Advances in amination
    1.
    发明授权
    Advances in amination 有权
    胺化进展

    公开(公告)号:US06888030B2

    公开(公告)日:2005-05-03

    申请号:US10277551

    申请日:2002-10-22

    IPC分类号: C08F8/04 C07C209/34

    CPC分类号: C08F8/04 C08F10/00

    摘要: Inclusion of a branched alcohol in the catalytic hydrogenation reaction involving an aliphatic nitro compound dramatically increases the efficiency of the conversion of nitro groups into amino groups. This discovery is of particular value in the production of polyalkyleneamines via nitration of a polyalkene, such as a polybutene, and its subsequent reduction. The polyalkyleneamines so produced are useful as dispersant additives for motor oils and fuels.

    摘要翻译: 在涉及脂族硝基化合物的催化氢化反应中包含支链醇显着提高了硝基转化为氨基的效率。 该发现在通过聚烯烃如聚丁烯的硝化生产聚亚烷基胺以及随后的还原中是特别有价值的。 如此生产的聚亚烷基胺可用作机油和燃料的分散剂添加剂。

    Fuel compositions containing etheramine alkoxylates
    3.
    发明授权
    Fuel compositions containing etheramine alkoxylates 失效
    含有醚胺烷氧基化物的燃料组合物

    公开(公告)号:US6063145A

    公开(公告)日:2000-05-16

    申请号:US105773

    申请日:1998-06-26

    摘要: This invention concerns a fuel additive comprising an etheramine alkoxylate, and fuel compositions and additive concentrates made therefrom. The etheramine alkoxylate may be of formula: ##STR1## where R.sup.1 is a straight or branched alkyl, or alkylaryl; R.sup.2 is independently in each occurrence hydrogen or alkyl from 1 to 6 carbons; R.sup.3 is independently in each occurrence hydrogen or alkyl of from 1 to 6 carbons; m averages from about 2 to about 20; and x and y each independently average from about 0 to 2, where x+y averages from about 1 to about 4.

    摘要翻译: 本发明涉及一种包含醚胺烷氧基化物的燃料添加剂和由其制备的燃料组合物和添加剂浓缩物。 醚胺烷氧基化物可以具有下式:其中R 1是直链或支链烷基或烷基芳基; R2各自独立地为氢或1至6个碳的烷基; R3各自独立地为氢或1至6个碳的烷基; m平均从约2到约20; x和y各自独立地平均为约0至2,其中x + y平均为约1至约4。

    Co-production of cyclohexylamine and bis(para-aminocyclohexyl) methane
    5.
    发明授权
    Co-production of cyclohexylamine and bis(para-aminocyclohexyl) methane 失效
    共生产环己胺和双(对 - 氨基环己基)甲烷

    公开(公告)号:US07304183B2

    公开(公告)日:2007-12-04

    申请号:US11300991

    申请日:2005-12-15

    IPC分类号: C07C209/72

    摘要: Embodiments of the present invention disclose a process for the co-production of bis(para-aminocyclohexyl) methane (PACM). Also disclosed are articles of manufacture made using PACM produced by methods of this invention. The methods of the present invention generally include a first mixture having methylene di-aniline (MDA) and a second aromatic amine. The first mixture has less than 15% polymeric MDA by weight and the second aromatic amine is present in an amount to render the first mixture a liquid. The first mixture is hydrogenated to produce a product mixture comprising PACM and at least one second non-aromatic amine.

    摘要翻译: 本发明的实施方案公开了双(对 - 氨基环己基)甲烷(PACM)共同生产的方法。 还公开了使用通过本发明的方法生产的PACM制造的制品。 本发明的方法通常包括具有亚甲基二苯胺(MDA)和第二芳族胺的第一混合物。 第一混合物的重量小于15%的聚合物MDA,第二芳族胺以使第一混合物成为液体的量存在。 将第一混合物氢化以产生包含PACM和至少一种第二非芳族胺的产物混合物。

    Imidazolidone polyetheramide surfactant
    6.
    发明授权
    Imidazolidone polyetheramide surfactant 失效
    咪唑啉酮聚醚酰胺表面活性剂

    公开(公告)号:US5436351A

    公开(公告)日:1995-07-25

    申请号:US112295

    申请日:1993-08-27

    IPC分类号: C07D233/32

    摘要: Disclosed is a novel composition of the formula: ##STR1## wherein R=H, methyl, ethyl, or a mixture thereof and R.sup.5 =a saturated or unsaturated alkyl group from a fatty acid containing 7 to 22 carbon atoms and a+b=n, wherein n is from about 2 to 80, resulting from alkoxylating an substituted imidazolidone, reductively aminating the alkoxylated product and reacting the aminated product with a fatty acid; and, to its use as a surfactant in glycol-water mixtures, such as, for example, propylene glycol based wing deicers thickened with polyacrylic acids.

    摘要翻译: 公开了下式的新型组合物:其中R = H,甲基,乙基或其混合物,R5 =来自含有7-22个碳原子的脂肪酸和a + b = n的饱和或不饱和烷基 其中n为约2-80,由烷氧基化取代的咪唑烷酮,还原性胺化所述烷氧基化产物并使所述胺化产物与脂肪酸反应; 并且其用作二醇 - 水混合物中的表面活性剂,例如用聚丙烯酸增稠的丙二醇基翼除冰剂。

    Polyoxyalkylene glycols containing imidazolidones
    7.
    发明授权
    Polyoxyalkylene glycols containing imidazolidones 失效
    含有咪唑烷酮的聚亚烷基二醇

    公开(公告)号:US5238971A

    公开(公告)日:1993-08-24

    申请号:US984760

    申请日:1992-12-03

    IPC分类号: C08G18/48 C08G18/50

    摘要: This invention is concerned with polyoxyalkylene glycols prepared by alkoxylating a hydroxyalkyl-2-imidazolidone and to a process for preparing flexible polyurethane foams by reacting an organic isocyanate with an admixture of a polyether polyol and an alkoxylated hydroxyalkyl-2-imidazolidone in the presence of a urethane catalyst and a blowing agent.

    摘要翻译: 本发明涉及通过烷氧基化羟烷基-2-咪唑啉酮制备的聚氧亚烷基二醇和通过使有机异氰酸酯与聚醚多元醇与烷氧基化羟烷基-2-咪唑啉酮的混合物在有机异氰酸酯的存在下反应制备柔性聚氨酯泡沫的方法 氨基甲酸酯催化剂和发泡剂。

    Polyether amide from polyalkylene glycol diamine and diacid mixture
    9.
    发明授权
    Polyether amide from polyalkylene glycol diamine and diacid mixture 失效
    来自聚亚烷基二醇二胺和二酸混合物的聚醚酰胺

    公开(公告)号:US5086162A

    公开(公告)日:1992-02-04

    申请号:US506990

    申请日:1990-04-10

    IPC分类号: C08G69/26 C08G69/28 C08G69/40

    CPC分类号: C08G69/40

    摘要: Novel polyether amides produced by reacting at least one polyalkylene glycol diamine with at least two dicarboxylic acids or esters thereof are described. The polyethylene glycol diamine has the formula NH.sub.2 --(CH.sub.2 CH.sub.2 O).sub.x --CH.sub.2 CH.sub.2 --NH.sub.2, where x ranges from 2 to 6, and at least one of the dicarboxylic acids is an aromatic discarboxylic acid. These novel polyether amides may have the formula: ##STR1## where each R and R' are independently an alkylene or arylene moiety having from 3 to 34 carbon atoms, where at least one R or R' is an arylene moiety, and where each x and y independently have the values noted. Suitable dicarboxylic acids include adipic acid, azelaic acid, sebacic acid, dodecanedioic acid, terephthalic acid, isophthalic acid, t-butyl isophthalic acid, and mixtures thereof. Suitable diamines include triethylene glycol diamine (JEFFAMINE.RTM. EDR-148 amine) and tetraethylene glycol diamine (JEFFAMINE.RTM. EDR-192 amine), among others. The resulting polyether amides are useful to make polymers, including fibers, with unusually good water absorbancy properties. The inventive methods successfully incorporate triethylene glycol diamine and aromatic dibasic acids, where this cannot be accomplished directly.

    摘要翻译: 描述了通过使至少一种聚亚烷基二醇二胺与至少两种二羧酸或其酯反应制备的新型聚醚酰胺。 聚乙二醇二胺具有式NH 2 - (CH 2 CH 2 O)x -CH 2 CH 2 -NH 2,其中x为2-6,并且至少一种二羧酸为芳族四羧酸。 这些新型聚醚酰胺可以具有下式:其中每个R和R'独立地是具有3至34个碳原子的亚烷基或亚芳基部分,其中至少一个R或R'是亚芳基部分 ,并且其中每个x和y独立地具有所述的值。 合适的二羧酸包括己二酸,壬二酸,癸二酸,十二烷二酸,对苯二甲酸,间苯二甲酸,叔丁基间苯二甲酸及其混合物。 合适的二胺包括三甘醇二胺(JEFFAMINE TM EDR-148胺)和四甘醇二胺(JEFFAMINE TM EDR-192胺)等。 所得聚醚酰胺可用于制备包括纤维在内的聚合物,具有非常好的吸水性。 本发明的方法成功地并入三甘醇二胺和芳族二元酸,其中这不能直接实现。

    1-isopropyl-2-tolylimidazole as an epoxy resin curative
    10.
    发明授权
    1-isopropyl-2-tolylimidazole as an epoxy resin curative 失效
    1-异丙基-2-甲苯咪唑作为环氧树脂固化剂

    公开(公告)号:US5086155A

    公开(公告)日:1992-02-04

    申请号:US589110

    申请日:1990-09-27

    CPC分类号: C08G59/686 C08G59/5073

    摘要: Disclosed is an epoxy resin curative exhibiting extended pot life, lower reactivity and lower viscosity at ambient temperatures and increased reactivity at moderately elevated temperatures which comprises from 1 to 10 parts by weight of the ortho, meta or para form of 1-isopropyl-2-tolylimidazole per 100 parts by weight epoxy resin. The latent reactive properties make the curative potentially useful in a variety of applications.

    摘要翻译: 公开了一种环氧树脂固化剂,其具有延长的适用期,在环境温度下具有较低的反应性和较低的粘度,并且在适度升高的温度下具有增加的反应性,其包含1至10重量份的邻位,间位或对位形式的1-异丙基-2- 每100份重量的环氧树脂中含有tolylimidazole。 潜在的反应性质使其在各种应用中具有潜在的应用价值。