公开(公告)号：US20120117953A1

公开(公告)日：2012-05-17

申请号：US13384570

申请日：2011-02-01

申请人： Paul Joseph Andersen ,  Ralf Dotzel ,  Kwangmo Koo ,  Rainer Leppelt ,  Jörg Werner Münch ,  Jeffery Scott Rieck ,  Hubert Schedel ,  Duncan John William Winterborn ,  Todd Howard Ballinger ,  Julian Peter Cox

发明人： Paul Joseph Andersen ,  Ralf Dotzel ,  Kwangmo Koo ,  Rainer Leppelt ,  Jörg Werner Münch ,  Jeffery Scott Rieck ,  Hubert Schedel ,  Duncan John William Winterborn ,  Todd Howard Ballinger ,  Julian Peter Cox

IPC分类号： F01N3/28 ,  B01J37/08 ,  B01J29/74 ,  B01J29/068 ,  B01D53/94

CPC分类号： B01D53/9413 ,  B01D53/9418 ,  B01D53/945 ,  B01D2255/20738 ,  B01D2255/20776 ,  B01D2255/9155 ,  B01J23/30 ,  B01J23/83 ,  B01J23/888 ,  B01J29/7415 ,  B01J29/7815 ,  B01J35/04 ,  B01J37/0009 ,  C04B35/50 ,  C04B35/63488 ,  C04B35/6365 ,  C04B35/803 ,  C04B35/82 ,  C04B38/0006 ,  C04B2111/00793 ,  C04B2111/0081 ,  C04B2235/3218 ,  C04B2235/322 ,  C04B2235/3229 ,  C04B2235/6021 ,  C04B2235/606 ,  F01N3/035 ,  Y02A50/2325 ,  Y02T10/22 ,  Y02T10/24 ,  Y10S55/30 ,  Y10T29/49345 ,  C04B38/0074

摘要： A three way catalyst comprises an extruded solid body comprising: 10-100% by weight of at least one binder/matrix component; 5-90% by weight of a zeolitic molecular sieve, a non-zeolitic molecular sieve or a mixture of any two or more thereof; and 0-80% by weight optionally stabilised ceria, which catalyst comprising at least one precious metal and optionally at least one non-precious metal, wherein: (i) the at least one precious metal is carried in one or more coating layer(s) on a surface of the extruded solid body; (ii) at least one metal is present throughout the extruded solid body and at least one precious metal is also carried in one or more coating layer(s) on a surface of the extruded solid body; or (iii) at least one metal is present throughout the extruded solid body, is present in a higher concentration at a surface of the extruded solid body and at least one precious metal is also carried in one or more coating layer(s) on the surface of the extruded solid body.

摘要翻译： 三元催化剂包括挤出固体，其包含：10-100重量％的至少一种粘合剂/基质组分; 5-90重量％的沸石分子筛，非沸石分子筛或其任何两种或更多种的混合物; 和0-80重量％的任选稳定的二氧化铈，所述催化剂包含至少一种贵金属和任选的至少一种非贵金属，其中：（i）所述至少一种贵金属在一个或多个涂层 ）在挤出的固体的表面上; （ii）至少一种金属存在于整个挤出的固体中，并且至少一种贵金属也被承载在挤出的固体的表面上的一个或多个涂层中; 或（iii）至少一种金属存在于整个挤出的固体中，在挤出的固体的表面上以更高的浓度存在，并且至少一种贵金属也被携带在一个或多个涂层上 挤压固体的表面。

公开(公告)号：US08603423B2

公开(公告)日：2013-12-10

申请号：US13384570

申请日：2011-02-01

申请人： Paul Joseph Andersen ,  Ralf Dotzel ,  Kwangmo Koo ,  Rainer Leppelt ,  Jörg Werner Münch ,  Jeffery Scott Rieck ,  Hubert Schedel ,  Duncan John William Winterborn ,  Todd Howard Ballinger ,  Julian Peter Cox

发明人： Paul Joseph Andersen ,  Ralf Dotzel ,  Kwangmo Koo ,  Rainer Leppelt ,  Jörg Werner Münch ,  Jeffery Scott Rieck ,  Hubert Schedel ,  Duncan John William Winterborn ,  Todd Howard Ballinger ,  Julian Peter Cox

IPC分类号： B01D53/94 ,  B01J23/10 ,  B01J29/06 ,  B01J29/068 ,  F01N3/10 ,  F01N3/28

CPC分类号： B01D53/9413 ,  B01D53/9418 ,  B01D53/945 ,  B01D2255/20738 ,  B01D2255/20776 ,  B01D2255/9155 ,  B01J23/30 ,  B01J23/83 ,  B01J23/888 ,  B01J29/7415 ,  B01J29/7815 ,  B01J35/04 ,  B01J37/0009 ,  C04B35/50 ,  C04B35/63488 ,  C04B35/6365 ,  C04B35/803 ,  C04B35/82 ,  C04B38/0006 ,  C04B2111/00793 ,  C04B2111/0081 ,  C04B2235/3218 ,  C04B2235/322 ,  C04B2235/3229 ,  C04B2235/6021 ,  C04B2235/606 ,  F01N3/035 ,  Y02A50/2325 ,  Y02T10/22 ,  Y02T10/24 ,  Y10S55/30 ,  Y10T29/49345 ,  C04B38/0074

摘要： A three way catalyst includes an extruded solid body having: 10-95% by weight of at least one binder/matrix component; 5-90% by weight of a zeolitic molecular sieve; and 0-80% by weight optionally stabilized ceria. The catalyst further includes at least one precious metal and optionally at least one non-precious metal. The at least one precious metal is carried in a coating layer on a surface of the extruded solid body; at least one metal is present throughout the extruded solid body and at least one precious metal is also carried in a coating layer on a surface of the extruded solid body; or at least one metal is present throughout the extruded solid body, is present in a higher concentration at a surface of the extruded solid body and at least one precious metal is also carried in a coating layer on the surface of the extruded solid body.

摘要翻译： 三元催化剂包括挤出固体，其具有：10-95重量％的至少一种粘合剂/基质组分; 5-90重量％的沸石分子筛; 和0-80重量％的任选稳定的二氧化铈。 催化剂还包括至少一种贵金属和任选的至少一种非贵金属。 所述至少一种贵金属在被挤出的固体的表面上的涂层中载带; 至少一种金属存在于整个挤出的固体中，并且至少一种贵金属也被承载在挤出的固体的表面上的涂层中; 或至少一种金属存在于整个挤出的固体中，在挤出的固体的表面上以更高的浓度存在，并且至少一种贵金属也被承载在挤出的固体的表面上的涂层中。

公开(公告)号：US06634169B1

公开(公告)日：2003-10-21

申请号：US09486486

申请日：2000-06-05

申请人： Paul Joseph Andersen ,  Todd Howard Ballinger ,  David Scott Lafyatis ,  Raj Rao Rajaram ,  Andrew Peter Walker

发明人： Paul Joseph Andersen ,  Todd Howard Ballinger ,  David Scott Lafyatis ,  Raj Rao Rajaram ,  Andrew Peter Walker

IPC分类号： F01N300

CPC分类号： F02D41/1475 ,  B01D53/9454 ,  B01D53/9495 ,  F01N3/0842 ,  F01N3/101 ,  F01N3/20 ,  F01N3/2013 ,  F01N3/22 ,  F01N13/009 ,  F01N13/0093 ,  F01N2260/04 ,  F01N2570/04 ,  F01N2610/03 ,  F02D41/024 ,  F02D41/027 ,  F02D41/028 ,  Y02A50/2324 ,  Y02T10/22 ,  Y02T10/26

摘要： A catalyst system includes a three-way catalyst (TWC) mounted underfloor and an engine management system programmed to initiate an enrichment of the exhaust gases exiting the engine with at least one of CO and hydrocarbons and to add secondary air to the exhaust gases in the exhaust passage upstream of the TWC. This periodic enrichment and addition of secondary air causes catalytic oxidation of the at least one of CO and hydrocarbons over the TWC thereby raising the underfloor TWC temperature to at least 550° C., preferably higher, in order to reduce sulphur poisoning of the catalyst and maintain the desired catalytic activity.

摘要翻译： 一种催化剂体系包括安装在地板下面的三元催化剂（TWC）和一种发动机管理系统，该发动机管理系统被编程为开始利用CO和烃中的至少一种来排出离开发动机的排气，并且在二氧化碳 排气通道在TWC上游。 这种二次空气的周期性富集和添加导致在TWC上的CO和烃中的至少一种的催化氧化，从而将地板下的TWC温度升高至至少550℃，优选更高，以便减少催化剂的硫中毒， 保持所需的催化活性。

公开(公告)号：US06617276B1

公开(公告)日：2003-09-09

申请号：US09621596

申请日：2000-07-21

申请人： Todd Howard Ballinger ,  Paul Joseph Andersen

发明人： Todd Howard Ballinger ,  Paul Joseph Andersen

IPC分类号： B01J2906

CPC分类号： B01D53/945 ,  B01D53/944 ,  B01D2255/1021 ,  B01D2255/1023 ,  B01D2255/1025 ,  B01D2255/204 ,  B01D2255/50 ,  B01D2255/912 ,  Y02A50/2324 ,  Y02T10/22

摘要： An active metal, particularly cesium, impregnated hydrocarbon adsorbent, such as zeolite, comprises an improved hydrocarbon trap/oxidizing catalyst for use in effectively adsorbing hydrocarbons during automotive cold-start and subsequently desorbing, oxidizing and removing hydrocarbons during warmer operating conditions. The active metal modified hydrocarbon adsorbent may be combined in other forms of multi-layer automotive exhaust gas catalytic structures.

摘要翻译： 活性金属，特别是铯，浸渍的烃类吸附剂，如沸石，包括一种改进的烃捕集器/氧化催化剂，用于在汽车冷启动期间有效吸附碳氢化合物，随后在较暖的运行条件下解吸，氧化和除去碳氢化合物。 活性金属改性烃类吸附剂可以以其它形式的多层汽车废气催化结构组合。

公开(公告)号：US08906820B2

公开(公告)日：2014-12-09

申请号：US13567705

申请日：2012-08-06

申请人： Joseph Michael Fedeyko ,  Rodney Kok Shin Foo ,  John Leonello Casci ,  Hai-Ying Chen ,  Paul Joseph Andersen ,  Jillian Elaine Collier ,  Raj Rao Rajaram

发明人： Joseph Michael Fedeyko ,  Rodney Kok Shin Foo ,  John Leonello Casci ,  Hai-Ying Chen ,  Paul Joseph Andersen ,  Jillian Elaine Collier ,  Raj Rao Rajaram

IPC分类号： B01J29/04 ,  B01J29/06 ,  B01J21/00 ,  B01J47/00 ,  B01D53/94 ,  B01J29/072 ,  B01J29/46 ,  B01J29/076 ,  B01J29/83 ,  B01J29/76 ,  B01J29/85 ,  B01J29/064 ,  B01J29/56 ,  B01J29/87

CPC分类号： B01D53/9418 ,  B01D53/565 ,  B01D53/8628 ,  B01D53/9431 ,  B01D53/945 ,  B01D2251/2062 ,  B01D2251/2067 ,  B01D2255/2065 ,  B01D2255/20738 ,  B01D2255/20761 ,  B01D2255/2092 ,  B01D2255/30 ,  B01D2255/50 ,  B01D2255/502 ,  B01D2255/504 ,  B01J29/005 ,  B01J29/061 ,  B01J29/064 ,  B01J29/072 ,  B01J29/076 ,  B01J29/46 ,  B01J29/56 ,  B01J29/72 ,  B01J29/76 ,  B01J29/7615 ,  B01J29/763 ,  B01J29/80 ,  B01J29/83 ,  B01J29/85 ,  B01J29/87 ,  B01J35/04 ,  B01J2029/062 ,  B01J2229/18 ,  B01J2229/183 ,  B01J2229/36 ,  C01B39/38 ,  C01B39/46 ,  C01B39/54 ,  Y02A50/2324 ,  Y02A50/2325 ,  Y02C20/10 ,  Y02T10/22 ,  Y02T10/24

摘要： A method of converting nitrogen oxides in a gas to nitrogen by contacting the nitrogen oxides with a nitrogenous reducing agent in the presence of a zeolite catalyst containing at least one transition metal, wherein the zeolite is a small pore zeolite containing a maximum ring size of eight tetrahedral atoms, wherein the at least one transition metal is selected from the group consisting of Cr, Mn, Fe, Co, Ce, Ni, Cu, Zn, Ga, Mo, Ru, Rh, Pd, Ag, In, Sn, Re, Ir and Pt.

摘要翻译： 在含有至少一种过渡金属的沸石催化剂存在下，通过使氮氧化物与含氮还原剂接触而将气体中的氮氧化物转化为氮的方法，其中沸石是含有最大环尺寸为8的小孔沸石 四面体原子，其中所述至少一种过渡金属选自Cr，Mn，Fe，Co，Ce，Ni，Cu，Zn，Ga，Mo，Ru，Rh，Pd，Ag，In，Sn，Re ，Ir和Pt。

公开(公告)号：US08753598B2

公开(公告)日：2014-06-17

申请号：US13959369

申请日：2013-08-05

申请人： Paul Joseph Andersen ,  Hai-Ying Chen ,  Joseph Michael Fedeyko ,  Erich Weigert

发明人： Paul Joseph Andersen ,  Hai-Ying Chen ,  Joseph Michael Fedeyko ,  Erich Weigert

IPC分类号： B01D53/56 ,  B01D53/86 ,  B01D53/94 ,  F01N3/28

CPC分类号： B01D53/9418 ,  B01D53/56 ,  B01D53/8628 ,  B01D53/9431 ,  B01D53/9481 ,  B01D2251/2062 ,  B01D2253/1122 ,  B01D2255/20738 ,  B01D2255/20761 ,  B01D2255/50 ,  B01D2255/9202 ,  B01D2258/012 ,  B01J29/072 ,  B01J29/76 ,  B01J29/763 ,  B01J29/85 ,  Y02E50/12 ,  Y02T10/24

摘要： A method of using a catalyst comprises exposing a catalyst to at least one reactant in a chemical process. The catalyst comprises copper and a small pore molecular sieve having a maximum ring size of eight tetrahedral atoms. The chemical process undergoes at least one period of exposure to a reducing atmosphere. The catalyst has an initial activity and the catalyst has a final activity after the at least one period of exposure to the reducing atmosphere. The final activity is within 30% of the initial activity at a temperature between 200 and 500° C.

摘要翻译： 使用催化剂的方法包括在化学方法中将催化剂暴露于至少一种反应物。 催化剂包括铜和最大环尺寸为八面体原子的小孔分子筛。 化学过程经历至少一个暴露于还原气氛的时期。 催化剂具有初始活性，并且在暴露于还原气氛的至少一个时间段之后催化剂具有最终活性。 最终活性在200-500℃之间的初始活性的30％以内。

公开(公告)号：US08263032B2

公开(公告)日：2012-09-11

申请号：US13384568

申请日：2011-02-01

申请人： Paul Joseph Andersen ,  Todd Ballinger ,  David Bergeal ,  Hsiao-Lan Chang ,  Hai-Ying Chen ,  Julian Cox ,  Ralf Dotzel ,  Rainer Leppelt ,  Jörg Werner Münch ,  Hubert Schedel ,  Duncan John William Winterborn

发明人： Paul Joseph Andersen ,  Todd Ballinger ,  David Bergeal ,  Hsiao-Lan Chang ,  Hai-Ying Chen ,  Julian Cox ,  Ralf Dotzel ,  Rainer Leppelt ,  Jörg Werner Münch ,  Hubert Schedel ,  Duncan John William Winterborn

IPC分类号： B01D53/94 ,  B01J29/00 ,  B01J35/00 ,  B01J35/04 ,  F01N3/10 ,  F01N3/28

CPC分类号： B01D53/9413 ,  B01D53/9418 ,  B01D53/945 ,  B01D2255/20738 ,  B01D2255/20776 ,  B01D2255/9155 ,  B01J23/30 ,  B01J23/83 ,  B01J23/888 ,  B01J29/7415 ,  B01J29/7815 ,  B01J35/04 ,  B01J37/0009 ,  C04B35/50 ,  C04B35/63488 ,  C04B35/6365 ,  C04B35/803 ,  C04B35/82 ,  C04B38/0006 ,  C04B2111/00793 ,  C04B2111/0081 ,  C04B2235/3218 ,  C04B2235/322 ,  C04B2235/3229 ,  C04B2235/6021 ,  C04B2235/606 ,  F01N3/035 ,  Y02A50/2325 ,  Y02T10/22 ,  Y02T10/24 ,  Y10S55/30 ,  Y10T29/49345 ,  C04B38/0074

摘要： An oxidation catalyst comprises an extruded solid body comprising: 10-95% by weight of at least one binder/matrix component; 5-90% by weight of a zeolitic molecular sieve, a non-zeolitic molecular sieve or a mixture of any two or more thereof; and 0-80% by weight optionally stabilized ceria, which catalyst comprising at least one precious metal and optionally at least one non-precious metal, wherein: (i) a majority of the at least one precious metal is located at a surface of the extruded solid body; (ii) the at least one precious metal is carried in one or more coating layer(s) on a surface; (iii) at least one metal is present throughout the extruded solid body and in a higher concentration at a surface; (iv) at least one metal is present throughout the extruded solid body and in a coating layer(s) on a surface; or (v) a combination of (ii) and (iii).

摘要翻译： 氧化催化剂包括挤出的固体，其包含：10-95重量％的至少一种粘合剂/基质组分; 5-90重量％的沸石分子筛，非沸石分子筛或其任何两种或更多种的混合物; 和0-80重量％的任选稳定的二氧化铈，所述催化剂包含至少一种贵金属和任选的至少一种非贵金属，其中：（i）所述至少一种贵金属的大部分位于 挤出固体; （ii）所述至少一种贵金属在表面的一个或多个涂层中承载; （iii）至少一种金属存在于整个挤出的固体中并且在表面上的浓度较高; （iv）至少一种金属存在于挤出的固体物体和表面上的涂层中; 或（v）（ii）和（iii）的组合。

公开(公告)号：US20120122660A1

公开(公告)日：2012-05-17

申请号：US13384568

申请日：2011-02-01

申请人： Paul Joseph Andersen ,  Todd Ballinger ,  David Bergeal ,  Hsiao-Lan Chang ,  Hai-Ying Chen ,  Julian Cox ,  Ralf Dotzel ,  Rainer Leppelt ,  Jörg Werner Münch ,  Hubert Schedel ,  Duncan John William Winterborn

发明人： Paul Joseph Andersen ,  Todd Ballinger ,  David Bergeal ,  Hsiao-Lan Chang ,  Hai-Ying Chen ,  Julian Cox ,  Ralf Dotzel ,  Rainer Leppelt ,  Jörg Werner Münch ,  Hubert Schedel ,  Duncan John William Winterborn

IPC分类号： B01J29/04 ,  F01N3/28 ,  B01J29/03 ,  B01J35/02 ,  B01D53/94 ,  B01J37/04

CPC分类号： B01D53/9413 ,  B01D53/9418 ,  B01D53/945 ,  B01D2255/20738 ,  B01D2255/20776 ,  B01D2255/9155 ,  B01J23/30 ,  B01J23/83 ,  B01J23/888 ,  B01J29/7415 ,  B01J29/7815 ,  B01J35/04 ,  B01J37/0009 ,  C04B35/50 ,  C04B35/63488 ,  C04B35/6365 ,  C04B35/803 ,  C04B35/82 ,  C04B38/0006 ,  C04B2111/00793 ,  C04B2111/0081 ,  C04B2235/3218 ,  C04B2235/322 ,  C04B2235/3229 ,  C04B2235/6021 ,  C04B2235/606 ,  F01N3/035 ,  Y02A50/2325 ,  Y02T10/22 ,  Y02T10/24 ,  Y10S55/30 ,  Y10T29/49345 ,  C04B38/0074

摘要： An oxidation catalyst comprises an extruded solid body comprising: 10-95% by weight of at least one binder/matrix component; 5-90% by weight of a zeolitic molecular sieve, a non-zeolitic molecular sieve or a mixture of any two or more thereof; and 0-80% by weight optionally stabilised ceria, which catalyst comprising at least one precious metal and optionally at least one non-precious metal, wherein: (i) a majority of the at least one precious metal is located at a surface of the extruded solid body; (ii) the at least one precious metal is carried in one or more coating layer(s) on a surface; (iii) at least one metal is present throughout the extruded solid body and in a higher concentration at a surface; (iv) at least one metal is present throughout the extruded solid body and in a coating layer(s) on a surface; or (v) a combination of (ii) and (iii).

摘要翻译： 氧化催化剂包括挤出的固体，其包含：10-95重量％的至少一种粘合剂/基质组分; 5-90重量％的沸石分子筛，非沸石分子筛或其任何两种或更多种的混合物; 和0-80重量％的任选稳定的二氧化铈，所述催化剂包含至少一种贵金属和任选的至少一种非贵金属，其中：（i）所述至少一种贵金属的大部分位于 挤出固体; （ii）所述至少一种贵金属在表面的一个或多个涂层中承载; （iii）至少一种金属存在于整个挤出的固体中并且在表面上的浓度较高; （iv）至少一种金属存在于挤出的固体物体和表面上的涂层中; 或（v）（ii）和（iii）的组合。

公开(公告)号：US07682583B2

公开(公告)日：2010-03-23

申请号：US10878240

申请日：2004-06-28

申请人： Kwangmo Koo ,  Paul Joseph Andersen

发明人： Kwangmo Koo ,  Paul Joseph Andersen

IPC分类号： B01D53/00

CPC分类号： B01J23/78 ,  B01D53/9422 ,  B01D53/944 ,  B01D53/945 ,  B01D2255/1021 ,  B01D2255/2022 ,  B01D2255/20746 ,  B01D2255/91 ,  Y02T10/22

摘要： A process and composition for converting nitrogen oxides present in exhaust gases produced by an internal combustion engine utilize cobalt and at least one alkali metal or alkaline earth metal as a component of an adsorbent. The process involves contacting the exhaust gas with an adsorbent which adsorbs the nitrogen oxides in lean-burn conditions and recurrently reducing the oxygen concentration of the exhaust gas. During such periods of reduced oxygen concentration, the nitrogen oxides are then desorbed and reduced to nitrogen, thereby reducing the concentration of the nitrogen oxides in the exhaust gas. The composition of the adsorbent comprises an oxide support and at least two components loaded on the support and containing cobalt and at least one alkali metal or alkaline earth metal. The composition demonstrates improved activity at higher temperatures and improved thermal stability.

摘要翻译： 用于转化由内燃机产生的废气中存在的氮氧化物的方法和组合物使用钴和至少一种碱金属或碱土金属作为吸附剂的组分。 该方法包括使废气与在贫燃条件下吸附氮氧化物的吸附剂接触并且循环地降低废气的氧浓度。 在氧浓度降低的时期，氮氧化物然后解吸并还原成氮气，从而降低排气中氮氧化物的浓度。 吸附剂的组成包括氧化物载体和负载在载体上并含有钴和至少一种碱金属或碱土金属的至少两种组分。 该组合物显示出在较高温度下改善的活性和改善的热稳定性。

公开(公告)号：US08347614B2

公开(公告)日：2013-01-08

申请号：US13462379

申请日：2012-05-02

申请人： Paul Joseph Andersen ,  Hai-Ying Chen ,  Joseph Michael Fedeyko ,  Erich Weigert

发明人： Paul Joseph Andersen ,  Hai-Ying Chen ,  Joseph Michael Fedeyko ,  Erich Weigert

IPC分类号： F01N3/10

CPC分类号： B01D53/9418 ,  B01D53/56 ,  B01D53/8628 ,  B01D53/9431 ,  B01D53/9481 ,  B01D2251/2062 ,  B01D2253/1122 ,  B01D2255/20738 ,  B01D2255/20761 ,  B01D2255/50 ,  B01D2255/9202 ,  B01D2258/012 ,  B01J29/072 ,  B01J29/76 ,  B01J29/763 ,  B01J29/85 ,  Y02E50/12 ,  Y02T10/24

摘要： A method of using a catalyst comprises exposing a catalyst to at least one reactant in a chemical process. The catalyst comprises copper and a small pore molecular sieve having a maximum ring size of eight tetrahedral atoms. The chemical process undergoes at least one period of exposure to a reducing atmosphere. The catalyst has an initial activity and the catalyst has a final activity after the at least one period of exposure to the reducing atmosphere. The final activity is within 30% of the initial activity at a temperature between 200 and 500° C.