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公开(公告)号：US08669114B2
公开(公告)日：2014-03-11
申请号：US12227351
申请日：2007-05-17
申请人： Jorg Sundermeyer , Thomas Linder
发明人： Jorg Sundermeyer , Thomas Linder
IPC分类号： B01J20/22 , B01J20/281 , C07C211/63 , C07C211/03 , C07C233/06 , C07C233/54 , C07C233/56 , H01M10/052 , C07D233/06 , C07D235/08 , C07D213/20 , G01N30/00
CPC分类号： C07D233/06 , B01J20/22 , B01J20/281 , C07C211/63 , C07D233/54 , C07D233/56 , C07F9/5442 , H01M10/052 , H01M10/0568
摘要： The subject of the invention at hand are novel, a little basic, fluorinated pentafluorophenyl imide anions, which can be used as anions in ionic liquids. Methods for producing ionic liquids are described, which contain these novel pentafluorophenyl imide ions as anions, as well as quaternary organic ammonium ions, guanidinium ions, N-organo-pyridinium ions, imidazolium, imidazolidinium or benzimidazolidinium ions, alkyl-alkylidene phosphoranes or aryl-alkylidene phosphoranes as cations. Alternative methods according to the present invention provide ionic liquids through reaction of ketene N,N-diacetals or alkyl or aryl-alkylidene phosphoranes with acids.The ionic liquids according to the present invention are suitable, for example, as solvents for syntheses, as mobile and/or stationary phase in chromatography, as electrolyte systems for batteries, galvanic elements, fuel cells and rechargeable battery packs.
摘要翻译： 本发明的主题是新颖的，一些基本的氟化五氟苯基酰亚胺阴离子，其可以用作离子液体中的阴离子。 描述了制备离子液体的方法，它们包含这些新的五氟苯基酰亚胺离子作为阴离子，以及季铵有机铵离子，胍离子，N-有机 - 吡啶鎓离子，咪唑鎓，咪唑鎓或苯并咪唑鎓离子，烷基亚烷基膦或芳基 - 亚烷基膦作阳离子。 根据本发明的替代方法通过烯酮N，N-二缩醛或烷基或芳基 - 亚烷基膦与酸的反应提供离子液体。 根据本发明的离子液体例如作为用于合成的溶剂，作为色谱中的可移动和/或固定相，作为电池，电流元件，燃料电池和可充电电池组的电解质体系是合适的。
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2.发明申请LITHIUM SALTS OF PENTAFLUOROPHENYLAMIDE ANIONS, PREPARATION THEREOF AND USE THEREOF 审中-公开二芳基酰胺阴离子的锂盐，其制备及其用途公开(公告)号：US20120245387A1
公开(公告)日：2012-09-27
申请号：US13502894
申请日：2010-10-20
IPC分类号： C07C311/13 , C07C303/40
CPC分类号： C07C307/00 , C07C311/09 , H01M10/0525 , H01M10/0568
摘要： The present invention provides new lithium salts comprising pentafluorophenylamide anions following the general formula Li+[N(SO2—R)(C6F5)]−, which are optionally present as solvent-free complexes. R is hereby selected from fluorine, linear or branched acyclic or cyclic alkyl groups with 1 to 20 carbon atoms which are not fluorinated, partially fluorinated or fully fluorinated; or not fluorinated, partially fluorinated or fully fluorinated aryl or benzyl groups with 1 to 20 carbon atoms. The lithium salts according to the present invention are produced by reacting the corresponding NH acid of the pentafluorophenylamide with one equivalent of lithium bis(trimethylsilyl)amide or lithium organyl, wherein the reaction is carried out advantageously in the presence of apolar aprotic solvents. In this way, lithium salts in the form of solvent-free complexes are obtained. These solvent-free lithium complexes are thermally, electrochemically and against oxidation stable and comprise a high ionic conductivity. The lithium salts according to the present invention are suitable to be used as ion-conducting materials, electrically conductive materials, dyes and in chemical catalysis. They are preferably used as ion-conducting electrolytes in lithium ion accumulators.
摘要翻译： 本发明提供新的锂盐，其包含以通式Li + [N（SO 2 -R）（C 6 F 5）] - 的五氟苯基酰胺阴离子，它们任选作为无溶剂络合物存在。 R选自具有1至20个碳原子的氟，直链或支链无环或环状烷基，其不是氟化的，部分氟化的或完全氟化的; 或不含氟化，部分氟化或完全氟化的具有1至20个碳原子的芳基或苄基。 根据本发明的锂盐通过使五氟苯基酰胺的相应NH酸与一当量的双（三甲基甲硅烷基）氨基锂或有机锂的锂反应制备，其中该反应有利地在非极性非质子溶剂的存在下进行。 以这种方式获得无溶剂络合物形式的锂盐。 这些无溶剂的锂络合物是热的，电化学的和抗氧化稳定的并且包含高离子电导率。 根据本发明的锂盐适合用作离子导电材料，导电材料，染料和化学催化剂。 它们优选用作锂离子蓄电池中的离子传导电解质。
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公开(公告)号：US20090298189A1
公开(公告)日：2009-12-03
申请号：US12227351
申请日：2007-05-17
申请人： Jorg Sundermeyer , Thomas Linder
发明人： Jorg Sundermeyer , Thomas Linder
IPC分类号： C07C211/03 , C07D233/06 , C07D235/08 , C07D213/20 , H01M6/00 , G01N30/00
CPC分类号： C07D233/06 , B01J20/22 , B01J20/281 , C07C211/63 , C07D233/54 , C07D233/56 , C07F9/5442 , H01M10/052 , H01M10/0568
摘要： The subject of the invention at hand are novel, a little basic, fluorinated pentafluorophenyl imide anions, which can be used as anions in ionic liquids. Methods for producing ionic liquids are described, which contain these novel pentafluorophenyl imide ions as anions, as well as quaternary organic ammonium ions, guanidinium ions, N-organo-pyridinium ions, imidazolium, imidazolidinium or benzimidazolidinium ions, alkyl-alkylidene phosphoranes or aryl-alkylidene phosphoranes as cations. Alternative methods according to the present invention provide ionic liquids through reaction of ketene N,N-diacetals or alkyl or aryl-alkylidene phosphoranes with acids.The ionic liquids according to the present invention are suitable, for example, as solvents for syntheses, as mobile and/or stationary phase in chromatography, as electrolyte systems for batteries, galvanic elements, fuel cells and rechargeable battery packs.
摘要翻译： 本发明的主题是新颖的，一些基本的氟化五氟苯基酰亚胺阴离子，其可以用作离子液体中的阴离子。 描述了制备离子液体的方法，它们包含这些新的五氟苯基酰亚胺离子作为阴离子，以及季铵有机铵离子，胍离子，N-有机 - 吡啶鎓离子，咪唑鎓，咪唑鎓或苯并咪唑鎓离子，烷基亚烷基膦或芳基 - 亚烷基膦作阳离子。 根据本发明的替代方法通过烯酮N，N-二缩醛或烷基或芳基 - 亚烷基膦与酸的反应提供离子液体。 根据本发明的离子液体例如作为用于合成的溶剂，作为色谱中的可移动和/或固定相，作为电池，电流元件，燃料电池和可充电电池组的电解质体系是合适的。
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公开(公告)号：US20050282982A1
公开(公告)日：2005-12-22
申请号：US11152718
申请日：2005-06-14
CPC分类号： C07F9/005
摘要： The present invention relates to compounds containing vanadium in the oxidation state +III or +IV and one or more amido groups, a process for preparing these compounds, the use of the compounds of the invention for preparing a catalyst composition, a process for preparing the catalyst composition and also a process for preparing homopolymers and/or copolymers using the catalyst composition.
摘要翻译： 本发明涉及含有氧化态+ III或+ IV和一个或多个酰胺基的钒的化合物，制备这些化合物的方法，本发明化合物用于制备催化剂组合物的用途，制备 催化剂组合物以及使用该催化剂组合物制备均聚物和/或共聚物的方法。
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5.发明授权Detergents or cleaning agents containing a bleach-enhancing transition metal complex which is optionally produced in situ 有权含有漂白剂增强过渡金属络合物的洗涤剂或清洁剂，其任选地原位生产公开(公告)号：US08481475B2
公开(公告)日：2013-07-09
申请号：US13478464
申请日：2012-05-23
CPC分类号： C11D3/3932 , C11D3/168 , C11D3/26 , C11D3/3917
摘要： The aim of the invention is to improve the cleaning power of detergents and cleaning agents, especially with regard to bleachable stains, while avoiding any damage to the textile treated with said detergents and cleaning agents. For this purpose, a bleach catalyst in the form of a complex of Fe—, Mo—, Mn— and/or W with a ligand having a skeleton of formula (I) is used.
摘要翻译： 本发明的目的是提高洗涤剂和清洁剂的清洁能力，特别是在可漂白污渍方面，同时避免对用所述洗涤剂和清洁剂处理的织物的任何损坏。 为此，使用Fe-，Mo-，Mn-和/或W与具有式（I）骨架的配体的络合物形式的漂白催化剂。
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公开(公告)号：US20090099361A1
公开(公告)日：2009-04-16
申请号：US12249463
申请日：2008-10-10
申请人： Knud Reuter , Daniel Gaess , Jorg Sundermeyer
发明人： Knud Reuter , Daniel Gaess , Jorg Sundermeyer
IPC分类号： C07F9/00
CPC分类号： C07F9/005 , H01L21/28556
摘要： The present invention relates to specific, novel tantalum and niobium compounds which can serve as starting materials for the preparation of chemical vapour deposition (CVD) precursors.
摘要翻译： 本发明涉及可用作制备化学气相沉积（CVD）前体的起始材料的具体的新型钽和铌化合物。
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7.发明申请Tungsten and molybdenum compounds and thier use for chemical vapour deposition (CVD) 失效钨和钼化合物及其用于化学气相沉积（CVD）公开(公告)号：US20070160761A1
公开(公告)日：2007-07-12
申请号：US11649504
申请日：2007-01-04
申请人： Knud Reuter , Jorg Sundermeyer , Alexei Merkoulov , Wolfgang Stolz , Kestin Volz , Michael Pokoj , Thomas Ochs
发明人： Knud Reuter , Jorg Sundermeyer , Alexei Merkoulov , Wolfgang Stolz , Kestin Volz , Michael Pokoj , Thomas Ochs
CPC分类号： C23C16/34 , C07F11/005 , C23C16/18 , Y10T428/12174
摘要： The present invention relates to specific novel tungsten and molybdenum compounds to the use thereof for the deposition of tungsten- or molybdenum-containing layers by means of chemical vapour deposition, and to the tungsten- or molybdenum-containing layers produced by this process.
摘要翻译： 本发明涉及用于通过化学气相沉积沉积含钨或含钼层的特定新型钨和钼化合物以及通过该方法生产的含钨或钼的层。
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8.发明授权Preparation of epoxides from olefins using bis(triorganosilyl) peroxides in the presence of activators based on metallic acid derivatives 失效在基于金属酸衍生物的活化剂存在下，使用双（三有机甲硅烷基）过氧化物从烯烃制备环氧化物
公开(公告)号：US6090956A
公开(公告)日：2000-07-18
申请号：US142042
申请日：1998-09-02
IPC分类号： C07D301/14 , B01J31/18 , B01J31/22 , C07B61/00 , C07D301/12 , C07D301/19 , C07D303/04 , C07F7/00 , C07F7/18 , C07F11/00
CPC分类号： C07D303/04 , B01J31/1805 , B01J31/1875 , B01J31/1895 , C07D301/12 , C07D301/14 , B01J2231/72 , B01J2531/64 , B01J2531/66 , B01J2531/74
摘要： Epoxides are prepared from olefins using bis(triorganosilyl) peroxides in the presence of activators based on metalic acid derivatives of the formula ##STR1## where M is a metal of transition groups IV to VII, in particular molybdenum, tungsten or rheniumL is an uncharged ligand selected from the group consisting of amine oxides, phosphine oxides, arsine oxides, phosphoric triamides, formamides and pyridine N-oxidesX is an inorganic ligandx is from 1 to 5y is 0, 1 or 2,Z is 1 or 2 andn is 1 or 2.
摘要翻译： PCT No.PCT / EP97 / 00982 Sec。 371日期：1998年9月2日 102（e）1998年9月2日PCT PCT 1997年2月28日提交PCT公布。 公开号WO97 / 32867 PCT 日期1997年9月12日在基于金属酸衍生物的活化剂存在下，使用双（三有机甲硅烷基）过氧化物，使用双（三有机甲硅烷基）过氧化物来制备氧化物，其中M为转变基团IV至VII的金属，特别是钼，钨或铼L为 选自氧化胺，氧化膦，胂氧化物，磷酸三酰胺，甲酰胺和吡啶N-氧化物的不带电荷的配体X是无机配体x为1至5个y为0,1或2，Z为1或 2，n为1或2。
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9.发明授权Peroxo-containing metal complexes having amine oxide, phosphine oxide, arsine oxide, pyridine N-oxide or pyridine ligands as epoxidation catalysts 失效具有氧化胺，氧化膦，氧化砷，吡啶N-氧化物或吡啶配体的含氧氧化物的金属络合物作为环氧化催化剂
公开(公告)号：US6054407A
公开(公告)日：2000-04-25
申请号：US29737
申请日：1998-03-11
IPC分类号： B01J31/16 , B01J31/18 , B01J31/22 , C07B61/00 , C07D301/06 , C07D301/12 , C07D303/04 , B01J31/32 , B01J31/34 , B01J31/36 , B01J31/38
CPC分类号： C07D303/04 , B01J31/1805 , B01J31/1875 , C07D301/12 , B01J2231/72 , B01J2531/64 , B01J2531/66
摘要： Olefins can be epoxidized using catalysts I ##STR1## where M is a metal of the 4th to 7th transition group of the Periodic Table of the Elements,L.sup.1 is an amine oxide, phosphine oxide, arsine oxide, pyridine N-oxide or pyridine ligand of the formula II, III, VII or VIII,L.sup.2 is a customary auxiliary ligand or a further ligand L.sup.1 or a free coordination site,X is oxo oxygen or an imido ligand,m is 1 or 2, andn is 1, 2 or 3.
摘要翻译： PCT No.PCT / EP96 / 03888 Sec。 371日期1998年3月11日 102（e）1998年3月11日PCT PCT 1996年9月4日PCT公布。 公开号WO97 / 10054 日期1997年3月20日可以使用催化剂I来环氧化烯烃，其中M是元素周期表第4至第7转移基团的金属，L1是氧化胺，氧化膦，氧化胂，吡啶N-氧化物或吡啶 式II，III，VII或VIII的配体，L2是常规辅助配体或另外的配体L1或自由配位位点，X是氧代氧或亚氨基配体，m是1或2，n是1,2 或3。
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10.发明授权Detergents or cleaning agents containing a bleach-enhancing transition metal complex which is optionally produced in situ 有权含有漂白剂增强过渡金属络合物的洗涤剂或清洁剂，其任选地原位生产公开(公告)号：US08513177B2
公开(公告)日：2013-08-20
申请号：US13478438
申请日：2012-05-23
CPC分类号： C11D3/168 , C11D3/28 , C11D3/3932
摘要： A bleach catalyst includes a complex of Fe—, Mo—, Mn— and/or W with a ligand having a skeleton of formula (I).
摘要翻译： 漂白催化剂包括Fe-，Mo-，Mn-和/或W与具有式（I）骨架的配体的络合物。
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