 - 锡合金组成，其厚度对应于马口铁板坯中整个锡层的厚度的5至100％，并且其中侧缝的内表面和外表面的反射率对应于 马口铁反射率的至少60％。 这种明亮的焊缝可以在接缝的外观上，耐腐蚀性和涂层的粘附性优异。
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7.发明授权Process for preparing a metal coating material comprising condensation polymerized resin nanoparticles 有权制备包含缩聚树脂纳米粒子的金属涂层材料的方法公开(公告)号：US07763315B2
公开(公告)日：2010-07-27
申请号：US10569597
申请日：2004-08-20
CPC分类号： C09D5/08 , Y10T428/2982 , Y10T428/31678 , Y10T428/31681
摘要： Disclosed are a coating material for metal wherein a thin coating film without pinholes having excellent corrosion resistance, retort resistance, impact resistance, processing resistance, abrasion resistance, adhesiveness to a metal, flavor preservability for contents etc can be formed when applying on a metal plate or a metallic container, and a metallic container on which the coating material is applied. The coating material for metal includes thermoplastic resin particles having an average primary particle size of 10 to 800 nm obtained by cooling a solution of the thermoplastic resin. A process for preparing the coating material for metal comprises steps of (a) obtaining a solution wherein a thermoplastic resin is dissolved into an organic solvent, (b) obtaining a dispersion of particles of the thermoplastic resin having an average primary particle size of 10 to 800 nm by cooling the solution, (c) separating particles from the dispersion and (d) dispersing the separated particles in a solvent.
摘要翻译： 公开了一种用于金属的涂层材料，其中，当施加在金属板上时，可以形成具有优异的耐腐蚀性，耐蒸煮性，耐冲击性，耐加工性，耐磨性，对金属的粘合性，内含物的香味保存性的无针孔的薄涂膜 或金属容器，以及涂覆有涂料的金属容器。 金属用涂料包括通过冷却热塑性树脂的溶液得到的平均一次粒径为10〜800nm的热塑性树脂粒子。 制备金属涂料的方法包括以下步骤：（a）获得其中将热塑性树脂溶解在有机溶剂中的溶液，（b）获得平均初级粒径为10的热塑性树脂颗粒的分散体， 通过冷却溶液800nm，（c）从分散体中分离颗粒和（d）将分离的颗粒分散在溶剂中。
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公开(公告)号：US07738263B2
公开(公告)日：2010-06-15
申请号：US12007972
申请日：2008-01-17
IPC分类号： H05K9/00
CPC分类号： H01L23/04 , H01L23/10 , H01L24/45 , H01L24/48 , H01L2224/45144 , H01L2224/48091 , H01L2224/48227 , H01L2924/00014 , H01L2924/01079 , H01L2924/01327 , H01L2924/09701 , H01L2924/15165 , H01L2924/16153 , H01L2924/16315 , H01L2924/181 , H01L2924/3025 , H05K3/341 , H05K9/0056 , H05K2201/10371 , H05K2203/043 , H05K2203/0465 , Y02P70/613 , Y10T29/4913 , Y10T29/49155 , Y10T29/49156 , Y10T29/49158 , Y10T29/49165 , Y10T29/49171 , H01L2924/15153 , H01L2924/00 , H01L2224/05599
摘要： A circuit module containing a ceramic carrier substrate to carry electronic parts, ceramic substrate pads provided on a surface of the ceramic carrier substrate, and a lid having a cavity and a bottom surface joined to the ceramic substrate pads with solder, the lid being a stepped lid having protrusions adjacent to the cavity, and dents adjacent to the cavity with the protrusions intervening therebetween, the protrusions being in contact with the ceramic carrier substrate with a prescribed distance to the ceramic substrate pads, and the dents being joined to the ceramic substrate pads with solder.
摘要翻译： 一种电路模块，其包含用于承载电子部件的陶瓷载体基板，设置在陶瓷载体基板的表面上的陶瓷基板焊盘，以及具有用焊料与陶瓷基板焊盘接合的空腔和底面的盖， 具有邻近腔体的突起的盖子，以及与腔体相邻的突起，其间插入突起，突起与陶瓷载体衬底接触，距离陶瓷衬底焊盘具有规定的距离，并且凹陷接合到陶瓷衬底焊盘 用焊料。
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公开(公告)号：US4409456A
公开(公告)日：1983-10-11
申请号：US240824
申请日：1981-03-05
申请人： Yoichi Kitamura , Hisashi Hotta , Chikara Yurita
发明人： Yoichi Kitamura , Hisashi Hotta , Chikara Yurita
CPC分类号： B23K11/063 , Y10S220/29 , Y10T428/1259 , Y10T428/12708 , Y10T428/12722 , Y10T428/12847
摘要： Disclosed is a process for the preparation of welded cans, which comprises forming a blank comprised of a surface-treated steel plate into a cylinder and passing a lap portion of the formed cylinder between a pair of electrode rollers through an electrode wire to effect electric resistance welding, wherein said surface-treated steel plate comprises a layer of metallic tin or a tin-iron alloy formed on the steel plate substrate in an amount of 0.05 to 1.0 g/m.sup.2 as calculated as metallic tin and a hydrated chromium oxide layer formed on said tin layer in an amount of 0.005 to 0.05 g/m.sup.2 as calculated as metallic chromium and electric resistance welding is carried out in an inert atmosphere in the state where an electrode wire having a plating layer of tin or a tin alloy having a thickness of 0.1 to 20 .mu.m is kept in close contact with the surface of said surface-treated steel plate.In the inner and outer surface portions of the side seam of a welded can prepared according to this process, the thickness of the oxide layer is controlled below 400 A and the amount of tin in these inner and outer surface portions is at least 60% of the amount of tin in the starting surface-treated steel plate, and this welded can is excellent in the corrosion resistance, lacquer adhesion and appearance characteristics of the seam.
摘要翻译： 公开了一种用于制备焊接罐的方法，其包括将由表面处理的钢板组成的坯料成形为圆柱体，并将成形的圆筒的搭接部分通过电极线通过一对电极辊之间以实现电阻 焊接，其中所述表面处理钢板包括金属锡或锡 - 铁合金层，其形成在钢板基材上，其量为0.05-1.0g / m 2，以金属锡计算，并且水合氧化铬层形成在 所述锡层以金属铬计算为0.005〜0.05g / m 2，并且在惰性气氛中进行电阻焊接，其中在具有锡或锡合金镀层的电极线的厚度为 0.1〜20μm与表面处理钢板的表面保持紧密接触。 在根据该方法制备的焊接罐的侧缝的内表面和外表面部分中，氧化物层的厚度被控制在400A以下，并且这些内表面部分和外表面部分中的锡的量为至少60％ 起始表面处理钢板中的锡量，该焊接罐的接缝的耐腐蚀性，漆附着性和外观特性优异。
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公开(公告)号：US4392582A
公开(公告)日：1983-07-12
申请号：US251945
申请日：1981-04-07
申请人： Yoichi Kitamura , Hisashi Hotta
发明人： Yoichi Kitamura , Hisashi Hotta
IPC分类号： B65D8/00 , B32B15/08 , B32B15/088 , B32B15/092 , B65D1/12 , B65D8/04 , B65D8/16 , B65D8/22 , B65D25/34 , C08G8/04 , C09D163/00 , C25D3/04 , C25D5/26 , C25D11/38 , B65D25/14 , B32B27/38
CPC分类号： C25D11/38 , C08G8/04 , C09D163/00 , Y10S220/917 , Y10T428/12549 , Y10T428/12569 , Y10T428/1259 , Y10T428/1359 , Y10T428/31529
摘要： A retortable bonded TFS can coated with an organic lacquer film in which the seaming portion of the can body is bonded with an organic adhesive, characterized in that (1) the amounts of the metallic chromium layer and the chromium oxide layer deposited are 70-130 mg/m.sup.2 and 5-30 mg/m.sup.2, respectively, as metallic chromium; the amount of alkali-soluble chromium in these layers after heating at 210.degree. C. for 10 minutes is not more than 12 mg/m.sup.2 and not more than 70% by weight of the amount of the deposited chromium oxide before heating; the area of thickness unevenness of the chromium oxide is not more than 10%; and the amount of metal exposed is not more than 30 mg/dm.sup.2, expressed as the amount of copper deposited (2) the organic lacquer film layer is a baked and cured film of a mixed lacquer composed of 70 to 85 parts by weight of an epichlorohydrin-bisphenol A type epoxy resin having a number average molecular weight of 2900 to 3750 and 30 to 15 parts by weight of a resol-type phenolic resin derived from a monohydric phenol, bisphenol A and an aldehyde; the phenolic resin has such a molecular weight distribution that the proportion of a high-molecular-weight portion having 3 or more rings is 60 to 70% by weight and the proportion of a low-molecular-weight portion having 2 or less rings is 40 to 30% by weight; and the baked and cured film contains 83 to 87 parts by weight of the epoxy resin and 17 to 13 parts by weight of the phenolic resin, and (3) the adhesive is a linear polyamide adhesive.
摘要翻译： 可蒸煮的TFS可以涂覆有机漆膜，其中罐体的接缝部分用有机粘合剂粘合，其特征在于：（1）金属铬层和沉积的氧化铬层的量为70-130 mg / m2和5-30 mg / m2，分别为金属铬; 在210℃下加热10分钟后，这些层中的碱溶性铬的量不超过加热前沉积的氧化铬的量的12mg / m 2且不大于70重量％ 氧化铬的厚度不均匀面积不大于10％; 并且暴露的金属量不大于30mg / dm 2，表示为沉积的铜量（2）有机漆膜层是由70至85重量份的混合漆组成的混合漆的烘烤和固化膜 数均分子量为2900〜3750的表氯醇 - 双酚A型环氧树脂和30〜15重量份由一元酚，双酚A和醛衍生的甲阶酚醛树脂型酚醛树脂; 酚醛树脂具有这样的分子量分布，即具有3个以上环的高分子量部分的比例为60〜70重量％，具有2个以下环的低分子量部分的比例为40 至30重量％; 并且烘烤和固化膜含有83至87重量份的环氧树脂和17至13重量份的酚醛树脂，和（3）粘合剂是线性聚酰胺粘合剂。
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