-
公开(公告)号:US4246351A
公开(公告)日:1981-01-20
申请号:US088927
申请日:1979-10-29
CPC分类号: C12N11/08 , B01J20/22 , C07K1/16 , C08J9/286 , C12H1/0424 , Y10S210/905 , Y10S435/815 , Y10S530/806
摘要: A novel protein adsorbent consisting essentially of a porous copolymer obtained by copolymerizing a monomer mixture comprising at least one cyano group-containing monomer and at least one cross-linkable monomer, said copolymer having an average pore diameter (d) of from 40 A to 9,000 A and a total pore volume of from 0.05.sqroot.X ml to 1.5.sqroot.X ml per gram of the copolymer in a dry state, in which X designates the weight proportion of said cross-linkable monomer expressed in terms of the percent by weight based on the total monomers. The present porous copolymer adsorbent has a remarkably high protein adsorbing capacity. The adorbent can advantageously be used for various purposes such as purification and separation of proteins, and removal of proteins. Copolymer-protein composites obtained by adsorption of proteins on the present porous copolymer also are industrially useful and have a wide variety of applications.
摘要翻译: 一种新型蛋白质吸附剂,其基本上由多孔共聚物组成,所述多孔共聚物通过使包含至少一个含氰基单体和至少一种可交联单体的单体混合物共聚而获得,所述共聚物的平均孔径(d)为40〜9,000 A,并且在干燥状态下每克共聚物的总孔体积为0.05×2×UV×1.5×2××××X,其中X表示所述可交联单体的重量比例,以基于 总单体。 本发明的多孔共聚物吸附剂具有非常高的蛋白质吸附能力。 该助剂可有利地用于各种目的,例如蛋白质的纯化和分离以及蛋白质的去除。 通过在本发明的多孔共聚物上吸附蛋白获得的共聚物 - 蛋白质复合物在工业上也是有用的并且具有广泛的应用。
-
公开(公告)号:US4118457A
公开(公告)日:1978-10-03
申请号:US687844
申请日:1976-05-19
申请人: Maomi Seko , Tetsuya Miyake , Kunihiko Takeda , Akihiko Ikeda , Kazuo Imamura
发明人: Maomi Seko , Tetsuya Miyake , Kunihiko Takeda , Akihiko Ikeda , Kazuo Imamura
IPC分类号: C22B60/02 , B01D15/00 , B01D59/30 , B01J41/14 , B01J41/20 , C08F212/08 , C08F226/06
摘要: An anion exchange resin particle provided with specific structure as well as specific functional groups is found to be suitable for uranium technology, especially for separation of uranium isotopes.
摘要翻译: 发现具有特定结构和特定官能团的阴离子交换树脂颗粒适用于铀技术,特别是用于分离铀同位素。
-
公开(公告)号:US4093570A
公开(公告)日:1978-06-06
申请号:US677120
申请日:1976-04-14
申请人: Tetsuya Miyake , Kunihiko Takeda , Akihiko Ikeda , Kazuo Imamura
发明人: Tetsuya Miyake , Kunihiko Takeda , Akihiko Ikeda , Kazuo Imamura
CPC分类号: C08J9/286 , C08F2/06 , C08F2/16 , C08F236/04
摘要: A method of producing a polar, porous polymer comprising polymerizing a monomer mixture comprising:(A) about 2 to about 98 percent by weight of at least one cross-linkable monomer having a plurality of CH.sub.2 .dbd.C
摘要翻译: 一种制备极性多孔聚合物的方法,包括聚合单体混合物,其包括:
-
公开(公告)号:US4311799A
公开(公告)日:1982-01-19
申请号:US54055
申请日:1979-07-02
申请人: Tetsuya Miyake , Kunihiko Takeda , Akihiko Ikeda
发明人: Tetsuya Miyake , Kunihiko Takeda , Akihiko Ikeda
IPC分类号: C08F12/00 , B01J41/14 , C08F8/44 , C08F212/00 , C08F212/14 , C08F212/34 , C08F212/36 , C08F236/00 , C08F236/04 , C08J9/28 , C08F112/08 , B01J39/20
CPC分类号: C08J9/286 , B01J41/14 , C08F212/14 , C08F212/36 , C08F8/44 , C08J9/28 , C08J2201/0542
摘要: A basic copolymer whose main chain is cross-linked which comprises about 6 to about 98% by weight of recurring units of Formula (A) or (B), ##STR1## wherein R.sub.1, R.sub.2 and R.sub.3, which may be the same or different, each represents a hydrogen atom or a hydrocarbon group selected from the group consisting of C.sub.1-20 alkyl groups, C.sub.3-10 cycloalkyl groups, C.sub.3-8 alkenyl groups, C.sub.6-15 aryl groups, C.sub.7-12 arylalkyl groups and C.sub.1-15 aminoalkyl groups; and X is an acid radical, and about 2 to about 94% by weight of cross-linked units based on the total weight of the recurring units of Formula (A) or (B) and the cross-linked units and, if desired, up to about 92% by weight of units of a monoethylenically unsaturated monomer or a conjugated monomer based on the total weight of the recurring units of Formula (A) or (B), the cross-linked units and the units of the monoethylenically unsaturated monomer or the conjugated monomer.
摘要翻译: 其主链交联的基本共聚物,其包含约6至约98重量%的式(A)或(B),(IMA)(A)或(B)的重复单元,其中R1,R2 和R 3可以相同或不同,表示氢原子或选自C 1-20烷基,C 3-10环烷基,C 3-8烯基,C 6-15芳基, C7-12芳基烷基和C1-15氨基烷基; 和X为酸基,约2至约94重量%的基于式(A)或(B)的重复单元和交联单元的总重量的交联单元,如果需要, 基于式(A)或(B)的重复单元的总重量,高达约92重量%的单烯属不饱和单体或共轭单体的单元,单烯属不饱和单体的交联单元和单元 或共轭单体。
-
公开(公告)号:US4376687A
公开(公告)日:1983-03-15
申请号:US206587
申请日:1980-11-13
申请人: Tetsuya Miyake , Kunihiko Takeda , Akihiko Ikeda
发明人: Tetsuya Miyake , Kunihiko Takeda , Akihiko Ikeda
IPC分类号: C08L63/00 , C08L75/00 , C09D125/18 , C09D133/06 , C25D13/06
CPC分类号: C09D125/18 , C09D133/062 , C08L63/00 , C08L75/00 , Y10T428/31529
摘要: A nitrogen-containing acrylic copolymer composition comprising:(i) a linear copolymer comprising about 2 to about 90% by weight of recurring units of Formula (A), ##STR1## wherein R.sub.1 and R.sub.2, which may be the same or different, each represents a hydrogen atom, a C.sub.1-20 alkyl group, a C.sub.3-10 cycloalkyl group, a C.sub.3-8 alkenyl group, a C.sub.1-15 aminoalkyl group, a C.sub.6-20 aryl group or a C.sub.7-12 arylalkyl group,based on the total weight of the linear copolymer, about 10 to about 98% by weight of recurring units of formula (B), ##STR2## wherein R.sub.3 represents a hydrogen atom, a methyl group, a C.sub.1-6 alkoxy group, a halogen atom or a --CH.sub.2 COOR.sub.6 group wherein R.sub.6 represents a hydrogen atom, a C.sub.1-10 alkyl group or a C.sub.7-12 arylalkyl group,R.sub.4 represents a hydrogen atom, a C.sub.1-20 alkyl group, a C.sub.3-10 cycloalkyl group, a C.sub.3-10 halocycloalkyl group, a C.sub.6-20 aryl group, a C.sub.6-20 haloaryl group, a C.sub.7-12 arylalkyl group, a C.sub.1-12 haloalkyl group, a C.sub.1-12 hydroxyalkyl group, a C.sub.2-12 alkoxyalkyl group, a tetrahydrofurfuryl group, a glycidyl group, a --CH.sub.2 --CH.sub.2 --O--.sub.m R.sub.7, wherein R.sub.7 is a C.sub.1-8 alkyl group and m is an integer of 1 to 30, or a C.sub.3-20 dialkylaminoalkyl group, andR.sub.5 represents a hydrogen atom or a --COOR.sub.8 group wherein R.sub.8 is a hydrogen atom or a C.sub.1-20 alkyl group,based on the total weight of the linear copolymer and 0 to about 88% by weight of recurring units of at least one of Formulae (C.sup.1), (C.sup.2) and (C.sup.3), ##STR3## wherein V and W each independently is a hydrogen atom, a C.sub.1-8 alkyl group, a phenyl group or a halogen atom,based on the total weight of the linear copolymer,(ii) about 0.1 to about 10% by weight of an amine-modified epoxy compound where all or part of the epoxy group has been replaced by the unit of Formula (I), ##STR4## wherein R.sub.12 and R.sub.13 each independently is a hydrogen atom, a C.sub.1-20 alkyl group, a C.sub.3-10 cycloalkyl group, a C.sub.1-12 hydroxyalkyl group, a C.sub.1-15 aminoalkyl group, a H--NH--CH.sub.2 --CH.sub.2 --.sub.n wherein n is an integer of 1 to 8, a C.sub.6-15 aryl group or a C.sub.7-12 arylalkyl group,based on the weight of the linear copolymer and(iii) about 0.05 to about 12% by weight of a blocked polyisocyanate where all or part of the isocyanate groups has been replaced by an alcohol and/or an amine, based on the weight of the linear copolymer.
-
公开(公告)号:US4092398A
公开(公告)日:1978-05-30
申请号:US687843
申请日:1976-05-19
申请人: Tetsuya Miyake , Maomi Seko , Kunihiko Takeda , Akihiko Ikeda , Kazuo Imamura
发明人: Tetsuya Miyake , Maomi Seko , Kunihiko Takeda , Akihiko Ikeda , Kazuo Imamura
CPC分类号: B01D59/30
摘要: An anion exchange column, containing anion exchange resin particles with uniform degree of sphericity, restricted average diameter and uniform particle size distribution and having devices for flowing a liquid uniformly, is suitably used for uranium technology, especially for separation of uranium isotopes.
摘要翻译: 具有均匀球形度的阴离子交换树脂粒子,平均直径均匀,粒度分布均匀,并且具有使液体均匀流动的装置的阴离子交换柱适用于铀技术,特别是用于分离铀同位素。
-
公开(公告)号:US4394353A
公开(公告)日:1983-07-19
申请号:US213110
申请日:1980-12-04
CPC分类号: C22B3/0024 , B01D15/422 , B01J39/26 , C01F17/0006 , C22B3/24 , C22B3/42 , G01N30/02 , Y02P10/234
摘要: A process for the separation of one rare earth metal from another in a mixture of rare earth metals by chromatographic displacement using a complexing agent and a cation exchanger, which process comprises using a cation exchanger having a micro-void volume void ratio of 0.5 to 0.95, preferably 0.5 to 0.88.
摘要翻译: 一种通过使用络合剂和阳离子交换剂的色谱置换在稀土金属混合物中分离一种稀土金属的方法,该方法包括使用具有微孔隙体积空隙率为0.5至0.95的阳离子交换剂 ,优选为0.5〜0.88。
-
公开(公告)号:US4280984A
公开(公告)日:1981-07-28
申请号:US941505
申请日:1978-09-11
申请人: Tetsuya Miyake , Norito Ogawa , Kohji Inada , Kunihiko Takeda
发明人: Tetsuya Miyake , Norito Ogawa , Kohji Inada , Kunihiko Takeda
CPC分类号: B01D59/30 , Y10S422/903
摘要: An isotope separation apparatus comprises a plurality of independent developing units, each comprising 2 to 20 adsorbent-packed columns forming a continuous developing circuit or passageway, and the developing units are connected to at least one common main pipe for supplying an isotope mixture solution, a regenerating agent solution, or an eluent solution. Also, in a further embodiment the developing units are connected to common liquid-discharge main pipes.The separation or concentration of isotopes such as uranium isotopes, nitrogen isotopes, boron isotopes, etc., is performed by continuously developing the isotope mixture solution passed through the individual adsorbent-packed columns successively in each developing units.
摘要翻译: 同位素分离装置包括多个独立的显影单元,每个显影单元包括形成连续显影回路或通道的2至20个吸附剂填充柱,显影单元连接至至少一个用于提供同位素混合溶液的公共主管, 再生剂溶液或洗脱液。 此外,在另一实施例中,显影单元连接到共同的排液主管。 通过在每个显影单元中连续地开发通过单独的吸附剂填充塔的同位素混合物溶液来进行同位素如铀同位素,氮同位素,硼同位素等的分离或浓缩。
-
公开(公告)号:US4285811A
公开(公告)日:1981-08-25
申请号:US7527
申请日:1979-01-29
申请人: Tetsuya Miyake , Kunihiko Takeda , Naoki Miyata , Tatsushi Saeki , Maomi Seko
发明人: Tetsuya Miyake , Kunihiko Takeda , Naoki Miyata , Tatsushi Saeki , Maomi Seko
CPC分类号: C07C45/79 , Y10S95/902
摘要: A mixture containing formaldehyde and water is separated effectively by contacting with adsorbents of specific type A zeolites containing exchanged cations of the elements from Group IA (4) to (6) or Group IIA (6) or mixture thereof of the Periodic Table of Elements.
摘要翻译: 通过与元素周期表第IA(4)至(6)或IIA(6)或其组合的元素的交换阳离子的特定A型沸石的吸附剂接触,可以有效地分离含甲醛和水的混合物。
-
公开(公告)号:US4124770A
公开(公告)日:1978-11-07
申请号:US764129
申请日:1977-01-31
申请人: Tetsuya Miyake , Kunihiko Takeda
发明人: Tetsuya Miyake , Kunihiko Takeda
CPC分类号: C07C37/82
摘要: A mixture of xylenols and cresols is contacted with a zeolite with aperture of 5.5 A or more containing at least one cations selected from lithium, potassium, cesium, rubidium, calcium, barium, strontium, cadmium, chromium, molybdenum, manganese, iron, nickel, cobalt, and ammonium to separate xylenols from cresols.
摘要翻译: 将二甲苯酚和甲酚的混合物与含有至少一种选自锂,钾,铯,铷,钙,钡,锶,镉,铬,钼,锰,铁,镍的至少一种阳离子的沸点接触的沸石 ,钴和铵,以将二甲苯酚与甲酚分离。
-
-
-
-
-
-
-
-
-