摘要:
A method for preparing a functionalized polymer, the method comprising the steps of preparing a reactive polymer, and reacting the reactive polymer with a halosilane compound containing an amino group.
摘要:
There are provided a rubber composition simultaneously improving low loss factor and wear resistance as compared with the conventional ones as well as a tire using such a rubber composition.The invention lies in a rubber composition using a modified conjugated diene rubber and being excellent in the low loss factor and wear resistance as well as a tire. The rubber composition of the invention is formed by compounding a filler to a rubber component containing (A) a modified conjugated diene rubber having a cis-bond content in conjugated diene portion of not less than 87% and a vinyl bond content of not more than 2% and containing a functional group reactive with a filler and (B) a modified polymer having a modifying functional group number per 1 molecule of an unmodified polymer of not less than 0.6.
摘要:
This invention relates to an aromatic vinyl compound-conjugated diene compound copolymer capable of giving excellent wear resistance and resistance to wet skid to a tire, and more particularly to an aromatic vinyl compound-conjugated diene compound copolymer obtained by an addition polymerization of an aromatic vinyl compound and a conjugated diene compound in the presence of a polymerization catalyst composition comprising at least one specified metallocene complex selected from the group consisting of a metallocene complex represented by the following general formula (I): (wherein M is a lanthanoid element, scandium or yttrium, and CpR is independently a non-substituted or substituted indenyl, and Ra to Rf are independently an alkyl group having a carbon number of 1-3 or a hydrogen atom, and L is a neutral Lewis base, and w is an integer of 0-3) and so on, wherein a content of cis-1,4 bond in a conjugated diene compound portion is not less than 80%.
摘要:
There are provided a rubber composition simultaneously improving low loss factor and wear resistance as compared with the conventional ones as well as a tire using such a rubber composition.The invention lies in a rubber composition using a modified conjugated diene rubber and being excellent in the low loss factor and wear resistance as well as a tire. The rubber composition of the invention is formed by compounding a filler to a rubber component containing (A) a modified conjugated diene rubber having a cis-bond content in conjugated diene portion of not less than 87% and a vinyl bond content of not more than 2% and containing a functional group reactive with a filler and (B) a modified polymer having a modifying functional group number per 1 molecule of an unmodified polymer of not less than 0.6.
摘要:
The invention provides a method for producing a modified conjugated diene (co)polymer, the method including comprising: a modification reaction step including causing an organic silane compound to react with a conjugated diene (co)polymer having an active site at the active site, the organic silane compound having a characteristic group for forming a silanol group through hydrolysis and, in the vicinity of the characteristic group, (i) a functional group which binds the organic silane compound to the conjugated diene (co)polymer via addition to or substitution at the active site and which promotes reaction between the silanol group and a reinforcing filler after the addition or substitution reaction, or (ii) a functional group which promotes reaction between the silanol group and a reinforcing filler, and a hydrolyzation step performed after the modification reaction step; a modified conjugated diene (co)polymer having, at a molecular end of the conjugated diene (co)polymer, a silanol group, and a functional group in the vicinity of the silanol group, the functional group accelerating reaction between the silanol group and the reinforcing filler; a rubber composition containing the (co)polymer and carbon black having specific characteristics; and a tire formed from the rubber composition.
摘要:
This invention provides a polybutadiene capable of improving wear resistance and resistance to crack growth in a rubber composition and a tire, wherein values of e, f and g derived from the following determinant (I): ( 1.7455 0 - 0.0151 - 0.0454 0.4292 - 0.0129 - 0.007 0 0.3746 ) ( log 10 ( a / d ) log 10 ( a / b ) log 10 ( a / c ) ) = ( e f g ) ( I ) (wherein a is a mountain peak value around 1130 cm−1 in a transmittance spectrum through Fourier transform infrared spectroscopy (FT-IR), and b is a valley peak value around 967 cm−1, and c is a valley peak value around 911 cm−1, and d is a valley peak value around 736 cm−1) satisfy relationships of equation (II): (Calculated value of cis-1,4 bond)=e/(e+f+g)×100≧99 and equation (III): (Calculated value of vinyl bond)=g/(e+f+g)×100≦0.
摘要翻译:本发明提供一种能够改善橡胶组合物和轮胎中的耐磨性和抗裂纹生长性的聚丁二烯,其中衍生自以下决定基(I)的e,f和g的值:(1.7455-0.0151-0.0454±0.4292-0.0129 - 0.007 0 0.3746)(log 10(a / d)log 10(a / b)log 10(a / c))=(efg)(I)(其中a为1130cm左右的山峰值 -1,傅立叶变换红外光谱(FT-IR)为透射光谱,b为967cm -1左右的谷峰值,c为911cm -1附近的谷峰值,d为谷峰值 约736厘米-1)满足式(II)的关系:(顺式-1,4-键的计算值)= e /(e + f + g)×100≧99和式(III):(乙烯基的计算值 键)= g /(e + f + g)×100≦̸ 0。
摘要:
This invention relates to an aromatic vinyl compound-conjugated diene compound copolymer capable of giving excellent wear resistance and resistance to wet skid to a tire, and more particularly to an aromatic vinyl compound-conjugated diene compound copolymer obtained by an addition polymerization of an aromatic vinyl compound and a conjugated diene compound in the presence of a polymerization catalyst composition comprising at least one specified metallocene complex selected from the group consisting of a metallocene complex represented by the following general formula (I): (wherein M is a lanthanoid element, scandium or yttrium, and CpR is independently a non-substituted or substituted indenyl, and Ra to Rf are independently an alkyl group having a carbon number of 1-3 or a hydrogen atom, and L is a neutral Lewis base, and w is an integer of 0-3) and so on, wherein a content of cis-1,4 bond in a conjugated diene compound portion is not less than 80%.
摘要:
The invention provides a method for producing a modified conjugated diene (co)polymer, the method including comprising: a modification reaction step including causing an organic silane compound to react with a conjugated diene (co)polymer having an active site at the active site, the organic silane compound having a characteristic group for forming a silanol group through hydrolysis and, in the vicinity of the characteristic group, (i) a functional group which binds the organic silane compound to the conjugated diene (co)polymer via addition to or substitution at the active site and which promotes reaction between the silanol group and a reinforcing filler after the addition or substitution reaction, or (ii) a functional group which promotes reaction between the silanol group and a reinforcing filler, and a hydrolyzation step performed after the modification reaction step; a modified conjugated diene (co)polymer having, at a molecular end of the conjugated diene (co)polymer, a silanol group, and a functional group in the vicinity of the silanol group, the functional group accelerating reaction between the silanol group and the reinforcing filler; a rubber composition containing the (co)polymer and carbon black having specific characteristics; and a tire formed from the rubber composition.
摘要:
A method for preparing a functionalized polymer, the method comprising the steps of preparing a reactive polymer, and reacting the reactive polymer with a halosilane compound containing an amino group.
摘要:
A method for preparing a functionalized polymer, the method comprising the steps of preparing a reactive polymer, and reacting the reactive polymer with a halosilane compound containing an amino group.