摘要:
The instant invention relates to a process for producing stable equilibrium mixtures of carbodiimides, uretone imines and organic isocyanates and storage-stable solutions of carbodiimides and uretone imines in polyisocyanates which are free from carbodiimide groups. Either the carbodiimide, or the uretone imine, or both, may contain isocyanate groups. The invention relates to the process for the preparation of these products by so-called heterogeneous catalysis and the use of these products for the production of polyurethane resins.
摘要:
The instant invention relates to novel carbodiimidization catalysts consisting of a high molecular weight, insoluble matrix and low molecular weight carbodiimidization catalysts fixed to the matrix via ionic bonds. The novel high molecular weight catalysts are suitable for the preparation of storage stable, catalyst free, equilibrium mixtures of organic carbodiimides, uretone imines and isocyanates. Either the carbodiimide, or the uretone imine or both may contain isocyanate groups. Alternatively, mono and/or polyisocyanates free from carbodiimide and uretone imine groups may be added to the equilibrium mixture. The catalysts according to the invention are capable of bringing about selective carbodiimidization of individual isocyanates in a mixture of various isocyanates.
摘要:
The present invention relates to stable equilibrium mixtures of carbodiimides, uretone imines and organic isocyanates and to stable solutions of carbodiimides and uretone imines in polyisocyanates which are free from carbodiimide groups. Either the carbodiimide, or the uretone imine, or both, may contain isocyanate groups. The present invention also relates to a process for the preparation of such products by "heterogeneous catalysis" and the use thereof for the production of polyurethane resins. According to one embodiment of the process according to the instant invention, individual isocyanates in a mixture of various isocyanates may be carbodiimidized selectively.
摘要:
This invention relates to a continuous process for the preparation of silane by catalytic disproportionation of trichlorosilane in a reactive/distillative reaction zone having a catalyst bed of catalytically active solid.
摘要:
A process for the recovery by distillation of tributyl phosphate (TBPO) from spent hydraulic oils, which are employed particularly in aircraft used for civilian air traffic.
摘要:
The present invention relates to fluorinated carboxylic acid esters of phosphono- and phosphinocarboxylic acids containing hydroxyl and/or mercapto groups, their use as waterproofing and/or oil-repellency agents, and a method for their preparation.
摘要:
Thermoplastic, branched aromatic polyphosphonates with average molecular weights (number average M.sub.n) of from 11,000 to more than 200,000, obtainable by transesterifying (a) from 97 to 100 moles of at least one diaryl phosphonate, and (b) from 0 to 3 moles of at least one triaryl phosphate--the sum of the moled of (a) and (b) being 100--with (c) from 90 to 99 moles of at least one aromatic dihydroxy compound, and (d) from 0 to 3 moles of at least one aromatic trihydroxy or tetrahydroxy compound--with the proviso that at least one of the components (b) and (d) is present in a quantity of at least 0.001 mole and that, where (b) and (d) are used, the maximum limit on the moles is 3.0.
摘要:
Synergistic arthropodicidal compositions containing (1) a phosphorus-containing compound of the formula ##STR1## in which R.sup.1, R.sup.2 and R.sup.3 each independently is an optionally substituted alkyl, alkenyl or aryl radical, at least one of R.sup.1, R.sup.2 and R.sup.3 being an optionally substituted alkenyl radical unsaturated in the 2-position,X is oxygen or sulphur, andY and Z each independently is oxygen, sulphur or a direct bond; and if both Y and Z are oxygen or sulphur or a direct bond, then any of R.sup.1, R.sup.2 and R.sup.3 can denote propargyl in addition to the radicals indicated above,and (2) at least one (A) carbamate, (B) carboxylic acid ester, (C) phosphoric acid ester other than (1), (D) halogenocycloalkane or (E) halogenoalkane.
摘要:
A process for the production of an alkoxy phospholane oxide or sulphide of the formula ##STR1## in which R.sup.1 is an alkyl, alkoxy or aryl radical having up to 14 carbon atoms.R.sup.2, r.sup.3 and R.sup.4 each independently is a C.sub.1 to C.sub.4 alkyl radical, hydrogen, chlorine or bromine,R.sup.5 is an alkyl, alkenyl, alkynyl radical having from 1 to 14 carbon atoms, andX is oxygen or sulphur,Comprising reacting a phospholene oxide or sulphide of the formula ##STR2## with an alcohol of the formulaR.sup.5 -- O -- Hin the presence of an alkaline catalyst, such as sodium methylate. The products catalyze the conversion of isocyanates into carbodiimides with evolution of carbon dioxide.
摘要:
The invention relates to a method and a device for producing globular grains of high-purity silicon by atomising a silicon melt (6) in an ultrasonic field (10). Globular grains having a grain size of 50 μm can be produced by means of said method and device and can be used to separate high-purity silicon from silane in the fluid bed. The silicon melt (6) is fed into the ultrasonic field (10) at a distance of