摘要:
The instant invention is directed to a process for the preparation of glass constructions comprising applying to glass, compositions comprising(a) a polyisocyanate component and(b) a polyol component comprising at least one dihydroxy polyester carbonate with a molecular weight of from 800 to 3000 which is a reaction product of hexanediol-(1,6) with .epsilon.-caprolactone and/or .epsilon.-hydroxycaproic acid, in a molar ratio of hexanediol-(1,6) to .epsilon.-caprolactone and/or .epsilon.-hydroxycaproic acid of from 4:1 to 1:3, and diaryl carbonates, which reaction product is optionally present as a mixture with up to 40% by weight, based on the total quantity of said polyol component, of other polyols with molecular weights of from 62 to 4000, optionally containing ester groups,the quantities of the said components corresponding to an isocyanate index of from 80 to 130, or compositions comprising(c) an isocyanate prepolymer based on said polyols, optionally present in admixture with other polyisocyanates, and optionally(d) free- or blocked-diamine chain-lengthening agents.
摘要:
The invention relates to a process for the production of oligourethanes containing terminal mercapto groups by reacting 1-isocyanatomethyl-1,3,3-trimethyl-5-isocyanatocyclohexane with substoichiometric quantities of relatively high molecular weight polyether polyols and mercapto ethanol and to the use of the oligourethanes obtainable in this way as binders for coating and sealing compositions hardenable by oxidation and as additives for epoxide resins.
摘要:
The present invention is directed to a process for the production of oligourethanes having terminal mercapto groups by reacting organic polyisocyanates with sub-equivalent quantities of organic polyhydroxyl compounds and a mercapto-alkanol in the presence of at least one ester of phosphoric acid containing at least one hydroxyl group bound to phosphorus. The present invention is also directed to the mercapto group-containing oligourethanes obtainable by this process and their use as binders for oxidatively-hardenable coating and sealing compositions, additives for epoxide resins and cross-linking agents for plastics materials and plastics crude products containing olefinic double bonds.
摘要:
This invention relates to the use of catalyst systems containing (a) dibenzothiazyl disulphide, (b) carboxylates and/or organic complex compounds of manganese, iron, nickel or cobalt and (c) organic bases selected from the group consisting of guanidines and tertiary amines optionally containing inert substituents, as reaction accelerators for the oxidative hardening of plastics precursors containing mercapto groups.
摘要:
The present invention is concerned with a hydrocurable composition suitable for use as coatings, adhesives or grouts. The composition contains oxazolidine compounds and free isocyanate group containing prepolymers. The prepolymers are obtained by the reaction of polyisocyanates with special types of dispersions wherein the dispersed phase is synthesized in situ in a dispersing media of polyhydroxyl compounds. The dispersed phase may be a free radical addition polymer, an aminoplast polycondensate or a polyisocyanate addition product. In the last case, the non-isocyanate reactants used to form the dispersed phase are substantially more reactive with isocyanates than the dispersing media. An especially preferred composition is based on urethane oxazolidines and prepolymers of aliphatic or cycloaliphatic isocyanates with dispersions of isocyanate hydrazine or hydrazine hydrate condensates in polyhydroxy-polyethers having molecular weights of 200 to 16,000.
摘要:
The present invention is directed to a process for the preparation of air drying binders containing free isocyanate groups, having thixotropic properties and prepared by reacting aromatic diamines which have at least one alkyl substituent in the ortho position to each amino group with either prepolymers or semi-prepolymers containing free isocyanate groups and based on polyisocyanate mixture of the diphenylmethane series containing at least 20% by weight of 2,4'-diisocyanatodiphenylmethane and organic polyhydroxyl compounds or mixtures of these prepolymers or semi-prepolymers with prepolymers or semi-prepolymers based on other organic polyisocyanates, provided that the mixture contains at least 3% of the prepolymers or semi-prepolymers based on polyisocyanate mixtures of the diphenylmethane series. The invention further relates to the binders produced by this process and their use for the preparation of coating and sealing compounds which harden under the influence of atmospheric moisture.
摘要:
The present invention relates to an insulated one-piece roof for use over heatable rooms comprising at least three layers, the first layer being a solid or other load-bearing construction, the second layer being an insulating board and the third layer being a prepared roofing, said one-piece roof further characterized in that the characteristics value .mu..multidot.s where .mu. is the diffusion resistance index and s is the layer thickness of the constituent material of the vertically adjacent layers, decreases outwardly, said prepared roofing being firmly joined to the underlying insulating board and having a characteristic value .mu..multidot.s of less than 4 m.
摘要:
The present invention relates to a process for the preparation of coatings using a coating compound based on a system comprising (i) an isocyanate prepolymer based on isophorone diisocyanate and polyalkylene ether polyols having a hydroxyl functionality of 2 to 3 and (ii) at least one diprimary aromatic diamine having at least one alkyl substituent with 2 to 3 carbon atoms in an ortho-position to each amino group.
摘要:
The present invention relates to a process for the production of polyureas by reacting organic polyisocyanates containing blocked isocyanate groups with organic compounds containing at least two primary and/or secondary amino groups in the presence of catalysts which accelerate the condensation reaction of the above-mentioned starting materials, characterized in that compounds containing at least one guanidine group corresponding to the following formula: ##STR1## are used as catalysts.
摘要:
Hardeners for polyepoxides containing more than one, 1,2-epoxide group per molecule comprising a cyanoethylated polyamide amine containing free secondary or primary or secondary and primary amino groups, said cyanoethylated poly-amide amine is a reaction product of polyadded units of(A) 1 mole of a polyamine corresponding to the formula: ##STR1## in which p=0, n=2 or 3, m=0 to 6 and X=NH.sub.2, or p=1, n=2 or 3, m=0 and X=H,(B) from 0.5 to 2.3 moles of a saturated lactam, and(C) from 0.4 to 2.8 moles of acrylonitrile, methacrylonitrile or mixtures thereof.The hardener may be additionally modified with from 0.01 to 1.8 moles of a 1,2-alkylene oxide containing from 2 to 4 carbon atoms or with from 0.001 to 0.3 moles of a carboxylic acid or with the 1,2-alkylene oxide and the carboxylic acid in the quantities indicated, based in each case on 1 mole of the polyamine. The hardeners harden with 1,2-polyepoxides even in thin layers, over a period of 24 hours at room temperature to form clear, smooth films having a non-tacky fault-free surface.