Process for the preparation of overbased, molybdenum-alkaline earth
metal sulfonate dispersions
    1.
    发明授权
    Process for the preparation of overbased, molybdenum-alkaline earth metal sulfonate dispersions 失效
    制备高碱性,钼 - 碱土金属磺酸盐分散体的方法

    公开(公告)号:US4601837A

    公开(公告)日:1986-07-22

    申请号:US773173

    申请日:1985-09-06

    CPC分类号: C10M159/20

    摘要: The process comprises in sequence the following steps: (a) introducing into a reaction zone a sulfonic acid comprising a neutral ammonium sulfonate; (b) adding to and mixing with said sulfonic acid a substantially inert diluent, an alkaline earth metal compound, water, and an alkanol to form a hydration mixture; (c) heating said hydration mixture at an elevated temperature to hydrate said alkaline earth metal compound; (d) adding a molybdenum-containing compound to said reaction zone at a time during the period beginning after the introduction of said sulfonic acid and extending through said refluxing of said hydration mixture; and (e) adding an acidic material to said reaction zone at a temperature within the range of about 26.7.degree. C. (80.degree. F.) to about 68.5.degree. C. (155.degree. F.) to form a molybdenum-alkaline earth metal sulfonate dispersion. In an embodiment of the process, the process is characterized further by stripping the alkanol from the reaction zone prior to adding the acidic material.A polybutene succinic anhydride can be added to the reaction zone during the process as a process aid. Preferably, it is added prior to the addition of the molybdenum-containing compound.

    摘要翻译: 该方法按顺序包括以下步骤:(a)将包含中性磺酸铵的磺酸引入反应区; (b)向所述磺酸中加入基本上惰性的稀释剂,碱土金属化合物,水和链烷醇并与其混合以形成水合混合物; (c)在高温下加热所述水合混合物以使所述碱土金属化合物水合; (d)在引入所述磺酸并延伸通过所述水合混合物的回流之后的期间的一段时间向所述反应区添加含钼化合物; 和(e)在约26.7℃(80°F)至约68.5℃(155°F)的温度下向所述反应区中加入酸性物质以形成钼 - 碱土金属 磺酸盐分散体。 在该方法的一个实施方案中,该方法的特征还在于在加入酸性物质之前从反应区中汽提链烷醇。 聚丁烯琥珀酸酐可以在该方法中作为加工助剂加入到反应区中。 优选在加入含钼化合物之前加入。

    Copolymer dispersants via vinyl terminated propene polymers
    2.
    发明授权
    Copolymer dispersants via vinyl terminated propene polymers 失效
    共聚物分散剂通过乙烯基封端的丙烯聚合物

    公开(公告)号:US5616153A

    公开(公告)日:1997-04-01

    申请号:US538310

    申请日:1995-10-03

    摘要: A novel copolymer of an unsaturated acidic reactant and an atactic vinyl terminated propene polymer (VTPP) and its use in preparation of fuel and lubricant additives is taught. The VTPP has a major amount of polymer chains containing terminal vinyl unsaturation, a number average molecular weight of at least 500, and comprises at least 70 weight per cent propene and 0 to 30 weight per cent of at least one olefin selected from the group consisting of C.sub.2 and C.sub.4 to C.sub.10 olefins. The unsaturated acidic reactant comprises at least one unsaturated C.sub.4 to C.sub.10 carboxylic or dicarboxylic acid or anhydride. An oil soluble dispersant additive of the invention useful in oleaginous compositions is prepared by contacting the atactic VTPP copolymer with at least one nucleophilic reagent selected from the group consisting of amines, alcohols, metal reactants and mixtures thereof under conditions effective to form adducts of the nucleophilic reagent with the copolymer. The novel dispersants made from the copolymers and terpolymers of the invention can be polymeric succinic ester-amide dispersants, polymeric succinimide dispersants, polymeric succinic amide-triazole dispersants, or polymeric succinic triazole dispersants. Fuel and lubricant compositions containing such additives are a part of the invention.

    摘要翻译: 教导了不饱和酸性反应物和无规乙烯基封端的丙烯聚合物(VTPP)的新型共聚物及其在制备燃料和润滑剂添加剂中的用途。 VTPP具有大量含有末端乙烯基不饱和键,数均分子量至少为500的聚合物链,并且包含至少70重量%的丙烯和0至30重量%的至少一种选自以下的烯烃: 的C2和C4至C10烯烃。 不饱和酸性反应物包含至少一种不饱和C 4至C 10羧酸或二羧酸或酸酐。 通过使无规VTPP共聚物与选自胺,醇,金属反应物及其混合物的至少一种亲核试剂在有效形成亲核的加合物的条件下接触来制备本发明的油性组合物中的油溶性分散剂添加剂 试剂与共聚物。 由本发明的共聚物和三元共聚物制成的新型分散剂可以是聚合琥珀酸酯 - 酰胺分散剂,聚合琥珀酰亚胺分散剂,聚合琥珀酰胺 - 三唑分散剂或聚合琥珀酸三唑分散剂。 包含这些添加剂的燃料和润滑剂组合物是本发明的一部分。

    Lubricant overbased detergent-dispersants with improved solubility
    4.
    发明授权
    Lubricant overbased detergent-dispersants with improved solubility 失效
    润滑剂高碱性洗涤剂分散剂,溶解性好

    公开(公告)号:US4614602A

    公开(公告)日:1986-09-30

    申请号:US729468

    申请日:1985-05-01

    IPC分类号: C10M159/24 C10M125/00

    CPC分类号: C10M159/24

    摘要: A lubricant composition is disclosed comprising a major amount of a lubricating oil composition and a minor amount of an overbased detergent-dispersant lubricant additive comprising a reaction product of an alkaline earth metal phenate and an ammonium alkylbenzene sulfonate wherein the phenate and the sulfonate are reacted in the presence of an alcohol of 1 to 4 carbon atoms and said reaction product is stripped to remove ammonia, water and said alcohol.

    摘要翻译: 公开了一种润滑剂组合物,其包含主要量的润滑油组合物和少量高碱性洗涤剂 - 分散剂润滑剂添加剂,其包含碱土金属酚盐和烷基苯磺酸铵的反应产物,其中酚盐和磺酸盐在 汽提出具有1至4个碳原子的醇和所述反应产物以除去氨,水和所述醇。

    Oil recovery and mobility control using succinate surfactant systems
    8.
    发明授权
    Oil recovery and mobility control using succinate surfactant systems 失效
    使用琥珀酸盐表面活性剂体系的油回收和流动性控制

    公开(公告)号:US4122020A

    公开(公告)日:1978-10-24

    申请号:US827550

    申请日:1977-08-25

    IPC分类号: C09K8/584 E21B43/22

    摘要: A method is disclosed for moving and eventually recovering oil from a subterranean oil-bearing formation which comprises injecting into the formation an aqueous fluid containing a succinamate surface-active agent and method for mobility control (imparting viscosity) to a surfactant system used for recovery or moving of oil in an oil-bearing formation.

    摘要翻译: 公开了一种用于移动并最终从地下含油地层回收油的方法,其包括将含有琥珀酸盐表面活性剂的含水流体和用于迁移率控制(赋予粘度)的表面活性剂系统用于回收或 在含油层中移动油。