公开(公告)号：US20140163193A1

公开(公告)日：2014-06-12

申请号：US14234375

申请日：2011-09-23

申请人： Mingjie Zhou ,  Ping Wang ,  Zhenhua Zhang ,  Jixing Chen

发明人： Mingjie Zhou ,  Ping Wang ,  Zhenhua Zhang ,  Jixing Chen

IPC分类号： C08G61/12 ,  H01L51/00

CPC分类号： C08G61/126 ,  B82Y10/00 ,  C08G61/123 ,  C08G2261/1412 ,  C08G2261/1424 ,  C08G2261/3221 ,  C08G2261/3223 ,  C08G2261/3241 ,  C08G2261/3243 ,  C08G2261/414 ,  C08G2261/91 ,  C09B69/109 ,  H01L51/0036 ,  H01L51/0047 ,  H01L51/4253 ,  Y02E10/549

摘要： Disclosed are a difluoro benzotriazolyl solar cell polymeric material and preparation method and use thereof; the copolymer has a structure as represented by formula (I), wherein both R1 and R2 are alkyls from C1 to C20, and n is an integer from 10 to 100. In the difluoro benzotriazolyl solar cell polymeric material of the present invention, because the 1,2,3-benzotriazole copolymer contains two fluorine atoms, the HOMO energy level will be reduced by 0.11 eV while the fluorine-substituted 1,2,3-benzotriazole has two imido groups with strong electron-withdrawing property; the fluorine-substituted 1,2,3-benzotriazole is a heterocyclic compound with strong electron-withdrawing property, and an alkyl chain can be easily introduced to the N-position of the N—H bond of the benzotriazole; the functional group of the alkyl chain can improve solar energy conversion efficiency, thus solving the low efficiency problem of polymer solar cells.

摘要翻译： 公开了二氟苯并三唑基太阳能电池聚合材料及其制备方法和用途; 共聚物具有由式（I）表示的结构，其中R1和R2均为C1至C20的烷基，n为10至100的整数。在本发明的二氟苯并三唑基太阳能电池聚合物材料中，因为 1,2,3-苯并三唑共聚物含有两个氟原子，HOMO能级将降低0.11eV，而氟取代的1,2,3-苯并三唑具有强吸电性的两个亚氨基; 氟取代的1,2,3-苯并三唑是具有强吸电性的杂环化合物，烷基链可以容易地引入到苯并三唑的N-H键的N位上; 烷基链的官能团可以提高太阳能转换效率，从而解决聚合物太阳能电池的低效问题。

公开(公告)号：US09270084B2

公开(公告)日：2016-02-23

申请号：US14130228

申请日：2011-06-28

申请人： Mingjie Zhou ,  Ping Wang ,  Jixing Chen ,  Hui Huang

发明人： Mingjie Zhou ,  Ping Wang ,  Jixing Chen ,  Hui Huang

IPC分类号： C09K11/77 ,  C23C14/34 ,  H01J37/34 ,  H01S5/30 ,  C23C14/08 ,  C23C14/35 ,  H05B33/14

CPC分类号： H01S5/3018 ,  C09K11/7718 ,  C09K11/7768 ,  C23C14/081 ,  C23C14/35 ,  H05B33/14

摘要： Cerium doped magnesium barium tungstate luminescent thin film, manufacturing method and application thereof are provided, said method for manufacturing cerium doped magnesium barium tungstate luminescent thin film comprises the following steps: mixing MgO, BaO, WO3 and Ce2O3, sintering for forming sputtering target, forming the precursor of cerium doped magnesium barium tungstate luminescent thin film by magnetron sputtering, annealing the precursor of cerium doped magnesium barium tungstate luminescent thin film, and then forming cerium doped magnesium barium tungstate luminescent thin film. Said cerium doped magnesium barium tungstate luminescent thin film exhibits high luminescence efficiency and high light emitting peaks in red and blue regions. Said method presents the advantages of simplified operation, less cost, and suitable for industrial preparation.

摘要翻译： 提供铈掺杂的钡钡钨酸盐发光薄膜，其制造方法和应用，所述制造铈掺杂的钡钡钨酸盐发光薄膜的方法包括以下步骤：将MgO，BaO，WO 3和Ce 2 O 3混合，烧结以形成溅射靶，形成 通过磁控溅射法铈铈掺杂镁钡钨酸盐发光薄膜的前体，对铈掺杂的钡钡钨酸盐发光薄膜进行退火，然后形成铈掺杂的钡钡钨酸盐发光薄膜。 所述铈掺杂的钡钡钨酸盐发光薄膜在红色和蓝色区域表现出高发光效率和高发光峰。 所述方法具有操作简单，成本低，适用于工业制备的优点。

公开(公告)号：US20150255745A1

公开(公告)日：2015-09-10

申请号：US14431972

申请日：2012-09-28

申请人： Mingjie Zhou ,  Ping Wang ,  Hui Huang ,  Jixing Chen

发明人： Mingjie Zhou ,  Ping Wang ,  Hui Huang ,  Jixing Chen

IPC分类号： H01L51/52 ,  H01L51/56

CPC分类号： H01L51/5221 ,  H01L51/0021 ,  H01L51/0078 ,  H01L51/0091 ,  H01L51/0092 ,  H01L51/5092 ,  H01L51/5231 ,  H01L51/5234 ,  H01L51/56 ,  H01L2251/305 ,  H01L2251/5315 ,  H01L2251/5353 ,  H01L2251/5369

摘要： Disclosed are an organic electroluminescent device and a preparation method thereof. The organic electroluminescent device is a top-emitting organic electroluminescent device having a reversed structure, and the preparation method is: dissolving zinc oxide with acetic acid to obtain a zinc oxide solution with a concentration of 0.3 g/ml-0.6 g/ml, adding a phthalocyanine substance in a mass of 1%-10% of the mass of the zinc oxide to obtain a mixture, spin-coating the mixture on a glass substrate (1) and then drying to obtain a cathode (2), and then preparing by vapor deposition, an electron injection layer (3), an electron transport layer (4), a luminescent layer (5), a hole transport layer (6), a hole injection layer (7) and an anode (8), successively, so as to obtain the organic electroluminescent device.

摘要翻译： 公开了一种有机电致发光器件及其制备方法。 有机电致发光器件是具有相反结构的顶发光有机电致发光器件，其制备方法是：用乙酸溶解氧化锌，得到浓度为0.3g / ml-0.6g / ml的氧化锌溶液，加入 得到质量为氧化锌质量的1％-10％的酞菁物质以获得混合物，将该混合物旋涂在玻璃基板（1）上，然后干燥以获得阴极（2），然后制备 通过气相沉积，电子注入层（3），电子传输层（4），发光层（5），空穴传输层（6），空穴注入层（7）和阳极（8） ，以获得有机电致发光器件。

公开(公告)号：US20130248780A1

公开(公告)日：2013-09-26

申请号：US13992190

申请日：2010-12-24

申请人： Mingjie Zhou ,  Ping Wang ,  Jixing Chen ,  Xiaoming Feng

发明人： Mingjie Zhou ,  Ping Wang ,  Jixing Chen ,  Xiaoming Feng

IPC分类号： C09D5/24 ,  C23C14/35

CPC分类号： C09D5/24 ,  C03C3/06 ,  C03C17/245 ,  C03C2217/23 ,  C03C2218/156 ,  C04B35/453 ,  C04B2235/3206 ,  C04B2235/3217 ,  C04B2235/3284 ,  C04B2235/3418 ,  C04B2235/658 ,  C23C14/35 ,  H01L31/022483 ,  H01L31/1884 ,  Y02E10/50

摘要： An electrically conductive film is provided, which comprises a film formed of zinc oxide adulterated with alumina, silicon dioxide and magnesia. The transparence of the zinc oxide film is increased by means of magnesium ion in the adulterated magnesia widening the transparent window of the zinc oxide film, the conductivity is increased and thus the resistivity is reduced by means of adulterating with alumina and silicon dioxide, and the resistivity during working is stabilized by means of adulterating with alumina, silicon dioxide and magnesia. A method for manufacturing the electrically conductive film and an application therefor are also provided. The method has simple process, mild conditions, low cost and high productivity, which is suit for industrialized produce.

摘要翻译： 提供导电膜，其包括由氧化铝，二氧化硅和氧化镁掺杂的氧化锌形成的膜。 氧化锌膜的透明度通过掺杂氧化镁中的镁离子增加，使氧化锌膜的透明窗口变宽，导电性增加，因此通过掺杂氧化铝和二氧化硅的电阻率降低， 通过掺杂氧化铝，二氧化硅和氧化镁来稳定工作期间的电阻率。 还提供了一种用于制造导电膜的方法及其应用。 该方法工艺简单，条件温和，成本低，生产效率高，适用于工业化生产。

公开(公告)号：US20130167922A1

公开(公告)日：2013-07-04

申请号：US13821502

申请日：2010-09-27

申请人： Mingjie Zhou ,  Ping Wang ,  Hui Huang ,  Jixing Chen

发明人： Mingjie Zhou ,  Ping Wang ,  Hui Huang ,  Jixing Chen

IPC分类号： H01G9/20 ,  H01G9/00

CPC分类号： H01G9/2022 ,  H01G9/0029 ,  Y02E10/542

摘要： A conducting polymer-carbon material combined counter electrode for dye-sensitized solar cell comprises a conducting substrate (3), and a carbon material (1) and a conducting polymer (2) coated on the conducting substrate (3). A method for manufacturing the conducting polymer-carbon material combined counter electrode comprises steps: mixing the carbon material (1) with the conducting polymer (2) into a uniform suspension, cleaning and surface processing the conducting substrate (3), coating the suspension on the conducting substrate (3) and drying, to obtain the combined counter electrode.

摘要翻译： 用于染料敏化太阳能电池的导电聚合物 - 碳材料组合对电极包括导电衬底（3）和涂覆在导电衬底（3）上的碳材料（1）和导电聚合物（2）。 导电聚合物 - 碳材料组合对电极的制造方法包括以下步骤：将碳材料（1）与导电聚合物（2）混合成均匀的悬浮液，清洁并表面处理导电基材（3），将悬浮液涂覆在 导电基板（3）并干燥，以获得组合的对电极。

公开(公告)号：US09570700B2

公开(公告)日：2017-02-14

申请号：US14431972

申请日：2012-09-28

申请人： Mingjie Zhou ,  Ping Wang ,  Hui Huang ,  Jixing Chen

发明人： Mingjie Zhou ,  Ping Wang ,  Hui Huang ,  Jixing Chen

IPC分类号： H01L51/52 ,  H01L51/50 ,  H01L51/56 ,  H01L51/00

CPC分类号： H01L51/5221 ,  H01L51/0021 ,  H01L51/0078 ,  H01L51/0091 ,  H01L51/0092 ,  H01L51/5092 ,  H01L51/5231 ,  H01L51/5234 ,  H01L51/56 ,  H01L2251/305 ,  H01L2251/5315 ,  H01L2251/5353 ,  H01L2251/5369

摘要： Disclosed are an organic electroluminescent device and a preparation method thereof. The organic electroluminescent device is a top-emitting organic electroluminescent device having a reversed structure, and the preparation method is: dissolving zinc oxide with acetic acid to obtain a zinc oxide solution with a concentration of 0.3 g/ml-0.6 g/ml, adding a phthalocyanine substance in a mass of 1%-10% of the mass of the zinc oxide to obtain a mixture, spin-coating the mixture on a glass substrate (1) and then drying to obtain a cathode (2), and then preparing by vapor deposition, an electron injection layer (3), an electron transport layer (4), a luminescent layer (5), a hole transport layer (6), a hole injection layer (7) and an anode (8), successively, so as to obtain the organic electroluminescent device.

摘要翻译： 公开了一种有机电致发光器件及其制备方法。 有机电致发光器件是具有相反结构的顶发光有机电致发光器件，其制备方法是：用乙酸溶解氧化锌，得到浓度为0.3g / ml-0.6g / ml的氧化锌溶液，加入 得到质量为氧化锌质量的1％-10％的酞菁物质以获得混合物，将该混合物旋涂在玻璃基板（1）上，然后干燥以获得阴极（2），然后制备 通过气相沉积，电子注入层（3），电子传输层（4），发光层（5），空穴传输层（6），空穴注入层（7）和阳极（8） ，以获得有机电致发光器件。

公开(公告)号：US20140332796A1

公开(公告)日：2014-11-13

申请号：US14372214

申请日：2012-03-31

申请人： Mingjie Zhou ,  Ping Wang ,  Xiaoming Feng ,  Jixing Chen

发明人： Mingjie Zhou ,  Ping Wang ,  Xiaoming Feng ,  Jixing Chen

IPC分类号： H01L51/50 ,  H01L51/00

CPC分类号： H01L51/5024 ,  B82Y10/00 ,  H01L51/0001 ,  H01L51/0021 ,  H01L51/0045 ,  H01L51/5215 ,  H01L51/5275 ,  H01L2251/56

摘要： An organic electroluminescence device (100, 200) comprises a substrate (110), an anode (130), a light emitting layer (160) and a cathode (190) stacked sequentially. The anode (130) comprises a light transmittance increased layer (131), a conductive layer (132) and a hole injection auxiliary layer (133) stacked on the substrate (110) sequentially. The materials of the light transmittance increased layer (131) are inorganic compounds of zinc with a light transmittance of 400 nm to 800 nm in the visible region and a refractive index greater than 2.3. The material of the conductive layer (132) is graphene. The utilization of light transmittance increased principle for multilayer anode structure can make the light transmittance of the anode in the visible region high and surface resistance low. The utilization of inorganic material with hole injection ability can reduce the hole injection barrier, make the luminous performance of the organic electroluminescence device (100, 200) stable and luminous efficiency high. A method for manufacturing the organic electroluminescence device (100, 200) is also provided. The anode is prepared by vacuum evaporation and pulling method, which is convenient to operate and is suitable for large scale production.

摘要翻译： 有机电致发光器件（100,200）包括依次堆叠的衬底（110），阳极（130），发光层（160）和阴极（190）。 阳极（130）依次包括层叠在基板（110）上的透光率增加层（131），导电层（132）和空穴注入辅助层（133）。 透光率增加层（131）的材料是可见光区的透光率为400nm〜800nm，折射率大于2.3的锌的无机化合物。 导电层（132）的材料是石墨烯。 利用透光率增加原理，多层阳极结构可使阳极在可见光区域的透光率高，表面电阻较低。 利用具有空穴注入能力的无机材料可以减少空穴注入势垒，使有机电致发光器件（100,200）的发光性能稳定，发光效率高。 还提供了一种用于制造有机电致发光器件（100,200）的方法。 阳极采用真空蒸发拉拔法制备，操作方便，适合大规模生产。

公开(公告)号：US20130334688A1

公开(公告)日：2013-12-19

申请号：US14002589

申请日：2011-03-25

申请人： Mingjie Zhou ,  Ping Wang ,  Jixing Chen ,  Hui Huang

发明人： Mingjie Zhou ,  Ping Wang ,  Jixing Chen ,  Hui Huang

IPC分类号： H01B1/08 ,  H01L21/02 ,  H01L23/48

CPC分类号： H01B1/08 ,  C04B35/453 ,  C04B2235/3217 ,  C04B2235/3286 ,  C04B2235/3418 ,  C23C14/0057 ,  C23C14/086 ,  C23C14/3414 ,  C23C14/35 ,  H01L21/02697 ,  H01L23/48 ,  H01L2924/0002 ,  H01L2924/00

摘要： The invention relates to the semiconductor material manufacturing technical field. A multi-elements-doped zinc oxide film as well as manufacturing method and application in photo-electric devices thereof are provided. The manufacturing method comprises the following steps: (1) mixing the powder of Ga2O3, Al2O3, SiO2 and ZnO according to the following percentage by mass: 0.5%˜10% of Ga2O3, 0.5%˜5% of Al2O3, 0.5%˜1.5% of SiO2, and the residue of ZnO; (2) sintering the powder mixture as target material; (3) putting the target material into a magnetic sputtering chamber, evacuating, setting-up work pressure of 0.2 Pa-5 Pa, introducing mixed gas of inert gas and hydrogen with a flow rate of 15 sccm˜25 sccm, adopting a sputtering power of 40 W˜200 W, and sputtering on the substrate to obtain the multi-elements-doped zinc oxide film.

摘要翻译： 本发明涉及半导体材料制造技术领域。 提供多元素掺杂的氧化锌膜以及其光电装置中的制造方法和应用。 制造方法包括以下步骤：（1）按照以下的质量百分比混合Ga2O3，Al2O3，SiO2和ZnO的粉末：Ga2O3的0.5％〜10％，Al2O3的0.5％〜5％，Al2O3的0.5％〜1.5 ％的SiO 2，和ZnO的残留物; （2）将粉末混合物烧结成目标材料; （3）将目标材料放入磁性溅射室，抽真空，设定工作压力为0.2Pa-5Pa，引入惰性气体和氢气的混合气体，流速为15sccm〜25sccm，采用溅射功率 为40W〜200W，在基板上溅射，得到多元素掺杂的氧化锌膜。

公开(公告)号：US20130306951A1

公开(公告)日：2013-11-21

申请号：US13981416

申请日：2011-03-22

申请人： Mingjie Zhou ,  Ping Wang ,  Hui Huang ,  Jixing Chen

发明人： Mingjie Zhou ,  Ping Wang ,  Hui Huang ,  Jixing Chen

IPC分类号： H01L51/52

CPC分类号： H01L51/5218 ,  H01L51/5215 ,  H01L51/5275 ,  Y10T428/24942

摘要： An organic electroluminescent device and a conductive substrate thereof are provided. Said conductive substrate includes a glass substrate, an indium tin oxide (ITO) layer and a metal oxide layer located between said glass substrate and said ITO layer. The refractive index of said metal oxide layer ranges between that of said glass substrate and said ITO layer. Due to the metal oxide layer, the refractive index of which ranges between that of the glass substrate and the ITO layer, is inserted into said conductive substrate, when the light extracts between the ITO/metal oxide layer and the metal oxide layer/glass, the critical angle of total reflection increases compared with that without the inserted metal oxide layer. Most part of light extracts out of the interface after refraction, and only small part of light is totally reflected, thus the light extraction enhances.

摘要翻译： 提供有机电致发光器件及其导电衬底。 所述导电衬底包括玻璃衬底，氧化铟锡（ITO）层和位于所述玻璃衬底和所述ITO层之间的金属氧化物层。 所述金属氧化物层的折射率在所述玻璃基板和所述ITO层的折射率之间。 由于在ITO /金属氧化物层和金属氧化物层/玻璃之间的光提取时，由于金属氧化物层的折射率在玻璃基板和ITO层的折射率之间插入到所述导电基板中， 与没有插入的金属氧化物层的临界角相比，全反射的临界角增加。 大部分光线在折射后从界面中提取出来，只有一小部分光被全部反射，从而提高了光的提取。

公开(公告)号：US20150263285A1

公开(公告)日：2015-09-17

申请号：US14431993

申请日：2012-09-28

申请人： Mingjie ZHOU ,  Ping WANG ,  Hui HUANG ,  Jixing CHEN

发明人： Mingjie Zhou ,  Ping Wang ,  Hui Huang ,  Jixing Chen

IPC分类号： H01L51/00

CPC分类号： H01L51/0007 ,  H01L51/0035 ,  H01L51/0037 ,  H01L51/4273 ,  H01L51/441 ,  H01L51/442 ,  H01L2251/305 ,  Y02E10/549 ,  Y02P70/521

摘要： Disclosed are a polymer solar cell and a preparation method thereof. The preparation method comprises: successively preparing on a clean glass substrate (1), a cathode (2), an electronic buffer layer (3) and an active layer (4) by the steps of dissolving poly(3,4-ethylenedioxythiophene) and polymerized p-styrene sulphonic acid, dissolving zinc oxide into acetic acid to obtain a zinc oxide solution, mixing the zinc oxide solution with the solution of poly(3,4-ethylenedioxythiophene) and polymerized p-styrene sulphonic acid to obtain a mixed solution, spin-coating the mixed solution on the active layer (4) and then by drying to obtain the anode (5), and finally obtain the polymer solar cell.

摘要翻译： 公开了一种聚合物太阳能电池及其制备方法。 该制备方法包括：通过以下步骤，在干净的玻璃基板（1），阴极（2），电子缓冲层（3）和活性层（4）上依次制备聚（3,4-亚乙基二氧噻吩）和 聚合的对苯乙烯磺酸，将氧化锌溶解在乙酸中以得到氧化锌溶液，将氧化锌溶液与聚（3,4-亚乙基二氧噻吩）和聚合的对苯乙烯磺酸的溶液混合，得到混合溶液， 将混合溶液旋涂在活性层（4）上，然后通过干燥得到阳极（5），最后得到聚合物太阳能电池。