摘要:
The invention provides a novel photocurable organopolysiloxane composition having an unusually high photosensitivity suitable, for example, for providing an anti-sticking layer on a release paper. The composition comprises an organopolysiloxane having, in a molecule, at least one thioacyloxy-containing organosiloxane unit as the photosensitive functional group and a photosensitizer. Further improved photocurable composition of the invention comprises an organopolysiloxane having, in addition to the above mentioned thioacyloxy-containing organosiloxane units, at least one mercaptohydrocarbyl-containing organosiloxane unit in a molecule. Alternatively, photosensitivity of the similar degree is obtained when the composition comprises a first organopolysiloxane having, in a molecule, at least one thioacyloxy-containing organosiloxane unit and a second organopolysiloxane having, in a molecule, at least one mercaptohydrocarbyl-containing organosiloxane unit as combined.
摘要:
A novel photocurable composition suitable for preparing, for example, release papers is proposed which is formulated with photocrosslinkable organopolysiloxanes necessitating no conventional photosensitizers. Thus, the composition comprises(a) an organopolysiloxane having at least two mercaptoalkyl, e.g. mercaptopropyl, groups bonded to the silicon atoms in a molecule,(b) an organopolysiloxane having at least two alkenyl, e.g. vinyl groups directly bonded to the silicon atoms in a molecule, and(c) an organopolysiloxane having at least one benzoin group ##STR1## where Ph is a phenyl group, bonded to the silicon atom in a molecule, which component (c) serves as a photosensitizing ingredient. Alternatively, the inventive composition comprises (a) a mercaptoalkyl-containing organopolysiloxane as above and (b') an organopolysiloxane having, simultaneously, at least two alkenyl groups and at least one benzoin group directly bonded to the silicon atoms in a molecule, which component (b') serves both as the crosslinking agent and as the photosensitizing ingredient simultaneously. Owing to the unquestionable affinity of the photosensitizing ingredient with the other components, the inventive compositions have very high sensitivity in photocuring along with several other advantageous characteristics.
摘要:
The invention provides a novel class of organopolysiloxane compounds having at least one benzoin group represented by the general formula ##STR1## in which Ph is a phenyl group and R is a hydrogen atom or an alkyl group, bonded to the silicon atom in a molecule. The benzoin-bonded organopolysiloxane compounds can readily be prepared by the dehydrohalogenation, dehydrogenation, dehydration or dealkoholation condensation reaction between a corresponding organopolysiloxane having silicon-bonded halogen atoms, hydrogen atoms, hydroxy groups or alkoxy groups and an .alpha.-substituted or unsubstituted benzoin compound in the presence of a suitable reaction promotor or a condensation catalyst.
摘要:
The invention provides a benzoin group-containing cyclic organopolysiloxane, which belongs to a novel class of organosilicon compounds hitherto not known or not described in any prior art literatures. The compound has at least one benzoin group of the formula ##STR1## in which Ph is a phenyl group and R.sup.1 is a hydrogen atom or an alkyl group having from 1 to 4 carbon atoms or, in particular, a methyl group, directly bonded to the silicon atom in the cyclic tri-, tetra-, penta- or hexasiloxane. The compound is useful as a sensitizer for the crosslinking reaction of a photo- or radiation-curable organopolysiloxane composition owing to the high miscibility of the inventive compounds with the organopolysiloxane composition.
摘要:
A novel scuff-masking composition for glass vessels comprises a specific organopolysiloxane, a curing catalyst therefor, and a surfactant and is highly effective in a method of masking scuffs on glass vessels, which comprises providing the composition on the scuffs and curing the coated composition.
摘要:
The invention provides a novel class of organosilane compound represented by the general formulaX--CF.sub.2 --CF.sub.2).sub.n CH.sub.2 --CH.sub.2 --Si(OCOR.sup.2).sub.m (R.sup.1).sub.3-m'in which R.sup.1 is a monovalent hydrocarbon group having from 1 to 6 carbon atoms, R.sup.2 is a monovalent hydrocarbon group having from 7 to 21 carbon atoms, X is a hydrogen atom or a fluorine atom, n is a positive integer not exceeding 4 and m is a positive integer not exceeding 3. The fluoroalkyl-containing acyloxy silanes are useful as an additive ingredient in a synthetic resin composition for shaping articles or a coating composition with a synthetic resin as the vehicle when improved lubricity is desired on the surface of the shaped article or on the coated surface.
摘要:
A scuff-masking composition for glass vessels comprises a specific organopolysiloxane and a curing catalyst therefor, and is highly effective in a method of masking scuffs on glass vessels, which comprises providing the composition on the scuffs and curing the coated composition.
摘要:
The invention provides a novel method for the preparation of a printing plate suitable for dry planographic printing without supply of dampening water utilizing the ink-repellency of a cured silicone resin. In the inventive method, a base plate provided with two successive layers of a first adhesive agent and a photocurable organopolysiloxane composition is overlaid with a UV-transparent covering sheet provided with a layer of a second adhesive agent in such a manner that the layers of the organopolysiloxane composition and the second adhesive agent are in direct contact with each other and irradiated with UV light pattern-wise through the sheet. The adhesive bonding strength between the second adhesive agent and the organopolysiloxane composition exhibited by the exposure to light is larger than between the first adhesive agent and the organopolysiloxane composition so that peeling of the covering sheet off the base plate leaves the layer of the organopolysiloxane composition pattern-wise in the unirradiated areas, which is subsequently photocured by the second exposure to light to give image-wise ink-repellent areas formed of the cured organopolysiloxane composition bonded to the base plate useful as a planographic printing plate of high durability.
摘要:
The coating composition is prepared by partial co-hydrolysis and co-condensation of a mixture comprising an organotrialkoxysilane or its combination with a tetraalkoxysilane, a fluoroalkylalkoxysilane and a hydroxy-endblocked diorganopolysiloxane in the presence of an acid catalyst. The organopolysiloxanes thus prepared are suitable for coating plastic surfaces to produce a coating on the surfaces, the cured coating film having hardness as well as flexibility sufficient to ensure a very strong resistance to swelling, dissolution or corrosion by attacks of solvents and chemicals.
摘要:
The magnetic recording medium contains the magnetic layer comprising the magnetic or magnetizable powders or particles and the binder comprising a composition containing(A) a compound represented by formula (V): ##STR1## (wherein R is methyl or ethyl group and X is a group containing an acrylic or methacrylic double bond; i is a number in the range of approximately 200 to 800, j is a number in the range of approximately 10 to 200, k is a number in the range up to approximately 200, and l is a number in the range of approximately 3 to 100, provided that the division of l by the sum of k and l is in the range from approximately 0.2 to 1.0)and(B) a compound having at least two acrylic and/or methacrylic double bonds in the molecule thereof and having a molecular weight ranging from approximately 1,000 to 6,000 in which the molecular weight in the molecule per one double bond is in the range from approximately 80 to 3,000.The composition is cured by the irradiation of radiation so that the magnetic recording medium has an improved durability as well as physical strengths in the magnetic layer thereon.