Process for producing aromatic hydrocarbon and hydrogen
    1.
    发明授权
    Process for producing aromatic hydrocarbon and hydrogen 有权
    芳烃和氢气的制备方法

    公开(公告)号:US08148590B2

    公开(公告)日:2012-04-03

    申请号:US11658399

    申请日:2005-07-28

    IPC分类号: C07C15/00

    摘要: A process for producing aromatic hydrocarbons and hydrogen, in which a lower hydrocarbons-containing feedstock gas is reformed by being supplied to and being brought into contact with a catalyst under high temperature conditions thereby forming aromatic hydrocarbons and hydrogen. The method includes the steps of (a) supplying a hydrogen gas together with the feedstock gas during a supply of the feedstock gas; and (b) suspending the supply of the feedstock gas for a certain period of time while keeping a condition of a supply of the hydrogen gas. The catalyst is exemplified by a metallo-silicate carrying molybdenum and a metallo-silicate carrying molybdenum and rhodium. An amount of the hydrogen gas supplied together with the feedstock gas is set to be preferably larger than 2% and smaller than 10%, more preferably within a range of from 4 to 8%, much more preferably 8%. As a pretreatment for a reforming reaction by which aromatic hydrocarbons and hydrogen are formed, the catalyst is increased in temperature and kept at the temperature for a certain period of time while a gas containing methane and hydrogen is supplied thereto.

    摘要翻译: 一种生产芳烃和氢的方法,其中含低级烃的原料气体通过在高温条件下被供给并与催化剂接触而重整,从而形成芳族烃和氢。 该方法包括以下步骤:(a)在原料气体的供给期间,与原料气体一起供应氢气; 和(b)在保持氢气供应状态的同时暂停供应原料气一段时间。 催化剂的例子是载有钼的金属硅酸盐和携带钼和铑的金属硅酸盐。 与原料气体一起供给的氢气的量优选设定为2%以上且小于10%,更优选在4〜8%的范围内,进一步优选为8%以下。 作为形成芳烃和氢的重整反应的预处理,催化剂的温度升高并在该温度下保持一段时间,同时向其中供给含有甲烷和氢气的气体。

    Process for production of aromatic compound
    2.
    发明授权
    Process for production of aromatic compound 有权
    芳香族化合物生产工艺

    公开(公告)号:US08097763B2

    公开(公告)日:2012-01-17

    申请号:US12067148

    申请日:2006-09-29

    IPC分类号: C07C2/42

    CPC分类号: C07C2/76 C07C15/02

    摘要: An aromatic compound, particularly benzene, is stably produced in the presence of a catalyst from a lower hydrocarbon having 2 or more carbon atoms, particularly from an ethane-containing gas composition such as ethane gas and natural gas. Disclosed is a process for producing an aromatic compound by reacting ethane or an ethane-containing raw gas in the presence of a catalyst. The catalyst may comprise molybdenum carried on metallosilicate such as H-type ZSM-5H or H-type MCM-22. In the reaction, the temperature is from 550 to 750° C., preferably not lower than 600° C. and not higher than 680° C. Additionally, the raw gas further contains methane and hydrogen is added thereto, thereby improving the production efficiency and stability.

    摘要翻译: 在具有2个或更多个碳原子的低级烃的催化剂的存在下,特别是从含乙烷的气体组合物如乙烷气体和天然气中稳定地制备芳族化合物,特别是苯。 公开了一种在催化剂存在下使乙烷或含乙烷的原料气体反应生成芳族化合物的方法。 催化剂可以包括载在金属硅酸盐上的钼,例如H型ZSM-5H或H型MCM-22。 在该反应中,温度为550〜750℃,优选为600℃以上且不高于680℃。此外,原料气体还含有甲烷,向其中添加氢,从而提高生产效率 和稳定性。

    PROCESS FOR PRODUCTION OF AROMATIC COMPOUND
    3.
    发明申请
    PROCESS FOR PRODUCTION OF AROMATIC COMPOUND 有权
    芳香化合物生产工艺

    公开(公告)号:US20090240093A1

    公开(公告)日:2009-09-24

    申请号:US12067148

    申请日:2006-09-29

    IPC分类号: C07C2/00

    CPC分类号: C07C2/76 C07C15/02

    摘要: An aromatic compound, particularly benzene, is stably produced in the presence of a catalyst from a lower hydrocarbon having 2 or more carbon atoms, particularly from an ethane-containing gas composition such as ethane gas and natural gas. Disclosed is a process for producing an aromatic compound by reacting ethane or an ethane-containing raw gas in the presence of a catalyst. The catalyst may comprise molybdenum carried on metallosilicate such as H-type ZSM-5H or H-type MCM-22. In the reaction, the temperature is from 550 to 750° C., preferably not lower than 600° C. and not higher than 680° C. Additionally, the raw gas further contains methane and hydrogen is added thereto, thereby improving the production efficiency and stability.

    摘要翻译: 在具有2个或更多个碳原子的低级烃的催化剂的存在下,特别是从含乙烷的气体组合物如乙烷气体和天然气中稳定地制备芳族化合物,特别是苯。 公开了一种在催化剂存在下使乙烷或含乙烷的原料气体反应生成芳族化合物的方法。 催化剂可以包括载在金属硅酸盐上的钼,例如H型ZSM-5H或H型MCM-22。 在该反应中,温度为550〜750℃,优选为600℃以上且不高于680℃。此外,原料气体还含有甲烷,向其中添加氢,从而提高生产效率 和稳定性。

    Process for Producing Aromatic Hydrocarbon and Hydrogen
    4.
    发明申请
    Process for Producing Aromatic Hydrocarbon and Hydrogen 有权
    生产芳香烃和氢的方法

    公开(公告)号:US20080312483A1

    公开(公告)日:2008-12-18

    申请号:US11658399

    申请日:2005-07-28

    IPC分类号: C07C5/367

    摘要: A process for producing aromatic hydrocarbons and hydrogen, in which a lower hydrocarbons-containing feedstock gas is reformed by being supplied to and being brought into contact with a catalyst under high temperature conditions thereby forming aromatic hydrocarbons and hydrogen. The method includes the steps of (a) supplying a hydrogen gas together with the feedstock gas during a supply of the feedstock gas; and (b) suspending the supply of the feedstock gas for a certain period of time while keeping a condition of a supply of the hydrogen gas. The catalyst is exemplified by a metallo-silicate carrying molybdenum and a metallo-silicate carrying molybdenum and rhodium. An amount of the hydrogen gas supplied together with the feedstock gas is set to be preferably larger than 2% and smaller than 10%, more preferably within a range of from 4 to 8%, much more preferably 8%. As a pretreatment for a reforming reaction by which aromatic hydrocarbons and hydrogen are formed, the catalyst is increased in temperature and kept at the temperature for a certain period of time while a gas containing methane and hydrogen is supplied thereto.

    摘要翻译: 一种生产芳烃和氢的方法,其中含低级烃的原料气体通过在高温条件下被供给并与催化剂接触而重整,从而形成芳族烃和氢。 该方法包括以下步骤:(a)在原料气体的供给期间,与原料气体一起供应氢气; 和(b)在保持氢气供应状态的同时暂停供应原料气一段时间。 催化剂的例子是载有钼的金属硅酸盐和携带钼和铑的金属硅酸盐。 与原料气体一起供给的氢气的量优选设定为2%以上且小于10%,更优选在4〜8%的范围内,进一步优选为8%以下。 作为形成芳烃和氢的重整反应的预处理,催化剂的温度升高并在该温度下保持一段时间,同时向其中供给含有甲烷和氢气的气体。

    Catalyst for aromatization of lower hydrocarbons and process for production of aromatic compounds
    5.
    发明授权
    Catalyst for aromatization of lower hydrocarbons and process for production of aromatic compounds 有权
    用于低级烃芳构化的催化剂和用于生产芳族化合物的方法

    公开(公告)号:US08278237B2

    公开(公告)日:2012-10-02

    申请号:US12524029

    申请日:2008-02-13

    IPC分类号: B01J29/06 C07C2/52 C07C15/00

    摘要: A catalyst for producing aromatic compounds from lower hydrocarbons while improving activity life stability of methane conversion rate; benzene formation rate; naphthalene formation rate; and total formation rate of benzene, toluene and xylene is formed by loading molybdenum and copper on metallo-silicate serving as a substrate and then calcining the metallo-silicate. When the catalyst is reacted with a reaction gas containing lower hydrocarbons and carbonic acid gas, aromatic compounds are produced. In order to obtain the catalyst, it is preferable that molybdenum and copper are loaded on zeolite formed of metallo-silicate after the zeolite is treated with a silane compound larger than a pore of the zeolite in diameter and having an amino group and a straight-chain hydrocarbon group, the amino group being able to selectively react with the zeolite at a Bronsted acid point of the zeolite. It is preferable that a loaded amount of molybdenum is within a range of from 2 to 12 wt. % based on total amount of the calcined catalyst while copper is loaded at a copper to molybdenum molar ratio of 0.01 to 0.8.

    摘要翻译: 一种用于从低级烃生产芳族化合物的催化剂,同时提高甲烷转化率的活性寿命稳定性; 苯形成率; 萘形成率; 苯,甲苯和二甲苯的总形成速率是通过将钼和铜负载在作为基底的金属硅酸盐上,然后煅烧金属硅酸盐而形成的。 当催化剂与含有低级烃和碳酸气体的反应气体反应时,产生芳族化合物。 为了得到催化剂,优选在沸石用直径大于沸石孔的硅烷化合物进行处理并具有氨基和直链状烷基的情况下,将钼和铜负载在由金属硅酸盐形成的沸石上, 链烷烃基,该氨基能够在沸石的布朗斯台德酸点处与沸石选择性反应。 钼的负载量优选在2〜12重量%的范围内。 基于煅烧催化剂的总量的%,而铜以铜与钼的摩尔比为0.01至0.8。

    METHOD FOR PRODUCING AROMATIC HYDROCARBON
    6.
    发明申请
    METHOD FOR PRODUCING AROMATIC HYDROCARBON 审中-公开
    生产芳香烃的方法

    公开(公告)号:US20120022309A1

    公开(公告)日:2012-01-26

    申请号:US13146274

    申请日:2010-01-15

    申请人: Hongtao Ma Yuji Ogawa

    发明人: Hongtao Ma Yuji Ogawa

    IPC分类号: C07C2/76

    摘要: [Object] To produce aromatic hydrocarbon stably for a long time maintaining a high aromatic hydrocarbon yield when the aromatic hydrocarbon is produced upon making a contact reaction between lower hydrocarbon and a catalyst.[Solving Means] In a method of producing aromatic hydrocarbon, including repeating a reaction step for obtaining aromatic hydrocarbon upon making a contact reaction between lower hydrocarbon and a catalyst and a regeneration step for regenerating the catalyst used in the reaction step, carbon dioxide in an amount of 0.33 to 1.6% by volume relative to an amount of the lower hydrocarbon is added to the lower hydrocarbon, in the reaction step.

    摘要翻译: 当在低级烃和催化剂之间进行接触反应制备芳族烃时,长时间稳定地制备芳族烃,保持高的芳族烃产率。 [解决方案]在制备芳族烃的方法中,包括在进行低级烃和催化剂之间的接触反应时重复进行芳烃的反应步骤和用于再生反应步骤中使用的催化剂的再生步骤, 在反应步骤中相对于低级烃的量加入到低级烃中的量为0.33〜1.6体积%。

    METHOD FOR PRODUCING AROMATIC HYDROCARBON AND APPARATUS FOR PRODUCING AROMATIC HYDROCARBON
    7.
    发明申请
    METHOD FOR PRODUCING AROMATIC HYDROCARBON AND APPARATUS FOR PRODUCING AROMATIC HYDROCARBON 有权
    生产芳香烃的方法和制备芳香烃的装置

    公开(公告)号:US20110288355A1

    公开(公告)日:2011-11-24

    申请号:US13146272

    申请日:2010-01-15

    申请人: Yuji Ogawa Hongtao Ma

    发明人: Yuji Ogawa Hongtao Ma

    IPC分类号: C07C15/04 B01J8/00

    摘要: To economically regenerate a catalyst and to produce aromatic hydrocarbon stably for a long time maintaining a high aromatic hydrocarbon yield when the aromatic hydrocarbon is produced upon making a contact reaction between lower hydrocarbon and the catalyst.A method of producing aromatic hydrocarbon and an apparatus for producing aromatic hydrocarbon by repeating a reaction step for obtaining aromatic hydrocarbon upon making a contact reaction between lower hydrocarbon and a catalyst and a regeneration step for regenerating the catalyst used in the reaction step. Off-gas which is gas obtained by removing aromatic hydrocarbon produced in the reaction step from discharge gas passing through the reaction step is used as a regeneration gas in the regeneration step.

    摘要翻译: 为了经济地再生催化剂并长时间稳定地制备芳族烃,当在低级烃和催化剂之间进行接触反应时产生芳族烃时,保持高的芳族烃产率。 通过重复在低级烃和催化剂之间进行接触反应获得芳族烃的反应步骤和用于再生反应步骤中使用的催化剂的再生步骤的芳族烃的制备方法和芳香族烃的制造装置。 作为在再生工序中的再生气体,使用作为在反应工序中产生的芳香族烃的废气通过反应工序的排出气体而得到的废气。

    Structure of mounting shield cover and display device
    8.
    发明授权
    Structure of mounting shield cover and display device 有权
    安装屏蔽罩和显示装置的结构

    公开(公告)号:US07719857B2

    公开(公告)日:2010-05-18

    申请号:US11928401

    申请日:2007-10-30

    申请人: Yuji Ogawa

    发明人: Yuji Ogawa

    IPC分类号: H05K9/00

    CPC分类号: H05K9/0054

    摘要: A structure of mounting a shield cover according to the present invention includes a shield cover having an insertion part which is inserted into a gap formed between a circuit substrate and a shield cover fastening part along the circuit substrate. The insertion part of the shield cover includes a convex part that is elastic and deformable, and the end of the insertion part and the shield cover fastening part come in contact with each other by the elasticity with the convex part being in contact with the circuit substrate as the fulcrum.

    摘要翻译: 根据本发明的安装屏蔽罩的结构包括屏蔽盖,其具有插入部分,插入部分沿着电路基板插入形成在电路基板和屏蔽盖紧固部分之间的间隙中。 屏蔽罩的插入部分包括弹性和可变形的凸起部分,并且插入部分和屏蔽盖紧固部分的端部通过弹性而彼此接触,凸起部分与电路基板接触 为支点。

    AUTOMATIC ANALYZER
    9.
    发明申请
    AUTOMATIC ANALYZER 审中-公开
    自动分析仪

    公开(公告)号:US20100053620A1

    公开(公告)日:2010-03-04

    申请号:US12613405

    申请日:2009-11-05

    申请人: Yuji Ogawa

    发明人: Yuji Ogawa

    IPC分类号: G01N21/00

    摘要: An automatic analyzer including a light source device. The light source device includes a plurality of light sources that emit respective lights of different peak wavelengths, in which a wavelength range of one of the light emitted contains the peak wavelength of the other light emitted from the other light source; and a mixing unit that mixes the respective lights emitted from the light sources. The light source device outputs a light having a desired mixed peak wavelength that is different from the peak wavelengths.

    摘要翻译: 一种包括光源装置的自动分析装置。 光源装置包括发射不同峰值波长的各种光的多个光源,其中发射的一个光的波长范围包含从另一个光源发射的另一个光的峰值波长; 以及混合单元,其将从光源发射的各个光混合。 光源装置输出具有与峰值波长不同的期望的混合峰值波长的光。

    Saw device manufacturing method
    10.
    发明申请
    Saw device manufacturing method 有权
    锯装置制造方法

    公开(公告)号:US20060150381A1

    公开(公告)日:2006-07-13

    申请号:US10559238

    申请日:2004-06-01

    IPC分类号: H04R17/00

    摘要: To provide a high quality SAW device with enhanced productivity, wherein an outer face of a SAW chip mounted on a mounting substrate is covered with a heat-softened resin sheet and resin is filled on the SAW chip to form an airtight space below an IDT in the SAW device. A method for manufacturing the SAW device includes: a step of flip-chip mounting the SAW chip on the mounting substrate, a step of placing the resin sheet on an upper face of the SAW chip; a laminating step of setting ambient environment to pressure-reduced or vacuum atmosphere and covering the outer face of the SAW chip with resin while securing the airtight space by pressurizing the resin sheet while heating the resin sheet; a press forming step of curing the resin while maintaining the airtight space by maintaining pressurized and heated state in the laminating step; and a post-curing step of performing heating at a temperature and for a time in which the resin completely cures, wherein a thickness tr of the resin sheet before the laminating step satisfies an equation of L/{(X+Gx)(Y+Gy)}≦tr.

    摘要翻译: 为了提供提高生产率的高品质SAW器件,其中安装在安装基板上的SAW芯片的外表面被热软化的树脂片覆盖,树脂填充在SAW芯片上,以在IDT下方形成气密空间 SAW器件。 一种制造SAW器件的方法包括:将SAW芯片倒装安装在安装基板上的步骤,将树脂片放置在SAW芯片的上表面上的步骤; 将周围环境设置为减压或真空气氛并用树脂覆盖SAW芯片的外表面的层压步骤,同时通过在加热树脂板的同时加压树脂板来确保气密空间; 压制成形步骤,通过在层叠步骤中保持加压和加热状态,同时保持气密空间而固化树脂; 以及在树脂完全固化的温度和时间进行加热的后固化步骤,其中层压步骤之前的树脂片的厚度tr满足方程式<?in-line-formula description =“In 线/公式“end =”lead“?> L / {(X + Gx)(Y + Gy)} <= tr。 <?in-line-formula description =“In-line Formulas”end =“tail”?>