摘要:
A high pressure gas discharge lamp system includes a high pressure discharge lamp selected to have a lowest lamp resonant frequency above the audible, on a current basis above about 19 kHz and on a power basis of above about 38 kHz. The ballast circuit energizes the discharge device so as to have a fundamental frequency below the lowest lamp resonant frequency and above the audible, while keeping the magnitude of any harmonics above the lowest lamp resonant frequency sufficiently small so as to avoid acoustic resonance. By operating below the lowest lamp resonant frequency, greatly simplifying ballast construction and cost. According to one embodiment, the discharge vessel encloses a discharge space which is circular cylindrical and having a L:ID ratio of about 1:1 to maximize the lowest lamp resonant frequency. According to another embodiment, two or more discharge devices are operated concurrently by the ballast, each having a lowest lamp resonant frequency of above the audible, and the ballast operating frequency so as to increase light output while still avoiding acoustic resonance.
摘要:
A high pressure gas discharge lamp system includes a high pressure discharge lamp selected to have a lowest lamp resonant frequency above the audible, on a current basis above about 19 kHz and on a power basis of above about 38 kHz. The ballast circuit energizes the discharge device so as to have a fundamental frequency below the lowest lamp resonant frequency and above the audible, while keeping the magnitude of any harmonics above the lowest lamp resonant frequency sufficiently small so as to avoid acoustic resonance. By operating below the lowest lamp resonant frequency, greatly simplifying ballast construction and cost. According to one embodiment, the discharge vessel encloses a discharge space which is circular cylindrical and having a L:ID ratio of about 1:1 to maximize the lowest lamp resonant frequency. According to another embodiment, two or more discharge devices are operated concurrently by the ballast, each having a lowest lamp resonant frequency of above the audible, and the ballast operating frequency so as to increase light output while still avoiding acoustic resonance.
摘要:
An integrated reflector lamp includes a sealed envelope enclosing a high pressure gas discharge device. A shell has a rim portion which receives the sealed envelope and an opposing basal portion carrying a screw base. A ballast for igniting and operating the discharge device is enclosed within the shell between the screw base and the sealed envelope. The sealed envelope includes a reflective surface which directs light emitted by the discharge device. The reflective surface also provides effective heat management for preventing overheating of the ballast by the heat generated by the discharge device. The integrated lamp has photometrics and luminous efficacy which exceeds that of corresponding halogen and halogen IR reflector lamps while having an overall planform which fits within that of the corresponding lamp. In a favorable embodiment, the ballast drives the discharge device at a high frequency above about 19 kHz and below the lowest acoustic resonant frequency of the discharge device, facilitating a small physical size for the ballast while also avoiding acoustic resonance. In one embodiment, the reflector lamp fits within the ANSI outline for a PAR 38 lamp and has total lumens at least substantially equal to and a luminous efficacy which substantially exceeds that of a corresponding PAR 38 lamp having an incandescent filament.
摘要:
The present disclosure provides a fluorination process which involves reacting a hydrohaloalkene of the formula RfC—Cl═CH2 with HF in a reaction zone in the presence of a fluorination catalyst selected from the group consisting of TaF5 and TiF4 to produce a product mixture containing a hydrohaloalkane of the formula RfCFClCH3, wherein Rf is a perfluorinated alkyl group.
摘要:
This invention relates to a polyalpha-olefin (and hydrogenated analogs thereof) comprising more than 50 mole % of one or more C5 to C24 alpha-olefin monomers where the polyalpha-olefin has: a) 40 mole % or more of mm triads, b) a Bromine number of Y or greater, where Y is equal to 89.92*(V)′°5863, where V is the Kinematic Viscosity of the polyalpha-olefin measured at 100° C. in cSt, and c) 1,2 disubstituted olefins present at 7 mole % or more, preferably having Z mole % or more of units represented by the formula: where j, k and m are each, independently, 3, 4, 5, 6, 7, 8, 9, 10, 11, 12, 13, 14, 15, 16, 17, 18, 19, 20, 21, or 22, n is an integer from 1 to 350, and where Z=8.420*Log(V)−4.048, where V is the kinematic viscosity of the polyalpha-olefin measured at 1000 C in cSt This invention also relates to process to produce such polyalpha-olefins.
摘要:
Disclosed is a process for the manufacture of 2,3,3,3-tetrafluoropropene comprising: (a) contacting 1,1,1,2,3-pentafluoropropane with a catalyst comprised of chromium (III) oxide having a surface area of at least 150 m2/g and having an alkali metal loading of at least 7 milligrams of alkali metal per 100 square meters of catalyst surface area, to produce a product mixture comprising 2,3,3,3-tetrafluoropropene and hydrogen fluoride; and (b) recovering said 2,3,3,3-tetrafluoropropene from the product mixture produced in (a).
摘要:
Disclosed is a process for the manufacture of 2,3,3,3-tetrafluoropropene comprising: (a) contacting 1,1,1,2,tetrafluoro-2-chloropropane with a catalyst comprised of chromium (III) oxide, and at least 1% of an alkali metal, to produce a product mixture comprising 2,3,3,3-tetrafluoropropene; and (b) recovering said 2,3,3,3-tetrafluoropropene from the product mixture produced in step (a) above.
摘要:
Production processes and systems are provided that include reacting halogenated compounds, dehalogenating compounds, reacting alcohol's, reacting olefins and a saturated compounds, reacting reactants having at least two —CF3 groups with reactants having cyclic groups, RF-compositions such as RF-intermediates, RF-surfactants, RF-monomers, RF-monomer units, RF-metal complexes, RF-phosphate esters, RF-glycols, RF-urethanes, and or RF-foam stabilizers. The RF portion can include at least two groups —CF3 groups, at least three —CF3 groups, and/or at least two —CF3 groups and at least two —CH2 groups. Detergents, emulsifiers, paints, adhesives, inks, wetting agents, foamers, and defoamers including the RF-surfactant composition are provided. Acrylics, resins, and polymers are provided that include a RF-monomer unit. Compositions are provided that include a substrate having a RF-composition thereover. Aqueous Film Forming Foam (“AFFF”) formulations are provided that can include RF-surfactants and/or RF-foam stabilizers are provided.
摘要:
Disclosed is a process for the manufacture of 2,3,3,3-tetrafluoropropene comprising: (a) dehydrofluorinating 1,1,1,2,3-pentafluoropropane in the presence of a dehydrofluorination catalyst comprised of chromium (III) oxide, and alkali metal, to produce a product mixture comprising 2,3,3,3-tetrafluoropropene and less than 20 parts per hundred 1,3,3,3-tetrafluoro-1-propene; and (b) recovering said 2,3,3,3-tetrafluoropropene from the product mixture produced in (a).
摘要:
Disclosed in one embodiment is a hydrocarbon blend made from 0.001 to 10 wt % of at least one poly-α-olefin, by weight of the blend, the at least one poly-α-olefin having a Kv100 within the range of from 10 to 3000 cSt and a molecular weight distribution within the range of from 1.0 to 4.5; and a base stock having a Kv100 below 20.0 cSt; wherein the at least one poly-α-olefin is present in an amount sufficient to lower the pour point of the blend by at least 5° C. relative to the pour point of the base stock. In certain embodiments the blend is formed by (a) reacting a catalyst composition and a feed containing at least two sets of α-olefins, wherein the first set of α-olefins is selected from C4 to C12 α-olefins and the second set of α-olefins is selected from C14 or larger α-olefins. The α-olefin feed may have a number average carbon number of at least 8 carbon atoms or greater.