公开(公告)号：US20160096194A1

公开(公告)日：2016-04-07

申请号：US14967823

申请日：2015-12-14

Applicant: KURARAY CO., LTD.

Inventor： Kentaro Yoshida ,  Ryoichi Sasaki ,  Mamoru Omoda ,  Wataru Hirose ,  Manabu Shibata ,  Tatsuya Oshita

IPC: B05D3/00

Abstract: The composite structural material of the present invention includes a base (X) and a layer (Y) stacked on the base (X). The layer (Y) includes a reaction product (R) of a metal oxide (A) and a phosphorus compound (B). In the infrared absorption spectrum of the layer (Y) in the range of 800 to 1400 cm−1, the wave number (n1) at which the infrared absorption reaches maximum is in the range of 1080 to 1130 cm−1.

Abstract translation: 本发明的复合结构材料包括基材（X）和层叠在基材（X）上的层（Y）。 层（Y）包括金属氧化物（A）和磷化合物（B）的反应产物（R）。 在800〜1400cm -1范围内的层（Y）的红外吸收光谱中，红外线吸收达到最大的波数（n1）为1080〜1130cm -1的范围。

公开(公告)号：US09914837B2

公开(公告)日：2018-03-13

申请号：US14349594

申请日：2012-10-05

Applicant: KURARAY CO., LTD.

Inventor： Ryoichi Sasaki ,  Kentaro Yoshida ,  Mamoru Omoda ,  Suehiko Nagano ,  Tatsuya Oshita

IPC: C09D5/00 ,  C08J7/06 ,  C08J7/04 ,  C01B25/36 ,  C04B28/34 ,  C09D1/00 ,  B32B7/12 ,  B32B27/32 ,  B32B27/36 ,  C09D5/02 ,  C09D7/12 ,  B32B9/00 ,  B32B9/04 ,  C04B111/00 ,  C08K3/32

CPC classification number: C09D5/00 ,  B32B7/12 ,  B32B9/00 ,  B32B9/04 ,  B32B27/32 ,  B32B27/36 ,  B32B2307/7244 ,  B32B2307/7246 ,  B32B2439/70 ,  C01B25/36 ,  C04B28/34 ,  C04B28/342 ,  C04B2111/00482 ,  C04B2111/00525 ,  C04B2111/00534 ,  C08J7/045 ,  C08J7/047 ,  C08J7/06 ,  C08J2367/02 ,  C08J2377/02 ,  C08J2429/04 ,  C08J2443/02 ,  C08K2003/327 ,  C09D1/00 ,  C09D5/002 ,  C09D5/024 ,  C09D7/61 ,  C09D7/66 ,  Y10T428/1307 ,  Y10T428/1334 ,  Y10T428/1393 ,  Y10T428/25 ,  C04B14/303

Abstract: The method disclosed includes: a step (I) of preparing a dispersion liquid (S) including an aluminum compound (A); a step (II) of mixing the dispersion liquid (S) and a predetermined phosphorus compound (B) so as to prepare a coating liquid (U); a step (III) of applying the coating liquid (U) onto the base (X) so as to form a precursor layer of the layer (Y); and a step (IV) of subjecting the precursor layer to heat treatment at a temperature of 110° C. or more so as to form the layer (Y). The aluminum compound (A) can be formed by adding an acid to a solution including an aluminate. The number of moles (NM) of aluminum atoms derived from the aluminum compound (A) and the number of moles (NP) of phosphorus atoms derived from the phosphorus compound (B) satisfy 0.8≦(NM)/(NP)≦4.5.

公开(公告)号：US10814350B2

公开(公告)日：2020-10-27

申请号：US14967823

申请日：2015-12-14

Applicant: KURARAY CO., LTD.

Inventor： Kentaro Yoshida ,  Ryoichi Sasaki ,  Mamoru Omoda ,  Wataru Hirose ,  Manabu Shibata ,  Tatsuya Oshita

IPC: C23C18/12 ,  B05D3/00 ,  C09D123/08 ,  B32B7/12 ,  B32B27/08 ,  B32B27/10 ,  B32B27/32 ,  B32B27/34 ,  B32B27/36 ,  C09D1/00 ,  C09D133/02 ,  B32B21/08 ,  B32B27/30 ,  B32B15/08 ,  B32B21/04 ,  B32B27/28 ,  B32B21/06 ,  B32B15/10 ,  B32B27/20 ,  B32B29/00 ,  B32B15/085 ,  B32B29/02 ,  B32B15/09 ,  B32B15/12 ,  B32B15/082 ,  B32B15/14 ,  B32B5/26 ,  B32B21/10 ,  B32B27/12 ,  B32B15/088 ,  B32B29/06 ,  C08J7/04 ,  C09D123/02 ,  C08J7/06

Abstract: The composite structural material of the present invention includes a base (X) and a layer (Y) stacked on the base (X). The layer (Y) includes a reaction product (R) of a metal oxide (A) and a phosphorus compound (B). In the infrared absorption spectrum of the layer (Y) in the range of 800 to 1400 cm−1, the wave number (n1) at which the infrared absorption reaches maximum is in the range of 1080 to 1130 cm−1.

公开(公告)号：US10265935B2

公开(公告)日：2019-04-23

申请号：US14765957

申请日：2014-02-07

Applicant: KURARAY CO., LTD.

Inventor： Ryoichi Sasaki ,  Kentaro Yoshida ,  Mamoru Omoda ,  Masakazu Nakaya ,  Hiroyuki Ogi

IPC: B32B27/34 ,  B32B27/32 ,  B32B15/08 ,  B32B15/20 ,  B32B27/28 ,  B32B27/06 ,  B32B27/10 ,  B32B27/08 ,  B32B27/36 ,  C09D143/02 ,  B32B27/30 ,  C08F230/02

Abstract: A product provided includes a packaging material, and the packaging material includes a multilayer structure. The multilayer structure includes at least one base (X), at least one layer (Y), and at least one layer (Z). The layer (Y) contains an aluminum atom. The layer (Z) contains a polymer (E) containing a monomer unit having a phosphorus atom. The multilayer structure includes at least one pair of the layer (Y) and the layer (Z) that are contiguously stacked. This product is excellent in gas barrier properties, and adapted to maintain the gas barrier properties at a high level even when subjected to physical stresses such as deformation and impact.

公开(公告)号：US09403998B2

公开(公告)日：2016-08-02

申请号：US14349809

申请日：2012-10-05

Applicant: KURARAY CO., LTD.

Inventor： Kentaro Yoshida ,  Ryoichi Sasaki ,  Mamoru Omoda ,  Wataru Hirose ,  Manabu Shibata ,  Tatsuya Oshita

IPC: C09D7/12 ,  C09D185/02 ,  C09D1/00 ,  C08J7/06

CPC classification number: C09D7/63 ,  C08J7/045 ,  C08J7/06 ,  C08J2367/02 ,  C08J2377/00 ,  C09D1/00 ,  C09D185/02 ,  Y10T428/31739 ,  Y10T428/31746 ,  Y10T428/31786 ,  Y10T428/31797

Abstract: A composite structure disclosed includes a base (X) and a layer (Y) stacked on the base (X). The layer (Y) includes a reaction product (R). The reaction product (R) is a reaction product formed by a reaction at least between a metal oxide (A) and a phosphorus compound (B). A peak for a binding energy of an oxygen-atom 1s orbital observed by X-ray photoelectron spectroscopy of the layer (Y) is located at 532.0 eV or higher, and the peak has a half width of less than 2.0 eV.

Abstract translation: 所公开的复合结构包括底座（X）和层叠在基座（X）上的层（Y）。 层（Y）包括反应产物（R）。 反应产物（R）是通过至少在金属氧化物（A）和磷化合物（B）之间的反应形成的反应产物。 通过层（Y）的X射线光电子能谱观察到的氧原子1s轨道的结合能的峰位于532.0eV以上，峰的半宽度小于2.0eV。

公开(公告)号：US20140248500A1

公开(公告)日：2014-09-04

申请号：US14349809

申请日：2012-10-05

Applicant: KURARAY CO., LTD.

Inventor： Kentaro Yoshida ,  Ryoichi Sasaki ,  Mamoru Omoda ,  Wataru Hirose ,  Manabu Shibata ,  Tatsuya Oshita

IPC: C09D7/12

CPC classification number: C09D7/63 ,  C08J7/045 ,  C08J7/06 ,  C08J2367/02 ,  C08J2377/00 ,  C09D1/00 ,  C09D185/02 ,  Y10T428/31739 ,  Y10T428/31746 ,  Y10T428/31786 ,  Y10T428/31797

Abstract: A composite structure disclosed includes a base (X) and a layer (Y) stacked on the base (X). The layer (Y) includes a reaction product (R). The reaction product (R) is a reaction product formed by a reaction at least between a metal oxide (A) and a phosphorus compound (B). A peak for a binding energy of an oxygen-atom 1s orbital observed by X-ray photoelectron spectroscopy of the layer (Y) is located at 532.0 eV or higher, and the peak has a half width of less than 2.0 eV.

Abstract translation: 所公开的复合结构包括底座（X）和层叠在基座（X）上的层（Y）。 层（Y）包括反应产物（R）。 反应产物（R）是通过至少在金属氧化物（A）和磷化合物（B）之间的反应形成的反应产物。 通过层（Y）的X射线光电子能谱观察到的氧原子1s轨道的结合能的峰位于532.0eV以上，峰的半宽度小于2.0eV。

公开(公告)号：US20140248450A1

公开(公告)日：2014-09-04

申请号：US14349594

申请日：2012-10-05

Applicant: KURARAY CO., LTD.

Inventor： Ryoichi Sasaki ,  Kentaro Yoshida ,  Mamoru Omoda ,  Suehiko Nagano ,  Tatsuya Oshita

IPC: C09D5/00 ,  C08J7/06 ,  C08J7/04

CPC classification number: C09D5/00 ,  B32B7/12 ,  B32B9/00 ,  B32B9/04 ,  B32B27/32 ,  B32B27/36 ,  B32B2307/7244 ,  B32B2307/7246 ,  B32B2439/70 ,  C01B25/36 ,  C04B28/34 ,  C04B28/342 ,  C04B2111/00482 ,  C04B2111/00525 ,  C04B2111/00534 ,  C08J7/045 ,  C08J7/047 ,  C08J7/06 ,  C08J2367/02 ,  C08J2377/02 ,  C08J2429/04 ,  C08J2443/02 ,  C08K2003/327 ,  C09D1/00 ,  C09D5/002 ,  C09D5/024 ,  C09D7/61 ,  C09D7/66 ,  Y10T428/1307 ,  Y10T428/1334 ,  Y10T428/1393 ,  Y10T428/25 ,  C04B14/303

Abstract: The method disclosed includes: a step (I) of preparing a dispersion liquid (S) including an aluminum compound (A); a step (II) of mixing the dispersion liquid (S) and a predetermined phosphorus compound (B) so as to prepare a coating liquid (U); a step (III) of applying the coating liquid (U) onto the base (X) so as to form a precursor layer of the layer (Y); and a step (IV) of subjecting the precursor layer to heat treatment at a temperature of 110° C. or more so as to form the layer (Y). The aluminum compound (A) can be formed by adding an acid to a solution including an aluminate. The number of moles (NM) of aluminum atoms derived from the aluminum compound (A) and the number of moles (NP) of phosphorus atoms derived from the phosphorus compound (B) satisfy 0.8≦(NM)/(NP)≦4.5.

Abstract translation: 所述方法包括：制备包含铝化合物（A）的分散液（S）的步骤（I）; 混合分散液（S）和预定的磷化合物（B）以制备涂布液（U）的步骤（II）; 将涂布液（U）施加到基材（X）上以形成层（Y）的前体层的步骤（III）; 以及使前体层在110℃以上的温度下进行热处理以形成层（Y）的工序（Ⅳ）。 铝化合物（A）可以通过向包含铝酸盐的溶液中加入酸形成。 衍生自铝化合物（A）的铝原子的摩尔数（NM）和由磷化合物（B）衍生的磷原子的摩尔数（NP）满足0.8≤nlE;（NM）/（NP）＆nlE; 4.5。

公开(公告)号：US10273379B2

公开(公告)日：2019-04-30

申请号：US14765628

申请日：2014-02-07

Applicant: KURARAY CO., LTD.

Inventor： Ryoichi Sasaki ,  Kentaro Yoshida ,  Mamoru Omoda ,  Masakazu Nakaya ,  Hiroyuki Ogi

IPC: C09D143/02 ,  C08F230/02 ,  B32B27/34 ,  B32B27/32 ,  B32B15/08 ,  B32B15/20 ,  B32B27/28 ,  B32B27/06 ,  B32B27/10 ,  B32B27/08 ,  B32B27/36 ,  G02B1/14 ,  B05D7/00

Abstract: A multilayer structure disclosed is a multilayer structure including at least one base (X), at least one layer (Y), and at least one layer (Z). The layer (Y) contains an aluminum atom. The layer (Z) contains a polymer (E) having a plurality of phosphorus atoms. The polymer (E) is a polymer of at least one monomer including a vinylphosphonic acid compound. The multilayer structure includes at least one pair of the layer (Y) and the layer (Z) that are contiguously stacked. The layer (Z) is formed by applying a coating liquid (V) which is a solution of the polymer (E) having a plurality of phosphorus atoms. The multilayer structure disclosed is excellent in gas barrier properties, and can maintain the gas barrier properties at a high level even when subjected to physical stresses such as deformation and impact.

公开(公告)号：US09840630B2

公开(公告)日：2017-12-12

申请号：US14349251

申请日：2012-10-05

Applicant: KURARAY CO., LTD.

Inventor： Ryoichi Sasaki ,  Kentaro Yoshida ,  Mamoru Omoda ,  Wataru Hirose ,  Manabu Shibata ,  Tatsuya Oshita

IPC: B29D22/00 ,  C09D7/12 ,  C09D1/00 ,  C09D105/00 ,  C09D133/02

CPC classification number: C09D7/63 ,  C09D1/00 ,  C09D105/00 ,  C09D133/02 ,  Y10T428/1307 ,  Y10T428/1334 ,  Y10T428/1393

Abstract: A composite structure disclosed includes a base (X) and a layer (Y). The layer (Y) includes a mixture of a metal oxide (A), a phosphorus compound (B), and a compound (La) (silicon compound). Examples of the phosphorus compound (B) and the compound (La) include a compound containing a site capable of reacting with the metal oxide (A). When the number of moles of metal atoms (M) derived from the metal oxide (A) is denoted by NM and the number of moles of Si atoms derived from the compound (La) is denoted by NSi, 0.01≦NSi/NM≦0.30 is satisfied. When the number of moles of phosphorus atoms derived from the phosphorus compound (B) is denoted by NP, 0.8≦NM/NP≦4.5 is satisfied.

公开(公告)号：US20140248449A1

公开(公告)日：2014-09-04

申请号：US14349251

申请日：2012-10-05

Applicant: KURARAY CO., LTD.

Inventor： Ryoichi Sasaki ,  Kentaro Yoshida ,  Mamoru Omoda ,  Wataru Hirose ,  Manabu Shibata ,  Tatsuya Oshita

IPC: C09D7/12

CPC classification number: C09D7/63 ,  C09D1/00 ,  C09D105/00 ,  C09D133/02 ,  Y10T428/1307 ,  Y10T428/1334 ,  Y10T428/1393

Abstract: A composite structure disclosed includes a base (X) and a layer (Y). The layer (Y) includes a mixture of a metal oxide (A), a phosphorus compound (B), and a compound (La) (silicon compound). Examples of the phosphorus compound (B) and the compound (La) include a compound containing a site capable of reacting with the metal oxide (A). When the number of moles of metal atoms (M) derived from the metal oxide (A) is denoted by NM and the number of moles of Si atoms derived from the compound (La) is denoted by NSi, 0.01≦NSi/NM≦0.30 is satisfied. When the number of moles of phosphorus atoms derived from the phosphorus compound (B) is denoted by NP, 0.8≦NM/NP≦4.5 is satisfied.

Abstract translation: 所公开的复合结构包括基底（X）和层（Y）。 层（Y）包括金属氧化物（A），磷化合物（B）和化合物（La）（硅化合物）的混合物。 磷化合物（B）和化合物（La）的实例包括含有能够与金属氧化物（A）反应的位点的化合物。 衍生自金属氧化物（A）的金属原子（M）的摩尔数以NM表示，来自化合物（La）的Si原子的摩尔数由NSi表示，0.01＆nlE; NSi / NM＆lt; nlE; 0.30满足。 当由磷化合物（B）衍生的磷原子的摩尔数用NP表示时，满足0.8＆nlE; NM / NP＆nlE; 4.5。