Tunable, rapid uptake, aminopolymer aerogel sorbent for direct air capture of CO2

    公开(公告)号:US11612852B2

    公开(公告)日:2023-03-28

    申请号:US17211588

    申请日:2021-03-24

    Abstract: A porous polymer aerogel, wherein the aerogel has greater than 5 wt % of amine containing vinyl monomers integrated into a polymer backbone. A method of fabrication of a porous polymer aerogel amine material, includes preparing a solution comprising at least a solvent, amine monomers having protected amino groups, one or more crosslinkers, one or more radical initiators, and a nitroxide mediator, removing oxygen from the solution, heating the solution to promote polymerization and to produce a polymerized material, performing solvent exchange with the polymerized material, causing a deprotection reaction in the polymerized material to remove groups protecting the amino groups, soaking and rinsing the material to remove excess reagents and any byproducts of the deprotection reaction, and drying the material to produce the amine sorbent. A system to separate CO2 from other gases, comprising a polymer porous aerogel sorbent having greater than 5 wt % of amine containing vinyl monomers integrated into a polymer backbone.

    Method for joining dissimilar materials

    公开(公告)号:US10947419B2

    公开(公告)日:2021-03-16

    申请号:US16042679

    申请日:2018-07-23

    Abstract: A composition of matter includes a first compatible material having particles containing chemical elements similar to a first substrate, and second compatible material having particles containing chemical elements similar to a second substrate, wherein the first substrate and the second substrate are chemically different. The particles are dispersed into a matrix that is in between the first and the second substrate. A deposition system has a multi-material printhead, a first reservoir of a first compatible material having particles containing chemical elements similar to a first substrate, a second reservoir of a second compatible material having particles containing chemical elements similar to a second substrate, a third reservoir of an polymer precursor material, and at least one mixer. A method of bonding a joint between dissimilar substrate materials includes functionalizing a first compatible material having chemical elements similar to a first substrate, mixing the first compatible material with a polymer precursor material, functionalizing a second compatible material having chemical elements similar to a second substrate, mixing the second compatible material with a polymer precursor material, and using the deposition system to deposit the first and second compatible materials and a polymer precursor material on the joint between the first and second substrate materials.

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