公开(公告)号：US20120237685A1

公开(公告)日：2012-09-20

申请号：US13501137

申请日：2010-09-01

申请人： Waltraud Werdecker ,  Gerrit Scheich ,  Christian Schenk

发明人： Waltraud Werdecker ,  Gerrit Scheich ,  Christian Schenk

IPC分类号： B05D7/00 ,  B82Y30/00

CPC分类号： C03C17/02 ,  C03C2218/11

摘要： In a known method, a SiO2 slip layer is applied to a basic quartz glass body by means of spraying on an SiO2 slip, the slip layer is dried and sintered to form an SiO2-containing functional layer. In order to permit the reproducible production of a functional quartz glass layer, even in the case of surfaces that are curved or inclined with respect to the vertical, having high layer thicknesses which satisfy high requirements on the layer homogeneity, the invention proposes that the slip contain the following components in a dispersion liquid: splintery, amorphous SiO2 granules having a gain size distribution having a D50 value in the range of 3 μm to 30 μm and having a proportion by weight of at least 10% by weight, based on the total solids content; spherical, amorphous SiO2 particles having a particle size distribution having a D50 value in the range of 1 μm to 50 μm and having a proportion by weight of at least 30% by weight, based on the total solids content; SiO2 nano particles having particle sizes of less than 100 nm and having a proportion by weight between 0.2% and 10% by weight, based on the total solids content; and a non-ionic, alkali-free surfactant having a proportion in the range of 0.005 to 0.5%, based on the volume of the dispersion liquid.

摘要翻译： 在已知的方法中，通过喷涂在SiO 2滑移上将SiO2滑移层施加到碱性石英玻璃体上，将滑移层干燥并烧结以形成含SiO 2的功能层。 为了允许可再生产的功能性石英玻璃层，即使在相对于垂直方向弯曲或倾斜的表面的情况下，具有满足对层均匀性的高要求的高层厚度，本发明提出了滑动 在分散液中含有以下组分：分散体，具有D50值在3μm至30μm范围内并且按重量计至少10重量％的增益尺寸分布的无定形SiO 2颗粒，基于总计 固体含量; 基于总固体含量，具有D50值在1μm至50μm范围内并具有至少30重量％的重量比的粒度分布的球形无定形SiO 2颗粒; 基于总固体含量，粒径小于100nm并且重量比为0.2％至10％的SiO 2纳米颗粒; 和非离子型无碱性表面活性剂，其比例基于分散液体积的0.005〜0.5％。

公开(公告)号：US08920878B2

公开(公告)日：2014-12-30

申请号：US13501137

申请日：2010-09-01

申请人： Waltraud Werdecker ,  Gerrit Scheich ,  Christian Schenk

发明人： Waltraud Werdecker ,  Gerrit Scheich ,  Christian Schenk

IPC分类号： B05D3/02 ,  C03C17/02

CPC分类号： C03C17/02 ,  C03C2218/11

摘要： In a known method, a SiO2 slip layer is applied to a basic quartz glass body by means of spraying on an SiO2 slip, the slip layer is dried and sintered to form an SiO2-containing functional layer. In order to permit the reproducible production of a functional quartz glass layer, even in the case of surfaces that are curved or inclined with respect to the vertical, having high layer thicknesses which satisfy high requirements on the layer homogeneity, the invention proposes that the slip contain the following components in a dispersion liquid: splintery, amorphous SiO2 granules having a gain size distribution having a D50 value in the range of 3 μm to 30 μm and having a proportion by weight of at least 10% by weight, based on the total solids content; spherical, amorphous SiO2 particles having a particle size distribution having a D50 value in the range of 1 μm to 50 μm and having a proportion by weight of at least 30% by weight, based on the total solids content; SiO2 nano particles having particle sizes of less than 100 nm and having a proportion by weight between 0.2% and 10% by weight, based on the total solids content; and a non-ionic, alkali-free surfactant having a proportion in the range of 0.005 to 0.5%, based on the volume of the dispersion liquid.

摘要翻译： 在已知的方法中，通过喷涂在SiO 2滑移上将SiO2滑移层施加到碱性石英玻璃体上，将滑移层干燥并烧结以形成含SiO 2的功能层。 为了允许可再生产的功能性石英玻璃层，即使在相对于垂直方向弯曲或倾斜的表面的情况下，具有满足对层均匀性的高要求的高层厚度，本发明提出了滑动 在分散液中含有以下组分：分散体，具有D50值在3μm至30μm范围内并且按重量计至少10重量％的增益尺寸分布的无定形SiO 2颗粒，基于总计 固体含量; 基于总固体含量，具有D50值在1μm至50μm范围内并具有至少30重量％的重量比的粒度分布的球形无定形SiO 2颗粒; 基于总固体含量，粒径小于100nm并且重量比为0.2％至10％的SiO 2纳米颗粒; 和非离子型无碱性表面活性剂，其比例基于分散液体积的0.005〜0.5％。

公开(公告)号：US07947335B2

公开(公告)日：2011-05-24

申请号：US12448406

申请日：2007-12-13

申请人： Waltraud Werdecker ,  Rolf Gerhardt ,  Juergen Weber

发明人： Waltraud Werdecker ,  Rolf Gerhardt ,  Juergen Weber

IPC分类号： B32B17/06 ,  C23C4/00

CPC分类号： C03C17/25 ,  C03C2217/213 ,  C03C2217/24 ,  C03C2218/112 ,  G02B5/02 ,  H01J9/20 ,  H01J61/025 ,  H01J61/35 ,  H01K1/325 ,  H01K3/005 ,  Y10T428/26 ,  Y10T428/261 ,  Y10T428/265

摘要： Methods for producing a quartz glass component with reflector layer are known in which a reflector layer composed of quartz glass acting as a diffuse reflector is produced on at least part of the surface of a substrate body composed of quartz glass. In order, taking this as a departure point, to specify a method which enables cost-effective and reproducible production of uniform SiO2 reflector layers on quartz glass components, it is proposed according to the invention that the reflector layer is produced by thermal spraying by means of SiO2 particles being fed to an energy carrier, being incipiently melted or melted by means of said energy carrier and being deposited on the substrate body. In the case of a quartz glass component obtained according to the method, the SiO2 reflector layer is formed as a layer which is produced by thermal spraying and has an opaque effect and which is distinguished by freedom from cracks and uniformity.

摘要翻译： 制造具有反射层的石英玻璃组件的方法是已知的，其中在由石英玻璃构成的基板主体的表面的至少一部分上产生由用作漫反射器的石英玻璃构成的反射层。 为了以此作为出发点，为了指定能够在石英玻璃部件上实现均匀的SiO 2反射层的成本有效且可重复的生产的方法，根据本发明提出，反射器层是通过热喷涂 的SiO 2颗粒被馈送到能量载体，通过所述能量载体初始地熔化或熔化并沉积在基体上。 在根据该方法获得的石英玻璃组分的情况下，SiO 2反射层形成为通过热喷涂制成的层并且具有不透明效果，其区别在于不受裂缝和均匀性的限制。

公开(公告)号：US06660671B2

公开(公告)日：2003-12-09

申请号：US10103660

申请日：2002-03-21

申请人： Waltraud Werdecker ,  Udo Gertig ,  Johann Leist ,  Rainer Koeppler

发明人： Waltraud Werdecker ,  Udo Gertig ,  Johann Leist ,  Rainer Koeppler

IPC分类号： C03C100

CPC分类号： C04B35/653 ,  C03B19/06 ,  C03B19/066 ,  C03B19/12 ,  C03B20/00 ,  C03C3/06 ,  C03C14/004 ,  C03C2201/02 ,  C04B35/14 ,  Y10S977/775 ,  Y10S977/776 ,  Y10S977/90

摘要： Composite material with high resistance to temperature changes and a high density, and having an SiO2-containing matrix with quartz glass grains embedded therein is produced by preparing a suspension from a particle mixture of finely divided SiO2 powder having at least two different particle fractions and of the quartz glass grains, forming a green compact and sintering the compact. The matrix has an SiO2 content of at least 99% by wt. and is formed from at least first and second particle fractions, each of which is present as granules of nanoscale, amorphous, synthetically produced SiO2 primary particles having a mean primary particle size of less than 100 nm. The composite material has an SiO2-containing matrix with an SiO2 content of at least 99% by wt. It is particularly suited for applications such as starting material for producing a permanent mold for melting solar silicon.

摘要翻译： 通过从具有至少两种不同颗粒级分的细分SiO 2粉末和具有至少两种不同颗粒级分的颗粒混合物制备悬浮液，制备具有高耐温变化和高密度的复合材料，并且具有嵌入石英玻璃颗粒的含SiO 2基质 石英玻璃颗粒，形成一个生坯并烧结成型。 该基质具有至少99重量％的SiO 2含量。 并且由至少第一和第二颗粒组分形成，每个颗粒级分以纳米级，无定形，合成产生的平均一次粒径小于100nm的SiO 2一次颗粒的颗粒形式存在。 复合材料具有SiO 2含量至少为99重量％的含SiO 2的基体。 特别适合用于制造用于熔化太阳能硅的永久模具的起始材料。

公开(公告)号：US06380110B1

公开(公告)日：2002-04-30

申请号：US09484113

申请日：2000-01-14

申请人： Waltraud Werdecker ,  Heinz Fabian ,  Udo Gertig ,  Johann Leist ,  Rolf Göbel

发明人： Waltraud Werdecker ,  Heinz Fabian ,  Udo Gertig ,  Johann Leist ,  Rolf Göbel

IPC分类号： C03B2000

CPC分类号： C03C1/026 ,  C03B19/1065 ,  C03C3/06 ,  C03C2201/02 ,  C03C2201/24 ,  C03C2201/26 ,  C03C2201/32 ,  C03C2201/80 ,  C03C2203/10 ,  C03C2203/54

摘要： In a known process for the production of opaque quartz glass a blank is formed from synthetic SiO2 granulate and is heated at a vitrification temperature to form a body of opaque quartz glass. In order to provide on this basis a process for the production of pure opaque quartz glass with a homogenous pore distribution, high density, high viscosity and a low tendency to devitrify, it is proposed according to the invention that the SiO2 granulate to be used is a SiO2 granulate (21; 31) composed of at least partially porous agglomerates of SiO2 primary particles, with a specific BET surface ranging from 1.5 m2/g to 40 m2/g and an apparent density of at least 0.8 g/cm3. A SiO2 granulate (21; 31) suitable for the implementation of the process is distinguished in that it is formed from at least partially porous agglomerates of SiO2 primary particles and in that it has a specific BET surface ranging from 1.5 m2/g to 40 m2/g and an apparent density of at least 0.6 g/cm3.

摘要翻译： 在制造不透明石英玻璃的已知方法中，由合成SiO 2颗粒形成坯料，并在玻璃化温度下加热以形成不透明石英玻璃体。 为了在此基础上提供具有均匀孔分布，高密度，高粘度和低失透倾向的纯不透明石英玻璃的制备方法，根据本发明提出使用的SiO 2颗粒是 SiO 2颗粒（21; 31），其由SiO 2一次颗粒的至少部分多孔的附聚物组成，BET比表面积为1.5m 2 / g至40m 2 / g，表观密度为至少0.8g / cm 3。 适用于实施该方法的SiO 2颗粒（21; 31）的特征在于其由SiO 2一次颗粒的至少部分多孔的附聚物形成，并且其具有范围为1.5m 2 / g至40m 2的比BET表面积 / g，表观密度为0.6g / cm 3以上。

公开(公告)号：US4591537A

公开(公告)日：1986-05-27

申请号：US741711

申请日：1985-06-05

申请人： Fritz Aldinger ,  Richard Keilberth ,  Waltraud Werdecker

发明人： Fritz Aldinger ,  Richard Keilberth ,  Waltraud Werdecker

IPC分类号： C04B35/581 ,  H01B3/12 ,  H01L21/52 ,  H01L23/15 ,  H05K1/03 ,  B32B9/00 ,  C04B35/58

CPC分类号： H01L23/15 ,  C04B35/581 ,  H01L2924/0002 ,  H05K1/0306 ,  Y10S428/901

摘要： A heat conductive ceramic substrate for semiconductor circuits, comprising polycrystalline aluminum nitride of high density containing as an additive boron nitride or oxides of calcium, magnesium, aluminum, titanium, zirconium, chrome, silicon, and/or rare earth metals. The boron nitride additive concentration ranges between 0.1 and 3% by weight, preferably between 0.5 and 2% by weight. The oxide additive concentration ranges between 0.1 and 5% by weight. The substrate has a significantly higher thermal conductivity than aluminum oxide substrates and is more economincal to manufacture than beryllium oxide substrates.

摘要翻译： 一种用于半导体电路的导热陶瓷基板，包括高密度的多晶氮化铝，其包含作为添加剂的氮化硼或钙，镁，铝，钛，锆，铬，硅和/或稀土金属的氧化物。 氮化硼添加剂的浓度范围为0.1〜3重量％，优选为0.5〜2重量％。 氧化物添加剂的浓度范围为0.1〜5重量％。 该衬底具有比氧化铝衬底显着更高的热导率，并且与氧化铍衬底相比制造更加经济。

公开(公告)号：US4564433A

公开(公告)日：1986-01-14

申请号：US626860

申请日：1984-06-21

申请人： Waltraud Werdecker ,  Peter Fabian

发明人： Waltraud Werdecker ,  Peter Fabian

IPC分类号： C25B11/02 ,  C25B1/26 ,  C25B9/00 ,  C25B9/04 ,  C25B9/06 ,  C25B11/00 ,  C25B11/10

CPC分类号： C25B11/00 ,  C25B9/04

摘要： A bipolar electrode has plate-like anode and cathode parts. The anode and cathode parts are secured together, edge-to-edge, to form a single element in one plane by an intermediate connecting piece. The intermediate connecting piece itself is a composite element having parts of materials which are compatible with the respectively adjacent anode and cathode. The two parts of the composite element are joined together by hot isostatic pressure, explosion-plating or diffusion-welding into the composite body, the resultant composite body then permitting welding of the respective anode and cathode plates to the respective anode part and cathode part of the composite element or body.

摘要翻译： PCT No.PCT / EP83 / 00265 Sec。 371日期1984年6月21日 102（e）日期1984年6月21日PCT提交1983年10月8日PCT公布。 公开号WO84 / 01789 日期：1984年5月10日。双极电极具有板状阳极和阴极部分。 阳极和阴极部分被固定在一起，边缘到边缘，以通过中间连接件在一个平面中形成单个元件。 中间连接件本身是具有与相邻的阳极和阴极相容的材料部分的复合元件。 复合元件的两部分通过热等静压，爆镀或扩散焊接在复合体中，所得到的复合体然后允许相应的阳极和阴极板焊接到相应的阳极部分和阴极部分 复合元件或主体。

公开(公告)号：US08158542B2

公开(公告)日：2012-04-17

申请号：US12311446

申请日：2007-09-12

申请人： Waltraud Werdecker ,  Norbert Traeger ,  Juergen Weber

发明人： Waltraud Werdecker ,  Norbert Traeger ,  Juergen Weber

IPC分类号： C03C3/076

CPC分类号： C03C17/02 ,  C03B19/06 ,  C03B19/066 ,  C03B20/00 ,  C03C2218/11

摘要： A known SiO2 slurry for the production of quartz glass contains a dispersion liquid and amorphous SiO2 particles with particle sizes to a maximum of 500 μm, wherein the largest volume fraction is composed of SiO2 particles with particle sizes in the range 1 μm-60 μm, as well as SiO2 nanoparticles with particle sizes less than 100 nm in the range 0.2-15% volume by weight (of the entire solids content). In order to prepare such a slurry for use, and to optimize the flow behavior of such a slurry with regard to later processing by dressing or pouring the slurry mass, and with regard to later drying and sintering without cracks, the invention suggests a slurry with SiO2 particles with a multimodal distribution of particle sizes, with a first maximum of the sizes distribution in the range 1 μm-3 μm and a second maximum in the range 5 μm-50 μm, and a solids content (percentage by weight of the SiO2 particles and the SiO2 nanoparticles together) in the range 83%-90%.

摘要翻译： 用于生产石英玻璃的已知SiO 2浆料包含分散液和粒径为最大500μm的无定形SiO 2颗粒，其中最大体积分数由粒径在1μm-60μm的SiO 2颗粒组成， 以及颗粒尺寸小于100nm的SiO 2纳米颗粒在0.2-15重量％（整个固体含量）的范围内。 为了制备这样的浆料，并且通过修整或倒出浆料来优化这种浆料在后续加工过程中的流动行为，并且关于稍后的干燥和烧结而没有裂纹，本发明提出了具有 SiO 2颗粒具有多峰分布的粒径，第一最大尺寸分布在1μm-3μm范围内，第二最大值在5μm-50μm范围内，固体含量（SiO 2重量百分比 颗粒和SiO 2纳米颗粒）在83％-90％的范围内。

公开(公告)号：US07749930B2

公开(公告)日：2010-07-06

申请号：US11630405

申请日：2006-03-30

申请人： Juergen Weber ,  Tobias Pogge ,  Martin Trommer ,  Bodo Kuehn ,  Ulrich Kirst ,  Waltraud Werdecker

发明人： Juergen Weber ,  Tobias Pogge ,  Martin Trommer ,  Bodo Kuehn ,  Ulrich Kirst ,  Waltraud Werdecker

IPC分类号： C03C3/06 ,  C03C3/04 ,  C03C15/00 ,  C03B19/00 ,  C03B21/00 ,  C03B32/00 ,  C03B25/00

CPC分类号： C03C3/06 ,  C03B19/06 ,  C03B19/09 ,  C03B32/00 ,  C03B2201/07 ,  C03B2201/075 ,  C03B2201/24 ,  C03B2201/32 ,  C03C15/00 ,  C03C19/00 ,  C03C23/0025 ,  C03C23/006 ,  C03C2201/11 ,  C03C2201/12 ,  C03C2201/23 ,  C03C2201/24 ,  C03C2201/32 ,  C03C2201/50 ,  C03C2203/54 ,  C30B25/12 ,  C30B31/14 ,  C30B35/00 ,  Y02P40/57

摘要： An ideal quartz glass for a wafer jig for use in an environment having an etching effect is distinguished by both high purity and high resistance to dry etching. To indicate a quartz glass that substantially fulfills these requirements, it is suggested according to the invention that the quartz glass is doped with nitrogen at least in a near-surface area, has a mean content of metastable hydroxyl groups of less than 30 wt ppm and that its fictive temperature is below 1250° C. and its viscosity is at least 1013 dPa·s at a temperature of 1200° C. An economic method for producing such a quartz glass comprises the following method steps: melting an SiO2 raw material to obtain a quartz glass blank, the SiO2 raw material or the quartz glass blank being subjected to a dehydration measure, heating the SiO2 raw material or the quartz glass blank to a nitriding temperature in the range between 1050° C. and 1850° C. in an ammonia-containing atmosphere, a temperature treatment by means of which the quartz glass of the quartz glass blank is set to a fictive temperature of 1250° C. or less, and a surface treatment of the quartz glass blank with formation of the quartz glass jig.

摘要翻译： 用于具有蚀刻效果的环境中的晶片夹具的理想石英玻璃的特征在于高纯度和高耐干蚀刻性。 为了表明基本满足这些要求的石英玻璃，根据本发明提出，石英玻璃至少在近表面积中掺杂氮，其平均含量小于30重量ppm， 其虚拟温度低于1250℃，在1200℃的温度下其粘度至少为1013dPa·s。制备这种石英玻璃的经济方法包括以下方法步骤：将SiO 2原料熔化得到 将石英玻璃坯料，SiO 2原料或石英玻璃坯料进行脱水处理，将SiO2原料或石英玻璃坯料加热至1050℃〜1850℃的氮化温度， 含有氨的气氛，将石英玻璃坯料的石英玻璃设定为1250℃以下的假想温度的温度处理，以及格式化的石英玻璃坯料的表面处理 在石英玻璃夹具上。

公开(公告)号：US20090316268A1

公开(公告)日：2009-12-24

申请号：US12448406

申请日：2007-12-13

申请人： Waltraud Werdecker ,  Rolf Gerhardt ,  Juergen Weber

发明人： Waltraud Werdecker ,  Rolf Gerhardt ,  Juergen Weber

IPC分类号： G02B5/02 ,  G02B1/10 ,  C23C4/10

CPC分类号： C03C17/25 ,  C03C2217/213 ,  C03C2217/24 ,  C03C2218/112 ,  G02B5/02 ,  H01J9/20 ,  H01J61/025 ,  H01J61/35 ,  H01K1/325 ,  H01K3/005 ,  Y10T428/26 ,  Y10T428/261 ,  Y10T428/265

摘要： Methods for producing a quartz glass component with reflector layer are known in which a reflector layer composed of quartz glass acting as a diffuse reflector is produced on at least part of the surface of a substrate body composed of quartz glass. In order, taking this as a departure point, to specify a method which enables cost-effective and reproducible production of uniform SiO2 reflector layers on quartz glass components, it is proposed according to the invention that the reflector layer is produced by thermal spraying by means of SiO2 particles being fed to an energy carrier, being incipiently melted or melted by means of said energy carrier and being deposited on the substrate body. In the case of a quartz glass component obtained according to the method, the SiO2 reflector layer is formed as a layer which is produced by thermal spraying and has an opaque effect and which is distinguished by freedom from cracks and uniformity.

摘要翻译： 制造具有反射层的石英玻璃组件的方法是已知的，其中在由石英玻璃构成的基板主体的表面的至少一部分上产生由用作漫反射器的石英玻璃构成的反射层。 为了以此作为出发点，为了指定能够在石英玻璃部件上实现均匀的SiO 2反射层的成本有效且可重复的生产的方法，根据本发明提出，反射层通过手段热喷涂 的SiO 2颗粒被馈送到能量载体，通过所述能量载体初始地熔化或熔化并沉积在基体上。 在根据该方法获得的石英玻璃组分的情况下，SiO 2反射层形成为通过热喷涂制成的层并且具有不透明效果，其区别在于不受裂缝和均匀性的限制。