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公开(公告)号：US4021332A
公开(公告)日：1977-05-03
申请号：US586130
申请日：1975-06-12
摘要： This invention is directed to the shape selective conversion of a hydrocarbon charge over erionite which has been activated by the steps comprising calcining the erionite as a first step, contacting with a solution of an ammonium salt, contacting with a solution of metal salt containing a metal such as calcium, calcining again, contacting again with a solution of an ammonium salt and then with a solution of a metal salt containing nickel or another similar metal, and finally calcining. It is also directed to the catalyst utilized in affecting said conversion and to the method for preparing such catalyst.
摘要翻译： 本发明涉及通过以下步骤活化的烃电荷在毛沸石上的形状选择性转化：包括煅烧作为第一步的毛沸石的步骤，与铵盐溶液接触，与含有金属的金属盐的溶液接触 例如钙，再次煅烧，再次与铵盐溶液接触，再与含有镍或其它类似金属的金属盐溶液接触，最后煅烧。 还涉及用于影响所述转化率的催化剂和制备这种催化剂的方法。
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公开(公告)号：US4077910A
公开(公告)日：1978-03-07
申请号：US746352
申请日：1976-12-01
CPC分类号： B01J29/56 , C10G2400/02
摘要： This invention is directed to the shape selective conversion of a hydrocarbon charge over erionite which has been activated by the steps comprising calcining the erionite as a first step, contacting with a solution of an ammonium salt, contacting with a solution of metal salt containing a metal such as calcium, calcining again, contacting again with a solution of an ammonium salt and then with a solution of a metal salt containing nickel or another similar metal, and finally calcining. It is also directed to the catalyst utilized in affecting said conversion and to the method for preparing such catalyst.
摘要翻译： 本发明涉及通过以下步骤活化的烃电荷在毛沸石上的形状选择性转化：包括煅烧作为第一步的毛沸石的步骤，与铵盐溶液接触，与含有金属的金属盐的溶液接触 例如钙，再次煅烧，再次与铵盐溶液接触，再与含有镍或其它类似金属的金属盐溶液接触，最后煅烧。 还涉及用于影响所述转化率的催化剂和制备这种催化剂的方法。
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公开(公告)号：US4552648A
公开(公告)日：1985-11-12
申请号：US577941
申请日：1984-02-08
CPC分类号： B01J29/80 , B01J29/40 , C10G11/05 , B01J2229/26 , B01J2229/36 , B01J2229/42 , B01J29/08 , B01J29/084
摘要： A process for catalytically cracking a hydrocarbon feed in a reaction zone under catalytic cracking conditions in the absence of added hydrogen with a catalyst comprising a conventional cracking catalyst. The improvement comprises adding to the conventional cracking catalyst a thermally treated zeolite having a mole ratio of SiO.sub.2 :Al.sub.2 O.sub.3 of about 10:1 to 100:1 and a constraint index of about 1 to 12. Thermal treatment reduces the additive zeolite's alpha activity to about 1 to 10 prior to use.
摘要翻译： 在催化裂化条件下，在没有加入氢气的情况下，用含有常规裂化催化剂的催化剂，在反应区中催化裂化烃原料的方法。 改进包括向常规裂化催化剂中加入具有约10:1至100:1摩尔比的SiO 2 :Al 2 O 3的热处理沸石，约1至12的约束指数。热处理将添加沸石的α活性降低至约 使用前1至10。
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4.发明授权
公开(公告)号：US4452958A
公开(公告)日：1984-06-05
申请号：US497319
申请日：1983-05-23
CPC分类号： C08F10/00
摘要： There is provided the polymerization of 1-olefins such as ethylene with zeolite supported, chromium catalyst compositions. Chromium ions are ion exchanged with zeolites to produce such catalysts.
摘要翻译： 提供1-烯烃如乙烯与负载沸石的铬催化剂组合物的聚合。 铬离子与沸石离子交换以产生这样的催化剂。
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5.发明授权Aromatic conversion reactions with zeolitic catalyst composition of improved shape selectivity 失效具有改进的形状选择性的沸石催化剂组合物的芳族转化反应
公开(公告)号：US4899007A
公开(公告)日：1990-02-06
申请号：US679673
申请日：1984-12-10
申请人： Pochen Chu , Francis G. Dwyer , Albert B. Schwartz
发明人： Pochen Chu , Francis G. Dwyer , Albert B. Schwartz
CPC分类号： C07C6/123 , B01J29/40 , B01J29/46 , C07C2/66 , B01J2229/20 , B01J2229/26 , B01J2229/36 , B01J2229/42 , C07C2529/46 , C07C2529/68 , C07C2529/76
摘要： There are provided aromatic conversion reactions for preparation of dialkyl benzenes, such as xylene and ethyltoluene, of enhanced para isomer content with a zeolitic catalyst composition of improved shape selectivity. The catalysts comprise certain zeolites which have been calcined at a high temperature of at least 649.degree. C. (i.e., 1200.degree. F.). These zeolites have a silica/alumina ratio of at least about 12 and a constraint index within the approximate range of 1 to 12. Examples of such zeolites include ZSM-5 and ZSM-11.
摘要翻译： 提供芳族转化反应，用于制备具有改进的形状选择性的沸石催化剂组合物，具有增强的对位异构体含量的二烷基苯如二甲苯和乙基甲苯。 催化剂包括已在至少649℃（即1200°F）的高温下煅烧的某些沸石。 这些沸石的二氧化硅/氧化铝比至少约为12，约束指数在1至12的近似范围内。这种沸石的实例包括ZSM-5和ZSM-11。
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6.发明授权Moving bed catalytic cracking process with platinum group metal or rhenium supported directly on the cracking catalyst 失效用铂族金属或铼直接负载在裂化催化剂上的移动床催化裂解过程
公开(公告)号：US4473658A
公开(公告)日：1984-09-25
申请号：US524103
申请日：1983-08-17
申请人： Albert B. Schwartz
发明人： Albert B. Schwartz
CPC分类号： B01J29/061 , B01J29/90 , B01J38/22
摘要： An improved moving bed continuous catalytic cracking process for cracking hydrocarbon feedstocks, such as gas oil, in the absence of added hydrogen, which includes the use of a minute amount of dispersed platinum supported directly on a cracking catalyst. The trace of platinum induces a substantial increase in the heat efficiency with which coke on catalyst is converted to CO.sub.2 in the regenerator section with minimal or no detriment to the cracking reaction.
摘要翻译： 一种改进的移动床连续催化裂化方法，用于在没有加入氢气的情况下裂化烃原料如瓦斯油，其包括使用微量的分散的铂直接负载在裂化催化剂上。 铂的痕迹导致热效率的显着增加，在该热效率下，催化剂上的焦炭在再生器部分中转化为CO 2，同时对裂解反应的影响最小或没有损害。
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公开(公告)号：US4174272A
公开(公告)日：1979-11-13
申请号：US869079
申请日：1978-01-13
申请人： Albert B. Schwartz
发明人： Albert B. Schwartz
CPC分类号： B01J29/061 , C10G11/05 , C10G11/18
摘要： Non-hydrogenative endothermic catalytic cracking of hydrocarbon, particularly petroleum, fractions at relatively low pressures and high temperatures in a system where the endothermic heat required for cracking is supplied by catalyst as the heat transfer medium, which catalyst has been heated by burning coke deposited on the catalyst during cracking; and wherein a decomposable compound of platinum, palladium, ruthenium, iridium, osmium, rhodium or rhenium, is introduced into contact with the cracking catalyst during said process.
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公开(公告)号：US4093535A
公开(公告)日：1978-06-06
申请号：US806713
申请日：1977-06-15
申请人： Albert B. Schwartz
发明人： Albert B. Schwartz
CPC分类号： C10G11/18 , Y10S208/01
摘要： A catalytic process for cracking of gas oil is disclosed, wherein trace amounts of metals of Periods 5 and 6 of Group VIII or rhenium is added to the total catalyst inventory so as to enhance significant conversion of the CO in the regenerator while maintaining the efficiency of the cracking reaction at high levels.
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公开(公告)号：US4091007A
公开(公告)日：1978-05-23
申请号：US627158
申请日：1975-10-30
CPC分类号： C01B39/40 , B01J29/40 , B01J29/7011 , C01B39/34 , C07C2/00 , B01J2229/26 , B01J2229/36 , B01J2229/42 , C07C2529/40 , Y10S423/22 , Y10S423/26
摘要： An improved method for preparing a crystalline aluminosilicate zeolite having uniform pores and greater than 40 percent crystallinity which comprises forming a critical reaction mixture containing a source of at least two cations, silica, alumina and water, wherein at least about 70 weight percent of the alumina is provided to the reaction mixture by an alumina-containing clay being added thereto, and maintaining the reaction mixture at a temperature and pressure for a time necessary to crystallize the crystalline aluminosilicate from the reaction mixture. It is desirable to preform said reaction mixture into discrete particles such as pellets or extrudates which retain their shape and acquire substantial strength in the crystallization process.
摘要翻译： 一种制备具有均匀孔和大于40％结晶度的结晶硅铝酸盐沸石的改进方法，其包括形成含有至少两种阳离子源，二氧化硅，氧化铝和水的临界反应混合物，其中至少约70重量％的氧化铝 通过向其中加入的含氧化铝粘土提供给反应混合物，并将反应混合物保持在温度和压力下使反应混合物中结晶硅铝酸盐结晶所需的时间。 期望将所述反应混合物预制成离散的颗粒，例如颗粒或挤出物，其保持其形状并在结晶过程中获得显着的强度。
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公开(公告)号：US4868146A
公开(公告)日：1989-09-19
申请号：US236414
申请日：1988-08-25
申请人： Pochen Chu , Albert B. Schwartz
发明人： Pochen Chu , Albert B. Schwartz
CPC分类号： C10G50/00 , B01J29/40 , B01J29/90 , C07C2/12 , B01J2229/123 , B01J2229/16 , B01J2229/32 , C07C2529/40 , C07C2529/70 , Y02P20/584
摘要： A surface-inactive shape selective metallosilicate catalyst, useful for the conversion of lower molecular weight olefins to liquid hydrocarbons such as gasoline, distillate, and high viscosity lube oils, is prepared by forming a silica shell on a medium pore metallosilicate core by crystallizing silica in the presence of fluoride ion onto the surface of the core.A novel catalyst composition is provided comprising an inner core portion and an outer portion disposed as a porous shell around the inner portion, wherein the inner portion consists essentially of metallosilicate zeolite having a medium pore structure, such as ZSM-5 or ZSM-23, and the outer portion comprising a fluoride-containing crystalline shell consisting essentially of silica substantially free of acid sites and having substantially the same crystalline structure as the inner core portion.
摘要翻译： 通过在中孔金属硅酸盐芯上通过使二氧化硅结晶形成二氧化硅壳来制备可用于将低分子量烯烃转化为液体烃如汽油，馏出物和高粘度润滑油的表面活性形状选择性金属硅酸盐催化剂 氟离子存在于芯的表面上。 提供了一种新颖的催化剂组合物，其包括内芯部分和围绕内部部分设置为多孔壳体的外部部分，其中内部部分基本上由具有中孔结构的金属硅酸盐沸石如ZSM-5或ZSM-23组成， 并且外部部分包含基本上由基本上不含酸性部位的二氧化硅组成并且具有与内芯部分基本相同的晶体结构的含氟化物结晶壳。
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