公开(公告)号：US4081578A

公开(公告)日：1978-03-28

申请号：US620515

申请日：1975-10-08

申请人： Willem J. van Essen ,  Henry Shanoski ,  Richard M. Griffith

发明人： Willem J. van Essen ,  Henry Shanoski ,  Richard M. Griffith

IPC分类号： B29C37/00 ,  B29C43/00 ,  B29C45/00 ,  B29C45/16 ,  C08G18/10 ,  C08G18/67 ,  C08G18/68 ,  B29C5/00 ,  B29D9/00

CPC分类号： C08G18/10 ,  B29C37/0028 ,  B29C45/1679 ,  C08G18/67 ,  C08G18/68 ,  B29C2791/001 ,  B29C43/00 ,  B29C45/0025 ,  B29K2067/06 ,  B29K2075/00 ,  B29K2105/08 ,  B29K2105/16 ,  Y10T428/20 ,  Y10T428/31565 ,  Y10T428/31794

摘要： An in-mold coating composition is disclosed which includes (a) an isocyanate-terminated material containing an excess of reactive isocyanate groups and (b) a material selected from the group consisting of a composition containing reactive hydrogen atoms, generally hydroxyl groups, and a catalyst capable of trimerizing the terminal isocyanate groups. The coating composition is applied to a molded substrate, such as an FRP part, by placing a charge of the composition in the mold on the substrate, the charge being sufficient to provide a coating having a thickness less than about 20 mils. Appropriate pressure is then applied to the charge, such as by closing the mold, so that the coating composition is forced to cover substantially the entire surface area of the substrate, filling any surface defects. The composition is cured to yield a crosslinked, isocyanate-based coating which adheres tightly to the substrate.

公开(公告)号：US4438062A

公开(公告)日：1984-03-20

申请号：US484760

申请日：1983-04-14

申请人： Richard M. Griffith ,  Henry Shanoski

发明人： Richard M. Griffith ,  Henry Shanoski

IPC分类号： B29C43/00 ,  B29C37/00 ,  B29C43/02 ,  B29C43/14 ,  B29C43/20 ,  B29C43/32 ,  B29C43/34 ,  B29C57/00 ,  B29K105/06 ,  B29C1/00 ,  B29C9/00

CPC分类号： B29C37/0028 ,  B29C43/02 ,  B29C43/146 ,  B29K2105/08

摘要： An SMC (FRP) molding is coated with a minimum amount of an IMC composition by skewing one of the mold halves during the initial IMC molding cycle to effect a scissoring action, the fulcrum being at or about the IMC injection point or placement to spread or wipe the IMC over the surface of the SMC part and then effecting at least substantial parallelism of the mold halves during the remaining IMC cycle of coating and curing the IMC.

摘要翻译： 在最初的IMC成型周期期间通过歪斜半模之一来涂覆最小量的IMC组合物以实现SMC（FRP）模制以实现剪切动作，支点位于或围绕IMC注射点或放置以扩展或 在IMC部件的表面上擦拭IMC，然后在剩余的IMC循环涂覆和固化IMC期间至少实现半模的实质平行度。

公开(公告)号：US4239796A

公开(公告)日：1980-12-16

申请号：US50902

申请日：1979-06-21

申请人： Henry Shanoski ,  Richard M. Griffith

发明人： Henry Shanoski ,  Richard M. Griffith

IPC分类号： B32B5/18 ,  B05D7/24 ,  B29C37/00 ,  B29C39/02 ,  B29C39/10 ,  B29C39/38 ,  B29C39/42 ,  B29K67/00 ,  B29L9/00 ,  C08J9/34 ,  C08J9/36 ,  B29D27/00

CPC分类号： B29C37/0028 ,  C08J9/365 ,  B29K2055/02 ,  B29K2067/00 ,  B29K2069/00 ,  B29K2105/16 ,  Y10S264/05 ,  Y10S264/06 ,  Y10S264/83 ,  Y10T428/233 ,  Y10T428/249992 ,  Y10T428/252

摘要： A method is disclosed comprising in-mold coating a structural foam part made from a thermoplastic aromatic polycarbonate resin or a thermoplastic ABS polymer resin with a thermosetting in-mold coating composition at a pressure of from about 25 to 50 p.s.i. and at a temperature not in excess of about 200.degree. F. for from about 1 to 10 minutes, preferably for from about 1 to 3 minutes, to provide hard, smooth and adherent coatings, said thermosetting in-mold coating composition comprising an ethylenically unsaturated polyester resin and an ethylenically unsaturated monomer(s) catalyzed with an organic perioxide initiator including an accelerator for the initiator.

摘要翻译： 公开了一种方法，其包括模内涂覆由热塑性芳族聚碳酸酯树脂或热塑性ABS聚合物树脂制成的结构泡沫部件，其中热塑性模内涂料组合物的压力为约25至50p.s.i。 并且在不超过约200°F的温度下进行约1至10分钟，优选约1至3分钟，以提供硬质，光滑和粘附的涂层，所述热固性模内涂料组合物包含烯属不饱和 聚酯树脂和含有用于引发剂的促进剂的有机二氧化物引发剂催化的烯属不饱和单体。

公开(公告)号：US4245006A

公开(公告)日：1981-01-13

申请号：US40255

申请日：1979-05-18

申请人： Henry Shanoski

发明人： Henry Shanoski

IPC分类号： C08J7/04 ,  B29C37/00 ,  B29C43/20 ,  B32B27/36 ,  C08G18/68 ,  B32B27/40

CPC分类号： C08G18/68 ,  B29C37/0028 ,  B29C43/203 ,  B29C2037/0035 ,  B29K2067/06 ,  B29K2105/06 ,  Y10T428/31565 ,  Y10T428/31794

摘要： A method comprises in-mold coating on a molded thermoset polyester glass fiber substrate an in-mold coating composition at a pressure of from about 25 to 50 p.s.i. and at a temperature not in excess of about 150.degree. F. for from about 2 to 12 minutes, said in-mold coating composition comprising the reaction product of an unsaturated aliphatic fumarate polyester diol, a saturated polyester diol flexibilizer, a cross-linking aliphatic polyol having from 3 to 6 OH groups, a diisocyanate in an amount by weight sufficient to provide from about 50 to 120%, preferably from about 80 to 103%, of the stoichiometric amount of --NCO groups required to react with all of the active hydrogen atoms in the coating composition and an ethylenically unsaturated monomer sufficient to polymerize with and crosslink the unsaturated polyester in admixture with a free radical peroxide initiator, an accelerator for said peroxide initiator and a polyurethane tin catalyst.

摘要翻译： 一种方法包括在模制的热固性聚酯玻璃纤维基材上模压涂覆在约25至50p.s.i的压力下的模内涂料组合物。 并且在不超过约150°F的温度下进行约2至12分钟，所述模内涂料组合物包含不饱和脂肪族富马酸酯聚酯二醇，饱和聚酯二醇增塑剂，交联脂肪族 具有3至6个OH基团的多元醇，二异氰酸酯的量足以提供与所有活性物质反应所需的化学计量量的-NCO基团的约50至120％，优选约80至103％ 涂料组合物中的氢原子和足够与自由基过氧化物引发剂，所述过氧化物引发剂的促进剂和聚氨酯锡催化剂混合并使不饱和聚酯交联的烯属不饱和单体。

公开(公告)号：US4414173A

公开(公告)日：1983-11-08

申请号：US435026

申请日：1982-10-25

申请人： David S. Cobbledick ,  Donald F. Reichenbach ,  Henry Shanoski

发明人： David S. Cobbledick ,  Donald F. Reichenbach ,  Henry Shanoski

IPC分类号： C08F299/02 ,  C08F299/06 ,  C08J5/00 ,  C09D175/16 ,  B29H9/02 ,  C08L75/00

CPC分类号： C08J5/00 ,  C08F299/026 ,  C08F299/065 ,  C09D175/16 ,  Y10T428/31511 ,  Y10T428/31565 ,  Y10T428/31794

摘要： An FRP molding can be in-mold coated using a free radical peroxide initiated thermosetting composition of at least one polymerizable epoxy based oligomer having at least two acrylate groups, at least one copolymerizable ethylenically unsaturated monomer, at least one copolymerizable monoethylenically unsaturated compound having a --CO-- group and a --NH.sub.2, --NH-- and/or --OH group, polyvinyl acetate, at least one zinc salt of a fatty acid having at least 10 carbon atoms, at least one accelerator for a peroxide initiator, conductive carbon black, a filler such as talc and a copolymerizable or cocurable compound selected from the group consisting of(I) at least one polyoxyalkylene glycol oligomer having two acrylate groups and(II) at least one polyurethane oligomer having two acrylate groups and mixtures of (I) and (II).Optionally and desirably, there additionally can be added to the foregoing composition at least one calcium salt of a fatty acid.

公开(公告)号：US4222929A

公开(公告)日：1980-09-16

申请号：US32049

申请日：1979-04-23

申请人： Henry Shanoski ,  Donald F. Reichenbach

发明人： Henry Shanoski ,  Donald F. Reichenbach

IPC分类号： C08G18/68 ,  C08L67/06 ,  C09D175/14 ,  C08K3/22 ,  C08K3/26 ,  C08K3/34 ,  C08K3/36

CPC分类号： C08L67/06 ,  C08G18/68 ,  C09D175/14

摘要： A laminate comprises an adherent in-mold thermoset coating composition on a thermoset polyester glass fiber substrate, the coating composition comprising essentially the reaction product of an unsaturated aliphatic fumarate polyester diol, a saturated polyester diol flexibilizer, a cross-linking aliphatic polyol having from 3 to 6 OH groups, a diisocyanate in an amount by weight sufficient to provide from about 50 to 120%, preferably from about 80 to 99%, of the stoichiometric amount of --NCO groups required to react with all of the active hydrogen atoms in the coating composition and an ethylenically unsaturated monomer sufficient to polymerize with and crosslink the unsaturated polyester in admixture with a minor amount by weight of polyvinyl acetate which serves to reduce or eliminate shrinkage of the coating composition.

公开(公告)号：US4508785A

公开(公告)日：1985-04-02

申请号：US592772

申请日：1984-03-26

申请人： David S. Cobbledick ,  Donald F. Reichenbach ,  Henry Shanoski

发明人： David S. Cobbledick ,  Donald F. Reichenbach ,  Henry Shanoski

IPC分类号： C08F299/02 ,  C08F299/06 ,  C08J5/00 ,  C09D175/16 ,  B32B27/06 ,  B32B27/36

CPC分类号： C08J5/00 ,  C08F299/026 ,  C08F299/065 ,  C09D175/16 ,  Y10T428/31576 ,  Y10T428/31786

摘要： An FRP molding can be in-mold coated using a free radical peroxide initiated thermosetting composition of at least one polymerizable epoxy based oligomer having at least two acrylate groups, at least one copolymerizable ethylenically unsaturated monomer, at least one copolymerizable monoethylenically unsaturated compound having a --CO-- group and a --NH.sub.2, --NH-- and/or --OH group, polyvinyl acetate, at least one zinc salt of a fatty acid having at least 10 carbon atoms, at least one accelerator for a peroxide initiator, conductive carbon black, a filler such as talc and a copolymerizable or cocurable compound selected from the group consisting of(I) at least one polyoxyalkylene glycol oligomer having two acrylate groups and(II) at least one polyurethane oligomer having two acrylate groups and mixtures of (I) and (II).Optionally and desirably, there additionally can be added to the foregoing composition at least one calcium salt of a fatty acid.

公开(公告)号：US4374238A

公开(公告)日：1983-02-15

申请号：US323213

申请日：1981-11-20

申请人： Henry Shanoski

发明人： Henry Shanoski

IPC分类号： C08G18/04 ,  C08G18/67 ,  C08G18/71 ,  C08G18/34

CPC分类号： C08G18/04 ,  C08G18/672 ,  C08G18/71

摘要： An FRP molding can be in-mold coated using a one-component peroxide initiated composition of (a) a liquid crosslinkable composition having an average molecular weight of up to about 5,000, having a plurality of polymerizable ethylenic double bonds, being essentially free of active hydrogen atoms and being essentially free of isocyanate groups and (b) a material selected from the group consisting of (I) a polyisocyanate and (II) the reaction product of an excess of equivalents of a polyisocyanate and an ethylenically unsaturated compound having --NH.sub.2, --NH-- and/or OH groups, said reaction product being free of active hydrogen atoms.

摘要翻译： 可以使用单组分过氧化物起始组合物（a）平均分子量高达约5,000的具有多个可聚合的烯属双键的液体可交联组合物，基本上不含活性成分 氢原子并且基本上不含异氰酸酯基团，和（b）选自（I）多异氰酸酯和（II）过量当量的多异氰酸酯和具有-NH 2的烯属不饱和化合物的反应产物的材料， -NH-和/或OH基团，所述反应产物不含活性氢原子。

公开(公告)号：US4189517A

公开(公告)日：1980-02-19

申请号：US958771

申请日：1978-11-08

申请人： Henry Shanoski ,  Donald F. Reichenbach

发明人： Henry Shanoski ,  Donald F. Reichenbach

IPC分类号： C08J7/04 ,  B29C37/00 ,  B32B27/36 ,  C08G18/68 ,  C08J5/00 ,  C09D175/04 ,  C09D175/06 ,  C09D175/14 ,  C09K3/10 ,  B32B9/04 ,  B32B27/40

CPC分类号： C08J5/00 ,  B29C37/0028 ,  C08G18/68 ,  C09D175/04 ,  C09D175/06 ,  C09D175/14 ,  B29K2075/00 ,  C08J2367/06 ,  Y10T428/31504 ,  Y10T428/31565 ,  Y10T428/31794

摘要： A laminate comprises an adherent in-mold thermoset coating composition on a thermoset polyester glass fiber substrate, the coating composition comprising essentially the reaction product of an unsaturated aliphatic fumarate polyester diol, a saturated polyester diol flexibilizer, a cross-linking aliphatic polyol having from 3 to 6 OH groups, a diisocyanate in an amount by weight sufficient to provide from about 50 to 120%, preferably from about 80 to 99%, of the stoichiometric amount of --NCO groups required to react with all of the active hydrogen atoms in the coating composition and an ethylenically unsaturated monomer sufficient to polymerize with and crosslink the unsaturated polyester in admixture with a minor amount by weight of polyvinyl acetate which serves to reduce or eliminate shrinkage of the coating composition.

摘要翻译： 层压体包括在热固性聚酯玻璃纤维基材上的粘附的模内热固性涂料组合物，该涂料组合物基本上包含不饱和脂肪族富马酸酯聚酯二醇，饱和聚酯二醇增塑剂，具有3个碳原子的交联脂族多元醇的反应产物 至6个OH基团，重量足以提供约50至120％，优选约80至99％的化学计量量的与所有活性氢原子反应所需的-NCO基团的量的二异氰酸酯 涂料组合物和烯键式不饱和单体，其足以使不饱和聚酯与少量的聚乙酸乙烯酯混合并交联，其用于减少或消除涂料组合物的收缩。

公开(公告)号：US5777053A

公开(公告)日：1998-07-07

申请号：US785514

申请日：1997-01-17

申请人： Douglas S. McBain ,  David S. Cobbledick ,  Henry Shanoski ,  Brian J. Sullivan

发明人： Douglas S. McBain ,  David S. Cobbledick ,  Henry Shanoski ,  Brian J. Sullivan

IPC分类号： B32B5/28 ,  B29C33/14 ,  B29C37/00 ,  C08F290/06 ,  C08G18/67 ,  C08J7/04 ,  C09D155/00 ,  C09D175/16 ,  C08F226/02 ,  B29B11/08 ,  C08F212/06 ,  C08F220/18

CPC分类号： C08F290/067 ,  B29C37/0028 ,  C08G18/672

摘要： An in-mold coating composition for a fiber reinforced plastic comprises an aliphatic resin such as a saturated aliphatic ester intermediate polyurethane having terminal acrylate end groups, a saturated (cyclo)aliphatic (meth)acrylate such as isobornyl acrylate, a hydroxyl alkyl (meth)acrylate, a polyacrylate ester of an alkylene polyol, and a vinyl substituted aromatic. The in-mold coating compositions have good end use weather-resistant properties so that there is no need for a subsequent paint coat thereon which heretofore has been required. The paint-free coating compositions can be either clear or pigmented and can contain various additives such as lubricants, adhesion aids, hardeners, and the like.

摘要翻译： 用于纤维增强塑料的模内涂料组合物包括脂族树脂，例如具有末端丙烯酸酯端基的饱和脂肪族酯中间体聚氨酯，饱和（环）脂族（甲基）丙烯酸酯如丙烯酸异冰片酯，（甲基） 丙烯酸酯，亚烷基多元醇的聚丙烯酸酯和乙烯基取代的芳族。 模内涂料组合物具有良好的最终用途耐候性能，因此不需要以前需要的随后的涂料。 无漆涂料组合物可以是透明的或着色的，并且可以含有各种添加剂，例如润滑剂，助粘剂，硬化剂等。