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27 条记录 (耗时 0.04 秒)

    Method of transformation of bridging organic groups in organosilica materials
    5.
    发明申请
    Method of transformation of bridging organic groups in organosilica materials 审中-公开
    有机硅材料中桥连有机基团的转化方法

    公开(公告)号：US20090130412A1

    公开(公告)日：2009-05-21

    申请号：US11921325

    申请日：2005-09-22

    申请人： Benjamin David Hatton ,  Geoffrey Alan Ozin ,  Doug Dragan Perovic ,  Kai Manfred Martin Landskron

    发明人： Benjamin David Hatton ,  Geoffrey Alan Ozin ,  Doug Dragan Perovic ,  Kai Manfred Martin Landskron

    IPC分类号： B32B15/02 ,  H01B1/12 ,  H01B1/02 ,  B32B19/00

    CPC分类号： B01J29/0308

    摘要： This invention relates to a chemical transformation of the bridging organic groups in metal oxide materials containing bridging organic groups, such as bridged organosilicas, wherein such a transformation greatly benefits properties for low dielectric constant (k) applications. A thermal treatment at specific temperatures is shown to cause a transformation of the organic groups from a bridging to a terminal configuration, which consumes polar hydroxyl groups. The transformation causes k to decrease, and the hydrophobicity to increase (through ‘self-hydrophobization’). As a result of the bridge-terminal transformation, porous organosilica films are shown to have k 6 GPa, do not require additional chemical surface treatment for dehydroxylation (hydrophobicity).

    摘要翻译： 本发明涉及桥接有机基团在含有桥连有机基团的金属氧化物材料中的化学转化，其中这种转变大大有利于低介电常数（k）应用的性能。 显示在特定温度下的热处理会引起有机基团从桥连转变为端基构型，其消耗极性羟基。 转化导致k降低，疏水性增加（通过“自我疏水化”）。 由于桥端转化，多孔有机硅膜显示为k <2.0，E> 6 GPa，不需要额外的化学表面处理脱羟基（疏水性）。

    Method of self-assembly and optical applications of crystalline colloidal patterns on substrates
    6.
    发明授权
    Method of self-assembly and optical applications of crystalline colloidal patterns on substrates 失效
    结晶胶体图案在基底上的自组装和光学应用的方法

    公开(公告)号：US07247349B2

    公开(公告)日：2007-07-24

    申请号：US10660588

    申请日：2003-09-12

    申请人： Geoffrey Alan Ozin ,  San Ming Yang ,  Hernan Miguez

    发明人： Geoffrey Alan Ozin ,  San Ming Yang ,  Hernan Miguez

    IPC分类号： B05D1/18 ,  B05D1/28 ,  B05D1/36

    CPC分类号： B32B9/00 ,  B05D1/283 ,  B32B3/30 ,  B82Y15/00 ,  B82Y20/00 ,  B82Y30/00 ,  B82Y40/00 ,  G02B6/1225 ,  G02B6/13 ,  Y10S977/779 ,  Y10S977/883 ,  Y10T428/24355 ,  Y10T428/24372 ,  Y10T428/24479 ,  Y10T428/2457 ,  Y10T428/24579 ,  Y10T428/2462

    摘要： This invention describes methods of synthesis and applications of planarized photonic crystals. Provided are simple, quick, reproducible and inexpensive methods that combine self-assembly and lithography to achieve the first examples of vectorial control of thickness, structure, area, topology, orientation and registry of colloidal crystals that have been patterned in substrates for use in lab-on-chip and photonic chip technologies. 1-, 2 and 3-D colloidal crystals patterned either on or within substrates can be used for templating inverted colloidal crystal replica patterns made of materials like silicon as well as building micron scale structural defects in such colloidal crystals. These photonic crystals can form the basis of a range of optical devices that may be integrated within photonic chips and coupled to optical fibers and/or waveguides to enable development of highly compact planarized optically integrated photonic crystal devices and circuits for use in future all-optical computers and optical telecommunication systems.

    摘要翻译： 本发明描述了平面化光子晶体的合成和应用方法。 提供了简单，快速，可再现和便宜的方法，其组合自组装和光刻以实现已经在用于实验室的基板中图案化的胶体晶体的厚度，结构，面积，拓扑，取向和注册表的矢量控制的第一示例 芯片和光子芯片技术。 图案化在衬底上或衬底内的1，2和3-D胶体晶体可用于模板化由硅材料制成的反胶体晶体复制图案以及在这种胶体晶体中构建微米级结构缺陷。 这些光子晶体可以形成一系列光学器件的基础，光学器件可以集成在光子芯片中并且耦合到光纤和/或波导，以便能够开发用于将来全光学的高度紧凑的平面化的光学集成光子晶体器件和电路 计算机和光通信系统。

    Compressible photonic crystal
    7.
    发明授权
    Compressible photonic crystal 有权
    可压缩光子晶体

    公开(公告)号：US08676016B2

    公开(公告)日：2014-03-18

    申请号：US12527382

    申请日：2007-02-16

    申请人： Andre Arsenault ,  Geoffrey Alan Ozin ,  Georg von Freymann

    发明人： Andre Arsenault ,  Geoffrey Alan Ozin ,  Georg von Freymann

    IPC分类号： G02B6/10

    CPC分类号： G02B6/1225 ,  B82Y20/00 ,  C08J5/18

    摘要： A compressible photonic crystal comprising a polymer with an ordered array of voids, the photonic crystal having a reflectance in a first wavelength range for light incident to its incident surface and its opposing incident surface; wherein compression against at least a portion of at least one of the surfaces shifts the reflectance to a second wavelength range in at least that portion of that surface. The crystal may be used in authentication devices of various types.

    摘要翻译： 一种可压缩光子晶体，其包含具有有序空间阵列的聚合物，所述光子晶体对于入射到其入射表面的光和其相对的入射表面具有在第一波长范围内的反射率; 其中针对至少一个表面的至少一部分的压缩将所述反射率在所述表面的至少所述部分中移动到第二波长范围。 该晶体可用于各种认证装置。

    WIDELY WAVELENGTH TUNEABLE POLYCHROME COLLOIDAL PHOTONIC CRYSTAL DEVICE
    10.
    发明申请
    WIDELY WAVELENGTH TUNEABLE POLYCHROME COLLOIDAL PHOTONIC CRYSTAL DEVICE 失效
    宽带波长可调谐聚合胶体光电晶体装置

    公开(公告)号：US20080224103A1

    公开(公告)日：2008-09-18

    申请号：US12046313

    申请日：2008-03-11

    申请人： Andre Arsenault ,  Hernan Miguez ,  Ian Manners ,  Geoffrey Alan Ozin

    发明人： Andre Arsenault ,  Hernan Miguez ,  Ian Manners ,  Geoffrey Alan Ozin

    IPC分类号： H01B1/12

    CPC分类号： B82Y20/00 ,  C09K2019/0496 ,  G02B6/1225 ,  G02F1/01 ,  G02F1/19 ,  G02F1/21 ,  G02F2201/305 ,  G02F2201/346 ,  G02F2202/022 ,  G02F2202/32 ,  G02F2203/055 ,  Y10T428/1023

    摘要： The present invention discloses a widely wavelength tunable polychrome colloidal photonic crystal device whose optical Bragg diffraction stop bands and higher energy bands wavelength, width and intensity can be tuned in a continuous and fine, rapid and reversible, reproducible and predictable fashion and over a broad spectral range by a controlled expansion or contraction of the colloidal photonic lattice dimension, effected by a predetermined change in the electronic configuration of the composite material. In its preferred embodiment, the material is a composite in the form of a film or a patterned film or shape of any dimension or array of shapes of any dimension comprised of an organized array of microspheres in a matrix of a cross-linked metallopolymer network with a continuously variable redox state of charge and fluid content. The chemo-mechanical and electro-mechanical optical response of the colloidal photonic crystal-metallopolymer gel is exceptionally fast and reversible, attaining its fully swollen state from the dry shrunken state and vice versa on a sub-second time-scale. These composite materials can be inverted by removal of the constituent microspheres from the aforementioned colloidal photonic crystal metallopolymer-gel network to create a macroporous metallopolymer-gel network inverse colloidal photonic crystal film or patterned film or shape of any dimension optical Bragg diffraction stop bands and higher energy bands wavelength, width and intensity can be redox tuned in a continuous and fine, rapid and reversible, reproducible and predictable fashion and over a broad spectral range by a controlled expansion or contraction of the colloidal photonic lattice dimensions.

    摘要翻译： 本发明公开了一种广泛波长可调谐的多色胶体光子晶体器件，其光学布拉格衍射阻挡带和更高能带的波长，宽度和强度可以以连续和精细，快速和可逆，可再现和可预测的方式调谐，并且在宽光谱 通过胶体光子晶格尺寸的受控扩展或收缩，由复合材料的电子构型的预定变化来实现。 在其优选实施方案中，该材料是膜或图案化膜的形式的复合材料或任何尺寸或任何尺寸形状阵列的形状的复合材料，其包含在交联金属聚合物网络的基质中的有组织的微球阵列， 不断变化的氧化还原电荷和流体含量。 胶体光子晶体金属聚合物凝胶的化学机械和机电光学响应特别快速和可逆，在亚秒级时间范围内从干收缩状态获得完全膨胀的状态，反之亦然。 这些复合材料可以通过从上述胶体光子晶体金属聚合物 - 凝胶网络中除去组成微球而反转，以产生大孔金属聚合物 - 凝胶网络反胶体光子晶体膜或任何尺寸的光学布拉格衍射阻带的图案化膜或更高的形状 能带的波长，宽度和强度可以通过胶体光子晶格尺寸的受控扩展或收缩，以连续和精细，快速和可逆，可再现和可预测的方式以及在宽光谱范围内进行氧化还原。