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公开(公告)号：US20130115440A1
公开(公告)日：2013-05-09
申请号：US13700229
申请日：2011-05-27
申请人： Bernd Hoevel , Martine M. Rousse , Alain M. Sagnard , Marvin L. Dettloff , Radhakrishnan Karunakaran
发明人： Bernd Hoevel , Martine M. Rousse , Alain M. Sagnard , Marvin L. Dettloff , Radhakrishnan Karunakaran
CPC分类号： B32B5/18 , B29C70/86 , B29K2063/00 , B32B5/22 , B32B2266/0228 , B32B2266/0235 , B32B2266/0242 , B32B2266/0257 , B32B2266/0264 , B32B2266/0278 , B32B2605/18 , C08G59/4238 , C08G59/444 , C08G59/504 , C08J5/24 , C08J9/34 , C08J2363/00 , C08L63/00 , Y10T428/249953
摘要： Embodiments include methods of forming a composite. The methods can include providing a foam core, wherein the foam core includes a foam having a softening point of 90° C. to 110° C., covering a portion of the foam core with a prepreg, contacting the prepreg that covers the portion of the foam core with a curable composition, and curing the prepreg and the curable composition to form the composite, wherein the prepreg insulates the foam core during the curing so that the foam maintains a temperature that is below the softening point. Embodiments include a composite obtained by curing the prepreg and the curable composition. Embodiments include B-stageable formulation having a resin component and a hardener component.
摘要翻译： 实施方案包括形成复合材料的方法。 该方法可以包括提供泡沫芯，其中泡沫芯包括软化点为90℃至110℃的泡沫，用预浸料覆盖泡沫芯的一部分，使覆盖部分的预浸料接触 所述泡沫芯具有可固化组合物，并且固化所述预浸料和所述可固化组合物以形成所述复合材料，其中所述预浸料在固化期间使泡沫芯绝缘，使得所述泡沫保持低于软化点的温度。 实施方案包括通过固化预浸料和可固化组合物获得的复合物。 实施方案包括具有树脂组分和硬化剂组分的B阶可制剂。
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公开(公告)号：US20130210961A1
公开(公告)日：2013-08-15
申请号：US13816529
申请日：2011-09-22
IPC分类号： C08L63/00 , C09J163/00 , C09D163/00
CPC分类号： C08L63/00 , C08G59/066 , C08K5/18 , C09D163/00 , C09J163/00
摘要： An epoxy resin composition formed, at least in part, as the reaction product of a mixture comprising 95 and 99 wt % of an epoxy component comprising one or more diglycidyl ethers of Bisphenol A and between 1 and 5 wt % of an additive component comprising one or more aromatic amines, wherein each aromatic amine contains no more than two amine hydrogen atoms is provided. Also provided is a method of using the epoxy resin composition including incorporating the epoxy resin composition into a coating, an adhesive, a sealant, a casting, a laminate, or a composite.
摘要翻译： 环氧树脂组合物至少部分形成为包含95-99重量％的包含双酚A的一种或多种二缩水甘油醚和1-5重量％的添加剂组分的环氧组分的混合物的反应产物，其包含一种 或更多芳族胺，其中每个芳族胺含有不超过两个胺氢原子。 还提供了使用环氧树脂组合物的方法，其包括将环氧树脂组合物掺入涂料，粘合剂，密封剂，铸塑，层压体或复合材料中。
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公开(公告)号：US20120172493A1
公开(公告)日：2012-07-05
申请号：US13389028
申请日：2010-09-21
申请人： Marvin L. Dettloff , Gary A. Hunter , Susan K. Falcone-Potts , Ha Q. Pham , Martine Rousse , Bernd Hoevel
发明人： Marvin L. Dettloff , Gary A. Hunter , Susan K. Falcone-Potts , Ha Q. Pham , Martine Rousse , Bernd Hoevel
CPC分类号： C08G59/64 , C08G59/621 , C08J5/24 , C08J2363/02
摘要： A curable epoxy resin composite composition including a reinforcing material and an epoxy resin composition, and a process for preparing a composite from such composition; wherein a combination of at least one alkanolamine and at least one styrenated phenol are present in the epoxy resin composition in a sufficient amount to increase the rate of reaction of the at least one epoxy resin and the at least one alkanolamine curing agent while maintaining the thermal and mechanical properties of the composite upon curing of the epoxy resin composition.
摘要翻译： 包含增强材料和环氧树脂组合物的可固化环氧树脂复合组合物及其制备方法。 其中至少一种链烷醇胺和至少一种苯乙烯化酚的组合以足够的量存在于环氧树脂组合物中以提高至少一种环氧树脂和至少一种链烷醇胺固化剂的反应速率同时保持热 以及环氧树脂组合物固化时复合材料的机械性能。
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4.发明申请公开(公告)号：US20120010330A1
公开(公告)日：2012-01-12
申请号：US13254180
申请日：2010-02-16
CPC分类号： C08G59/56 , C08G59/621 , C08L63/00
摘要： A curable composition including (a) at least one cyclic diamine, (b) at least one non-heterocyclic amine that has a pKa value of approximately 9.5 to about 12 at 25° C. for the most basic amine group in the non-heterocyclic amine molecule, (c) at least one epoxy resin, and (d) at least one alkylated phenol; (i) wherein the equivalents of the amine hydrogens from the cyclic diamine compared to the total amine hydrogens from both the cyclic diamine and the non-heterocyclic amine in the composition are greater than about 5%; (ii) wherein the ratio of the equivalents of the total amine hydrogens in the composition to the equivalents of the total epoxies in the composition is greater than or equal to about 1; and (iii) wherein the alkylated phenol is in an amount greater than about 10 wt % of the curable composition.
摘要翻译： 一种可固化组合物，其包含（a）至少一种环状二胺，（b）至少一种在25℃下对于非杂环中最碱性的胺基具有约9.5至约12的pKa值的非杂环胺 胺分子，（c）至少一种环氧树脂，和（d）至少一种烷基化苯酚; （i）其中来自环二胺的胺氢的当量与组合物中来自环二胺和非杂环胺的总胺氢相比大于约5％; （ii）其中组合物中总胺氢的当量与组合物中总环氧化物的当量的比例大于或等于约1; 和（iii）其中烷基化苯酚的量大于可固化组合物的约10重量％。
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公开(公告)号：US20090143544A1
公开(公告)日：2009-06-04
申请号：US12328868
申请日：2008-12-05
申请人： Zenon Lysenko , Bob R. Maughon , Jozef Bicerano , Kenneth A. Burdett , Christopher P. Christenson , Clark H. Cummins , Marvin L. Dettloff , Alan K. Schrock , P. J. Thomas , Richard D. Varjian , Jerry E. White , John Michael Maher
发明人： Zenon Lysenko , Bob R. Maughon , Jozef Bicerano , Kenneth A. Burdett , Christopher P. Christenson , Clark H. Cummins , Marvin L. Dettloff , Alan K. Schrock , P. J. Thomas , Richard D. Varjian , Jerry E. White , John Michael Maher
IPC分类号： C08L63/08 , C07C51/43 , C07C59/42 , C07C31/18 , C07C215/00 , C08L79/02 , C08L67/04 , C07C229/00 , C07C69/732 , C07C1/00
CPC分类号： C07D303/42 , C07C67/31 , C07C67/333 , C07C67/347 , C07C67/56 , C07C69/533 , C07C227/08 , C07C227/18 , C07C229/08 , Y02P20/125 , C07C69/716 , C07C69/675
摘要： Integrated processes of preparing industrial chemicals starting from seed oil feedstock compositions containing one or more unsaturated fatty acids or unsaturated fatty acid esters, which are essentially free of metathesis catalyst poisons, particularly hydroperoxides; metathesis of the feedstock composition with a lower olefin, such as ethylene, to form a reduced chain olefin, preferably, a reduced chain α-olefin, and a reduced chain unsaturated acid or ester, preferably, a reduced chain α,ω-unsaturated acid or ester. The reduced chain unsaturated acid or ester may be (trans)esterified to form a polyester polyolefin, which may be epoxidized to form a polyester polyepoxide. The reduced chain unsaturated acid or ester may be hydroformylated with reduction to produce an α,ω-hydroxy acid or α,ω-hydroxy ester, which may be (trans)esterified with a polyol to form an α,ωpolyester polyol. Alternatively, the reduced chain unsaturated acid or ester may be hydroformylated with reductive amination to produce an α,ω-amino acid or α,ω-amino ester, which may be (trans)esterified to form an α,ω-polyester polyamine.
摘要翻译： 从含有一种或多种不饱和脂肪酸或不饱和脂肪酸酯的种子油原料组合物制备工业化学品的综合方法，其基本上不含复分解催化剂毒物，特别是氢过氧化物; 原料组合物与低级烯烃如乙烯的复分解以形成还原链烯烃，优选还原链的α-烯烃和还原链不饱和酸或酯，优选还原链的α，ω-不饱和酸 或酯。 还原链不饱和酸或酯可以（反式）酯化以形成聚酯聚烯烃，其可以被环氧化以形成聚酯多环氧化物。 还原链不饱和酸或酯可以通过还原加氢甲酰化以产生α，ω-羟基酸或α，ω-羟基酯，其可以与多元醇反应形成α，ω-聚酯多元醇。 或者，还原链不饱和酸或酯可以通过还原胺化加氢甲酰化以产生α，ω-氨基酸或α，ω-氨基酯，其可以（反式）酯化形成α，ω-聚酯多胺。
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公开(公告)号：US5633020A
公开(公告)日：1997-05-27
申请号：US539138
申请日：1995-10-04
IPC分类号： B05D7/24 , B05D7/00 , C08G59/42 , C08G67/00 , C08G67/04 , C08L57/00 , C08L63/00 , C08L73/00 , C08L73/02 , C09D5/03 , C09D133/06 , C09D163/00 , C09D173/00 , C09D173/02 , C08L33/14
CPC分类号： B05D7/53 , C08G59/42 , C08L63/00 , C08L73/02 , C09D133/068 , C09D163/00 , C09D173/02 , C08L57/00 , Y10T428/31515 , Y10T428/31522 , Y10T428/31529 , Y10T428/31692
摘要： A coating composition with a solids content of at least about 65% by weight comprises a polyanhydride having more than one non-cyclic anhydride moiety, a co-reactant resin such as a glycidyl (meth)acrylate-containing polymer and a latent catalyst wherein the equivalent ratio of epoxy to anhydride is from about 0.8:1 to 1.3:1.
摘要翻译： 固体含量为至少约65重量％的涂料组合物包含具有多于一个非环酸酐部分的聚酐，共反应物树脂如含（甲基）丙烯酸酯缩水甘油酯聚合物和潜催化剂，其中， 环氧与酸酐的当量比为约0.8:1至1.3:1。
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公开(公告)号：US5602274A
公开(公告)日：1997-02-11
申请号：US396458
申请日：1995-02-28
IPC分类号： B05D7/24 , B05D7/00 , C08G59/42 , C08G67/00 , C08G67/04 , C08L57/00 , C08L63/00 , C08L73/00 , C08L73/02 , C09D5/03 , C09D133/06 , C09D163/00 , C09D173/00 , C09D173/02 , C07C69/75
CPC分类号： B05D7/53 , C08G59/42 , C08L63/00 , C08L73/02 , C09D133/068 , C09D163/00 , C09D173/02 , C08L57/00 , Y10T428/31515 , Y10T428/31522 , Y10T428/31529 , Y10T428/31692
摘要： A polyanhydride having a molecular weight of no more than about 2000 is useful in a coating composition with a coreactant resin such as an epoxy resin and comprises:(a) a polyvalent organic moiety;(b) a plurality of ester linkages bonded to the polyvalent organic moiety;(c) divalent organic moieties bonded to the ester linkages; and(d) non-cyclic anhydride moleties bonded to the divalent organic moleties.
摘要翻译： 分子量不大于约2000的聚酐可用于具有共反应树脂如环氧树脂的涂料组合物，并且包含：（a）多价有机部分; （b）与多价有机部分结合的多个酯键; （c）键合到酯键的二价有机基团; 和（d）与二价有机游动物结合的非环状酸酐摩尔。
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8.发明授权公开(公告)号：US08980979B2
公开(公告)日：2015-03-17
申请号：US13254180
申请日：2010-02-16
CPC分类号： C08G59/56 , C08G59/621 , C08L63/00
摘要： A curable composition including (a) at least one cyclic diamine, (b) at least one non-heterocyclic amine that has a pKa value of approximately 9.5 to about 12 at 25° C. for the most basic amine group in the non-heterocyclic amine molecule, (c) at least one epoxy resin, and (d) at least one alkylated phenol; (i) wherein the equivalents of the amine hydrogens from the cyclic diamine compared to the total amine hydrogens from both the cyclic diamine and the non-heterocyclic amine in the composition are greater than about 5%; (ii) wherein the ratio of the equivalents of the total amine hydrogens in the composition to the equivalents of the total epoxies in the composition is greater than or equal to about 1; and (iii) wherein the alkylated phenol is in an amount greater than about 10 wt % of the curable composition.
摘要翻译： 一种可固化组合物，其包含（a）至少一种环状二胺，（b）至少一种在25℃下对于非杂环中最碱性的胺基具有约9.5至约12的pKa值的非杂环胺 胺分子，（c）至少一种环氧树脂，和（d）至少一种烷基化苯酚; （i）其中来自环二胺的胺氢的当量与组合物中来自环二胺和非杂环胺的总胺氢相比大于约5％; （ii）其中组合物中总胺氢的当量与组合物中总环氧化物的当量的比例大于或等于约1; 和（iii）其中烷基化苯酚的量大于可固化组合物的约10重量％。
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公开(公告)号：US20140114022A1
公开(公告)日：2014-04-24
申请号：US14113144
申请日：2012-04-20
申请人： Marvin L. Dettloff
发明人： Marvin L. Dettloff
IPC分类号： C08L63/00
CPC分类号： C08L63/00 , C08G59/226 , C08G59/5006 , C08G59/5026 , C08G2650/50
摘要： Embodiments of the present disclosure provide a curable composition having an epoxy resin component having an epoxide equivalent weight of 75 grams/equivalent to 210 grams/equivalent, an amine component having a hydrogen equivalent weight of 18 grams/equivalent to 70 grants/equivalent, and an acrylate component having an acrylate equivalent weight of 85 grams/equivalent to 160 grams/equivalent, wherein the acrylate component is 1 part per hundred parts epoxy resin to less than 5 parts per hundred parts epoxy resin.
摘要翻译： 本公开的实施方案提供了具有环氧树脂组分的可固化组合物，其环氧当量为75克/当量至210克/当量，胺当量重量为18克/当量至70份/当量的胺组分，和 丙烯酸酯组分，其丙烯酸酯当量为85克/当量至160克/当量，其中丙烯酸酯组分为每100份环氧树脂1份至小于5份/ 100份环氧树脂。
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公开(公告)号：US07745652B2
公开(公告)日：2010-06-29
申请号：US12328868
申请日：2008-12-05
申请人： Zenon Lysenko , Bob R. Maughon , Jozef Bicerano , Kenneth A. Burdett , Christopher P. Christenson , Clark H. Cummins , Marvin L. Dettloff , Alan K. Schrock , P. J. Thomas , Richard D. Varjian , Jerry E. White , John Michael Maher
发明人： Zenon Lysenko , Bob R. Maughon , Jozef Bicerano , Kenneth A. Burdett , Christopher P. Christenson , Clark H. Cummins , Marvin L. Dettloff , Alan K. Schrock , P. J. Thomas , Richard D. Varjian , Jerry E. White , John Michael Maher
IPC分类号： C07C51/43
CPC分类号： C07D303/42 , C07C67/31 , C07C67/333 , C07C67/347 , C07C67/56 , C07C69/533 , C07C227/08 , C07C227/18 , C07C229/08 , Y02P20/125 , C07C69/716 , C07C69/675
摘要： Integrated processes of preparing industrial chemicals starting from seed oil feedstock compositions containing one or more unsaturated fatty acids or unsaturated fatty acid esters, which are essentially free of metathesis catalyst poisons, particularly hydroperoxides; metathesis of the feedstock composition with a lower olefin, such as ethylene, to form a reduced chain olefin, preferably, a reduced chain α-olefin, and a reduced chain unsaturated acid or ester, preferably, a reduced chain α,ω-unsaturated acid or ester. The reduced chain unsaturated acid or ester may be (trans)esterified to form a polyester polyolefin, which may be epoxidized to form a polyester polyepoxide. The reduced chain unsaturated acid or ester may be hydroformylated with reduction to produce an α,ω-hydroxy acid or α,ω-hydroxy ester, which may be (trans)esterified with a polyol to form an α,ω-polyester polyol. Alternatively, the reduced chain unsaturated acid or ester may be hydroformylated with reductive amination to produce an α,ω-amino acid or α,ω-amino ester, which may be (trans)esterified to form an α,ω-polyester polyamine.
摘要翻译： 从含有一种或多种不饱和脂肪酸或不饱和脂肪酸酯的种子油原料组合物制备工业化学品的综合方法，其基本上不含复分解催化剂毒物，特别是氢过氧化物; 原料组合物与低级烯烃如乙烯的复分解以形成还原链烯烃，优选还原链α-烯烃和还原链不饱和酸或酯，优选还原链α，ω-不饱和酸 或酯。 还原链不饱和酸或酯可以（反式）酯化以形成聚酯聚烯烃，其可以被环氧化以形成聚酯多环氧化物。 还原链不饱和酸或酯可以通过还原加氢甲酰化以产生α，ω-羟基酸或α，ω-羟基酯，其可以与多元醇反应形成α，ω-聚酯多元醇。 或者，还原链不饱和酸或酯可以通过还原胺化加氢甲酰化以产生α，ω-氨基酸或α，ω-氨基酯，其可以（反式）酯化形成α，ω-聚酯多胺。
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