公开(公告)号：US06767984B2

公开(公告)日：2004-07-27

申请号：US09851983

申请日：2001-05-10

申请人： Teruzo Toui ,  Hisaki Tanabe ,  Nobuhisa Sudo ,  Satoshi Urano ,  Manabu Yoshioka

发明人： Teruzo Toui ,  Hisaki Tanabe ,  Nobuhisa Sudo ,  Satoshi Urano ,  Manabu Yoshioka

IPC分类号： C08G77442

CPC分类号： C09D183/10

摘要： This invention provides a top coating composition which comprises a coating film-forming resin (I); as well as a silicate compound (II) besides a hydrolyzable silyl-containing resin (III) and/or a silicate-grafted resin (IV) resulting from graft polymerization of a silicate compound (II) onto a hydrolyzable silyl-containing resin (III).

摘要翻译： 本发明提供了一种顶涂层组合物，其包括涂膜形成树脂（I）; 以及除了可水解的含甲硅烷基的树脂（III）和/或由硅酸盐化合物（II）接枝聚合到可水解的含甲硅烷基的树脂（III）上的硅酸酯接枝树脂（IV）之外的硅酸盐化合物（II） 。

公开(公告)号：US06562903B2

公开(公告)日：2003-05-13

申请号：US09870776

申请日：2001-06-01

申请人： Teruzo Toui ,  Hisaki Tanabe ,  Nobuhisa Sudo ,  Hiroshi Kubota ,  Takakazu Yamane

发明人： Teruzo Toui ,  Hisaki Tanabe ,  Nobuhisa Sudo ,  Hiroshi Kubota ,  Takakazu Yamane

IPC分类号： C08F800

CPC分类号： C09D133/064 ,  B05D7/576 ,  B05D7/577 ,  C08L33/064 ,  C08L43/04 ,  C09D143/04 ,  C08L2666/04

摘要： A clear coating for top coating of automobiles which comprises a half-esterified acid group-containing acrylic copolymer (I) and a silicate-grafted acrylic copolymer (II) as resin constituents, said half-esterified acid group-containing acrylic copolymer (I) being obtainable by: preparing a copolymer from an acid anhydride group-containing, radical-polymerizable monomer (I-a) and another radical-polymerizable monomer (I-b) and then half-esterifying said acid anhydride group with a low-molecular alcohol compound, said silicate-grafted copolymer (II) being obtainable by grafting a silicate compound (II-B) onto a hydrolyzable silyl-containing copolymer (II-A), the amount of said silicate compound (II-B) grafted being 5 to 50% by mass (on solids basis) relative to the total amount of said resin constituents.

摘要翻译： 含有半酯化酸基的丙烯酸共聚物（I）和作为树脂成分的硅酸酯接枝丙烯酸共聚物（II）的汽车顶涂层用透明涂层，所述含半酯化酸基的丙烯酸共聚物（I）为 可通过以下方法获得：由含酸酐基团的可自由基聚合的单体（Ia）和另一种可自由基聚合的单体（Ib）制备共聚物，然后用低分子量醇化合物半酯化所述酸酐基团， 接枝共聚物（II）可通过将硅酸盐化合物（II-B）接枝到可水解甲硅烷基的共聚物（II-A）上获得，所述接枝的硅酸盐化合物（II-B）的量为5〜50质量％ 基于固体）相对于所述树脂成分的总量。

公开(公告)号：US20070298178A1

公开(公告)日：2007-12-27

申请号：US10592385

申请日：2005-03-11

申请人： Hisaki Tanabe ,  Hideaki Tsujioka

发明人： Hisaki Tanabe ,  Hideaki Tsujioka

IPC分类号： C08L63/00 ,  B05D1/36 ,  B05D7/24 ,  C08G59/32 ,  C08G59/40

CPC分类号： C08F220/08 ,  B05D1/34 ,  B05D3/0254 ,  B05D5/065 ,  B05D7/14 ,  B05D7/542 ,  B05D2202/15 ,  C08F220/32 ,  C08G59/3209 ,  C08G59/4246 ,  C09D163/00

摘要： The great decrease of the curing time (in particular, halving) of acid/epoxy curing system paint and the further improvement of other performances (in particular, film performance). A two packages type thermosetting resin composition comprising (a) an acid anhydride group-containing acryl resin having an acid anhydride group of 0.08 to 5.3 mmol/g (solid content) and a number average molecular weight of 500 to 8000 that is obtained by copolymerizing an acid anhydride group-containing ethylenically unsaturated monomer with an ethylenically unsaturated monomer having no acid anhydride group, (b) a carboxylic group-containing polyester resin having a carboxylic group of 0.8 to 6.3 mmol/g (solid content) and a number average molecular weight of 400 to 3500 and a ratio of weight average molecular weight to number average molecular weight of 1.8 or less that is obtained by reacting an acid anhydride group-containing ethylenically unsaturated monomer with polyester polyol having 3 or more of hydroxyl groups, and (c) an acryl resin with hydroxyl groups and epoxy groups having a hydroxyl group of 0.08 to 5.4 mmol/g (solid content), an epoxy group of 1.2 to 10.0 mmol/g (solid content) and a number average molecular weight of 200 to 10000 that is obtained by copolymerizing a hydroxyl group-containing ethylenically unsaturated monomer and an epoxy group-containing ethylenically unsaturated monomer with an ethylenically unsaturated monomer not having a hydroxyl group and an epoxy group.

摘要翻译： 酸/环氧树脂固化体系涂料的固化时间（特别是减半）大大降低，其他性能（特别是膜性能）进一步提高。 一种双包装型热固性树脂组合物，其包含（a）通过共聚合得到的酸酐基为0.08〜5.3mmol / g（固体成分）和数均分子量为500〜8000的含酸酐基的丙烯酸树脂 含有酸酐基团的烯属不饱和单体与不含酸酐基团的烯键式不饱和单体，（b）羧基含量为0.8〜6.3mmol / g（固体成分）和数均分子量 重量为400〜3500，通过使含酸酐基的烯属不饱和单体与具有3个以上羟基的聚酯多元醇反应得到的重均分子量与数均分子量的比值为1.8以下，（c ）具有羟基的丙烯酸树脂和羟基为0.08〜5.4mmol / g（固体成分）的环氧基，1.2〜10.0mmol / g的环氧基（soli d含量）和通过使含羟基的烯属不饱和单体和含环氧基的烯属不饱和单体与不具有羟基和环氧基的烯键式不饱和单体共聚得到的数均分子量为200〜10000。

公开(公告)号：US06635351B2

公开(公告)日：2003-10-21

申请号：US09919531

申请日：2001-07-31

申请人： Tatsuya Ishihara ,  Masahiko Yamanaka ,  Tetsuji Mizuno ,  Takashi Moriwake ,  Hisaki Tanabe ,  Goro Nagao

发明人： Tatsuya Ishihara ,  Masahiko Yamanaka ,  Tetsuji Mizuno ,  Takashi Moriwake ,  Hisaki Tanabe ,  Goro Nagao

IPC分类号： B32B904

CPC分类号： B05D7/532 ,  C09D7/65 ,  Y10T428/31663

摘要： It is an object of the invention to provide a clear coating composition, which can give coating films showing good water repellency, in other words a factor giving a care-free and deluxe feeling to car owners, and which are excellent in non-sanding recoatability in recoating dirtied coatings after due repair, as well as a method of forming a coating film and a multilayerd coating film. The invention provides a clear coating composition which comprises (A) 100 parts by mass of the sum of a crosslinkable coating film-forming resin and a crosslinking agent on the solid basis and (B) 0.01 to 2 parts by mass of a ladder silicone copolymer obtainable by copolymerizing (b-1) a (meth)acryloxyalkyl-containing ladder silicone oligomer, (b-2) a crosslinkable functional group-containing ethylenically unsaturated monomer and optionally (b-3) another copolymerizable ethylenically unsaturated monomer.

摘要翻译： 本发明的目的是提供一种透明的涂料组合物，其可以赋予具有良好防水性的涂膜，换句话说，对车主给予无忧无虑和豪华感的因素，并且非着色再涂性 在经过适当修复后重涂污垢涂层，以及形成涂膜和多层涂膜的方法。本发明提供了一种透明涂料组合物，其包含（A）100质量份可交联涂膜形成的总和 树脂和固体成分的交联剂，（B）0.01〜2质量份通过（b-1）含（甲基）丙烯酰氧基烷基的硅氧烷低聚物（b-2），交联性官能团 基团的烯属不饱和单体和任选的（b-3）另一种可共聚的烯属不饱和单体。

公开(公告)号：US5373052A

公开(公告)日：1994-12-13

申请号：US992749

申请日：1992-12-18

申请人： Koichi Fukuda ,  Hisaki Tanabe ,  Yoshio Eguchi

发明人： Koichi Fukuda ,  Hisaki Tanabe ,  Yoshio Eguchi

IPC分类号： C08F299/00 ,  A61K9/51 ,  C08F8/00 ,  C08F290/00 ,  C08F290/08 ,  C08H1/00 ,  C08G63/91 ,  C08H5/00 ,  C08L89/00

CPC分类号： A61K9/5138 ,  A61K9/5146 ,  A61K9/5161 ,  C08F290/08 ,  C08F8/00 ,  C08H1/00

摘要： Disclosed is an organic polymer microparticle which is obtainable from copolymerization of (a) an ethylenically unsaturated amine polymer obtained by reacting an amine polymer having at least two primary amino groups with 0.01 to 0.99 molar equivalents based on the amount of the primary amino group, of an unsaturation introducing monomer having at least one functional group which is reactive with the primary amino group and an ethylenic double bond with (b) 10 to 99000 parts by weight based on the total amount (100 parts by weight) of the amine polymer and the unsaturation introducing monomer, of a matrix forming ethylenically unsaturated monomer, in an aqueous medium. A process for producing the organic polymer microparticle is also disclosed.

摘要翻译： 公开了一种有机聚合物微粒，其可通过（a）通过使具有至少两个伯氨基的胺聚合物与基于伯氨基的量为0.01至0.99摩尔当量的胺聚合物反应而获得的烯属不饱和胺聚合物 具有至少一个与伯氨基反应的官能团和烯键式双键的不饱和引入单体，（b）基于胺聚合物的总量（100重量份）为10〜99000重量份，和 不饱和引入单体，在含水介质中形成烯属不饱和单体的基质。 还公开了制备有机聚合物微粒的方法。

公开(公告)号：US5070161A

公开(公告)日：1991-12-03

申请号：US356903

申请日：1989-05-25

申请人： Shinji Nakano ,  Hiroharu Ohsugi ,  Yasuhiko Nakae ,  Hisaki Tanabe ,  Ryozo Takagawa ,  Yoshio Eguchi ,  Koichi Tsutsui ,  Takeshi Endo

发明人： Shinji Nakano ,  Hiroharu Ohsugi ,  Yasuhiko Nakae ,  Hisaki Tanabe ,  Ryozo Takagawa ,  Yoshio Eguchi ,  Koichi Tsutsui ,  Takeshi Endo

IPC分类号： C07D213/20 ,  C07D213/61 ,  C07D213/84 ,  C08F4/20 ,  C08F4/42 ,  C08G59/68 ,  C08G65/10 ,  C08G85/00 ,  C08K5/19 ,  C08K5/3432

CPC分类号： C07D213/20 ,  C07D213/61 ,  C07D213/84 ,  C08G59/686 ,  C08G65/105 ,  C08G85/00 ,  C08K5/19 ,  C08K5/3432

摘要： Benzyl pyridinium or ammonium salts of a non-nucleophilic anion are useful as a cationic polymerization initiator having a heat latency. A variety of resinous compositions containing this initiator is also disclosed.

公开(公告)号：US4731422A

公开(公告)日：1988-03-15

申请号：US890484

申请日：1986-07-29

申请人： Hisaki Tanabe ,  Masahiko Togo ,  Hirotoshi Umemoto

发明人： Hisaki Tanabe ,  Masahiko Togo ,  Hirotoshi Umemoto

IPC分类号： C08G63/00 ,  C08G63/46 ,  C08G63/60 ,  C08G63/88 ,  C08G63/91 ,  C09D167/00 ,  C08G63/76

CPC分类号： C09D167/00 ,  C08G63/60

摘要： A resinous composition for a top coat comprising a polyester resin modified with a lactone, said polyester resin being characterized in that 10 to 80 mole % of acid component is an alicyclic polycarboxylic acid or anhydride thereof, and 10 to 100 mole % of the carboxyl groups capable of developing a resinous acid value is derived from a polycarboxylic acid which will show a potentiometric midpoint potential in a non-aqueous potentiometric titration, in the state being incorporated into the resin, of -350 mV or more.The coating composition based on said resinous composition is specifically useful as a top coat for automobile bodies in two-tone-color coating.

摘要翻译： 一种面漆用树脂组合物，其包含用内酯改性的聚酯树脂，所述聚酯树脂的特征在于10〜80摩尔％的酸成分为脂环族多元羧酸或其酸酐，10〜100摩尔％的羧基 能够显现树脂酸值的多元羧酸衍生自多羧酸，其在非水电位滴定中将在-350mV或更高的掺入状态下显示电位中点电位。 基于所述树脂组合物的涂料组合物特别可用作双色彩涂料中汽车车身的顶涂层。

公开(公告)号：US4535128A

公开(公告)日：1985-08-13

申请号：US567314

申请日：1983-12-30

申请人： Hirotoshi Umemoto ,  Hisaki Tanabe ,  Shinji Nakano

发明人： Hirotoshi Umemoto ,  Hisaki Tanabe ,  Shinji Nakano

IPC分类号： C08F8/30 ,  C08G18/08 ,  C08G63/88 ,  C08G63/91 ,  C09D133/04 ,  C09D167/00 ,  C09D167/08 ,  C09D201/02 ,  C09D201/08 ,  C08L61/28

CPC分类号： C09D201/08 ,  C08G18/0823 ,  C09D167/00

摘要： A resinous composition for coating use comprising a resin obtained by the reaction of base resin having as essential groups, both carboxyl groups derived from a polycarboxylic acid whose titration midpoint potential in non-aqueous potentiometric titration is more than -300 mV in a state capable of developing a resinous acid value and a functional group reactive with a crosslinking agent, and an alkyleneimine compound in an amount equivalent to resinous acid value of 0.01 to 50, the resinous acid value based on said polycarboxylic acid in the final composition being 2 to 50.This is useful for the preparation of a coating composition having improved curing property, storage stability and time color stability.

摘要翻译： 一种用于涂料用途的树脂组合物，其包含通过基本树脂作为必要基团反应获得的树脂，两个来自多元羧酸的羧基，其在非水电位滴定中的滴定中点电位大于-300mV， 形成树脂酸值和与交联剂反应的官能团，以及相当于树脂酸值为0.01〜50的烯丙基亚胺化合物，最终组合物中所述多元羧酸的树脂酸值为2-50。 这对于制备具有改进的固化性能，储存稳定性和时间颜色稳定性的涂料组合物是有用的。

公开(公告)号：US08138258B2

公开(公告)日：2012-03-20

申请号：US11313786

申请日：2005-12-22

申请人： Hideaki Tsujioka ,  Junji Shimada ,  Hisaki Tanabe ,  Mirei Kato ,  Yoshinori Narita

发明人： Hideaki Tsujioka ,  Junji Shimada ,  Hisaki Tanabe ,  Mirei Kato ,  Yoshinori Narita

IPC分类号： C08L75/00

CPC分类号： C08G18/791 ,  C08G18/6233 ,  C08G18/7831 ,  C09D133/14 ,  C09D175/04

摘要： An automotive clear coating composition includes a hydroxyl group-containing acrylic resin obtained using hydroxyalkyl(meth)acrylate having a hydroxyalkyl group having 4-9 carbon atoms as at least a part of its monomer; and a polyfunctional isocyanate compound in which at least a part thereof is an isocyanurate type isocyanate compound. The prepared composition has 25 to 50 mass % of a soft segment part with respect to a total solid content of such acrylic resin and the polyfunctional isocyanate compound, and a ratio of a soft segment part derived from a lactone-containing monomer with respect to the total solid content of such acrylic resin and the polyfunctional isocyanate compound of not more than 4.5 mass %. A cured coating film has a dynamic glass transition temperature within a range of 30 to 60° C. The soft segment part is represented by —CH2)n— wherein n represents an integer of 4 or more.

摘要翻译： 汽车透明涂料组合物包括使用具有4-9个碳原子的羟基烷基的（甲基）丙烯酸羟烷基酯作为其单体的至少一部分获得的含羟基的丙烯酸树脂; 和其中至少一部分为异氰脲酸酯型异氰酸酯化合物的多官能异氰酸酯化合物。 所制备的组合物相对于丙烯酸树脂和多官能异氰酸酯化合物的总固体含量为25〜50质量％的软链段部分，来自含内酯的单体的软链段的比例相对于 这种丙烯酸树脂和多官能异氰酸酯化合物的总固体含量不超过4.5质量％。 固化涂膜的动态玻璃化转变温度在30〜60℃的范围内。软链段部分由-CH 2）n表示，其中n表示4以上的整数。

公开(公告)号：US5599883A

公开(公告)日：1997-02-04

申请号：US534588

申请日：1995-09-27

申请人： Hiroharu Ohsugi ,  Shigeru Mikami ,  Hisaki Tanabe ,  Mitsuhiro Takarada ,  Yuji Yoshikawa

发明人： Hiroharu Ohsugi ,  Shigeru Mikami ,  Hisaki Tanabe ,  Mitsuhiro Takarada ,  Yuji Yoshikawa

IPC分类号： C08F290/14 ,  C08G77/442 ,  C08L55/00 ,  C08L83/05 ,  C08L83/06 ,  C08L83/10 ,  C08L101/00 ,  C09D183/06 ,  C09D183/10 ,  C08F283/00

CPC分类号： C09D183/10 ,  C08F290/148 ,  C08G77/442 ,  C08L101/00 ,  C08L55/005 ,  C08L83/06 ,  C08L83/10 ,  C09D183/06

摘要： A curable resin composition containing (a) a homo- or copolymer of an organohydrogenpolysiloxane macromonomer, (b) an alkenyl group-containing polymer, and (c) a hydrosilylation catalyst is disclosed. The organohydrogenpolysiloxane macromonomer may be incorporated into a single polymer entity together with an alkenyl group-containing monomer unit to produce a self-crosslinkable copolymer.

摘要翻译： 公开了包含（a）有机氢聚硅氧烷大分子单体，（b）含烯基的聚合物和（c）氢化硅烷化催化剂的均聚物或共聚物的可固化树脂组合物。 可以将有机氢聚硅氧烷大分子单体与含链烯基的单体单元一起加入到单一聚合物实体中以产生自交联共聚物。