Expansion temperature tolerant dry expandable sealant and baffle product
    2.
    发明授权
    Expansion temperature tolerant dry expandable sealant and baffle product 有权
    膨胀耐温可膨胀密封剂和挡板产品

    公开(公告)号:US06281260B1

    公开(公告)日:2001-08-28

    申请号:US09607311

    申请日:2000-06-30

    Abstract: An expansion temperature tolerant, dry, expandable sealant and baffle is provided which is capable of undergoing a desired degree of full expansion when an automobile body containing the sealant and baffle product is conveyed through a conventional bake and/or curing oven. The sealant and baffle product is fully expandable over a wider temperature and time range than heretofore available expandable baffle products. The composition for preparation of a molded expandable sealant and baffle component includes a grafted anhydride polymer, an epoxide terminated additive polymer which are capable of reacting with the grafted anhydride polymer and a blowing agent. The anhydride polymer and the epoxide terminated polymer react to a limited degree in the absence of a catalyst when the baffle product is heated in the bake and/or curing oven, thus providing an improved networked and bridged backbone polymer which effectively entraps gas emanating from the blowing agent, without adversely affecting the flexibility and expansion characteristics of the sealant baffles.

    Abstract translation: 提供了一种膨胀耐温,干燥,可膨胀的密封剂和挡板,当含有密封剂和挡板产品的汽车车身通过常规的烘烤和/或固化炉输送时,其能够经历所需的充分膨胀程度。 密封剂和挡板产品在比迄今为止可用的可膨胀挡板产品更宽的温度和时间范围内完全可膨胀。 用于制备可模制的可膨胀密封剂和挡板组分的组合物包括能够与接枝的酸酐聚合物和发泡剂反应的接枝的酸酐聚合物,环氧化物封端的添加剂聚合物。 当在烘烤和/或固化炉中加热挡板产物时,酸酐聚合物和环氧化物封端的聚合物在不存在催化剂的情况下有一定程度的反应,从而提供改进的网络化和桥连骨架聚合物,其有效地捕集从 发泡剂,而不会不利地影响密封剂挡板的柔性和膨胀特性。

    Expansion temperature tolerant dry expandable sealant and baffle product
and method of preparing same
    3.
    发明授权
    Expansion temperature tolerant dry expandable sealant and baffle product and method of preparing same 有权
    膨胀耐温可膨胀密封剂和挡板产品及其制备方法

    公开(公告)号:US6150428A

    公开(公告)日:2000-11-21

    申请号:US407820

    申请日:1999-09-28

    Abstract: An expansion temperature tolerant, dry, expandable sealant and baffle is provided which is capable of undergoing a desired degree of full expansion when an automobile body containing the sealant and baffle product is conveyed through a conventional bake and/or curing oven. The sealant and baffle product is fully expandable over a wider temperature and time range than heretofore available expandable baffle products. The composition for preparation of a molded expandable sealant and baffle component includes a grafted anhydride polymer, an epoxide terminated additive polymer which are capable of reacting with the grafted anhydride polymer and a blowing agent. The anhydride polymer and the epoxide terminated polymer react to a limited degree in the absence of a catalyst when the baffle product is heated in the bake and/or curing oven, thus providing an improved networked and bridged backbone polymer which effectively entraps gas emanating from the blowing agent, without adversely affecting the flexibility and expansion characteristics of the sealant baffles.

    Abstract translation: 提供了一种膨胀耐温,干燥,可膨胀的密封剂和挡板,当含有密封剂和挡板产品的汽车车身通过常规的烘烤和/或固化炉输送时,其能够经历所需的充分膨胀程度。 密封剂和挡板产品在比迄今为止可用的可膨胀挡板产品更宽的温度和时间范围内完全可膨胀。 用于制备可模制的可膨胀密封剂和挡板组分的组合物包括能够与接枝的酸酐聚合物和发泡剂反应的接枝的酸酐聚合物,环氧化物封端的添加剂聚合物。 当在烘烤和/或固化炉中加热挡板产物时,酸酐聚合物和环氧化物封端的聚合物在不存在催化剂的情况下有一定程度的反应,从而提供改进的网络化和桥连骨架聚合物,其有效地捕集从 发泡剂,而不会不利地影响密封剂挡板的柔性和膨胀特性。

    Pumpable desiccated mastic
    4.
    发明授权
    Pumpable desiccated mastic 失效
    可泵送干燥乳胶

    公开(公告)号:US5510416A

    公开(公告)日:1996-04-23

    申请号:US31602

    申请日:1993-03-15

    Abstract: A novel, pumpable, thermoplastic desiccated mastic capable of desiccating a sealed insulating glass unit. The compositions utilize adhesive materials which have a low vapor transmission rate but, nevertheless, have been found to effectively dry the air space in the unit. They do not contribute to chemical fogging and, in preferred embodiments, reduce or eliminate chemical fogging caused by other structures in the assembly. The compositions adhere well to the U-channel material and do not flow or sag under the normal range of service conditions encountered by an insulating glass assembly.The disclosed compositions comprise:4-30 weight percent of a film former selected from the group consisting of polyisobutylene polymers having a molecular weight in the range of about 35,000 to about 60,000, and mixtures of such polymers with minor amounts of a butyl rubber having a molecular weight of up to about 500,000;20-50 weight % of a non-crystalline homopolymer, copolymer, terpolymer or graft copolymer comprising polypropylene;0-20 weight % of a low volatile UV stable tackifier compatible with the film former and polypropylene components; and20-50 weight % of an adsorbent component comprising 20-50% by weight of the composition of a moisture or moisture and volatile organic chemical adsorbing material, and 0-10% by weight of the composition of an adsorbent of volatile organic compounds.

    Abstract translation: 一种新型可泵送的热塑性干燥乳胶,能够干燥密封的绝缘玻璃单元。 组合物使用具有低蒸气透过率但仍被发现有效干燥该单元中的空气空间的粘合剂材料。 它们对化学雾化没有贡献,并且在优选的实施方案中,减少或消除由组件中的其它结构引起的化学雾化。 组合物很好地粘附到U形槽材料上,并且在由绝缘玻璃组件遇到的正常使用条件下不会流动或下垂。 所公开的组合物包含:4-30重量%的选自分子量在约35,000至约60,000的聚异丁烯聚合物的成膜剂,以及这些聚合物与少量丁基橡胶的混合物,其具有 分子量高达约500,000; 20-50重量%的包含聚丙烯的非结晶均聚物,共聚物,三元共聚物或接枝共聚物; 0-20重量%与成膜剂和聚丙烯组分相容的低挥发性UV稳定增粘剂; 和20-50重量%的吸附剂组分,其包含20-50重量%的组合物的水分或水分和挥发性有机化学吸附材料,以及组合物的0-10重量%的挥发性有机化合物的吸附剂。

    Can end sealing rubber composition containing a styrene-butadiene
rubbery copolymer, a tackifier and a filler
    10.
    发明授权
    Can end sealing rubber composition containing a styrene-butadiene rubbery copolymer, a tackifier and a filler 失效
    可以封端含有苯乙烯 - 丁二烯橡胶共聚物,增粘剂和填料的密封橡胶组合物

    公开(公告)号:US4189418A

    公开(公告)日:1980-02-19

    申请号:US858208

    申请日:1977-12-07

    Abstract: A can end sealing rubber composition(A) consisting essentially of a styrene-butadiene rubbery copolymer, a tackifier and a filler, and(B) having (1) a creep resistance coefficient K defined by the following equation of at least 0.1 but not exceeding 0.6,K=log J.sub.90.sup.C (10)-log J.sub.90.sup.C (1) wherein J.sub.90.sup.C (10) is the creep compliance measured 10 minutes after exerting a load when a fabricated article of the composition as a specimen is compressed in water at 90.degree. C. by a parallel plate plastometer, and J.sub.90.sup.C (1) is the creep compliance measured 1 minute after exerting a load when the specimen is compressed in water at 90.degree. C. by a parallel plate plastomer,and (2) a creep compliance J.sub.25.sup.C (1) of at least 3.times.10.sup.-9 cm.sup.2 /dyne but not exceeding 1.times.10.sup.-6 cm.sup.2 /dyne, the creep compliance being measured 1 minute after exerting a load when the specimen is compressed in water at 25.degree. C. by a parallel plate plastometer.

    Abstract translation: 一种基本上由苯乙烯 - 丁二烯橡胶共聚物,增粘剂和填料组成的罐端密封橡胶组合物(A)和(B)具有(1)由下式定义的抗蠕变系数K至少为0.1但不超过 0.6,K = log J90C(10)-log J90C(1)其中J90C(10)是在作为样品的组合物的制品在90℃的水中压缩时施加负荷后10分钟测量的蠕变柔量。 J90C(1)是当试样在90℃的水中通过平行板塑性体压缩后施加载荷1分钟后测得的蠕变柔量,(2)蠕变顺应性J25C(1) )为至少3×10 -9 cm 2 /达因但不超过1×10 -6 cm 2 /达因,当试样在25℃的水中通过平行平板式塑性计压缩时,在施加载荷1分钟后测量蠕变柔量。

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