-
1.发明申请METHOD FOR RECYCLING ORGANIC RUTHENIUM COMPOUND FOR CHEMICAL VAPOR DEPOSITION 有权用于回收化学蒸气沉积的有机金属化合物的方法公开(公告)号：US20150087851A1
公开(公告)日：2015-03-26
申请号：US14396861
申请日：2013-06-06
IPC分类号： C07F15/00
CPC分类号： C07F15/0046 , B01J23/42 , B01J23/44 , B01J23/462 , B01J25/02 , C07C45/79 , C07C45/85 , C07C49/92
摘要： The present invention is a method for recycling an organic ruthenium compound for chemical vapor deposition, wherein an unreacted organic ruthenium compound is extracted from a used raw material through a thin film formation process. The method includes the following steps (a) to (c). (a) A modification step in which the used raw material and a hydrogenation catalyst are brought into contact with each other in a hydrogen atmosphere, thereby hydrogenating an oxidized organic ruthenium compound in the used raw material. (b) An adsorption step in which the used raw material and an adsorbent are brought into contact with each other, thereby removing impurities in the used raw material. (c) A restoration step in which the used raw material is heated at a temperature that is not lower than −100° C. and not higher than −10° C. with respect to the decomposition temperature of the organic ruthenium compound for eight hours or more, thereby adjusting the ratio of the isomers of the organic ruthenium compound in the used raw material.
摘要翻译： 本发明是一种用于化学气相沉积的有机钌化合物的再循环方法，其中通过薄膜形成方法从使用的原料中提取未反应的有机钌化合物。 该方法包括以下步骤（a）至（c）。 （a）在氢气氛中使使用的原料和氢化催化剂彼此接触的改性步骤，从而使所使用的原料中的氧化的有机钌化合物氢化。 （b）使原料和吸附剂相互接触的吸附工序，除去原料中的杂质。 （c）将有机钌化合物的分解温度在不低于-100℃且不高于-10℃的温度下加热8小时的恢复步骤 以上，由此调整所使用的原料中的有机钌化合物的异构体的比例。
-
2.发明申请CHEMICAL VAPOR DEPOSITION RAW MATERIAL COMPRISING ORGANOPLATINUM COMPOUND, AND CHEMICAL VAPOR DEPOSITION METHOD USING THE CHEMICAL VAPOR DEPOSITION RAW MATERIAL 有权化学气相沉积原料包含有机化合物，以及使用化学蒸气沉积原料的化学气相沉积方法公开(公告)号：US20150030772A1
公开(公告)日：2015-01-29
申请号：US14344603
申请日：2012-10-12
IPC分类号： C23C16/18 , C23C16/448 , C07F15/00 , C23C16/46
CPC分类号： C23C16/18 , C07F15/0086 , C23C16/4485 , C23C16/46
摘要： A chemical vapor deposition raw material for producing a platinum thin film or a platinum compound thin film by a chemical vapor deposition method, wherein the chemical vapor deposition raw material includes an organoplatinum compound having cyclooctadiene and alkyl anions coordinated to divalent platinum, and the organoplatinum compound is represented by the following formula. Here, one in which R1 and R2 are any combination of propyl and methyl, propyl and ethyl, or ethyl and methyl is particularly preferred. wherein R1 and R2 are alkyl groups, and R1 and R2 are different; and a number of carbon atoms of R1 and R2 is 3 to 5 in total.
摘要翻译： 一种用于通过化学气相沉积法生产铂薄膜或铂化合物薄膜的化学气相沉积原料，其中化学气相沉积原料包括具有环辛二烯的有机铂化合物和与二价铂配位的烷基阴离子，以及有机铂化合物 由下式表示。 这里，特别优选其中R 1和R 2是丙基和甲基，丙基和乙基之间的任何组合，或乙基和甲基的化合物。 其中R1和R2是烷基，R1和R2不同; 并且R1和R2的多个碳原子总共为3〜5。
-
3.发明授权公开(公告)号：US09556212B2
公开(公告)日：2017-01-31
申请号：US14422292
申请日：2013-08-19
发明人： Ryosuke Harada , Naoki Nakata , Masayuki Saito
CPC分类号： C07F15/0046 , C23C16/18 , C23C16/46
摘要： The present invention provides a raw material, formed of a ruthenium complex, for producing a ruthenium thin film or a ruthenium compound thin film by a chemical deposition method, wherein the ruthenium complex is a ruthenium complex represented by the following formula, in which carbonyl groups and a fluoroalkyl derivative of a polyene are coordinated to ruthenium. The present invention provides a raw material for chemical deposition having a preferable decomposition temperature, and the production cost therefor is low: (nR-L)Ru(CO)3 [Chemical Formula 1] wherein L is a polyene having a carbon number of from 4 to 8 and 2 to 4 double bonds, wherein the polyene L has n (n≧1) pieces of substituents Rs, wherein the substituents Rs are each a fluoroalkyl group having a carbon number of from 1 to 6 and a fluorine number of from 1 to 13, and in the case when the polyene L has two or more (n≧2) of the substituents Rs, the carbon numbers and the fluorine numbers of the substituents Rs may be different in the same molecule.
摘要翻译： 本发明提供一种由钌络合物形成的原料，用于通过化学沉积法制备钌薄膜或钌化合物薄膜，其中钌络合物是下式表示的钌络合物，其中羰基 多烯的氟烷基衍生物与钌配位。 本发明提供了具有优选的分解温度的化学沉积原料，其生产成本低：€ƒ€ƒ€ƒ€ƒ€ƒ€ƒ€ƒ€ƒ€ƒ€ƒ€ƒ€ ƒ€ƒƒ（nR-L）Ru（CO）3其中L是碳数为4至8的多烯和2至4个双键，其中多烯L具有n（n‰1） 取代基R 5，其中取代基R 5分别为碳数为1〜6，氟数为1〜13的氟代烷基，多烯L具有两个以上（n‰）2以下的 取代基Rs的取代基Rs，碳数和氟数可以在同一分子中不同。
-
公开(公告)号：US09394446B2
公开(公告)日：2016-07-19
申请号：US14440733
申请日：2013-11-12
发明人： Kenichi Inoue , Hiroki Sato , Masayuki Saito
CPC分类号： C09B57/10 , H01M14/00 , Y02E10/542 , Y02P70/521
摘要： The present invention relates to a method for recovering Ru complex dye from a used dye solution containing a polypyridine Ru complex as a Ru complex, the used dye solution having been discharged from a step of manufacturing a dye-sensitized solar cell, the method including the steps of: (a): filtering the used dye solution to separate and remove solid content. (b): bringing a separating solvent including an ether-based solvent indicated by a chemical formula CxH(2x+1)—O—CyH(2y+1) (x=1 to 4 and y=1 to 4, with the proviso that x+y≧4) or an alkane-based solvent indicated by a chemical formula CxH(2x+2) (x=5 to 7) into contact with the used dye solution to separate the Ru complex dye.
摘要翻译： 本发明涉及从含有作为Ru配合物的聚吡啶Ru配位化合物的使用的染料溶液中回收Ru络合染料的方法，所述染料敏化太阳能电池的制造工序已经排出了所使用的染料溶液， 步骤：（a）：过滤所使用的染料溶液以分离并除去固体含量。 （b）：使由化学式CxH（2x + 1）-O-CyH（2y + 1）（x = 1〜4，y = 1〜4）表示的醚系溶剂分离溶剂， x +y≥4）或由化学式CxH（2x + 2）（x = 5〜7）表示的烷烃系溶剂与所使用的染料溶液接触以分离Ru络合物染料。
-
5.发明授权Method for extracting asymmetric β-diketone compound from β-diketone compound 有权从β-二酮化合物中提取不对称＆bgr-二酮化合物的方法公开(公告)号：US09284249B2
公开(公告)日：2016-03-15
申请号：US14438963
申请日：2013-10-17
IPC分类号： C07C45/80
摘要： The present invention provides a method of extracting an asymmetric β-diketone compound from a β-diketone compound containing at least one symmetric β-diketone compound mixed in the asymmetric β-diketone compound, and the method includes the step (A) of adjusting a pH of a mixed solution of the β-diketone compound and water at 11.5 or more and dissolving the β-diketone compound into water to form a β-diketone compound solution and the step (B) of subsequently adjusting the pH of the β-diketone compound solution at 9.5 or less and recovering the asymmetric β-diketone compound of Chemical Formula 1 separated from the β-diketone compound solution. The present invention further includes at least either (a) a step of setting the upper limit of the pH of the mixed solution to 12.5 to form a β-diketone compound solution in the step (A) and bringing the β-diketone compound solution into contact with a hydrophobic solvent or (b) a step of setting the lower limit of the pH of the β-diketone compound solution to 8.0 in the step (B).
摘要翻译： 本发明提供了从含有至少一种混合在不对称 - 二 - 二酮化合物中的对称二酮化合物的β-二酮化合物中提取不对称二酮化合物的方法，该方法包括步骤（A ）将所述二 - 二酮化合物和水的混合溶液的pH调节至11.5以上，并将所述二酮化合物溶解在水中以形成二酮化合物溶液，并且随后调整步骤（B） 将二 - 二酮化合物溶液的pH调节至9.5或更低，并回收分离自二 - 二酮化合物溶液的化学式1的不对称 - 二酮化合物。 本发明还包括（a）将步骤（A）中将混合溶液的pH值的上限设定为12.5以形成步骤（A）中的β-二酮化合物溶液并使该二酮化合物 溶液与疏水性溶剂接触，或（b）在步骤（B）中将β-二酮化合物溶液的pH下限设定为8.0的步骤。
-
6.发明申请METHOD FOR EXTRACTING ASYMMETRIC B-DIKETONE COMPOUND FROM B-DIKETONE COMPOUND 有权从β-二酮化合物中提取不对称的β-二酮酮化合物的方法公开(公告)号：US20150291497A1
公开(公告)日：2015-10-15
申请号：US14438963
申请日：2013-10-17
IPC分类号： C07C45/80
摘要： The present invention provides a method of extracting an asymmetric β-diketone compound from a β-diketone compound containing at least one symmetric β-diketone compound mixed in the asymmetric β-diketone compound, and the method includes the step (A) of adjusting a pH of a mixed solution of the β-diketone compound and water at 11.5 or more and dissolving the β-diketone compound into water to form a β-diketone compound solution and the step (B) of subsequently adjusting the pH of the β-diketone compound solution at 9.5 or less and recovering the asymmetric β-diketone compound of Chemical Formula 1 separated from the β-diketone compound solution. The present invention further includes at least either (a) a step of setting the upper limit of the pH of the mixed solution to 12.5 to form a β-diketone compound solution in the step (A) and bringing the β-diketone compound solution into contact with a hydrophobic solvent or (b) a step of setting the lower limit of the pH of the β-diketone compound solution to 8.0 in the step (B).
摘要翻译： 本发明提供了从含有至少一种混合在不对称 - 二 - 二酮化合物中的对称二酮化合物的β-二酮化合物中提取不对称二酮化合物的方法，该方法包括步骤（A ）将所述二 - 二酮化合物和水的混合溶液的pH调节至11.5以上，并将所述二酮化合物溶解在水中以形成二酮化合物溶液，并且随后调整步骤（B） 将二 - 二酮化合物溶液的pH调节至9.5或更低，并回收分离自二 - 二酮化合物溶液的化学式1的不对称 - 二酮化合物。 本发明还包括（a）将步骤（A）中将混合溶液的pH值的上限设定为12.5以形成步骤（A）中的β-二酮化合物溶液并使该二酮化合物 溶液与疏水性溶剂接触，或（b）在步骤（B）中将β-二酮化合物溶液的pH下限设定为8.0的步骤。
-
7.发明授权Chemical vapor deposition raw material containing organic nickel compound, and chemical vapor deposition method using the chemical vapor deposition raw material 有权含有机镍化合物的化学气相沉积原料，以及使用化学气相沉积原料的化学气相沉积法公开(公告)号：US09447495B2
公开(公告)日：2016-09-20
申请号：US14890485
申请日：2013-12-27
摘要： The present invention provides a chemical vapor deposition raw material, which has a low melting point, has heat stability such that no thermal decomposition occurs during vaporization, readily decomposes at low temperature during film-formation, and can stably form a nickel thin-film having fewer impurities. The present invention relates to a chemical vapor deposition raw material containing an organic nickel compound, in which a cyclopentadienyl group or a derivative thereof is coordinated to nickel, and a cycloalkenyl group having one allyl group or a derivative thereof is coordinated to the carbon skeleton of cycloalkyl. This raw material has a low melting point, proper heat stability and film-formation ability at low temperature. Further, due to a high vapor pressure, the raw material is suitable for a three-dimensional electrode material having a three-dimensional structure.
摘要翻译： 本发明提供一种化学气相沉积原料，其熔点低，具有热稳定性，使得在蒸发时不会发生热分解，在成膜期间在低温下容易分解，并且可以稳定地形成具有 杂质少。 本发明涉及一种含有有机镍化合物的化学气相沉积原料，其中环戊二烯基或其衍生物与镍配位，并且具有一个烯丙基或其衍生物的环烯基与碳骨架配位 环烷基。 该原料在低温下具有低熔点，适当的热稳定性和成膜能力。 此外，由于高蒸气压，原料适用于具有三维结构的三维电极材料。
-
8.发明授权Chemical vapor deposition raw material comprising organoplatinum compound, and chemical vapor deposition method using the chemical vapor deposition raw material 有权包含有机铂化合物的化学气相沉积原料和使用化学气相沉积原料的化学气相沉积法公开(公告)号：US09382616B2
公开(公告)日：2016-07-05
申请号：US14344603
申请日：2012-10-12
IPC分类号： C23C16/00 , C23C16/18 , C07F15/00 , C23C16/448 , C23C16/46
CPC分类号： C23C16/18 , C07F15/0086 , C23C16/4485 , C23C16/46
摘要： A chemical vapor deposition raw material for producing a platinum thin film or a platinum compound thin film by a chemical vapor deposition method, wherein the chemical vapor deposition raw material includes an organoplatinum compound having cyclooctadiene and alkyl anions coordinated to divalent platinum, and the organoplatinum compound is represented by the following formula. Here, one in which R1 and R2 are any combination of propyl and methyl, propyl and ethyl, or ethyl and methyl is particularly preferred. wherein R1 and R2 are alkyl groups, and R1 and R2 are different; and a number of carbon atoms of R1 and R2 is 3 to 5 in total.
摘要翻译： 一种用于通过化学气相沉积法生产铂薄膜或铂化合物薄膜的化学气相沉积原料，其中化学气相沉积原料包括具有环辛二烯的有机铂化合物和与二价铂配位的烷基阴离子，以及有机铂化合物 由下式表示。 这里，特别优选其中R 1和R 2是丙基和甲基，丙基和乙基之间的任何组合，或乙基和甲基的化合物。 其中R1和R2是烷基，R1和R2不同; 并且R1和R2的多个碳原子总共为3〜5。
-
公开(公告)号：US09266916B2
公开(公告)日：2016-02-23
申请号：US14655076
申请日：2014-01-20
IPC分类号： C07F15/00
CPC分类号： C07F15/0046 , C01G55/008 , C23C16/16 , C23C16/45553
摘要： The present invention is a method for producing dodecacarbonyl triruthenium (DCR) including a process of carbonylating ruthenium chloride with carbon monoxide, in which an amine is added to a reaction system at 0.8 molar equivalent or more with respect to chlorine of the ruthenium chloride and the carbonylation is conducted at a reaction temperature of 50 to 100° C. and a reaction pressure of 0.2 to 0.9 MPa. According to the present invention, it is possible to produce dodecacarbonyl triruthenium having less residual impurity metals without applying a reaction condition of a high pressure.
摘要翻译： 本发明是一种生产十二羰基三钌（DCR）的方法，其包括使用一氧化碳羰基化氯化钌的方法，其中胺相对于氯化钌的氯为0.8摩尔当量以上而添加到反应体系中， 在50〜100℃的反应温度和0.2〜0.9MPa的反应压力下进行羰基化。 根据本发明，可以在不施加高压反应条件的情况下制造具有较少残留杂质金属的十二羰基三钌。
-
10.发明授权Method for recycling organic ruthenium compound for chemical vapor deposition 有权用于化学气相沉积的有机钌化合物回收方法公开(公告)号：US09108997B2
公开(公告)日：2015-08-18
申请号：US14396861
申请日：2013-06-06
IPC分类号： C07F17/02 , C07F15/00 , B01J23/44 , C07C45/79 , C07C45/85 , B01J23/42 , B01J23/46 , B01J25/02
CPC分类号： C07F15/0046 , B01J23/42 , B01J23/44 , B01J23/462 , B01J25/02 , C07C45/79 , C07C45/85 , C07C49/92
摘要： The present invention is a method for recycling an organic ruthenium compound for chemical vapor deposition, wherein an unreacted organic ruthenium compound is extracted from a used raw material through a thin film formation process. The method includes the following steps (a) to (c). (a) A modification step in which the used raw material and a hydrogenation catalyst are brought into contact with each other in a hydrogen atmosphere, thereby hydrogenating an oxidized organic ruthenium compound in the used raw material. (b) An adsorption step in which the used raw material and an adsorbent are brought into contact with each other, thereby removing impurities in the used raw material. (c) A restoration step in which the used raw material is heated at a temperature that is not lower than −100° C. and not higher than −10° C. with respect to the decomposition temperature of the organic ruthenium compound for eight hours or more, thereby adjusting the ratio of the isomers of the organic ruthenium compound in the used raw material.
摘要翻译： 本发明是一种用于化学气相沉积的有机钌化合物的再循环方法，其中通过薄膜形成方法从使用的原料中提取未反应的有机钌化合物。 该方法包括以下步骤（a）至（c）。 （a）在氢气氛中使使用的原料和氢化催化剂彼此接触的改性步骤，从而使所使用的原料中的氧化的有机钌化合物氢化。 （b）使原料和吸附剂相互接触的吸附工序，除去原料中的杂质。 （c）将有机钌化合物的分解温度在不低于-100℃且不高于-10℃的温度下加热8小时的恢复步骤 以上，由此调整所使用的原料中的有机钌化合物的异构体的比例。
-
-
-
-
-
-
-
-
-
搜索结果
11 条记录 (耗时 0.014 秒)
