摘要:
A process for reducing the phosphate content in waste water from the preparation of salts of ascorbic acid 2-monophosphate comprisesA. treating the waste water from the crystallization of the metal salts of ascorbic acid 2-monophosphate with an alkali metal or alkaline earth metal hypochlorite, chlorine or H.sub.2 O.sub.2,andB. precipitating, at a pH of 9-12, the inorganic phosphate which has been produced from organically bound phosphorus and/or was present in the waste water, especially as calcium phosphate.
摘要翻译:从制备抗坏血酸2-单磷酸盐的盐中降低废水中的磷酸盐含量的方法包括:用碱金属或碱土金属次氯酸盐对2-一磷酸抗坏血酸的金属盐进行结晶处理废水 ,氯或H 2 O 2,和B.在pH为9-12的条件下沉淀出由有机结合的磷生成的和/或存在于废水中,特别是作为磷酸钙的无机磷酸盐。
摘要:
A process for isolating the calcium salt of ascorbyl 2-monophosphate from aqueous alkaline reaction mixtures as are obtained on reaction of ascorbic acid with a molar excess of phosphorus oxychloride in the presence of a tertiary amine while maintaining a pH of from 12 to 13 during the reaction by means of an aqueous alkali metal hydroxide solution, which comprisesa) starting from a reaction mixture which has been obtained by reacting ascorbic acid with phosphorus oxychloride in the presence of pyridine while maintaining a pH of from 12 to 13 by means of an aqueous potassium hydroxide solution,b) precipitating, as potassium magnesium phosphate, the phosphate ions which have been formed in this reaction by means of magnesium chloride in amounts of about 1 mol per mol of phosphate ions,c) removing the potassium magnesium phosphate,d) distilling the remaining aqueous solution to remove the pyridine together with part of the water,e) reacting the resulting aqueous solution with calcium chloride andf) isolating the calcium salt of ascorbyl 2-monophosphate which crystallizes thereby, or first distilling the pyridine-water mixture according to step (d) from the reaction mixture obtained in step (a) and thereafter carrying out steps (b), (c), (e) and (f).
摘要:
A process for preparing retinyl glycosides of the formula I ##STR1## where Z is a glycosidic residue, by glycosidation of a completely acylated carbohydrate or completely acylated glycosidic polymer of the formula IIZ (acylated)-Y (II)where Y is a leaving group customary for glycosidations in the 1-position of the glycoside, comprises the acylated glycoside being reacted with an aldehyde-protected 4-hydroxy-2-methyl-2-buten-1-al under the conditions customary for glycosidations, eliminating the aldehyde protective group from the resulting compound, subjecting the resulting aldehyde to a Wittig reaction with a .beta.-ionylideneethyltriphenylphosphonium salt and eliminating the acyl groups on the resulting retinyl glycoside in a conventional manner.The process according to the invention is particularly important for preparing retinyl glycosides of the formula Ia ##STR2## where R is --CH.sub.2 --OH, --COOH or --COOCH.sub.3. Intermediates of this process are also claimed.
摘要:
An electric-motor adjusting unit for a metering system of an internal combustion engine, having an adjuster housing and an adjusting shaft rotatable therein that actuates a final control element, having a commutator motor coupled to the adjusting shaft, having a sensor for detecting the rotary position of the adjusting shaft, and having a carrier plate that can be secured in the adjuster housing, on which plate on the one hand a brush holder for the commutator motor and on the other a plug electrically connected to the brush holder and to the sensor are disposed, in order to obtain a prefabricatable assembly unit with which installation tolerances in the adjuster housing can be compensated for, the sensor being disposed on a carrier, and on the carrier and on the carrier plate, joining means corresponding with one another for joining the carrier and the carrier plate are embodied.
摘要:
A multipole electrical plug connector which is provided with a mating connector for a disconnectable connection having one or more contact elements, as well as electrical strip conductors which lead to the contact elements, and which jointly form a pressed screen designed as a one-piece part. The strip conductors at their free ends are provided with receptacles, into which contact elements may be plugged in. Due to a single flexibly designed pressed screen having appropriate receptacles, it is possible to cost-effectively manufacture various plug connectors having different contact element arrangements.
摘要:
A device for restoring a rotary member into a defined normal position, with a spatially stationary fixed catch, which predetermines the normal position, and a driver catch, which is coupled to the rotary member and can be moved past the fixed catch, each of which has stop surfaces embodied on each of its opposing sides, and with a clamping spring, which encompasses the catches in a prestressed fashion with two bent spring legs, in order to prevent a rotary play between the clamping spring and the catches in the normal position, and an elastic spring element in at least one leg section of the spring legs extending across the stop surfaces of the catches, which spring element is supported against the associated stop surface with a spring force that is less powerful than the prestressing force of the clamping spring.
摘要:
Process for separating water from a gas mixture, obtained in the manufacture of vinyl acetate by reacting ethylene with acetic acid and oxygen in contact with catalysts containing palladium or palladium compounds in the gaseous phase said gas mixture consisting essentially of acetic acid, vinyl acetate, water, carbon dioxide and ethylene, wherein(a) the gas mixture leaving the reaction zone is condensed to give a condensate containing the major portion of acetic acid, vinyl acetate and water and(b) an acetic acid solution containing the residual amount of vinyl acetate and water being prepared by absorption of the non-condensed gas in acetic acid, is characterized in that(c) the condensate obtained in step (a) and the solution obtained in step (b) are introduced separately from each other into the same distillation column, the feeding point of the condensate being above the feeding point of the solution, the water is distilled off at the head of said column as azeotrope together with the vinyl acetate and(d) the water phase is removed from the distillate separating into a water phase and a vinyl acetate phase.
摘要:
A method of inactivating microorganisms such as viruses within a fluid such as a biological fluid is disclosed. The method includes the steps of providing a UV reactor, which may take the form of an elongated generally annular reaction chamber surrounding at least one elongated UV lamp, moving the fluid within the reaction chamber in a primary flow directed along the length of the UV lamp, and inducing a circulating secondary flow within the fluid with the secondary flow being superimposed on the primary flow. As the fluid moves through the reaction chamber in the primary flow, it is circulated repeatedly toward and away from the UV lamp in the circulating secondary flow to provide uniform and controllable exposure of the entire volume of fluid to ultraviolet radiation. Microorganisms such as viruses are thus inactivated while desirable components in the fluid, such as proteins, are preserved without the use of a free radical scavenger.
摘要:
The present invention provides desazapurine-nucleoside derivatives of the general formula: wherein X is a nitrogen atom or a methine radical, W is a nitrogen atom or a C—R4 radical, R1, R2, R3 and R4, which can be the same or different, are hydrogen or halogen atoms, hydroxyl or mercapto groups, lower alkyl, lower alkylthio, lower alkoxy, aralkyl, aralkoxy or aryloxy radicals or amino groups optionally substituted once or twice, R5 is a hydrogen atom or a hydroxyl group, R6 and R7 are each hydrogen atoms or one of them is a halogen atom or a cyano or azido group or an amino group optionally substituted once or twice, whereby one of R6 and R7 can also be a hydroxyl group when X is a methine radical and, in addition, R5 and R7 can together also represent a further valency bond between C-2′ and C-3′ and Y is a hydrogen atom or a mono-, di- or tri-phosphate group.
摘要:
The invention is directed to an intake apparatus for an internal combustion engine with the apparatus including an intake pipe defining a longitudinal axis and a throttle flap mounted on the intake pipe, the throttle flap including a shaft having a shaft radius (r), a throttle flap having a thickness (t) and being mounted on the shaft to be rotatable through a displacement angle, and the shaft having a diameter (2r) greater than the thickness (t); a potentiometer operatively connected to the throttle flap for detecting the displacement angle thereof; a full-load stop for fixing the displacement angle of the flap at full load; the throttle flap being adjusted to a stop angle AW of the throttle flap by impacting on the full-load stop pursuant to the relationship:(2) (KETW)+(2) (AETW).congruent.(2) (WSW)-DAWwherein: WSW is a shaft shading angle, the angle of the throttle flap at which points on the throttle flap disposed farthest away from the shaft lie at a distance from the longitudinal axis equal to the radius (r); KETW is a permissible corresponding tolerance angle corresponding to the tolerance of the potentiometer; AETW is a permissible tolerance angle for the stop of the throttle flap; and, DAW is the difference angle by which a rearward tolerance limit for the throttle flap stop lies ahead of a rearward shaft shading limit. Because of the increased tolerance, adjusting devices can be omitted or adjusting measures such as preparatory procedures can be avoided.