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公开(公告)号：US5171869A
公开(公告)日：1992-12-15
申请号：US825222
申请日：1992-01-24
IPC分类号： C07D303/27 , C07C39/225 , C07D303/24 , C08F290/00 , C08F299/02 , C08G8/08 , C08G8/24 , C08G8/36 , C08G59/08 , C08G59/32
CPC分类号： C07D303/24 , C08G59/3218 , C08G8/08
摘要： A naphthalene of the following formula (1) having at least two allyl or propenyl groups ##STR1## wherein each G represents a hydrogen atoms or ##STR2## R.sup.1 's independently represent a hydrogen atom or an unsubstituted or substituted monovalent hydrocarbon group having from 1 to 6 carbon atoms, R.sup.2 's independently represent a hydrogen atom, an allyl group or a propenyl group, R.sup.3 represents an allyl group or a propenyl group, X represents a hydrogen atom or a halogen atom, and n is an integer of from 0 to 6. The derivative is useful for modifying curable resins or resin compositions to provide cured products which have a low water absorption, high strength and a high glass transition temperature. The derivative has good working properties and a good heat resistance.
摘要翻译： 具有至少两个烯丙基或丙烯基的下式（1）的萘，其中每个G表示氢原子，或者R 1独立地表示氢原子或未取代或取代的一价烃基，其具有 1〜6个碳原子，R2独立地表示氢原子，烯丙基或丙烯基，R3表示烯丙基或丙烯基，X表示氢原子或卤素原子，n表示0〜 该衍生物可用于改性可固化树脂或树脂组合物以提供具有低吸水性，高强度和高玻璃化转变温度的固化产物。 该衍生物具有良好的加工性能和良好的耐热性。
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公开(公告)号：US5290882A
公开(公告)日：1994-03-01
申请号：US928064
申请日：1992-08-11
申请人： Toshio Shiobara , Hisashi Shimizu , Manabu Narumi
发明人： Toshio Shiobara , Hisashi Shimizu , Manabu Narumi
IPC分类号： C08G59/32 , C08G59/40 , C08G77/42 , C08L61/06 , C08L63/00 , C08L79/08 , C08L83/04 , C08L63/04 , C08L63/10
CPC分类号： C08L61/06 , C08G59/3218 , C08G59/4042 , C08G77/42 , C08L63/00 , C08L79/08 , C08L83/04
摘要： A thermosetting resin composition contains (A) an imide compound having a maleimide group, (B) an epoxy resin, (C) a phenolic resin, and optionally, (D) an aromatic polymer/organopolysiloxane copolymer. Component (B) and/or (C) includes a compound containing a naphthalene ring having an allyl group and preferably, a compound containing a naphthalene ring and a double bond conjugated with an aromatic ring. The composition is easily workable and cures to products having improved heat resistance, low thermal expansion, and low water absorption.
摘要翻译： 热固性树脂组合物含有（A）具有马来酰亚胺基团的酰亚胺化合物，（B）环氧树脂，（C）酚醛树脂和任选的（D）芳族聚合物/有机聚硅氧烷共聚物。 组分（B）和/或（C）包括含有具有烯丙基的萘环的化合物，优选含有萘环和与芳环共轭的双键的化合物。 该组合物易于加工并固化成具有改善的耐热性，低热膨胀性和低吸水性的产品。
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公开(公告)号：US5243058A
公开(公告)日：1993-09-07
申请号：US824967
申请日：1992-01-24
IPC分类号： C07C39/225 , C07C43/215 , C07D303/24 , C08G59/24 , C08G59/32 , C08G59/40
CPC分类号： C07C43/215 , C07C39/225 , C07D303/24 , C08G59/245 , C08G59/3218 , C08G59/4042
摘要： A naphthalene derivative of the following general formula (1) having at least one allyl or propenyl group is described. ##STR1## In the formula, each G represents a hydrogen atoms or ##STR2## R.sup.1 's independently represent a hydrogen atom, an allyl group or a propenyl group provided that at least one or R.sup.1 's is an allyl group or a propenyl group, and R.sup.2 's independently represent a hydrogen atom, an unsubstituted or substituted monovalent hydrocarbon group having from 1 to 6 carbon atoms, or a halogen atom. The derivative is useful for modifying curable resins or resin compositions to provide cured products which have a low water absorption, high strength and a high glass transition temperature. The derivative has good working properties and a good heat resistance.
摘要翻译： 描述了具有至少一个烯丙基或丙烯基的下述通式（1）的萘衍生物。 （1）在该式中，每个G表示氢原子，或者如果至少一个或R 1为烯丙基或丙烯基，则R 1独立地表示氢原子，烯丙基或丙烯基， 并且R 2独立地表示氢原子，具有1至6个碳原子的未取代或取代的一价烃基或卤素原子。 该衍生物可用于改性可固化树脂或树脂组合物以提供具有低吸水性，高强度和高玻璃化转变温度的固化产物。 该衍生物具有良好的加工性能和良好的耐热性。
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4.发明授权
公开(公告)号：US5306748A
公开(公告)日：1994-04-26
申请号：US921251
申请日：1992-07-29
申请人： Toshio Shiobara , Hisashi Shimizu , Manabu Narumi
发明人： Toshio Shiobara , Hisashi Shimizu , Manabu Narumi
CPC分类号： C08L61/06 , C08G59/08 , C08G59/3218 , C08G59/3254 , C08G8/08 , C08L63/00
摘要： Fluorine-modified thermosetting reins are available as phenolic or epoxy resins having trifluoromethyl groups and a naphthalene skeleton in a molecule. They are useful as components of resin compositions or resin modifiers and cure to products having low water pickup, low coefficient of thermal expansion, and adhesion as well as heat resistance and mechanical strength. Thermosetting resin compositions having such a thermosetting resin blended therein are useful in semiconductor element packaging.
摘要翻译： 氟改性的热固性榫头可以作为分子中具有三氟甲基和萘骨架的酚醛树脂或环氧树脂来获得。 它们可用作树脂组合物或树脂改性剂的组分，并且固化成具有低吸水率，低热膨胀系数和粘合性以及耐热性和机械强度的产品。 具有这样的热固性树脂的热固性树脂组合物可用于半导体元件封装。
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公开(公告)号：US5610230A
公开(公告)日：1997-03-11
申请号：US561938
申请日：1995-11-22
申请人： Takeo Yoshida , Manabu Narumi
发明人： Takeo Yoshida , Manabu Narumi
摘要： A liquid silicone rubber composition contains (A) an organopolysiloxane having at least two alkenyl groups, (B) a reinforcing silica filler, (C) a condensation catalyst, (D) a silanol group-containing siloxane wetter, (E) an organohydrogenpolysiloxane having at least two hydrogen atoms, and (F) a platinum catalyst. Components (C) and (D) assist in blending a large amount of the silica filler in the composition. The composition is smoothly flowing, quickly curable and suitable for injection molding.
摘要翻译： 液体硅橡胶组合物含有（A）具有至少两个烯基的有机聚硅氧烷，（B）增强二氧化硅填料，（C）缩合催化剂，（D）含硅烷醇基的硅氧烷润湿剂，（E）有机氢聚硅氧烷， 至少两个氢原子，和（F）铂催化剂。 组分（C）和（D）有助于在组合物中混合大量的二氧化硅填料。 组合物流畅，快速固化，适合注射成型。
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6.发明授权Integrally molded automotive waterproof connector comprising thermoplastic resin and oil-bleeding silicone rubber 失效整体模制汽车防水连接器，包括热塑性树脂和出油硅橡胶
公开(公告)号：US5989704A
公开(公告)日：1999-11-23
申请号：US766963
申请日：1996-12-16
申请人： Hiroshi Hashimoto , Masahiro Kanda , Shigeru Muramatsu , Naoto Obayashi , Hironao Fujiki , Shigeki Shudo , Manabu Narumi
发明人： Hiroshi Hashimoto , Masahiro Kanda , Shigeru Muramatsu , Naoto Obayashi , Hironao Fujiki , Shigeki Shudo , Manabu Narumi
IPC分类号： F16L21/02 , B32B25/20 , C08K3/36 , C08K5/54 , C08K5/5419 , C08L67/06 , C08L69/00 , C08L83/05 , C08L83/07 , H01R13/52 , H01R43/18 , B32B5/16 , B32B27/36
CPC分类号： H01R43/18 , C08L67/06 , C08L69/00 , H01R13/5216 , Y10T428/259 , Y10T428/31507 , Y10T428/31667
摘要： An integrally molded automotive waterproof connector is disclosed which comprises a thermoplastic resin and integrated therewith an oil-bleeding silicone rubber, the thermoplastic resin containing a thermoplastic resin oligomer containing at least one aliphatic unsaturated group. In the connector, the adhesion between the thermoplastic resin and the silicone rubber is satisfactory regardless of the length of storage period as compared with connectors comprising a thermoplastic resin and a silicone rubber integrated therewith after priming. Further, the connector of the present invention is excellent in production efficiency and workability, is reduced in connector housing fitting force, and can retain satisfactory waterproofness.
摘要翻译： 公开了一种整体模制的汽车防水连接器，其包括热塑性树脂并与其一体的止油硅橡胶，该热塑性树脂含有含有至少一个脂族不饱和基团的热塑性树脂低聚物。 在连接器中，热封树脂和硅橡胶之间的粘附性与包含热塑性树脂的连接器和在起动之后与其一体化的硅橡胶相比，与储存周期长度无关，是令人满意的。 此外，本发明的连接器的生产效率和加工性优异，连接器壳体配合力降低，能够保持良好的防水性。
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公开(公告)号：US5908592A
公开(公告)日：1999-06-01
申请号：US965488
申请日：1997-11-06
申请人： Kenichi Kimura , Takeo Yoshida , Manabu Narumi , Masaya Arakawa
发明人： Kenichi Kimura , Takeo Yoshida , Manabu Narumi , Masaya Arakawa
IPC分类号： C08J3/20 , C08J3/22 , C08K3/36 , C08K5/54 , C08K5/5419 , C08L83/04 , C08L83/05 , C08L83/07 , B29C47/40 , B29C47/76 , C08K5/24
CPC分类号： C08J3/226 , C08K3/36 , C08K5/5419 , C08L83/04 , C08G77/06 , C08G77/12 , C08G77/20 , C08J2383/04 , C08J2483/00
摘要： A liquid silicone rubber base including (A) an alkenyl-containing organopolysiloxane, (B) a reinforcing silica filler, (C) a mixing assistant in the form of a silanol-containing compound, (E) an organohydrogen polysiloxane, (f) a platinum catalyst and optionally, (D) a wetting auxiliary catalyst is prepared by previously mixing 10-120 parts of component (A) with 1-35 parts of component (C) and 0-35 parts of component (D) to form a premix liquid, mixing the premix liquid with 100 parts of component (B) to form a premix power, and kneading the premix powder with the remainder of component (A). By adding a curing agent of organohydrogenpolysiloxane/platinum catalyst to the liquid silicone rubber base, there is obtained a liquid silicone rubber composition having improved fatigue endurance.
摘要翻译： 一种液体硅橡胶基质，其包含（A）含烯基的有机基聚硅氧烷，（B）增强二氧化硅填料，（C）含硅烷醇化合物形式的混合助剂，（E）有机氢聚硅氧烷，（f） 通过预先将10-120份组分（A）与1-35份组分（C）和0-35份组分（D）混合来制备（D）润湿助催化剂，以形成预混物 将预混合液与100份组分（B）混合以形成预混合动力，并将预混合粉末与组分（A）的其余部分捏合。 通过向液体硅橡胶基体中加入有机氢聚硅氧烷/铂催化剂的固化剂，得到具有改善的耐疲劳性的液体硅橡胶组合物。
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公开(公告)号：US5498660A
公开(公告)日：1996-03-12
申请号：US360094
申请日：1994-12-20
申请人： Masaharu Takahashi , Manabu Narumi
发明人： Masaharu Takahashi , Manabu Narumi
IPC分类号： C08L83/05 , C08K5/5419 , C08L83/04 , C08L83/07 , C08K5/04
CPC分类号： C08K5/5419 , C08L83/04 , C08G77/12 , C08G77/20
摘要： To a silicone rubber composition including (A) a diorganopolysiloxane having an aliphatic unsaturated hydrocarbon group, (B) an organohydrogenpolysiloxane having at least two SiH groups in a molecule, and (C) a platinum catalyst, is added (D) an organic silicon compound of the following general formula (2): ##STR1## wherein R.sup.2, R.sup.5, and R.sup.6 are independently selected from monovalent hydrocarbon groups free of an aliphatic unsaturated bond, R.sup.3 is a monovalent hydrocarbon group, R.sup.4 is hydrogen or methyl, and n is an integer of 0 to 3. The composition has a long pot life after addition of curing components (B) and (C) and is extrusion moldable into bubble-free transparent parts. The composition is prepared by mixing component (A) with components (B) and (C) while adding component (D) thereto.
摘要翻译： 对于包含（A）具有脂族不饱和烃基的二有机聚硅氧烷，（B）分子中具有至少两个SiH基的有机氢聚硅氧烷和（C）铂催化剂）的硅橡胶组合物，（D）有机硅化合物 （2）其中R 2，R 5和R 6独立地选自不含脂族不饱和键的一价烃基，R 3是一价烃基，R 4是氢或甲基，和 n为0〜3的整数。该组合物在添加固化成分（B）和（C）后具有长的适用期，并且可挤出成型为无气泡透明部分。 通过将组分（A）与组分（B）和（C）混合同时向其中加入组分（D）来制备组合物。
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