摘要:
Granulates which contain titanium silicalite-1 are composed of silicon dioxide, titanium dioxide and titanium silicalite-1 crystals. The granulates can be prepared by spray-drying or spray granulating the crystallization suspension. The granulates may be used as suspension catalysts, such as for the epoxidation of olefins using hydrogen peroxide.
摘要:
A method for epoxidation of olefins with 2 to 6 C atoms, especially propene, with hydrogen peroxide in the gas phase at a temperature below 250° C. The reaction is carried out by bringing a gas mixture containing the olefin, hydrogen peroxide and water into contact with the catalyst from the series of compounds of an element of the 4th to the 6th subgroup of the periodic table or of arsenic or selenium and molecular sieves in the absence of a liquid phase. Titanium-containing molecular sleeves are preferred catalysts.
摘要:
The present invention relates to an integrated plant which comprises a plant for the electrothermic production of ethyne and a plant for electricity generation, the plant for the electrothermic production of ethyne being connected to the plant for electricity generation via a conduit and electricity being generated in the plant for electricity generation from a product gas obtained in the plant for the electrothermic production of ethyne. This integrated plant affords flexible use of electricity by a method in which, at times of a high electricity supply, the plant for the electrothermic production of ethyne is operated and at least some of the hydrogen and/or gaseous hydrocarbons obtained in addition to ethyne is stored and, at times of a low electricity supply, stored hydrogen and/or gaseous hydrocarbons are fed to the plant for electricity generation.
摘要:
A method for providing control power for an electricity network in which at least one energy store connected to the electricity network supplies energy to the electricity network as required and/or takes up energy from the electricity network as required, the control power being delivered in dependence on a frequency deviation from a setpoint value of a network frequency, a tolerance with respect to the frequency deviation being used to set a charging state of the energy store at a same time as providing the control power by the energy store. A device for carrying out such a method includes a control system and an energy store, the device being connected or connectable to an electricity network, the control system being connected to the energy store and controlling the control power that is given off and/or taken up by the energy store.
摘要:
The present invention relates to a system, to a reactor and to a process for continuous industrial performance of a reaction wherein allyl glycidyl ether A is reacted with an HSi compound B in the presence of a catalyst C and optionally of further assistants, and the system is based at least on the combination of reactants (3) for components A (1) and B (2), at least one multielement reactor (5) which in turn comprises at least two reactor units in the form of exchangeable pre-reactors (5.1) and at least one further reactor unit (5.3) connected downstream of the prereactors, and on a product workup (8).
摘要:
The present invention relates to a system, to a reactor and to a process for continuous industrial performance of a reaction wherein an α,β-unsaturated fluorine-substituted olefin A is reacted with an HSi compound B in the presence of a catalyst C and optionally of further assistants, and the system is based at least on the combination of reactants (3) for components A (1) and B (2), at least one multielement reactor (5) which, in turn, comprises at least two reactor units in the form of exchangeable prereactors (5.1) and at least one further reactor unit (5.3) connected downstream of the prereactors, and on a product workup (8).
摘要:
A process for reactions with or to form peroxidic compounds in a wall reactor whose reaction space has a specific material coating is described.Both higher space-time yields and increased selectivities can be achieved by means of the process.
摘要:
Supports having a catalytic coating comprising at least one porous and cavity-containing catalyst layer are described, cavities being irregular spaces having dimensions greater than 5 μm in at least two dimensions or having cross-sectional areas of at least 10 μm2.The catalytic coatings are distinguished by a high adhesive strength and can preferably be used in microreactors.
摘要:
Reactions between at least two fluid reactants are performed in a reactor comprising wall elements (1), slot-shaped reaction spaces (3) and cavities (5) for conducting a fluid heat-carrier through. Depending on the process and throughput, a modular structural design is chosen wherein an arbitrary number of wall elements (1) are assembled to a right-parallelepipedal block (24), the reaction spaces (3) are formed between lateral surfaces (2) of right-parallelepipedal wall elements (1), the reactants are introduced into the reaction spaces (3) from edge regions of one side of the block (24) and are conducted through the reaction spaces (3) in parallel flows and the fluid heat-carrier is conducted through the tubular cavities (5) extending in the interior of the wall elements (1).
摘要:
The present invention relates to a process for preparing aqueous colloidal silica sols of high purity from silicate solutions, to aqueous colloidal silica sols with a specific profile of impurities, and to the use thereof. The invention further encompasses high-purity aqueous silica obtained as an intermediate in the course of the purification process, high-purity silicon dioxide obtainable by dewatering, and the use thereof.