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1.发明授权
公开(公告)号：US4271059A
公开(公告)日：1981-06-02
申请号：US149637
申请日：1980-05-14
CPC分类号： C08K5/13 , B41M5/155 , C08G8/08 , C08G8/24 , Y10T428/31967
摘要： Disclosed is a color-developing composition for pressure-sensitive recording sheet material of the self-contained type comprising (A) 100 parts by weight of a copolymer obtained by reacting a p-alkylphenol having an alkyl moiety of from 1 to 12 carbon atoms and phenol with formaldehyde and (B) from 1 to 20 parts by weight of a hindered phenolic compound selected from phenols having an alkyl, alkylene or hydroxyl substituent radical in at least the 2- or 6-position, or both, of the benzene ring and derivatives thereof, the copolymer and the hindered phenolic compound being homogeneously dissolved in mutual solution. The hindered phenolic compound is either added to the starting materials for the preparation of the copolymer or, at the end of the copolymerization reaction, added to the resulting copolymer and dissolved homogeneously in mutual solution.
摘要翻译： 公开了一种自包含型压敏记录片材的显色组合物，其包含（A）100重量份通过使具有1至12个碳原子的烷基部分的对烷基苯酚和 苯酚与甲醛和（B）1至20重量份的受阻酚化合物，其选自在苯环的至少2或6位或两者中具有烷基，亚烷基或羟基取代基的酚，以及 其衍生物，共聚物和受阻酚化合物均匀溶解在相互溶液中。 将受阻酚类化合物加入到共聚物的制备原料中，或者在共聚反应结束时，加入到所得共聚物中并均匀溶解在相互溶液中。
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2.发明授权
公开(公告)号：US4235769A
公开(公告)日：1980-11-25
申请号：US4770
申请日：1979-01-19
CPC分类号： C08K5/13 , B41M5/155 , C08G8/08 , C08G8/24 , Y10T428/31967
摘要： Disclosed is a color-developing composition for pressure-sensitive recording sheet material of the self-contained type comprising (A) 100 parts by weight of a copolymer obtained by reacting a p-alkylphenol having an alkyl moiety of from 1 to 12 carbon atoms and phenol with formaldehyde and (B) from 1 to 20 parts by weight of a hindered phenolic compound selected from phenols having an alkyl, alkylene or hydroxyl substituent radical in at least the 2- or 6-position, or both, of the benzene ring and derivatives thereof, the copolymer and the hindered phenolic compound being homogeneously dissolved in mutual solution. The hindered phenolic compound is either added to the starting materials for the preparation of the copolymer or, at the end of the copolymerization reaction, added to the resulting copolymer and dissolved homogeneously in mutual solution.
摘要翻译： 公开了一种自包含型压敏记录片材的显色组合物，其包含（A）100重量份通过使具有1至12个碳原子的烷基部分的对烷基苯酚和 苯酚与甲醛和（B）1至20重量份的受阻酚化合物，其选自在苯环的至少2或6位或两者中具有烷基，亚烷基或羟基取代基的酚，以及 其衍生物，共聚物和受阻酚化合物均匀溶解在相互溶液中。 将受阻酚类化合物加入到共聚物的制备原料中，或者在共聚反应结束时，加入到所得共聚物中并均匀溶解在相互溶液中。
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公开(公告)号：US4618714A
公开(公告)日：1986-10-21
申请号：US490546
申请日：1983-05-02
申请人： Keizaburo Yamaguchi , Kenichi Sugimoto , Yoshimitsu Tanabe , Saburo Kawashima , Akihiro Yamaguchi
发明人： Keizaburo Yamaguchi , Kenichi Sugimoto , Yoshimitsu Tanabe , Saburo Kawashima , Akihiro Yamaguchi
IPC分类号： C07B61/00 , B01J23/00 , B01J23/40 , B01J23/70 , B01J25/02 , B01J27/00 , B01J27/02 , B01J27/08 , C07C20060101 , C07C67/00 , C07C201/00 , C07C205/45 , C07C221/00 , C07C225/22 , C07C97/10
CPC分类号： C07C201/14 , C07C221/00
摘要： Preparation of 3,3'- or 3,4'-diaminobenzophenone by nitrating a chloronitrobenzophenone mixture obtained by the Friedel-Crafts reaction between 3- or 4-nitrobenzoyl chloride and chlorobenzene, and catalytically reducing and dechlorinating the resulting chlorodinitrobenzophenone mixture in the presence of a reduction catalyst and a dehydrochlorinating agent.
摘要翻译： 通过硝化由3-或4-硝基苯甲酰氯与氯苯之间的Friedel-Crafts反应获得的氯硝基二苯甲酮混合物，并在所述氯代二硝基二苯甲酮混合物存在下催化还原和脱氯，从而制备3,3'-或3,4'-二氨基二苯甲酮 还原催化剂和脱氯化氢剂。
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公开(公告)号：US4540818A
公开(公告)日：1985-09-10
申请号：US490730
申请日：1983-05-02
申请人： Keizaburo Yamaguchi , Kenichi Sugimoto , Yoshimitsu Tanabe , Saburo Kawashima , Akihiro Yamaguchi
发明人： Keizaburo Yamaguchi , Kenichi Sugimoto , Yoshimitsu Tanabe , Saburo Kawashima , Akihiro Yamaguchi
IPC分类号： C07B61/00 , B01J23/00 , B01J23/40 , B01J23/70 , B01J25/02 , B01J27/00 , B01J27/02 , B01J27/08 , C07C20060101 , C07C67/00 , C07C201/00 , C07C205/45 , C07C221/00 , C07C225/22 , C07C87/50
CPC分类号： C07C201/14 , C07C221/00
摘要： Preparation of 3,3'- or 3,4'-diaminodiphenylmethane by catalytically reducing and dechlorinating, in the presence of a reduction catalyst, a dinitrobenzophenone compound having the formula ##STR1## wherein X is chlorine and attached to a position 4 or 6 on the benzene ring, and Y is hydrogen or chlorine with the proviso that when Y is hydrogen, the nitro group is attached to a position 3' or 4', and when Y is chlorine, Y is attached to a position 4' and the nitro group is attached to a position 3'.
摘要翻译： 在还原催化剂存在下，通过催化还原和脱氯制备3,3'-或3,4'-二氨基二苯基甲烷，其具有下式的二硝基二苯甲酮化合物，其中X是氯并且连接到位置4或6上 苯环，Y为氢或氯，条件是当Y为氢时，硝基连接到3'或4'位置，当Y为氯时，Y连接到位置4'，硝基 组附加到位置3'。
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公开(公告)号：US4400492A
公开(公告)日：1983-08-23
申请号：US247123
申请日：1981-03-24
摘要： Disclosed is a color-developer for pressure-sensitive recording sheets, comprising a co-condensate of a reaction intermediate of a p-substituted phenol and a trifunctional or higher phenol, or a polyvalent metal salt of said co-condensate, said reaction intermediate being obtained by the reaction of said p-substituted phenol under acidic conditions with formaldehyde or a substance capable of generating formaldehyde.
摘要翻译： 公开了用于压敏记录片材的显色剂，其包含对取代的酚和三官能或更高级酚的反应中间体或所述共缩合物的多价金属盐的共缩合物，所述反应中间体为 通过所述对取代的苯酚在酸性条件下与甲醛或能产生甲醛的物质反应得到。
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6.发明授权Polyimides, process for the preparation thereof and polyimide resin compositions 失效聚酰亚胺，其制备方法和聚酰亚胺树脂组合物
公开(公告)号：US5380805A
公开(公告)日：1995-01-10
申请号：US143105
申请日：1993-10-29
申请人： Shoji Tamai , Masahiro Ohta , Saburo Kawashima , Katsuaki Iiyama , Hideaki Oikawa , Akihiro Yamaguchi , Kouji Ohkoshi , Masao Yoshikawa
发明人： Shoji Tamai , Masahiro Ohta , Saburo Kawashima , Katsuaki Iiyama , Hideaki Oikawa , Akihiro Yamaguchi , Kouji Ohkoshi , Masao Yoshikawa
CPC分类号： C08G73/1042 , C08G73/105 , C08G73/1071 , C08L79/08
摘要： In one aspect, the present invention relates to polyimides having excellent thermal resistance and process for preparing the same comprising carrying out condensation of 4,4'-bis(3-aminophenoxy)biphenyl with pyromellitic dianhydride in the presence of a different diamine compound and optionally with a different tetracarboxylic acid dianhydride.In a second aspect, the present invention relates to a heat resistant resin composition consisting essentially of an aromatic polyetherimide and a defined polyimide.In a third aspect, the present invention relates to a polyimide resin composition comprised on a defined polyimide and a separate high-temperature engineering polymer.In a fourth aspect, the present invention relates to a resin composition comprised of a defined polyimide and an aromatic polyamideimide.
摘要翻译： 一方面，本发明涉及具有优异耐热性的聚酰亚胺及其制备方法，包括在不同的二胺化合物和任选地存在下进行4,4'-双（3-氨基苯氧基）联苯与均苯四酸二酐的缩合 与不同的四羧酸二酐。 在第二方面，本发明涉及一种主要由芳族聚醚酰亚胺和所定义的聚酰亚胺组成的耐热树脂组合物。 在第三方面，本发明涉及包含在限定的聚酰亚胺和单独的高温工程聚合物上的聚酰亚胺树脂组合物。 在第四方面，本发明涉及由限定的聚酰亚胺和芳族聚酰胺酰亚胺组成的树脂组合物。
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公开(公告)号：US5043419A
公开(公告)日：1991-08-27
申请号：US261520
申请日：1988-10-24
申请人： Masahiro Ohta , Saburo Kawashima , Shoji Tamai , Hideaki Oikawa , Akihiro Yamaguchi , Tomohito Koba , Toshiyuki Nakakura , Hideo Sakai , Misao Masuda , Satoru Kishi , Chiaki Maruko
发明人： Masahiro Ohta , Saburo Kawashima , Shoji Tamai , Hideaki Oikawa , Akihiro Yamaguchi , Tomohito Koba , Toshiyuki Nakakura , Hideo Sakai , Misao Masuda , Satoru Kishi , Chiaki Maruko
CPC分类号： C08K7/04 , C08G73/1014 , C08G73/105 , C08G73/1064 , C08L79/08
摘要： This invention relates to a method for preparing a polyimide having good heat-stability and excellent flowability in a molten state.The polymide is prepared by reacting aromatic diamines such as 4,4'-bis(3-aminophenoxy)biphenyl, bis[4-(3-aminophenoxy)phenyl] ketone and bis [4-(3-aminophenoxy)phenyl] sulfone; tetracarboxylic dianhydrides such as pyromellitic dianhydride, 3,3', 4,4'-benzophenonetetracarboxylic dianhydride and bis(3,4-dicarboxyphenyl) ether dianhydride; and dicarboxylic anhydrides such as glutaric anhydride, 1,2-hexanedicarboxylic anhydride, phthalic anhydride and 3,4-benzophenonedicarboxylic anhydride. The molar ratio of aromatic diamine: tetracarboxylic dianhydride: dicarboxylic anhydride is 1:(0.9 to 1.0):(0.001 to 1.0).The invention also relates to polyimide composite materials which are excellent in mechanical strengths and processability. The materials contain the polyimide and fibrous reinforcing materials such as yarn, roving, tow, fabrics, mats and felts of glass fiber, carbon fibers or aromatic polyamide fibers.
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公开(公告)号：US5506311A
公开(公告)日：1996-04-09
申请号：US335332
申请日：1994-11-03
申请人： Shoji Tamai , Masahiro Ohta , Saburo Kawashima , Katsuaki Iiyama , Hideaki Oikawa , Akihiro Yamaguchi
发明人： Shoji Tamai , Masahiro Ohta , Saburo Kawashima , Katsuaki Iiyama , Hideaki Oikawa , Akihiro Yamaguchi
CPC分类号： C08G73/1042 , C08G73/105 , C08G73/1071 , C08L79/08
摘要： In one aspect, the present invention relates to polyimides having excellent thermal resistance and process for preparing the same comprising carrying out condensation of 4,4'-bis(3-aminophenoxy)biphenyl with pyromellitic dianhydride in the presence of a different diamine compound and optionally with a different tetracarboxylic acid dianhydride.In a second aspect, the present invention relates to a heat resistant resin composition consisting essentially of an aromatic polyetherimide and a defined polyimide.In a third aspect, the present invention relates to a polyimide resin composition comprised on a defined polyimide and a separate high-temperature engineering polymer.In a fourth aspect, the present invention relates to a resin composition comprised of a defined polyimide and an aromatic polyamideimide.
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公开(公告)号：US5205894A
公开(公告)日：1993-04-27
申请号：US724548
申请日：1991-06-17
申请人： Masahiro Ohta , Saburo Kawashima , Yoshiho Sonobe , Shoji Tamai , Hideaki Oikawa , Kouji Ohkoshi , Akihiro Yamaguchi
发明人： Masahiro Ohta , Saburo Kawashima , Yoshiho Sonobe , Shoji Tamai , Hideaki Oikawa , Kouji Ohkoshi , Akihiro Yamaguchi
IPC分类号： C08G73/10 , C09J179/08
CPC分类号： C08G73/1039 , C08G73/105 , C08G73/1064 , C08G73/1071 , C09J179/08
摘要： Polyimide having repeating units of the following formula (I) and its polyamic acid precursor having repeating units of the following formula (II) are disclosed; ##STR1## (where Y is a radical selected from the group consisting of a bond, divalent hydrocarbon having 1 to 10 carbons, hexafluorinated isopropylidene, carbonyl, thio, sulfinyl, sulfonyl and oxide, and R is a tetra-valent radical selected from the group consisting of aliphatic radical having 2 and more carbons, cyclo-aliphatic radical, monoaromatic radical, condensed polyaromatic radical, and non-condensed polyaromatic radical wherein aromatic radicals are mutually connected with a bond or a crosslinking function).Typical examples of polyimide and polyamic acid include where Y is thio radical and R is ##STR2## Y is a bond and R is III or IV, and Y is isopropylidene radical and R is IV.The polymers can be prepared from corresponding diamine and tetracarboxylic acid dianhydride.Polyimide or polyamic acid of this invention is excellent for high-temperature adhesive.
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公开(公告)号：US5086125A
公开(公告)日：1992-02-04
申请号：US574502
申请日：1990-08-24
申请人： Masahiro Ohta , Saburo Kawashima , Katsuaki Iiyama , Shoji Tamai , Hideaki Oikawa , Akihiro Yamaguchi
发明人： Masahiro Ohta , Saburo Kawashima , Katsuaki Iiyama , Shoji Tamai , Hideaki Oikawa , Akihiro Yamaguchi
IPC分类号： C08L79/08
CPC分类号： C08L79/08 , Y10S525/906 , Y10S525/928
摘要： This invention relates to molding resin compositions, and more particularly relates to polyimide resin compositions having markedly improved molding ability in addition to excellent high temperature stability, chemical resistance and mechanical strength.The polyimide resin composition of this invention comprises 99.9 to 50% by weight of the polyimide and 0.1 to 50% by weight of high temperature engineering polymer. The polyimide has recurring units of the following formula: ##STR1## wherein X is a sulfonyl radical or a carbonyl radical and R is a tetravalent radical selected from an aliphatic radical, alicyclic radical, monoaromatic radical, condensed aromatic radical and non-condensed aromatic radical. R is, for example, ##STR2## The high temperature engineering polymer is, for example, polyphenylene sulfide consisting of recurring units of the formula: ##STR3## aromatic polysulfone consisting of recurring units of the formula: ##STR4## or aromatic polyetherimide consisting of recurring units of the formula: ##STR5##
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