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公开(公告)号：US07459019B2
公开(公告)日：2008-12-02
申请号：US10504772
申请日：2003-02-14
IPC分类号： C04B7/02
CPC分类号： C04B28/02 , C04B14/106 , C04B40/0032 , C04B2111/00146 , C04B2111/56 , C04B2111/763 , C09K8/46 , Y02W30/92 , C04B20/008 , C04B28/04 , C04B28/06 , C04B14/062 , C04B18/08 , C04B20/0036
摘要： In a process to design high temperature cement sluries, the temperature stable phases (anorthite, wairakite) are selected; aluminum modifiers and silica oxides are added to the dry cement so that the elemental composition of the blend corresponds to the phases selected; the control of the particle size distribution and the relative amount of those minerals allow their addition at high concentration while leaving the slurry easily mixable and pumpable; and the kinetics of the targeted phases formation is then controlled by adjusting the crystallinity and the particles sizes of the different solids.
摘要翻译： 在设计高温水泥泥浆的过程中，选择温度稳定相（钙长石，白云石）; 将铝改性剂和二氧化硅氧化物加入到干燥水泥中，使得共混物的元素组成对应于所选择的相; 颗粒尺寸分布的控制和这些矿物质的相对量允许它们以高浓度添加，同时使浆料易于混合和可泵送; 然后通过调节不同固体的结晶度和颗粒尺寸来控制目标相形成的动力学。
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公开(公告)号：US07530408B2
公开(公告)日：2009-05-12
申请号：US10597049
申请日：2005-01-04
CPC分类号： E21B33/138 , C09K8/5083 , C09K8/512 , C09K8/5753 , C09K8/5756 , E21B2043/0115
摘要： A method of stabilizing an underground formation surrounding a borehole comprising placing a treatment fluid in the formation, the treatment fluid comprising cross-linkable polymer and a cross-linking agent, and allowing the treatment fluid to gel in-situ, characterized in that after placement of the treatment fluid in the formation, an activator fluid is pumped into the well to bring about cross linking of the polymer to form the gel.
摘要翻译： 一种稳定围绕钻孔的地下地层的方法，包括将处理流体放置在地层中，处理流体包括可交联聚合物和交联剂，并使处理流体原位凝胶化，其特征在于在放置之后 的地层中的处理流体，将活化剂流体泵送到井中以引起聚合物的交联以形成凝胶。
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3.发明授权Cementing composition and application of such compositions for cementing oil wells or the like 有权用于固井油井等的这种组合物的水泥组合物和应用公开(公告)号：US06911078B2
公开(公告)日：2005-06-28
申请号：US10239459
申请日：2001-03-21
CPC分类号： C09K8/46 , C04B7/00 , C04B28/04 , C04B14/062 , C04B14/303 , C04B20/008
摘要： The present invention concerns cementing compositions for an oil well or the like, based on a Portland cement, silica and alumina, wherein the mineralogical composition of the cement matrix is included in the Si—Ca—Al triangle in one of the margarite-haüyne-[epidote/pumpellyite], haüyne-prehnite-[epidote/pumpellyite] and haüyne-prehnite-pectolite composition triangles. More particularly, the cementing compositions of the invention are suitable for cementing wells subjected to high temperatures and to chemical attack by brines, and are more suitable when the brine—or a saline formulation close to that of the brine—is used as the mixing water.
摘要翻译： 本发明涉及一种基于波特兰水泥，二氧化硅和氧化铝的油井等的固井组合物，其中水泥基质的矿物组合物包含在其中一种玛格丽特 - 海因 - [表皮/泵石]，haenyne-preneite- [epidote / pumpilyite]和haynyne-preneite-pectolite组成三角形。 更具体地说，本发明的固井组合物适用于固井受高温的井和盐水的化学侵蚀，并且当将盐水或接近盐水的盐水配方用作混合水时更合适 。
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公开(公告)号：US07449061B2
公开(公告)日：2008-11-11
申请号：US10595435
申请日：2004-10-26
IPC分类号： C04B7/13
CPC分类号： C04B28/04 , C04B7/345 , C04B2111/00215 , C04B2111/28 , C04B14/041 , C04B14/043 , C04B14/06 , C04B20/0076 , C04B38/08 , C04B40/0263
摘要： A method of designing a cement composition comprises determination of the temperature to which the composition will be exposed in situ; determination of a stable, thermodynamic equilibrium composition of a CaO—Al2O3—SiO2—H2O (CASH) mineral system in the [xonotlite/wollastonite]-grossulaire-anorthite or grossulaire-anorthite-quartz triangles of the Si—Ca—Al phase diagram with a possible contribution of iron and/or magnesium, analogous to the cement when set, at the determined temperature; determining proportions of cement and mineral oxides required to provide a mixture having the determined composition; and defining a series of particulate materials of predetermined particle sizes and densities, comprising cement and mineral oxides in the determined proportions.
摘要翻译： 一种设计水泥组合物的方法包括测定组合物将在其上原地暴露的温度; 测定CaO-Al 2 O 3 -SiO 2 H 2 -SiO 2的稳定的热力学平衡组成， O（CASH）矿物系统在Si-Ca-Al相图的[xonotlite /硅灰石] - 石榴 - 钙长石或粗铜 - 长石 - 三角形中，具有铁和/或镁的可能贡献，类似于当凝固时的水泥 ，在确定的温度下; 确定提供具有确定组成的混合物所需的水泥和矿物氧化物的比例; 并且确定一系列具有预定粒度和密度的颗粒材料，其包含所确定比例的水泥和矿物氧化物。
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公开(公告)号：US08091642B2
公开(公告)日：2012-01-10
申请号：US12067823
申请日：2006-09-25
IPC分类号： E21B33/13
CPC分类号： E21B41/0064 , C04B28/02 , C04B28/08 , C04B2111/00146 , C04B2111/22 , C09K8/467 , Y02C10/14 , Y02W30/92 , Y02W30/94 , C04B14/06 , C04B14/106 , C04B14/24 , C04B18/082 , C04B18/141 , C04B20/0036 , C04B38/10 , C04B40/0236 , C04B14/062 , C04B20/0076 , C04B2103/20 , C04B2103/408
摘要： A cement composition resistant to carbon dioxide includes a hollow element for trapping carbonation products. The hollow element can be hollow spherical or quasi spherical particles including cenospheres, sodium-calcium-borosilicate glass microspheres, silica-alumina microspheres, or a combination thereof. Or the hollow element may be a spherical or quasi spherical void made in the set cement, for example by foaming the cement composition with a gas such as air, nitrogen or a combination thereof. The composition may be used to cement a subterranean well in which carbon dioxide is injected, stored or produced.
摘要翻译： 耐二氧化碳的水泥组合物包括用于捕获碳酸化产物的中空元件。 中空元件可以是中空球形或准球形颗粒，包括空心球体，钠 - 钙 - 硼硅酸盐玻璃微球体，二氧化硅 - 氧化铝微球体或其组合。 或者中空元件可以是在固化水泥中制成的球形或准球形空隙，例如通过用诸如空气，氮气或其组合的气体使水泥组合物发泡。 该组合物可以用于水泥注入，储存或生产二氧化碳的地下井。
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公开(公告)号：US07846250B2
公开(公告)日：2010-12-07
申请号：US11462731
申请日：2006-08-07
IPC分类号： C04B16/08
CPC分类号： C09K8/42 , C04B28/006 , C04B28/26 , C04B2103/0067 , C04B2111/00146 , C04B2111/00215 , C04B2111/22 , C09K8/46 , C09K8/467 , Y02C10/14 , Y02P20/544 , Y02P40/165 , Y02P40/18 , Y02W30/92 , Y02W30/94 , Y10S106/01 , C04B12/04 , C04B14/047 , C04B22/0013 , C04B22/0093 , C04B40/0231 , C04B14/106 , C04B2103/12 , C04B2103/22 , C04B18/08 , C04B20/10 , C04B22/16 , C04B2103/0008 , C04B18/146 , C04B22/062 , C04B24/18 , C04B14/10 , C04B14/18 , C04B18/141
摘要： The invention provides geopolymeric compositions intended for use in carbon dioxide injection or production wells or storage reservoirs and preferably in a supercritical carbon dioxide conditions. The geopolymeric composition is formed from a suspension comprising an aluminosilicate source, a metal silicate, an alkali activator, a retarder and/or an accelerator and a carrier fluid wherein the oxide molar ratio M2O/SiO2 is greater than 0.20 with M an alkali metal.
摘要翻译： 本发明提供旨在用于二氧化碳注入或生产井或储存储存器，优选在超临界二氧化碳条件下的地质聚合物组合物。 地质聚合物组合物由含有硅铝酸盐源，金属硅酸盐，碱活化剂，缓凝剂和/或促进剂的载体和载体流体形成，其中M为碱金属的氧化物摩尔比M 2 O / SiO 2大于0.20。
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公开(公告)号：US06511537B1
公开(公告)日：2003-01-28
申请号：US09623374
申请日：2000-10-20
IPC分类号： C04B1400
CPC分类号： C04B28/02 , C04B22/16 , C04B24/003 , C04B40/0039 , C04B2103/20 , C04B2103/22 , C09K8/46 , C04B24/18 , C04B24/06 , C04B24/14 , C04B24/38
摘要： Systems for retarding setting in an oilfield well cement slurry comprise a solution of a phosphonate selected from methylene phosphonic acid derivatives and a phosphate, in particular selected from the following salts or the corresponding acids: mono-phosphates (ortho-phosphates PO42; meta-phosphates PO3), acyclic poly-phosphates (pyrophosphates P2O74, tripolyphosphates P3O105) or cyclic poly-phosphates. The system preferably may also comprise a retarder booster and is more particularly applicable to cementing at low or medium temperatures.
摘要翻译： 用于在油田井水泥浆中延迟凝固的系统包括选自亚甲基膦酸衍生物和磷酸盐的膦酸盐溶液，特别是选自以下盐或相应的酸：单磷酸盐（正磷酸盐PO42;偏磷酸盐 PO 3），无环多磷酸盐（焦磷酸盐P2O74，三聚磷酸盐P3O105）或环状聚磷酸盐。 该系统优选地还可以包括缓凝剂助剂，并且更特别适用于在低或中等温度下固化。
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公开(公告)号：US07794537B2
公开(公告)日：2010-09-14
申请号：US11462724
申请日：2006-08-07
IPC分类号： C04B16/08
CPC分类号： C04B28/006 , C04B2103/10 , C04B2103/20 , C04B2111/00146 , C04B2111/00215 , C09K8/467 , Y02P40/165 , Y02W30/92 , Y02W30/94 , Y10S106/01 , C04B14/047 , C04B20/002 , C04B22/062 , C04B38/10 , C04B2103/34 , C04B2103/408 , C04B2103/46 , C04B2103/50 , C04B14/10 , C04B14/365 , C04B18/023 , C04B18/082 , C04B40/0633 , C04B2103/0008 , C04B22/0013 , C04B22/16 , C04B24/06 , C04B24/18 , C04B14/22 , C04B14/301 , C04B14/305 , C04B18/141 , C04B18/146 , C04B38/103
摘要： The invention provides geopolymeric compositions, which have controllable thickening and setting times for a wide range of temperatures and a large range of geopolymer slurry densities. The geopolymer slurry compositions have good mixability and pumpability, while the set materials develop good compressive strength and permeability. The invention discloses a method for preparing geopolymer for oilfield cementing applications. The geopolymeric compositions according to the invention comprises a suspension comprising an aluminosilicate source, a metal silicate, an alkali activator, lightweight or heavyweight fillers and a carrier fluid wherein the suspension of said geopolymeric composition is pumped in a well and allowed to set.
摘要翻译： 本发明提供了地质聚合物组合物，其在宽范围的温度和大范围的地质聚合物浆料密度下具有可控的增稠和凝固时间。 地质聚合物浆料组合物具有良好的混合性和可泵送性，而集合材料形成良好的抗压强度和渗透性。 本发明公开了一种制备用于油田胶结应用的地质聚合物的方法。 根据本发明的地质聚合物组合物包含包含硅铝酸盐源，金属硅酸盐，碱活化剂，轻质或重质填料和载体流体的悬浮液，其中将所述地质聚合物组合物的悬浮液泵送到井中并允许其固化。
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9.发明授权Cementing composition and application thereof to cementing oil wells or the like 有权水泥组合物及其在固井油井等中的应用公开(公告)号：US06656266B1
公开(公告)日：2003-12-02
申请号：US09857734
申请日：2001-09-20
IPC分类号： C04B2426
CPC分类号： C04B28/02 , C04B24/2623 , C04B7/527 , C04B24/2641 , C04B2103/402 , C04B20/008
摘要： Cementing compositions which are particularly suitable for squeeze cementing operations, comprise an aqueous phase, and a micro-cement, the aqueous phase including an aqueous suspension comprising a vinyl acetate type polymer obtained by chemically cross-linking a polyvinyl compound, a nanolatex and an anionic surfactant with a cloud point of more than 80° C.
摘要翻译： 特别适用于挤压固结操作的胶结组合物包括水相和微胶结物，所述水相包括水性悬浮液，所述水性悬浮液包含通过化学交联聚乙烯基化合物，Nanolatex和阴离子表面活性剂获得的乙酸乙烯酯型聚合物 浊点大于80℃的表面活性剂
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