摘要:
A two-coat coating system for producing a two-coat coating, comprising (A) a composition of a transparent radiation-curable or radiation-curable and thermally curable clearcoat material, comprising at least one hydroxy-functional binder, and (B) a pigmented coating composition, the pigmented coating composition comprising at least one blocked, water-soluble or water-dispersible isocyanate.
摘要:
A two-coat coating system for producing a two-coat coating, comprising (A) a composition of a transparent radiation-curable or radiation-curable and thermally curable clearcoat material, comprising at least one hydroxy-functional binder, and (B) a pigmented coating composition, the pigmented coating composition comprising at least one blocked, water-soluble or water-dispersible isocyanate.
摘要:
A process for producing sheets, in which a free-radically crosslinkable coating composition (K) which after crosslinking to completion gives a transparent coating (KE) is applied to a backing sheet (T), a coating (KT), dried but not yet crosslinked to completion, is produced from the coating composition (K), on (KT) a pigmented coating (PB) is produced and optionally on (PB) a tiecoat is applied, the crosslinkable coating composition (K) comprising a free-radically crosslinkable component (KK) based on urethane acrylate and containing carbamate and/or biuret and/or allophanate and/or urea and/or amide groups, (KK) having a number-average molecular weight of from 1000 to 50 000 g/mol, having a double bond content of from 1.0 to 5.0 mol of double bonds per 1000 g of reactive component (KK), containing on average per molecule >1 branching point, containing 5%-50% by weight, based in each case on the weight of component (KK), of cyclic structural elements, and containing at least one aliphatic structural element having at least 6 carbon atoms in the chain.
摘要:
A method of curing free-radically curable compositions under an inert gas atmosphere, where the curing, which proceeds in accordance with a free-radical mechanism, is initiated, or initiated and maintained, in the free-radically curable compositions by radiation and the lateral escape of the inert gas atmosphere is prevented, which involves (1) immersing the free-radically curable compositions in an inert gas atmosphere below a depth from which the inert gas atmosphere constantly exhibits its lowest oxygen concentration, and (2) irradiating the free-radically curable compositions below this depth in the inert gas atmosphere, at least one of the radiation sources being arranged beneath the inert gas/air interface, and then (3) emersing the resultant cured compositions again from the inert gas atmosphere, and apparatus (1) according to FIG. 1 for its implementation.
摘要:
A process for producing moldings, in which a solventborne or aqueous, pigmented coating composition (P) and a free-radically crosslinkable coating composition (K), which after crosslinking to completion produces a transparent coating (KE) are applied to a support sheet, a dried but as yet not completely crosslinked coating (KT) is produced from the coating composition (K), the coated support sheet is shaped and is injection backmolded or foam-backed with a liquid polymeric material, and the coating (KT)—if this has not already taken place—is cured or aftercured; the crosslinkable coating composition (K) comprising a free- radically crosslinkable component (KK) which comprises carbamate and/or biuret and/or allophanate and/or urea and/or amide groups.
摘要:
A process for producing polymer moldings with functional surfaces, in which a coating is produced on a support sheet, the coated support sheet is shaped and backed by injection molding or foaming with a liquid polymeric material, and the coating, if this has not already taken place, is cured or aftercured, the coating is covered at least temporarily with a protective sheet.
摘要:
A process for producing moldings, in which a pigmented coating composition (P) and a free-radically crosslinkable coating composition (K), which after crosslinking to completion produces a transparent coating (KE) are applied to a support sheet a dried but as yet not completely crosslinked coating (KT) is produced from the coating composition (K), the coated support sheet is shaped and is injection backmolded or foam-backed with a liquid polymeric material, and the coating (KT)—if this has not already taken place—is cured or aftercured; the crosslinkable coating composition (K) comprising a free-radically crosslinkable component (KK) which contains hydrogen bond forming structural elements in an amount such that 1. a coating (MT) produced from the mixture (M) of component (KK) with additives, but as yet not crosslinked to completion, has a ratio of storage modulus G(MT)′ to loss modulus G(MT)″ of from 5 to 200, G(MT)′ and G(MT)″ having been determined at 20° C. by means of rheological oscillation measurements, and 2. a coating (ME) produced from the mixture (M) of component (KK) with additives and crosslinked to completion has a storage modulus E(ME)″ of from 1.0*107.0 to 8.0*107.0 Pa, E(ME)′ having been measured in the rubber-elastic range by dynamic mechanical thermal analysis.
摘要:
A process is disclosed for producing moldings, in which a pigmented coating composition (P) and a free-radically crosslinkable coating composition (K), which after crosslinking to completion produces a transparent coating (KE) are applied to a support sheet, wherein a dried but as yet not completely crosslinked coating (KT) is produced from the coating composition (K), the coated support sheet is shaped and is injection backmolded or foam-backed, and the coating (KT) is cured or aftercured; the crosslinkable coating composition (K) comprising a free-radically crosslinkable component (KK) which contains hydrogen bond forming structural elements.
摘要:
The invention relates to a radiation-curable laminated sheet or film comprising at least one substrate layer and a top layer which comprises a radiation-curable material having a glass transition temperature below 50° C. and having a high double bond density and acid groups, processes for the production thereof and the use thereof.
摘要:
A pseudoplastic clearcoat slurry comprising solid and/or highly viscous particles which are dimensionally stable under storage and application conditions and which comprise as binders methacrylate copolymers containing in copolymerized form, based on a given methacrylate copolymer, at least 90% by weight of methacrylate comonomers, including (meth)acrylate comonomers having potentially ionic groups; process for preparing it, and its use.