摘要:
The aggregation and phase separation of inorganic particles are performed in a sol containing the inorganic particles and a solvent to produce a porous body having open pores. Preferably, the inorganic particles are particles of one or more inorganic material selected from the group consisting of titania, silica, alumina, zinc oxide and zirconia. Further, the sol may have strong acidity and the pH of the sol is elevated to perform the aggregation and phase separation of the inorganic particles. Alternatively, the sol may have strong basicity and the pH of the sol is lowered to perform the aggregation and phase separation of the inorganic particles. The present invention provides a novel method of producing a porous body and sintered body having co-continuous structure, applicable to a wide variety of inorganic materials.
摘要:
A support for solid phase extraction is provided for preventing the fracture of the porous body of the support and the space between the porous body and its container, and for processing various amounts of liquids to be processed while maintaining the ease of passage of liquid in use. The support for solid phase extraction comprises a ceramic substrate with one or more holes formed therein, and an inorganic porous material, filled in the hole or holes, which is produced by sol-gel transition accompanied by phase transition.
摘要:
The present invention provides a column for a liquid chromatograph having a honeycomb substrate including holes through which a sample flows and a separation phase filled in the holes. The separation phase is a porous bone structure composed of an inorganic material having open pores formed therein, and the porous bone structure is generated by a sol-gel transition process accompanied by a phase transition.
摘要:
An object of the present invention is to provide an inorganic porous body having an inorganic porous bone structure as the main body in which various kinds of particles can be uniformly loaded onto the wall surface facing the open pores. The inorganic porous composite body has an inorganic porous bone structure with open pores formed therein and particles for dispersion exposing to the wall surfaces of the bone structure facing the open pores. The bone structure is generated by sol-gel transition accompanied by phase transition.
摘要:
An object of the present invention is to provide a support for solid phase extraction for preventing the fracture of the porous body of the support and the space between the porous body and its container, and for processing various amounts of liquids to be processed while maintaining the ease of passage of liquid in use. A support 1 for solid phase extraction comprises a ceramic substrate 1 with a hole or holes 3 formed therein and an inorganic porous material 4 filled in the hole 3 produced by sol-gel transition accompanied by phase transition.
摘要:
An object of the present invention is to provide a support for solid phase extraction for preventing the fracture of the porous body of the support and the space between the porous body and its container, and for processing various amounts of liquids to be processed while maintaining the ease of passage of liquid in use. A support 1 for solid phase extraction comprises a ceramic substrate 1 with a hole or holes 3 formed therein and an inorganic porous material 4 filled in the hole 3 produced by sol-gel transition accompanied by phase transition.
摘要:
An object of the present invention is to provide a column for chromatograph having a structure for enabling the separation of a sample and for maintaining a high resolution of separation. The present invention provides a column 3 for chromatograph having a honeycomb substrate 1 having a hole 1a for flowing a sample and a separation phase 2 filled in the holes 1a. Preferably, the separation phase 2 comprises a porous bone structure composed of an inorganic material and with open pores formed therein, and the porous bone structure is generated by sol-gel transition accompanied by phase transition.
摘要:
An organic porous material is provided being excellent in mechanical properties such as strength and in which structures of a skeleton and pores are controlled more precisely. By a production process including (i) subjecting a low molecular compound having living radical and/or anionic polymerizability to living radical or anionic polymerization in a system including the compound, an organic polymer as a phase separation inducing component, a polymerization initiator, and a polymerization solvent, and thereby forming a gel including a skeletal phase rich in a polymer of the compound and a solvent phase rich in the solvent and having a co-continuous structure formed of the skeletal and solvent phases, and (ii) removing the solvent from the gel thus formed to form a skeleton containing the polymer as a base material thereof from the skeletal phase while forming first pores from the solvent phase, and thereby obtaining an organic porous material with a co-continuous structure formed of the skeleton and the first pores.
摘要:
Disclosed is a method for producing an inorganic porous body having precisely controlled macropores concurrently with mesopores of a narrow pore size distribution. The method comprises dissolving an amphiphilic substance as template component in an aqueous solution containing a sol-gel reaction catalyst, adding an inorganic low molecular weight compound having hydrolysable functional groups to the solution, forming a gel including a solvent-rich phase for the macropores, drying the gel to remove the solvent, and removing the template component by such means as thermal decomposition.
摘要:
The present invention provides a monolithic silicone in the form of an aerogel or a xerogel having flexibility and capable of dissolving molecules of a substance. This silicone monolithic body having continuous through passages is synthesized by copolymerizing starting materials of both a bifunctional alkoxysilane and a trifunctional alkoxysilane or tri- or higher functional alkoxysilanes through a sol-gel reaction for forming a Si—O network while causing phase separation.