Sealing pores of low-k dielectrics using CxHy
    2.
    发明授权
    Sealing pores of low-k dielectrics using CxHy 有权
    使用CxHy密封低k电介质的孔隙

    公开(公告)号:US07135402B2

    公开(公告)日:2006-11-14

    申请号:US11048518

    申请日:2005-02-01

    IPC分类号: H01L21/4763

    CPC分类号: H01L21/76831

    摘要: A semiconductor method of manufacturing involving porous and/or carbon containing, low-k dielectrics is provided. The method includes forming a hydrocarbon of the general composition CxHy on the surface of the low-k dielectric. The hydrocarbon layer includes depositing a precursor material, preferably C2H4 or (CH3)2CHC6H6CH3. In accordance with embodiments of this invention, carbon diffuses into the low-k dielectric, thereby reducing carbon depletion damage caused by plasma processing or etching. Surface dielectric pores damaged by plasma processing are also repaired by sealing them with the CxHy layer. Embodiments include semiconductor devices, such as devices having damascene interconnect structures, manufacturing using methods provided.

    摘要翻译: 提供了涉及含有多孔和/或碳的低k电介质的半导体制造方法。 该方法包括在低k电介质的表面上形成总体组成为C H 的烃。 烃层包括沉积前体材料,优选C 2 H 4 H 3或(CH 3 CH 3)2 CH 3, 6> 6 6 3。 根据本发明的实施例,碳扩散到低k电介质中,从而减少由等离子体处理或蚀刻引起的碳损耗损伤。 通过用等离子体处理损坏的表面电介质孔也通过用C x H H y层密封来修复。 实施例包括半导体器件,例如具有镶嵌互连结构的器件,使用提供的方法的制造。

    Sealing pores of low-k dielectrics using CxHy
    6.
    发明申请
    Sealing pores of low-k dielectrics using CxHy 有权
    使用CxHy密封低k电介质的孔隙

    公开(公告)号:US20060172531A1

    公开(公告)日:2006-08-03

    申请号:US11048518

    申请日:2005-02-01

    IPC分类号: H01L21/4763

    CPC分类号: H01L21/76831

    摘要: A semiconductor method of manufacturing involving porous and/or carbon containing, low-k dielectrics is provided. The method includes forming a hydrocarbon of the general composition CxHy on the surface of the low-k dielectric. The hydrocarbon layer includes depositing a precursor material, preferably C2H4 or (CH3)2CHC6H6CH3. In accordance with embodiments of this invention, carbon diffuses into the low-k dielectric, thereby reducing carbon depletion damage caused by plasma processing or etching. Surface dielectric pores damaged by plasma processing are also repaired by sealing them with the CXHY layer. Embodiments include semiconductor devices, such as devices having damascene interconnect structures, manufacturing using methods provided.

    摘要翻译: 提供了涉及含有多孔和/或碳的低k电介质的半导体制造方法。 该方法包括在低k电介质的表面上形成总体组成为C H 的烃。 烃层包括沉积前体材料,优选C 2 H 4 H 3或(CH 3 CH 3)2 CH 3, 6> 6 6 3。 根据本发明的实施例,碳扩散到低k电介质中,从而减少由等离子体处理或蚀刻引起的碳损耗损伤。 通过等离子体处理损坏的表面电介质孔也通过用C H 层密封来修复。 实施例包括半导体器件,例如具有镶嵌互连结构的器件,使用提供的方法的制造。

    CxHy sacrificial layer for cu/low-k interconnects
    7.
    发明申请
    CxHy sacrificial layer for cu/low-k interconnects 有权
    CxHy用于cu / low-k互连的牺牲层

    公开(公告)号:US20060172530A1

    公开(公告)日:2006-08-03

    申请号:US11048215

    申请日:2005-02-01

    IPC分类号: H01L21/461 H01L23/52

    摘要: A semiconductor method of manufacturing involving low-k dielectrics is provided. The method includes depositing a hydrocarbon of the general composition CxHy on the surface of a low-k dielectric. The hydrocarbon layer is deposited by reacting a precursor material, preferably C2H4 or (CH3)2CHC6H6CH3, using a PECVD process. In accordance with embodiments of this invention, carbon diffuses into the low-k dielectric, thereby reducing low-k dielectric damage caused by plasma processing or etching. Other embodiments comprise a semiconductor device having a low-k dielectric, wherein the low-k dielectric has carbon-adjusted dielectric region adjacent a trench sidewall and a bulk dielectric region. In preferred embodiments, the carbon-adjusted dielectric region has a carbon concentration not more than about 5% less than in the bulk dielectric region.

    摘要翻译: 提供涉及低k电介质的半导体制造方法。 该方法包括在低k电介质的表面上沉积一般组合物C x H y Y y的烃。 烃层通过使前体材料,优选C 2 H 4 H 3或(CH 3)3 H 2, CHC 6 6 H 3 CH 3,使用PECVD法。 根据本发明的实施例,碳扩散到低k电介质中,由此降低由等离子体处理或蚀刻引起的低k电介质损伤。 其他实施例包括具有低k电介质的半导体器件,其中低k电介质具有邻近沟槽侧壁和大块电介质区域的碳调节介电区域。 在优选的实施方案中,碳调节的电介质区域的碳浓度比体电介质区域的碳浓度小约不超过约5%。

    UV curing of low-k porous dielectrics
    8.
    发明申请
    UV curing of low-k porous dielectrics 有权
    低k多孔电介质的UV固化

    公开(公告)号:US20070161230A1

    公开(公告)日:2007-07-12

    申请号:US11328596

    申请日:2006-01-10

    IPC分类号: H01L21/4763 H01L21/469

    摘要: A method of manufacturing a semiconductor device having a low-k dielectric layer is provided. An embodiment comprises forming a dielectric layer on a substrate, wherein the layer comprises a pore generating material dispersed in an uncured matrix. A second step comprises forming pores in the uncured matrix by irradiating the layer with radiation having a first wavelength. After pore forming, a third step comprises cross-linking the dielectric by irradiating it at a second wavelength, the second being less than the first. In an embodiment, the irradiating wavelengths comprise ultra-violet radiation. Embodiments may further include repairing processing damage wherein the damage includes dangling bonds or silanol formation. The repairing includes annealing in a carbon-containing ambient such as C2H4, C3H6, or hexamethyldisilazane (HMDS).

    摘要翻译: 提供一种制造具有低k电介质层的半导体器件的方法。 一个实施方案包括在基底上形成介电层,其中该层包含分散在未固化的基质中的孔产生材料。 第二步骤包括通过用具有第一波长的辐射照射该层来在未固化的基质中形成孔。 在成孔之后,第三步骤包括通过以第二波长照射电介质来交联电介质,第二步小于第一波长。 在一个实施例中,照射波长包括紫外辐射。 实施方案可以进一步包括修复处理损伤,其中损伤包括悬挂键或硅烷醇形成。 修复包括在含碳环境中退火,例如C 2 H 4 H 3,C 3 H 6, 或六甲基二硅氮烷(HMDS)。

    Glue layer for adhesion improvement between conductive line and etch stop layer in an integrated circuit chip
    9.
    发明授权
    Glue layer for adhesion improvement between conductive line and etch stop layer in an integrated circuit chip 有权
    用于在集成电路芯片中的导电线和蚀刻停止层之间的粘附改善的胶层

    公开(公告)号:US07405481B2

    公开(公告)日:2008-07-29

    申请号:US11004065

    申请日:2004-12-03

    IPC分类号: H01L23/48 H01L23/52

    摘要: In an integrated circuit chip, a conductive line is formed in a first IMD layer. The conductive line is formed of a conductive line material that tends to form an oxide when exposed to an oxygen-containing substance. A glue layer is formed on the conductive line. The glue layer is formed of a non-oxygen-containing material capable of providing an oxygen barrier over the conductive line. The glue layer has a hardness greater than that of the conductive line. The glue layer preferably has a thickness between about 15 angstroms and about 75 angstroms. The etch stop layer is formed on the glue layer. The etch stop layer has a hardness greater than that of the glue layer. A second IMD layer is formed on the etch stop layer. The etch stop layer and/or the second IMD layer may be formed with a material comprising oxygen without oxidizing the conductive line.

    摘要翻译: 在集成电路芯片中,在第一IMD层中形成导线。 导电线由暴露于含氧物质时易于形成氧化物的导电线材料形成。 在导电线上形成胶层。 胶层由能够在导电线上提供氧阻隔的非含氧材料形成。 胶层的硬度大于导电线的硬度。 胶层优选地具有在约15埃至约75埃之间的厚度。 蚀刻停止层形成在胶层上。 蚀刻停止层的硬度大于胶层的硬度。 在蚀刻停止层上形成第二IMD层。 蚀刻停止层和/或第二IMD层可以由包含氧的材料形成而不氧化导电线。

    Glue layer for adhesion improvement between conductive line and etch stop layer in an integrated circuit chip
    10.
    发明申请
    Glue layer for adhesion improvement between conductive line and etch stop layer in an integrated circuit chip 有权
    用于在集成电路芯片中的导电线和蚀刻停止层之间的粘附改善的胶层

    公开(公告)号:US20060118921A1

    公开(公告)日:2006-06-08

    申请号:US11004065

    申请日:2004-12-03

    IPC分类号: H01L23/58

    摘要: In an integrated circuit chip, a conductive line is formed in a first IMD layer. The conductive line is formed of a conductive line material that tends to form an oxide when exposed to an oxygen-containing substance. A glue layer is formed on the conductive line. The glue layer is formed of a non-oxygen-containing material capable of providing an oxygen barrier over the conductive line. The glue layer has a hardness greater than that of the conductive line. The glue layer preferably has a thickness between about 15 angstroms and about 75 angstroms. The etch stop layer is formed on the glue layer. The etch stop layer has a hardness greater than that of the glue layer. A second IMD layer is formed on the etch stop layer. The etch stop layer and/or the second IMD layer may be formed with a material comprising oxygen without oxidizing the conductive line.

    摘要翻译: 在集成电路芯片中,在第一IMD层中形成导线。 导电线由暴露于含氧物质时易于形成氧化物的导电线材料形成。 在导电线上形成胶层。 胶层由能够在导电线上提供氧阻隔的非含氧材料形成。 胶层的硬度大于导电线的硬度。 胶层优选地具有在约15埃至约75埃之间的厚度。 蚀刻停止层形成在胶层上。 蚀刻停止层的硬度大于胶层的硬度。 在蚀刻停止层上形成第二IMD层。 蚀刻停止层和/或第二IMD层可以由包含氧的材料形成而不氧化导电线。