公开(公告)号：US20060204662A1

公开(公告)日：2006-09-14

申请号：US11433315

申请日：2006-05-11

申请人： Kentin Alford ,  Kevin Simmons ,  William Samuels ,  Thomas Zemanian ,  Jun Liu ,  Yongsoon Shin ,  Glen Fryxell

发明人： Kentin Alford ,  Kevin Simmons ,  William Samuels ,  Thomas Zemanian ,  Jun Liu ,  Yongsoon Shin ,  Glen Fryxell

IPC分类号： B05D3/00 ,  C23C16/00 ,  B05D3/02

CPC分类号： B82Y30/00 ,  B01J29/0308 ,  B01J29/06 ,  B01J29/70 ,  B01J29/7007 ,  B01J29/80 ,  B01J31/0274 ,  B01J37/00 ,  B01J2229/32 ,  B05D1/185 ,  B05D1/60 ,  B82Y40/00 ,  Y10T428/249969 ,  Y10T428/254 ,  Y10T428/2995

摘要： The invention pertains to methods of forming monolayers on various surfaces. The surfaces can be selected from a wide array of materials, including, for example, aluminum dioxide, silicon dioxide, carbon and SiC. The substrates can be planar or porous. The monolayer is formed under enhanced pressure conditions. The monolayer contains functionalized molecules, and accordingly functionalizes a surface of the substrate. The properties of the functionalized substrate can enhance the substrate's applicability for numerous purposes including, for example, utilization in extracting contaminants, or incorporation into a polymeric matrix.

公开(公告)号：US20060177686A1

公开(公告)日：2006-08-10

申请号：US11338952

申请日：2006-01-24

申请人： Charles Henager ,  Yongsoon Shin ,  William Samuels

发明人： Charles Henager ,  Yongsoon Shin ,  William Samuels

IPC分类号： B05D3/02

CPC分类号： C23C18/122 ,  C23C10/34 ,  C23C10/48 ,  C23C10/52 ,  C23C18/1216 ,  Y10T428/12576 ,  Y10T428/12736 ,  Y10T428/12743 ,  Y10T428/12757

摘要： Disclosed herein are aluminide coatings. In one embodiment coatings are used as a barrier coating to protect a metal substrate, such as a steel or a superalloy, from various chemical environments, including oxidizing, reducing and/or sulfidizing conditions. In addition, the disclosed coatings can be used, for example, to prevent the substantial diffusion of various elements, such as chromium, at elevated service temperatures. Related methods for preparing protective coatings on metal substrates are also described.

公开(公告)号：US06733835B2

公开(公告)日：2004-05-11

申请号：US10347040

申请日：2003-01-17

申请人： Glen E. Fryxell ,  Thomas S. Zemanian ,  Jun Liu ,  Yongsoon Shin

发明人： Glen E. Fryxell ,  Thomas S. Zemanian ,  Jun Liu ,  Yongsoon Shin

IPC分类号： B05D300

CPC分类号： B01J35/002 ,  B01J29/0308 ,  B01J29/06 ,  B01J29/70 ,  B01J29/7007 ,  B01J29/80 ,  B01J31/0274 ,  B01J37/00 ,  B01J2229/12 ,  B01J2229/32 ,  B82Y30/00 ,  B82Y40/00 ,  Y10T428/249955 ,  Y10T428/249956 ,  Y10T428/249969 ,  Y10T428/261 ,  Y10T428/2995 ,  Y10T428/2996 ,  Y10T428/31663

摘要： According to the present invention, the previously known functional material having a self-assembled monolayer on a substrate has a plurality of assembly molecules each with an assembly atom with a plurality of bonding sites (four sites when silicon is the assembly molecule) wherein a bonding fraction (or fraction) of fully bonded assembly atoms (the plurality of bonding sites bonded to an oxygen atom) has a maximum when made by liquid solution deposition, for example a maximum of 40% when silicon is the assembly molecule, and maximum surface density of assembly molecules was 5 silanes per square nanometer. Note that bonding fraction and surface population are independent parameters. The method of the present invention is an improvement to the known method for making a siloxane layer on a substrate, wherein instead of a liquid phase solution chemistry, the improvement is a supercritical phase chemistry. The present invention has the advantages of greater fraction of oxygen bonds, greater surface density of assembly molecules and reduced time for reaction of about 5 minutes to about 24 hours.

摘要翻译： 根据本发明，在衬底上具有自组装单层的先前已知的功能材料具有多个组装分子，每个组装分子具有多个结合位置的组装原子（当硅是组装分子时的四个位置），其中键合 完全结合的组装原子（多个与氧原子结合的键合位置）的分数（或分数）在通过液体溶液沉积制备时具有最大值，例如当硅是组装分子时最大为40％，最大表面密度 的组装分子是每平方毫米5硅烷。 注意，结合分数和表面总体数是独立的参数。 本发明的方法是对已知的在基材上制备硅氧烷层的方法的改进，其中代替液相溶液化学，改进是超临界相化学。 本发明具有氧键分数更高，组装分子表面密度更大，反应时间缩短约5分钟至约24小时的优点。

公开(公告)号：US07629028B2

公开(公告)日：2009-12-08

申请号：US10607870

申请日：2003-06-27

申请人： Kentin L. Alford ,  Kevin L. Simmons ,  William D. Samuels ,  Thomas S. Zemanian ,  Jun Liu ,  Yongsoon Shin ,  Glen E. Fryxell

发明人： Kentin L. Alford ,  Kevin L. Simmons ,  William D. Samuels ,  Thomas S. Zemanian ,  Jun Liu ,  Yongsoon Shin ,  Glen E. Fryxell

IPC分类号： B05D3/04

CPC分类号： B82Y30/00 ,  B01J29/0308 ,  B01J29/06 ,  B01J29/70 ,  B01J29/7007 ,  B01J29/80 ,  B01J31/0274 ,  B01J37/00 ,  B01J2229/32 ,  B05D1/185 ,  B05D1/60 ,  B82Y40/00 ,  Y10T428/249969 ,  Y10T428/254 ,  Y10T428/2995

摘要： The invention pertains to methods of forming monolayers on various surfaces. The surfaces can be selected from a wide array of materials, including, for example, aluminum dioxide, silicon dioxide, carbon and SiC. The substrates can be planar or porous. The monolayer is formed under enhanced pressure conditions. The monolayer contains functionalized molecules, and accordingly functionalizes a surface of the substrate. The properties of the functionalized substrate can enhance the substrate's applicability for numerous purposes including, for example, utilization in extracting contaminants, or incorporation into a polymeric matrix.

公开(公告)号：US07588798B2

公开(公告)日：2009-09-15

申请号：US11433315

申请日：2006-05-11

申请人： Kentin L. Alford ,  Kevin L. Simmons ,  William D. Samuels ,  Thomas S. Zemanian ,  Jun Liu ,  Yongsoon Shin ,  Glen E. Fryxell

发明人： Kentin L. Alford ,  Kevin L. Simmons ,  William D. Samuels ,  Thomas S. Zemanian ,  Jun Liu ,  Yongsoon Shin ,  Glen E. Fryxell

IPC分类号： B05D3/04

CPC分类号： B82Y30/00 ,  B01J29/0308 ,  B01J29/06 ,  B01J29/70 ,  B01J29/7007 ,  B01J29/80 ,  B01J31/0274 ,  B01J37/00 ,  B01J2229/32 ,  B05D1/185 ,  B05D1/60 ,  B82Y40/00 ,  Y10T428/249969 ,  Y10T428/254 ,  Y10T428/2995

摘要： The invention pertains to methods of forming monolayers on various surfaces. The surfaces can be selected from a wide array of materials, including, for example, aluminum dioxide, silicon dioxide, carbon and SiC. The substrates can be planar or porous. The monolayer is formed under enhanced pressure conditions. The monolayer contains functionalized molecules, and accordingly functionalizes a surface of the substrate. The properties of the functionalized substrate can enhance the substrate's applicability for numerous purposes including, for example, utilization in extracting contaminants, or incorporation into a polymeric matrix.

摘要翻译： 本发明涉及在各种表面上形成单层的方法。 表面可以从广泛的材料中选出，包括例如二氧化铝，二氧化硅，碳和SiC。 基底可以是平面的或多孔的。 单层在增强的压力条件下形成。 单层含有官能化分子，因此功能化了基材的表面。 功能化底物的性质可以增强底物适用于许多目的，包括例如在提取污染物中的利用或掺入聚合物基质中。

公开(公告)号：US06531224B1

公开(公告)日：2003-03-11

申请号：US09528345

申请日：2000-03-17

申请人： Glen E. Fryxell ,  Thomas S. Zemanian ,  Jun Liu ,  Yongsoon Shin

发明人： Glen E. Fryxell ,  Thomas S. Zemanian ,  Jun Liu ,  Yongsoon Shin

IPC分类号： B32B516

CPC分类号： B01J35/002 ,  B01J29/0308 ,  B01J29/06 ,  B01J29/70 ,  B01J29/7007 ,  B01J29/80 ,  B01J31/0274 ,  B01J37/00 ,  B01J2229/12 ,  B01J2229/32 ,  B82Y30/00 ,  B82Y40/00 ,  Y10T428/249955 ,  Y10T428/249956 ,  Y10T428/249969 ,  Y10T428/261 ,  Y10T428/2995 ,  Y10T428/2996 ,  Y10T428/31663

摘要： According to the present invention, the previously known functional material having a self-assembled monolayer on a substrate has a plurality of assembly molecules each with an assembly atom with a plurality of bonding sites (four sites when silicon is the assembly molecule) wherein a bonding fraction (or fraction) of fully bonded assembly atoms (the plurality of bonding sites bonded to an oxygen atom) has a maximum when made by liquid solution deposition, for example a maximum of 40% when silicon is the assembly molecule, and maximum surface density of assembly molecules was 5 silanes per square nanometer. Note that bonding fraction and surface population are independent parameters. The method of the present invention is an improvement to the known method for making a siloxane layer on a substrate, wherein instead of a liquid phase solution chemistry, the improvement is a supercritical phase chemistry. The present invention has the advantages of greater fraction of oxygen bonds, greater surface density of assembly molecules and reduced time for reaction of about 5 minutes to about 24 hours.

公开(公告)号：US06753038B2

公开(公告)日：2004-06-22

申请号：US10346866

申请日：2003-01-17

申请人： Glen E. Fryxell ,  Thomas S. Zemanian ,  Jun Liu ,  Yongsoon Shin

发明人： Glen E. Fryxell ,  Thomas S. Zemanian ,  Jun Liu ,  Yongsoon Shin

IPC分类号： B05D310

CPC分类号： B01J35/002 ,  B01J29/0308 ,  B01J29/06 ,  B01J29/70 ,  B01J29/7007 ,  B01J29/80 ,  B01J31/0274 ,  B01J37/00 ,  B01J2229/12 ,  B01J2229/32 ,  B82Y30/00 ,  B82Y40/00 ,  Y10T428/249955 ,  Y10T428/249956 ,  Y10T428/249969 ,  Y10T428/261 ,  Y10T428/2995 ,  Y10T428/2996 ,  Y10T428/31663

摘要： According to the present invention, the previously known functional material having a self-assembled monolayer on a substrate has a plurality of assembly molecules each with an assembly atom with a plurality of bonding sites (four sites when silicon is the assembly molecule) wherein a bonding fraction (or fraction) of fully bonded assembly atoms (the plurality of bonding sites bonded to an oxygen atom) has a maximum when made by liquid solution deposition, for example a maximum of 40% when silicon is the assembly molecule, and maximum surface density of assembly molecules was 5 silanes per square nanometer. Note that bonding fraction and surface population are independent parameters. The method of the present invention is an improvement to the known method for making a siloxane layer on a substrate, wherein instead of a liquid phase solution chemistry, the improvement is a supercritical phase chemistry. The present invention has the advantages of greater fraction of oxygen bonds, greater surface density of assembly molecules and reduced time for reaction of about 5 minutes to about 24 hours.

公开(公告)号：US08557441B2

公开(公告)日：2013-10-15

申请号：US12901527

申请日：2010-10-09

申请人： Jun Liu ,  Daiwon Choi ,  Wendy D Bennett ,  Gordon L Graff ,  Yongsoon Shin

发明人： Jun Liu ,  Daiwon Choi ,  Wendy D Bennett ,  Gordon L Graff ,  Yongsoon Shin

IPC分类号： H01M4/13 ,  H01M4/58 ,  H01M4/02 ,  H01M6/00 ,  H01M10/00

CPC分类号： H01M4/0457 ,  H01M4/0404 ,  H01M4/13 ,  H01M4/139 ,  H01M4/362 ,  H01M4/366 ,  H01M4/483 ,  H01M4/587 ,  Y02E60/122 ,  Y10T29/49115

摘要： A method for forming a nanocomposite material, the nanocomposite material formed thereby, and a battery made using the nanocomposite material. Metal oxide and graphene are placed in a solvent to form a suspension. The suspension is then applied to a current collector. The solvent is then evaporated to form a nanocomposite material. The nanocomposite material is then electrochemically cycled to form a nanocomposite material of at least one metal oxide in electrical communication with at least one graphene layer.

公开(公告)号：US20120088158A1

公开(公告)日：2012-04-12

申请号：US12901527

申请日：2010-10-09

申请人： Jun Liu ,  Daiwon Choi ,  Wendy D. Bennett ,  Gordon L. Graff ,  Yongsoon Shin

发明人： Jun Liu ,  Daiwon Choi ,  Wendy D. Bennett ,  Gordon L. Graff ,  Yongsoon Shin

IPC分类号： H01M4/133 ,  H01M4/139 ,  H01M4/48

CPC分类号： H01M4/0457 ,  H01M4/0404 ,  H01M4/13 ,  H01M4/139 ,  H01M4/362 ,  H01M4/366 ,  H01M4/483 ,  H01M4/587 ,  Y02E60/122 ,  Y10T29/49115

摘要： A method for forming a nanocomposite material, the nanocomposite material formed thereby, and a battery made using the nanocomposite material. Metal oxide and graphene are placed in a solvent to form a suspension. The suspension is then applied to a current collector. The solvent is then evaporated to form a nanocomposite material. The nanocomposite material is then electrochemically cycled to form a nanocomposite material of at least one metal oxide in electrical communication with at least one graphene layer.

摘要翻译： 形成纳米复合材料的方法，由此形成的纳米复合材料和使用纳米复合材料制成的电池。 将金属氧化物和石墨烯置于溶剂中以形成悬浮液。 然后将悬浮液施加到集电器。 然后将溶剂蒸发以形成纳米复合材料。 然后将纳米复合材料电化学循环以形成与至少一个石墨烯层电连通的至少一个金属氧化物的纳米复合材料。

公开(公告)号：US06846554B2

公开(公告)日：2005-01-25

申请号：US10347042

申请日：2003-01-17

申请人： Glen E. Fryxell ,  Thomas S. Zemanian ,  Jun Liu ,  Yongsoon Shin

发明人： Glen E. Fryxell ,  Thomas S. Zemanian ,  Jun Liu ,  Yongsoon Shin

IPC分类号： B01J29/03 ,  B01J29/06 ,  B01J29/70 ,  B01J29/80 ,  B01J31/02 ,  B01J35/00 ,  B01J37/00 ,  B32B3/06

CPC分类号： B01J35/002 ,  B01J29/0308 ,  B01J29/06 ,  B01J29/70 ,  B01J29/7007 ,  B01J29/80 ,  B01J31/0274 ,  B01J37/00 ,  B01J2229/12 ,  B01J2229/32 ,  B82Y30/00 ,  B82Y40/00 ,  Y10T428/249955 ,  Y10T428/249956 ,  Y10T428/249969 ,  Y10T428/261 ,  Y10T428/2995 ,  Y10T428/2996 ,  Y10T428/31663

摘要： According to the present invention, the previously known functional material having a self-assembled monolayer on a substrate has a plurality of assembly molecules each with an assembly atom with a plurality of bonding sites (four sites when silicon is the assembly molecule) wherein a bonding fraction (or fraction) of fully bonded assembly atoms (the plurality of bonding sites bonded to an oxygen atom) has a maximum when made by liquid solution deposition, for example a maximum of 40% when silicon is the assembly molecule, and maximum surface density of assembly molecules was 5 silanes per square nanometer. Note that bonding fraction and surface population are independent parameters. The method of the present invention is an improvement to the known method for making a siloxane layer on a substrate, wherein instead of a liquid phase solution chemistry, the improvement is a supercritical phase chemistry. The present invention has the advantages of greater fraction of oxygen bonds, greater surface density of assembly molecules and reduced time for reaction of about 5 minutes to about 24 hours.

摘要翻译： 根据本发明，在基板上具有自组装单层的先前已知的功能材料具有多个组装分子，每个组装分子具有多个结合位置的组装原子（当硅是组装分子时的四个位置），其中键合 完全结合的组装原子（多个与氧原子结合的键合位置）的分数（或分数）在通过液体溶液沉积制备时具有最大值，例如当硅是组装分子时最大为40％，最大表面密度 的组装分子是每平方毫米5硅烷。 注意，结合分数和表面总体数是独立的参数。 本发明的方法是对已知的在基材上制备硅氧烷层的方法的改进，其中代替液相溶液化学，改进是超临界相化学。 本发明具有氧键分数更高，组装分子表面密度更大，反应时间缩短约5分钟至约24小时的优点。