摘要:
A diesel exhaust fluid (DEF) doser includes a DEF inlet configured to receive DEF, a DEF outlet configured to spray DEF out of the DEF doser, and an electrochemical cell. The electrochemical cell is located between the DEF inlet and the DEF outlet and couplable to a power source. The electrochemical cell is configured such that, when DEF is flowing from the DEF inlet to the DEF outlet and when the electrochemical cell is coupled to the power source, the electrochemical cell causes an electrolytic reaction in the DEF flowing from the DEF inlet to the DEF outlet to produce gaseous products in the DEF flowing from the DEF inlet to the DEF outlet, and wherein the gaseous products comprise one or more of H2 or NH3.
摘要:
A thermally integrated catalyst aftertreatment exhaust system includes a flow channel that directs diesel exhaust through a diesel oxidation catalyst unit that includes a diesel oxidation catalyst, by a doser that introduces DEF into the diesel exhaust, through a mixing chamber that includes a static metallic mixer coated with a DEF hydrolysis catalyst, and through an SCR unit that includes an SCR catalyst. The diesel oxidation catalyst converts a portion of diesel exhaust into water, carbon dioxide, or nitrogen dioxide. The DEF hydrolysis catalyst facilitates hydrolysis of the mixed DEF and diesel exhaust. The SCR catalyst facilitates reduction of NOx in the diesel exhaust. A first portion of the flow channel is in direct thermal contact with a second portion of the flow channel that houses the SCR unit such that heat from the diesel exhaust before the diesel exhaust reaches the doser is passed to the SCR unit.
摘要:
This disclosure features an exhaust aftertreatment system that includes a selective catalytic reduction catalyst that includes (1) a metal oxide catalyst and a metal zeolite catalyst, (2) a metal oxide catalyst that is other than a vanadium oxide catalyst and a vanadium oxide catalyst, or (3) a metal oxide catalyst that is other than a vanadium oxide catalyst together with a metal zeolite catalyst and a vanadium oxide catalyst. When used in a selective catalytic reduction system in a diesel engine, the catalyst composition can increase a conversion efficiency of nitrogen oxides (NOx) to nitrogen and water by a minimum of 2 percent compared to the metal zeolite catalyst alone, the metal oxide catalyst alone, or the vanadium oxide catalyst alone, when present.
摘要:
This disclosure features an exhaust aftertreatment system that includes a selective catalytic reduction catalyst that includes a metal oxide catalyst and a metal zeolite catalyst, a metal oxide catalyst that is other than a vanadium oxide catalyst and a vanadium oxide catalyst, or a metal oxide catalyst that is other than a vanadium oxide catalyst together with a metal zeolite catalyst and a vanadium oxide catalyst. When used in a selective catalytic reduction system in a diesel engine, the catalyst composition can increase a conversion efficiency of nitrogen oxides (NOx) to nitrogen and water by a minimum of 2 percent compared to the metal zeolite catalyst alone, the metal oxide catalyst alone, or the vanadium oxide catalyst alone, when present.
摘要:
A thermally integrated catalyst aftertreatment exhaust system includes a flow channel that directs diesel exhaust through a diesel oxidation catalyst unit that includes a diesel oxidation catalyst, by a doser that introduces DEF into the diesel exhaust, through a mixing chamber that includes a static metallic mixer coated with a DEF hydrolysis catalyst, and through an SCR unit that includes an SCR catalyst. The diesel oxidation catalyst converts a portion of diesel exhaust into water, carbon dioxide, or nitrogen dioxide. The DEF hydrolysis catalyst facilitates hydrolysis of the mixed DEF and diesel exhaust. The SCR catalyst facilitates reduction of NOx in the diesel exhaust. A first portion of the flow channel is in direct thermal contact with a second portion of the flow channel that houses the SCR unit such that heat from the diesel exhaust before the diesel exhaust reaches the doser is passed to the SCR unit.
摘要:
Catalytic cores for a wall-flow filter include juxtaposed channels extending longitudinally between an inlet side and an outlet side of the core, wherein the inlet channels are plugged at the outlet side and outlet channels are plugged at the inlet side. Longitudinal walls forming the inlet and outlet channels separate the inlet channels from the outlet channels. The walls include pores that create passages extending across a width of the walls from the inlet channels to the outlet channels. Catalysts are distributed across the width and length of the walls within internal surfaces of the pores in a manner such that the loading of each catalyst across the width varies by less than 50% from an average loading across the width.
摘要:
The present disclosure describes a diesel oxidation catalyst, including a metal oxide including a metal on a metal oxide surface, and less than 10 g/ft3 by weight of Pt or Pd, wherein the diesel oxidation catalyst oxidizes carbon monoxide and hydrocarbons of a diesel exhaust to carbon dioxide and water.
摘要:
A hydrophobic polymer such as polysulfone or polyethersulfone is modified to contain an increased number of functionalizable chain ends such as by treating with an alkali hydroxide to provide hydroxyl groups. A linker is covalently bonded to a chain end of the polymer and a macromolecule is covalently bonded to the linker. A ligand may be covalently bonded to the macromolecule. The macromolecule can be a natural polymer, a synthetic polymer or a biologically active species. The hydrophobic polymer is preferably in the form of a microporous membrane. By the use of a four-component dope composition, substantially isotropic microporous structures in the form of flat sheets or hollow fibers are produced. An improved spinnerette assembly is provided for the production of hollow fibers.
摘要:
This disclosure features a urea conversion catalyst located within a urea decomposition reactor (e.g., a urea decomposition pipe) of a diesel exhaust aftertreatment system. The urea conversion catalyst includes a refractory metal oxide and a cationic dopant. The urea conversion catalyst can decrease the temperature at which urea converts to ammonia, can increase the urea conversion yield, and can decrease the likelihood of incomplete urea conversion.
摘要:
Catalytic cores for a wall-flow filter include juxtaposed channels extending longitudinally between an inlet side and an outlet side of the core, wherein the inlet channels are plugged at the outlet side and outlet channels are plugged at the inlet side. Longitudinal walls forming the inlet and outlet channels separate the inlet channels from the outlet channels. The walls include pores that create passages extending across a width of the walls from the inlet channels to the outlet channels. Catalysts are distributed across the width and length of the walls within internal surfaces of the pores in a manner such that the loading of each catalyst across the width varies by less than 50% from an average loading across the width.