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公开(公告)号:US4368175A
公开(公告)日:1983-01-11
申请号:US156727
申请日:1980-06-05
CPC分类号: B01D59/30
摘要: A process for the enrichment of one isotope in a mixture of uranium isotopes by passing a solution of the mixture in a solvent through an anion exchanger thereby forming on the anion exchanger a boundary (A) between a uranium adsorption zone and an adjacent reducing agent zone and/or a boundary (B) between a uranium adsorption zone and an adjacent oxidizing agent zone, the uranium adsorption zone advancing through the anion exchanger, effecting reduction at the boundary (A) and/or effecting oxidation at the boundary (B), thereby effecting enrichment adjacent said boundary, and separating a fraction enriched in one of said isotopes, which process comprises using as the solvent medium a composition comprising (a) a solvent having a dielectric constant of at least 80 at 20.degree. C., (b) hydrochloric acid and (c) at least one of hydrobromic acid and sulfuric acid, the solvent medium having a hydrogen ion concentration of about 0.1 M/l to about 10 M/l, a total chlorine ion concentration of about 0.1 M/l to about 12 M/l, at least one of bromine and sulfate ion being present in about 0.01 M/l to about 10 M/l and the other being present in from zero up to 10 M/l, and passing the materials through the ion exchanger at a rate such that the migration velocity of the uranium adsorption zone through the ion exchanger is at least about 1 cm per minute.
摘要翻译: 通过使混合物在溶剂中的溶液通过阴离子交换剂富集铀同位素混合物中的一种同位素,从而在阴离子交换器上形成铀吸附区和相邻的还原剂区之间的边界(A) 和/或铀吸附区和相邻氧化剂区之间的边界(B),铀吸附区前进通过阴离子交换器,在边界(A)处进行还原和/或在边界处进行氧化(B), 从而实现邻近所述边界的富集,并且分离富集所述同位素之一的级分,该方法包括使用作为溶剂介质的组合物,该组合物包含(a)在20℃下介电常数至少为80的溶剂(b )盐酸和(c)氢溴酸和硫酸中的至少一种,溶剂介质的氢离子浓度为约0.1M / l至约10M / l,总氯离子浓度为ab 出现0.1M / l至约12M / l,溴和硫酸根离子中的至少一种以约0.01M / l至约10M / l的量存在,另一种以0至10M / l存在,以及 以使得铀吸附区通过离子交换器的迁移速度为至少约1cm /分钟的速率使材料通过离子交换器。
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公开(公告)号:US4394353A
公开(公告)日:1983-07-19
申请号:US213110
申请日:1980-12-04
CPC分类号: C22B3/0024 , B01D15/422 , B01J39/26 , C01F17/0006 , C22B3/24 , C22B3/42 , G01N30/02 , Y02P10/234
摘要: A process for the separation of one rare earth metal from another in a mixture of rare earth metals by chromatographic displacement using a complexing agent and a cation exchanger, which process comprises using a cation exchanger having a micro-void volume void ratio of 0.5 to 0.95, preferably 0.5 to 0.88.
摘要翻译: 一种通过使用络合剂和阳离子交换剂的色谱置换在稀土金属混合物中分离一种稀土金属的方法,该方法包括使用具有微孔隙体积空隙率为0.5至0.95的阳离子交换剂 ,优选为0.5〜0.88。
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公开(公告)号:US4406870A
公开(公告)日:1983-09-27
申请号:US293220
申请日:1981-08-10
CPC分类号: B01D59/30 , Y10S423/07
摘要: A method for the separation of the isotopes of carbon comprising contacting an aqueous solution containing an acid-dissociated type chemical species of a carbon-containing acid and a non-dissociated type chemical species of said acid with an anion exchange resin as a solid phase, thereby to allow an isotope exchange reaction with respect to carbon to proceed between said acid-dissociated type chemical species and said non-dissociated type chemical species and, concurrently, to adsorb said acid-dissociated type chemical species on said anion exchange resin, and separate C.sup.12 and C.sup.13 respectively into a solution phase and the solid phase or the solid phase and a solution phase, whereby C.sup.13 is concentrated. This method can be practised at an extremely favorable efficiency and inexpensive cost, as compared with the prior art method for the separation utilizing a distillation method or a chemical exchange method between gas--liquid phases, gas--solution phases, solution--solution phases and the like.
摘要翻译: PCT No.PCT / JP80 / 00326 Sec。 371日期1981年8月10日 102(e)日期1981年8月10日PCT提交1980年12月2日PCT公布。 出版物WO81 / 01802 日本1981年7月9日。一种用于分离碳同位素的方法,包括使含有酸的酸的解离型化学物质和所述酸的非离解型化学物质的水溶液与阴离子 交换树脂作为固相,从而允许在所述酸解离型化学物质和所述非解离型化学物质之间进行相对于碳的同位素交换反应,并且同时将所述酸解离型化学物质吸附在 所述阴离子交换树脂,并将C12和C13分别分离成溶液相和固相或固相和溶液相,由此C13浓缩。 与现有技术的分离方法相比,可以以非常有利的效率和廉价的成本实现该方法,其中使用蒸气法或气 - 液相,气溶相,溶液相之间的化学交换方法 喜欢。
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公开(公告)号:US4137054A
公开(公告)日:1979-01-30
申请号:US760218
申请日:1977-01-17
申请人: Tetsuya Miyake , Kunihiko Takeda , Naoki Miyata , Tatsushi Saeki , Maomi Seko
发明人: Tetsuya Miyake , Kunihiko Takeda , Naoki Miyata , Tatsushi Saeki , Maomi Seko
CPC分类号: C07C45/79 , Y10S95/902
摘要: A mixture containing formaldehyde and water is separated effectively by contacting with adsorbents of specific type A zeolites containing exchanged cations of the elements from Group IA (4) to (6) or Group IIA (6) or mixture thereof of the Periodic Table of Elements.
摘要翻译: 通过与元素周期表第IA(4)至(6)或IIA(6)或其组合的元素的交换阳离子的特定A型沸石的吸附剂接触,可以有效地分离含甲醛和水的混合物。
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公开(公告)号:US4280984A
公开(公告)日:1981-07-28
申请号:US941505
申请日:1978-09-11
申请人: Tetsuya Miyake , Norito Ogawa , Kohji Inada , Kunihiko Takeda
发明人: Tetsuya Miyake , Norito Ogawa , Kohji Inada , Kunihiko Takeda
CPC分类号: B01D59/30 , Y10S422/903
摘要: An isotope separation apparatus comprises a plurality of independent developing units, each comprising 2 to 20 adsorbent-packed columns forming a continuous developing circuit or passageway, and the developing units are connected to at least one common main pipe for supplying an isotope mixture solution, a regenerating agent solution, or an eluent solution. Also, in a further embodiment the developing units are connected to common liquid-discharge main pipes.The separation or concentration of isotopes such as uranium isotopes, nitrogen isotopes, boron isotopes, etc., is performed by continuously developing the isotope mixture solution passed through the individual adsorbent-packed columns successively in each developing units.
摘要翻译: 同位素分离装置包括多个独立的显影单元,每个显影单元包括形成连续显影回路或通道的2至20个吸附剂填充柱,显影单元连接至至少一个用于提供同位素混合溶液的公共主管, 再生剂溶液或洗脱液。 此外,在另一实施例中,显影单元连接到共同的排液主管。 通过在每个显影单元中连续地开发通过单独的吸附剂填充塔的同位素混合物溶液来进行同位素如铀同位素,氮同位素,硼同位素等的分离或浓缩。
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公开(公告)号:US4246351A
公开(公告)日:1981-01-20
申请号:US088927
申请日:1979-10-29
CPC分类号: C12N11/08 , B01J20/22 , C07K1/16 , C08J9/286 , C12H1/0424 , Y10S210/905 , Y10S435/815 , Y10S530/806
摘要: A novel protein adsorbent consisting essentially of a porous copolymer obtained by copolymerizing a monomer mixture comprising at least one cyano group-containing monomer and at least one cross-linkable monomer, said copolymer having an average pore diameter (d) of from 40 A to 9,000 A and a total pore volume of from 0.05.sqroot.X ml to 1.5.sqroot.X ml per gram of the copolymer in a dry state, in which X designates the weight proportion of said cross-linkable monomer expressed in terms of the percent by weight based on the total monomers. The present porous copolymer adsorbent has a remarkably high protein adsorbing capacity. The adorbent can advantageously be used for various purposes such as purification and separation of proteins, and removal of proteins. Copolymer-protein composites obtained by adsorption of proteins on the present porous copolymer also are industrially useful and have a wide variety of applications.
摘要翻译: 一种新型蛋白质吸附剂,其基本上由多孔共聚物组成,所述多孔共聚物通过使包含至少一个含氰基单体和至少一种可交联单体的单体混合物共聚而获得,所述共聚物的平均孔径(d)为40〜9,000 A,并且在干燥状态下每克共聚物的总孔体积为0.05×2×UV×1.5×2××××X,其中X表示所述可交联单体的重量比例,以基于 总单体。 本发明的多孔共聚物吸附剂具有非常高的蛋白质吸附能力。 该助剂可有利地用于各种目的,例如蛋白质的纯化和分离以及蛋白质的去除。 通过在本发明的多孔共聚物上吸附蛋白获得的共聚物 - 蛋白质复合物在工业上也是有用的并且具有广泛的应用。
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公开(公告)号:US4311799A
公开(公告)日:1982-01-19
申请号:US54055
申请日:1979-07-02
申请人: Tetsuya Miyake , Kunihiko Takeda , Akihiko Ikeda
发明人: Tetsuya Miyake , Kunihiko Takeda , Akihiko Ikeda
IPC分类号: C08F12/00 , B01J41/14 , C08F8/44 , C08F212/00 , C08F212/14 , C08F212/34 , C08F212/36 , C08F236/00 , C08F236/04 , C08J9/28 , C08F112/08 , B01J39/20
CPC分类号: C08J9/286 , B01J41/14 , C08F212/14 , C08F212/36 , C08F8/44 , C08J9/28 , C08J2201/0542
摘要: A basic copolymer whose main chain is cross-linked which comprises about 6 to about 98% by weight of recurring units of Formula (A) or (B), ##STR1## wherein R.sub.1, R.sub.2 and R.sub.3, which may be the same or different, each represents a hydrogen atom or a hydrocarbon group selected from the group consisting of C.sub.1-20 alkyl groups, C.sub.3-10 cycloalkyl groups, C.sub.3-8 alkenyl groups, C.sub.6-15 aryl groups, C.sub.7-12 arylalkyl groups and C.sub.1-15 aminoalkyl groups; and X is an acid radical, and about 2 to about 94% by weight of cross-linked units based on the total weight of the recurring units of Formula (A) or (B) and the cross-linked units and, if desired, up to about 92% by weight of units of a monoethylenically unsaturated monomer or a conjugated monomer based on the total weight of the recurring units of Formula (A) or (B), the cross-linked units and the units of the monoethylenically unsaturated monomer or the conjugated monomer.
摘要翻译: 其主链交联的基本共聚物,其包含约6至约98重量%的式(A)或(B),(IMA)(A)或(B)的重复单元,其中R1,R2 和R 3可以相同或不同,表示氢原子或选自C 1-20烷基,C 3-10环烷基,C 3-8烯基,C 6-15芳基, C7-12芳基烷基和C1-15氨基烷基; 和X为酸基,约2至约94重量%的基于式(A)或(B)的重复单元和交联单元的总重量的交联单元,如果需要, 基于式(A)或(B)的重复单元的总重量,高达约92重量%的单烯属不饱和单体或共轭单体的单元,单烯属不饱和单体的交联单元和单元 或共轭单体。
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公开(公告)号:US4285811A
公开(公告)日:1981-08-25
申请号:US7527
申请日:1979-01-29
申请人: Tetsuya Miyake , Kunihiko Takeda , Naoki Miyata , Tatsushi Saeki , Maomi Seko
发明人: Tetsuya Miyake , Kunihiko Takeda , Naoki Miyata , Tatsushi Saeki , Maomi Seko
CPC分类号: C07C45/79 , Y10S95/902
摘要: A mixture containing formaldehyde and water is separated effectively by contacting with adsorbents of specific type A zeolites containing exchanged cations of the elements from Group IA (4) to (6) or Group IIA (6) or mixture thereof of the Periodic Table of Elements.
摘要翻译: 通过与元素周期表第IA(4)至(6)或IIA(6)或其组合的元素的交换阳离子的特定A型沸石的吸附剂接触,可以有效地分离含甲醛和水的混合物。
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公开(公告)号:US4124770A
公开(公告)日:1978-11-07
申请号:US764129
申请日:1977-01-31
申请人: Tetsuya Miyake , Kunihiko Takeda
发明人: Tetsuya Miyake , Kunihiko Takeda
CPC分类号: C07C37/82
摘要: A mixture of xylenols and cresols is contacted with a zeolite with aperture of 5.5 A or more containing at least one cations selected from lithium, potassium, cesium, rubidium, calcium, barium, strontium, cadmium, chromium, molybdenum, manganese, iron, nickel, cobalt, and ammonium to separate xylenols from cresols.
摘要翻译: 将二甲苯酚和甲酚的混合物与含有至少一种选自锂,钾,铯,铷,钙,钡,锶,镉,铬,钼,锰,铁,镍的至少一种阳离子的沸点接触的沸石 ,钴和铵,以将二甲苯酚与甲酚分离。
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公开(公告)号:US4118457A
公开(公告)日:1978-10-03
申请号:US687844
申请日:1976-05-19
申请人: Maomi Seko , Tetsuya Miyake , Kunihiko Takeda , Akihiko Ikeda , Kazuo Imamura
发明人: Maomi Seko , Tetsuya Miyake , Kunihiko Takeda , Akihiko Ikeda , Kazuo Imamura
IPC分类号: C22B60/02 , B01D15/00 , B01D59/30 , B01J41/14 , B01J41/20 , C08F212/08 , C08F226/06
摘要: An anion exchange resin particle provided with specific structure as well as specific functional groups is found to be suitable for uranium technology, especially for separation of uranium isotopes.
摘要翻译: 发现具有特定结构和特定官能团的阴离子交换树脂颗粒适用于铀技术,特别是用于分离铀同位素。
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